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1.
A three-dimensional, three-phase numerical model is presented for simulating the movement of immiscible fluids, including
nonaqueous-phase liquids (NAPLs), through porous media. The model is designed to simulate soil flume experiments and for practical
application to a wide variety of contamination scenarios involving light or dense NAPLs in heterogeneous subsurface systems.
The model is derived for the three-phase flow of water, NAPL, and air in porous media. The basic governing equations are based
upon the mass conservation of the constitutents within the phases. The descretization chosen to transform the governing equations
into the approximating equations, although logically regular, is very general. The approximating equations are a set of simultaneous
coupled nonlinear equations which are solved by the Newton-Raphson method. The linear system solutions needed for the Newton-Raphson
method are obtained using a matrix of preconditioner/accelerator iterative methods.
Because of the special way the governing equations are implemented, the model is capable of simulating many of the phenomena
considered necessary for the sucessful simulation of field problems including entry pressure phenomena, entrapment, and preferential
flow paths. The model is verified by comparing it with several exact analytic test solutions and three soil flume experiments
involving the introduction and movement of light nonaqueous-phase liquid (LNAPL) or dense nonaqueous-phase liquid (DNAPL)
in heterogeneous sand containing a watertable.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
2.
A. I. Serezhnikov 《Russian Journal of Pacific Geology》2011,5(3):250-261
The Balei epithermal vein gold-quartz deposit is located in the Lower Cretaceous sedimentary sequence. The detailed geological
and hydrogeological study of the deposit allowed us to reconstruct the paleohydrogeological conditions of the ore formation.
This was particularly promoted by the preservation of the initial geological and hydrogeological structure—a graben-like depression
hosting a subsurface water basin. The ore field was formed due to the Early Cretaceous high-temperature hydrothermal activity.
The ore-bearing solutions originated via the interaction of the deep fluids with rocks and local subsurface waters. The solutions
boiled at the depth of ∼600 m and gold was deposited from the degassed liquid phase. 相似文献
3.
A FEM model for analysis of fully coupled multiphase flow, thermal transport and stress/deformation in geological porous media was developed based on the momentum, mass and energy conservation laws of the continuum mechanics and the averaging approach of the mixture theory over a three phase (solid–liquid–gas) system. Six processes (i.e. stress–strain, water flow, gas flow, vapor flow, heat transport and porosity evolution processes) and their coupling effects are considered, which not only makes the problem well-defined, but renders the governing PDEs closed, complete, compact and compatible. Displacements, pore water pressure, pore gas pressure, pore vapor pressure, temperature and porosity are selected as basic unknowns. The physical phenomena such as phase transition, gas solubility in liquid, thermo-osmosis, moisture transfer and moisture swelling are modeled. As a result, the relative humidity and other related variables in porous media can be evaluated on a sounder physical basis. A three dimensional computer code, THYME3D, was developed, with eight degrees of freedom at each node. The laboratory CEA Mock-up test and the field scale FEBEX benchmark test on bentonite performance assessment for underground nuclear waste repositories were used to validate the numerical model and the software. The coupled THM behaviors of the bentonite barriers were satisfactorily simulated, and the effects and impacts of the governing equations, constitutive relations and property parameters on the coupled THM processes were understood in terms of more straightforward interpretation of physical processes at microscopic scale of the porous media. The work developed enables further in-depth research on fully coupled THM or THMC processes in porous media. 相似文献
4.
Hydrogen penetration in water through porous medium: application to a radioactive waste storage site
Hydrogen penetration in water through porous medium was analyzed in the paper. A two-phase compositional model approach was
considered. The first part of the work deals with the thermodynamic analysis of the hydrogen–water system. The thermodynamic
model was calibrated using the experimental data of hydrogen solubility in water. The phase densities, viscosities and phase
concentrations were presented in an analytical form. Moreover, the domain of validity of analytical laws—such as Henry’s,
Raoult’s and Kelvin’s laws—for the estimation of phase properties was presented for the analyzed system. The second part deals
with two-phase hydrodynamic behaviors. An analytical solution for the non-compressible flow was constructed. In general case,
the influence of relative permeabilities on the flow regimes was analyzed numerically. The notion pseudo-saturation was introduced
to define phase appearance. Actually, mobile gas created a time displaced front relatively slower than mobile gas flow. Diffusion
becomes really important for low mobile gas case as the penetration accelerates for the large range of saturation. In contrast,
the mass exchange phenomena have a small influence on the flow type. Thus, the regimes of hydrogen penetration in liquid were
shown really sensitive to the relative permeability form. 相似文献
5.
Analytical closed-form solutions for assessing pumping cycles,times, and costs required for NAPL remediation 总被引：2，自引：0，他引：2
R. Chesnaux 《Environmental Geology》2008,55(7):1381-1388
An analytical solution is given to evaluate the number and duration of pumping cycles required for the remediation by pumping
of contaminants, both single component and multi-component non-aqueous phase liquids (NAPLs), when no free product is present
in the system. The method can be applied in a homogenous medium if the contamination zones have been delineated and residual
total NAPL concentrations assessed. Based on the principle of the NAPL partitioning in unsaturated or saturated porous media,
analytical closed-form solutions are provided for both cases of remediation by pumping in saturated and unsaturated conditions:
“pump-and-treat” and “soil vapor extraction”. In each case we determine the number of pumping cycles required to reach the
residual required concentration of NAPL (for example, according to health-based standards), considering one or more chemicals
simultaneously present in an aquifer. The method requires information on the aquifer saturation state and the properties of
the chemicals of interest. Calculations are based on the assumption of equilibrium partitioning of chemicals between the pore
water, the soil solids, and the soil gas (in the case of unsaturated conditions), and no presence of a NAPL phase. 相似文献
6.
冰点下水合物在多孔介质的生成是一个复杂的多相转化过程,为了研究冰点下多孔介质中水合物生成过程的水相转化率、气体消耗量与稳定压力等生成特性,在定容条件下,进行不同孔径与粒径的多孔介质中甲烷水合物在冰点下的生成实验。所使用的多孔介质平均孔径为1295 nm、1796 nm和3320 nm。研究结果表明：水合物生成结束时水的转化率随着初始生成压力的增大而增大,随着温度的升高而降低,随着孔径的增大而增大;在相同的孔径下,多孔介质粒径的增大降低了水合物的生成速率但对最终气体消耗量没有影响;在相同的温度下,随着初始生成压力的增大,实验最终压力、气体消耗量与最终水的转化率均随之升高;温度越高,不同的生成初始生成压力下体系的最终稳定压力与水的转化率相差越大;在多孔介质的毛细管作用力与结合水的共同作用下,冰点下水合物生成的水的转化率会大大地降低。在本实验条件下,水相转化为水合物的比例最高为32.39%。 相似文献
7.
以多孔介质理论为基础,研究了稳态条件下非饱和土中温度?水分?盐分多场耦合问题。考虑非饱和土的孔隙被液态水、溶解的盐分、水蒸气和干燥气体等填充,在质量和能量守恒的基础上获得了非饱和土中水分、气体、盐分的质量守恒方程以及能量守恒方程。考虑一维稳态问题,选取温度、孔隙气压、孔隙水压和盐溶液浓度以及它们的导数作为状态变量,得到了问题的状态方程组。在给定的边界条件下,采用打靶法求解了该强耦合的非线性变系数微分方程组,通过与已有的试验结果相比较,验证了模型的有效性。基于数值算例,参数分析了含水率、温度边界、孔隙率等条件对非饱和土中温度场、水分场和盐分场分布的影响规律。 相似文献
8.
Perveiz Khalid Daniel Broseta Dan Vladimir Nichita Jacques Blanco 《Arabian Journal of Geosciences》2014,7(8):3281-3295
In seismic applications, the bulk modulus of porous media saturated with liquid and gas phases is often estimated using Gassmann's fluid substitution formula, in which the effective bulk modulus of the two-phase fluid is the Reuss average of the gas and liquid bulk moduli. This averaging procedure, referred to as Wood's approximation, holds if the liquid and gas phases are homogeneously distributed within the pore space down to sizes well below the seismic wavelength and if the phase transfer processes between liquid and gas domains induced by the pressure variations of the seismic wave are negligible over the timescale of the wave period. Using existing theoretical results and low-frequency acoustic measurements in bubbly liquids, we argue that the latter assumption of “frozen” phases, valid for large enough frequencies, is likely to fail in the seismic frequency range where lower effective bulk modulus and velocity, together with dispersion and attenuation effects, are expected. We provide a simple method, which extends to reservoir fluids a classical result by Landau and Lifshitz valid for pure fluids, to compute the effective bulk modulus of thermodynamically equilibrated liquid and gas phases. For low gas saturation, this modulus is significantly lower than its Wood's counterpart, especially at the crossing of bubble point conditions. A seismic reflector associated to a phase transition between a monophasic and a two-phase fluid thus will appear. We discuss the consequences of these results for various seismic applications including fizz water discrimination and hydrocarbon reservoir depletion and CO2 geological storage monitoring. 相似文献
9.
The enhanced velocity mixed finite element method, due to Wheeler et al. (Comput Geosci 6(3–4):315–332, 2002), is analyzed and extended to the problem of modeling slightly compressible flow coupled to the transport of chemical species
through porous media, on non-matching multiblock grids. Applications include modeling bio-remediation of heavy oil spills
and many other subsurface hazardous wastes, angiogenesis in transition of tumors from dormant to malignant states, transport
of contaminants in ground water flow, and acid injection from well bores to increase permeability of surrounding rock. The
analysis and numerical examples presented here demonstrate convergence and computational efficiency of this method. 相似文献
10.
Soil freezing is often used to provide temporary support of soft soils in geotechnical interventions. During the freezing process, the strength properties of the soil–water–ice mixture change from the original properties of the water-saturated soil to the properties of fully frozen soils. In the paper, a multiscale homogenization model for the upscaling of the macroscopic strength of freezing soil based upon information on three individual material phases—the solid particle phase (S), the crystal ice phase (C) and the liquid water phase (L)—is proposed. The homogenization procedure for the partially frozen soil–water–ice composite is based upon an extension of the linear comparison composite (LCC) method for a two-phase matrix–inclusion composite, using a two-step homogenization procedure. In each step, the LCC methodology is implemented by estimating the strength criterion of a two-phase nonlinear matrix–inclusion composite in terms of an optimally chosen linear elastic comparison composite with a similar underlying microstructure. The solid particle phase (S) and the crystal ice phase (C) are assumed to be characterized by two different Drucker–Prager strength criteria, and the liquid water phase (L) is assumed to have zero strength capacity under drained conditions. For the validation of the proposed upscaling strategy, the predicted strength properties for fully and partially frozen fine sands are compared with experimental results, focussing on the investigation of the influence of the porosity and the degree of ice saturation on the predicted failure envelope. 相似文献
11.
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13.
基于计算流体力学的寒区土壤水热耦合模型研究 总被引：1，自引：0，他引：1
土壤水文过程（水分运移和传热）及其对气候变化的响应是寒区水文学的前沿问题。然而,冻土的存在使得寒区土壤水文过程变得极其复杂。此外,寒区自然环境恶劣,较难获取长时间序列和高分辨率的野外观测资料。近年来,充分利用已有的观测数据,构建寒区土壤水热耦合模型,并开展相应的数值模拟研究,已成为理解寒区土壤水文物理过程,揭示其动力学机制的重要途径。基于寒区土壤水文物理过程和计算流体力学方法,构建了高分辨率、适用于完全饱和状态下的寒区土壤水热耦合模型,且自主研发了相应的数值求解器和软件包。随后,通过一系列完全饱和状态下的验证算例,如经典的一维传热方程解析解、被广泛应用的二维基准测试算例和室内土柱冻结实验等,对已构建的模型进行了系统的检验。模型模拟结果与解析解、基准算例的结果以及实验数据相比,均有较好的一致性,表明该模型较为准确且高效地模拟了寒区土壤在完全饱和状态下的水分运移和传热过程,尤其能够精细刻画冻土水-冰相态变化等关键过程,有望成为研究寒区土壤水文过程的有力工具。 相似文献
14.
光透法作为一种安全经济的非侵入监测方法广泛应用于室内砂箱多相流实验中,但该方法在局部空间点上结果的可
靠性尚缺乏验证。鉴于当前难以采用实验手段直接进行局部监测点取样验证光透法结果,本文以非均质孔隙介质中的水/气
两相流为例,基于砂箱实验开展了数值模拟研究以进行论证。研究表明：（1） 模拟结果中气体在非均质含水层中的迁移规
律、展布形态和饱和度分布总体上再现了光透法的测量结果。（2） 数值模拟和光透法得到的6个局部点饱和度数据在各时
刻均拟合较好。同时选取12个时刻共5316个监测点的饱和度数据进行分析,其决定系数达0.94,这表明模拟结果从统计
角度较好地验证了光透法在局部点监测上的有效性,两者间的差异主要由人工填砂导致的介质“不均匀”引起。（3） 气体
总量方面,实测排水值、模拟结果与光透法计算结果均拟合较好。因此数值模拟结果系统地验证了光透法监测流体饱和度
的有效性。 相似文献
15.
A wave method for suppression of multiple waves that does not require knowledge of a depth— velocity medium model is developed.
The method is constructed so as to completely suppress multiple waves in the case of a layer in a half-space. The efficiency
of the method for arbitrary 3D plane-layered media is demonstrated both theoretically and numerically. Examples of the method
application for real media showing a substantial decrease in the multiple wave amplitudes without distortion of the dynamics
of useful reflections are given. 相似文献
16.
Numerical simulation of gas migration driven by compressible two-phase partially miscible flow in porous media is of major importance for safety assessment of deep geological repositories for long-lived high-level nuclear waste. We present modeling of compositional liquid and gas flow for numerical simulations of hydrogen migration in deep geological radioactive waste repository based on persistent primary variables. Two-phase flow is considered, with incompressible liquid and compressible gas, which includes capillary effects, gas dissolution, and diffusivity. After discussing briefly the existing approaches to deal with phase appearance and disappearance problem, including a persistent set of variables already considered in a previous paper (Bourgeat et al., Comput Geosci 13(1):29–42, 2009), we focus on a new variant of the primary variables: dissolved hydrogen mass concentration and liquid pressure. This choice leads to a unique and consistent formulation in liquid saturated and unsaturated regions, which is well adapted to heterogeneous media. We use this new set of variable for numerical simulations and show computational evidences of its adequacy to simulate gas phase appearance and disappearance in different but typical situations for gas migration in an underground radioactive waste repository. 相似文献
17.
多孔介质渗透系数的空间尺度效应研究进展 总被引：6，自引：1，他引：5
多孔介质渗透系数的空间尺度问题是一个与地下流体运动和溶质运移的数值模拟密切相关的应用性课题,广泛的应用需求和新的计算方法使其成为近年的热门课题之一。它涉及到相互联系的两个方面：①非均质介质场渗透系数空间尺度行为的分析与模拟;②将局部测量尺度下的试验参数转化为数值模拟网格尺度下的参数输入值的升尺度（ｕｐｓｃａｌｉｎｇ）方法和计算模型。首先介绍了该课题在概念上的拓展及其物理含义,进而以方法为主线,对这一领域具有代表性的研究成果进行了分类和评述,讨论了该课题的研究对地下水流和溶质运移的模拟分析乃至整个多孔介质流体运动研究的意义。 相似文献
18.
Rahul Mohan Sunil Kumar Shukla Shramik M. Patil Suhas S. Shetye Karima K. Kerkar 《Journal of the Geological Society of India》2011,78(1):36-44
Diatoms from surface sediment samples collected from Enderby Basin of Indian Sector of Southern Ocean were analyzed to determine
the relative abundance and distribution of seven key indicator diatom species viz. Sea ice related species Fragilariopsis rhombica, F. separanda, F. curta, F. ritscheri, Thalassiosira tumida and Actinocyclus actinochilus and Open Ocean species F. kerguelensis on the basis of modern physico-chemical parameters. The relative abundances of different species observed viz. F. rhombica — 6.25%; F. separanda — 12.5%; F. curta — 10.53–13.33%; F. ritscheri — 4.55–12.5%; F. kerguelensis — 6.25–63.64%; T. tumida — 3.13% and A. actinochilus — 9.38–13.33%. The increasing abundance of F. kerguelensis consecutively suggests the effect of Antarctic bottom water in the study area which is further substantiated by the presence
and increasing abundance of F. ritscheri. The gradual decrease in abundance or absence of sea ice related species from the sampled stations indicates the summer and
winter sea ice extent concentration in the study area. The nutrient concentration correlates with the distribution and abundances
of diatom species. 相似文献
19.
在地球上,水是生命存在的基础之一.大量证据表明火星表面曾经存在液态水,而目前的火星表面环境不支持液态水的长期存在.因此,水可能以不同的状态赋存于火星的次表层.寻找火星次表层的水一直是火星探测的关键科学目标之一.次表层探测雷达,如探地雷达、探冰雷达,是了解地下物质结构的有效方法,近年来在地外天体上得到大量应用.在过去十余年,欧洲的火星快车(Mars Express)上搭载的火星次表层和电离层探测先进雷达(Mars Advanced Radar for Subsurface and Ionosphere Sounding,MARSIS)和美国火星勘测轨道飞行器(Mars Reconnaissance Orbiter,MRO)上搭载的浅表层雷达(Shallow Subsurface Radar,SHARAD)已在火星轨道上获取了大量数据,被广泛应用于研究火星的地下结构,尤其是地下水冰探测.我国的天问一号火星探测器也携带了高低频轨道探测雷达和高低频火星车探地雷达,有望在不同的顺轨向、交轨向和距离向分辨率上揭示火星次表层不同深部的结构.本文综述了轨道器次表层探测雷达的探测原理和优势,简要介绍了雷达数据的处理和解译方法,重点总结了 MARSIS和SHARAD近年来对火星水冰探测的最新进展,最后对天问一号环绕器雷达及其水冰探测作简要展望. 相似文献
20.
Manuel Helbig Julia Boike Moritz Langer Peter Schreiber Benjamin R. K. Runkle Lars Kutzbach 《Hydrogeology Journal》2013,21(1):133-147
The summer water balance of a typical Siberian polygonal tundra catchment is investigated in order to identify the spatial and temporal dynamics of its main hydrological processes. The results show that, besides precipitation and evapotranspiration, lateral flow considerably influences the site-specific hydrological conditions. The prominent microtopography of the polygonal tundra strongly controls lateral flow and storage behaviour of the investigated catchment. Intact rims of low-centred polygons build hydrological barriers, which release storage water later in summer than polygons with degraded rims and troughs above degraded ice wedges. The barrier function of rims is strongly controlled by soil thaw, which opens new subsurface flow paths and increases subsurface hydrological connectivity. Therefore, soil thaw dynamics determine the magnitude and timing of subsurface outflow and the redistribution of storage within the catchment. Hydraulic conductivities in the elevated polygonal rims sharply decrease with the transition from organic to mineral layers. This interface causes a rapid shallow subsurface drainage of rainwater towards the depressed polygon centres and troughs. The re-release of storage water from the centres through deeper and less conductive layers helps maintain a high water table in the surface drainage network of troughs throughout the summer. 相似文献