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1.
基于溶质运移模拟的某化工场地污染物对拟建水库污染风险预测 总被引：1，自引：0，他引：1
溶质运移模拟是污染风险预测的一种有效手段。本研究为查明研究区内某有机污染场地作为污染源对拟建水库的影响,基于对区内流场的精确测量,建立了准确的地下水流模型和化工厂泄露有机污染物的溶质运移模型,预测分析了研究区拟建水库修建前、后地下水流场及污染物迁移情形的变化。模拟结果表明：水库和周边两种设计水头的截渗沟建成后,改变了自然条件下的流场,形成水库向截渗沟排泄、截渗沟向周边排泄以及水库和周边区域均向截渗沟排泄两种地下水流场。某些污染羽扩散范围虽比自然条件下有所增大,但向水库方向的扩散均未超出300 m,不会对水库水质构成污染风险。 相似文献
2.
为查明场地污染分布特征,需对场地土壤和地下水进行钻探取样,按规范的检测指标进行逐一测试。在初查和详查阶段将获得大量的土壤和地下水污染数据,数据样本数量大、监测指标多,数据结构复杂,如何从场地大数据中提取价值信息已成为研究热点。以某有机污染场地为例,基于自组织映射神经网络（SOM）和K均值算法开展大数据分析,深入探讨地下水和土壤中各污染指标间的相关性。结果表明:（1）基于自组织映射神经网络的大数据分析可快速挖掘复杂多维的污染场地监测数据,有效完成关键信息的提取;（2）地下水中污染检出指标存在显著的聚类特征,同一聚类中的污染指标具备相似的空间分布特征。对场地污染物检测采取先分类后分级的优化筛选策略,减少污染物检测指标数目,从而有效降低场地检测费用;（3）土壤和地下水中污染检出指标存在良好的空间相关性,这与该污染场地地下水渗流速度缓慢有关。土壤和地下水污染检出指标空间分布的相关性,有助于场地污染源的追溯。 相似文献
3.
Volatile organic compound (VOC) contamination of subsurface geological material and groundwater was discovered on the Nortel
Monkstown industrial site, Belfast, Northern Ireland. The objectives of this study were to (1) investigate the characteristics
of the geological material and its influences on contaminated groundwater flow across the site using borehole logs and hydrological
evaluations, and (2) identify the contaminants and examine their distribution in the subsurface geological material and groundwater
using chemical analysis. This report focuses on the eastern car park (ECP) which was a former storage area associated with
trichloroethene (TCE) degreasing operations. This is where the greatest amount of volatile organic compounds (VOCs), particularly
TCE, were detected. The study site is on a complex deposit of clayey glacial till with discontinuous coarser grained lenses,
mainly silts, sands and gravel, which occur at 0.45–7.82 m below ground level (bgl). The lenses overall form an elongated
formation that acts as a small unconfined shallow aquifer. There is a continuous low permeable stiff clayey till layer beneath
the lenses that performs as an aquitard to the groundwater. Highest concentrations of VOCs, mainly TCE, in the geological
material and groundwater are in these coarser lenses at ∼4.5–7 m bgl. Highest TCE measurements at 390,000 μg L−1 for groundwater and at 39,000 μg kg−1 at 5.7 m for geological material were in borehole GA19 in the coarse lens zone. It is assumed that TCE gained entrance to
the subsurface near this borehole where the clayey till was thin to absent above coarse lenses which provided little retardation
to the vertical migration of this dense non-aqueous phase liquid (DNAPL) into the groundwater. However, TCE is present in
low concentrations in the geological material overlying the coarse lens zone. Additionally, VOCs appear to be associated with
poorly drained layers and in peat <3.0 m bgl in the ECP. Some indication of natural attenuation as VOCs degradation products
vinyl chloride (VC) and dichloromethane (DCM) also occur on the site. 相似文献
4.
岩溶地下水为全球约25%的人口提供饮用水源,地下河作为主要岩溶地下水类型,是中国西南岩溶区重要供水水源,掌握其水质污染状况及人体健康风险,对岩溶区水资源保护与安全用水具有重要意义。本文以广西桂林会仙狮子岩地下河系统为例,采集地下河水样品22组(无机和有机样品各11组),采用电感耦合等离子体质谱、离子色谱、气相色谱-质谱等方法测定11项无机离子、10项金属元素及41项有机指标的质量浓度,运用单指标污染标准指数法、健康风险评价模型揭示了研究区无机与有机指标分布、污染及健康风险。结果表明：(1)狮子岩地下河水中无机超标指标有NH~+4(1.33倍)、Fe(1.2倍)、Al(1.5倍)和Mn(1.01倍),超标点多位于地下河排泄区;检出18项有机物,其中挥发性有机物(VOCs)、半挥发性有机物(SVOCs)和有机氯农药(OCPs)检出率分别为18.75%、30.77%和91.67%,研究区存在普遍的农药残留(49.14～109.83ng/L)。(2)与地下水对照值相比,研究区受到10项无机指标的轻度～中度污染、14项有机指标的轻度污染,个别采样点受到NO~-3<... 相似文献
5.
《Applied Geochemistry》1998,13(1):3-16
The storage of low level radioactive waste in trenches overlying an unconfined groundwater flow system in sands has generated a contaminant plume (with chemical characteristics of dilute sanitary landfill leachate) containing 14C both as dissolved inorganic and organic C. In the groundwater, dissolved organic compounds account, on average, for 22% of the total C and 10% of the 14C. Approximately 300 m from the waste management site, the groundwater discharges to the surface in a wetland containing up to 3 m of peat and an extensive tree cover. Drainage from the wetland passes through a gauged stream. Radiocarbon input to the groundwater discharge area in 1991 was determined to be between 3.3 and 4.2 GBq, based on data from a line of sampling wells along the groundwater input boundary of the wetland, with control provided by water and tritium balance data. During the 1991 study year, only 1.5–2% of both the inorganic and organic 14C inputs left the wetland in surface water drainage. Vegetation growth in the wetland during the study year contained 8–10% of the released radiocarbon. If the rate of 14C accumulation in the peat has been constant, 7–9% of the annual radiocarbon input has been retained in the organic soil. Much of this soil accumulation can be attributed to litter from standing vegetation, making distribution coefficients an inappropriate model for 14C partitioning between groundwater and soil. The plant/soil 14C concentration ratio was 24 to 33, but application of a concentration ratio to describe the transfer of radiocarbon to plants is also believed to be inappropriate. This study indicates that over 80% of the groundwater radiocarbon is rapidly lost to the atmosphere when the groundwater comes to surface, and we infer that most of the 14C accumulation in vegetation occurs by CO2 transfer from the air to the plant. 相似文献
6.
Sandro Rinaldi Sihem Louati Hocine Bendjoudi Ghislain de Marsily 《Hydrogeology Journal》2014,22(4):943-956
Industrially sourced dense non-aqueous phase liquids (DNAPLs) contaminated an alluvial aquifer in France decades ago. The location(s) and nature of the pollution source zone(s) were unknown, and the dissolved concentrations of volatile organic compounds in the monitoring wells varied greatly with time. The aquifer was in hydraulic equilibrium with an artificial canal whose water level was highly variable (up to 5 m). These variations propagated into the aquifer, causing changes in the groundwater flow direction; a transient numerical model of flow and solute transport showed that they correlate with the concentration variations because the changes in the flow direction resulted in the contaminant plume shifting. The transient hydrogeological numerical model was built, taking into account solvent biodegradation with first-order chain, since biodegradation has a significant influence on the pollutant concentration evolution. The model parameterization confirms the position of the source zones among the potential troughs in the bedrock where DNAPLs could have accumulated. The groundwater model was successfully calibrated to reproduce the observed concentration variations over several years and allowed a rapid validation of the hypotheses on the functioning of the polluted system. 相似文献
7.
Hakim Khelfaoui Hicham Chaffai Jacques Mudry Azzedine Hani 《Arabian Journal of Geosciences》2013,6(11):4517-4527
The continuous increase of industrial activities in the area of Berrahal (northeast of Algeria) resulted in an increase of waste disposal, inducing environmental pollution and contamination of groundwater. Available data on groundwater contamination were used to develop a statistical study for contaminated regions and to identify exposure scenarios of pollution. Chemical analysis of the samples shows that water of most wells and drillings is in bad quality or not drinkable, whereas statistical processing of these data by principal component analysis and discriminant factorial analysis suggests that wastewater coming from companies of the industrial park of Berrahal is very rich in organic pollutants (high percentages of BOD5 and NO2 ?) and has high mineralization (has strong concentration in major elements and high electric conductivity); these constitute the main factors of the deterioration of the quality of this water. The considered exposure pathways were drinking water exploited from wells and drillings implanted in this area and its contact with soil (ingestion and dermal contact) that could threaten either humans or wildlife, on site or off site. In addition, groundwater was considered to be a potential risk pathway, especially for the ecosystem of Lake Fetzara and for the aquiferous system. 相似文献
8.
桂江流域地下水污染途径及防控措施研究 总被引：1，自引：1，他引：0
对桂江流域开展岩溶地下水污染调查发现:流域内地下水污染源分为“三氮”污染源、重金属污染源、有机污染源三类;“三氮”污染源主要包括工业、养殖和生活三类污水、生活垃圾渗滤液、农业施用氮肥等;重金属污染主要来自工矿企业;有机污染来自工业、养殖业。污染途径主要有孤峰平原的分散入渗式、孤峰平原的脚洞灌入式、峰丛洼地的消水洞灌入式、溶丘谷地的入渗式和峰丛峰林谷地的天窗灌入式等五类。并对88组地下水样品测试结果进行多指标地下水污染综合评价,结果表明36.5%的水点为“三氮”污染,多以分散入渗进入地下水,其污染形态呈面状分布;15.3%的水点为重金属污染,主要通过峰丛洼地消水洞灌入式补给和溶丘谷地入渗补给两种途径,呈点状分布于污染场地附近;3.49%的水点为有机污染,主要为分散入渗补给途径,污染呈短线状或点状分布。 相似文献
9.
贵阳观山湖区至白云区地下水有机污染现状与防治对策 总被引：2，自引：2，他引：0
文章按水文地质条件将全区划分为12个地下水系统,并选择43组控制性水点分丰枯两季进行有机样品采集和测试,在此基础上对研究区地下水中有机污染物的检出、超标、分布及来源均进行了分析。结果显示,参评的86组地下水样品中,有32组检出有机污染物;27种参评有机组分中,10种有机组分存在不同程度的检出,其中,三氯甲烷检出25次,检出率29.07%,其余组分检出率均低于5%;仅有1,2二氯丙烷超标1次,超标率低;区内地下水有机污染物检出浓度较低,超标率低,处于轻度污染阶段;12个系统中,有9个系统发现有机物污染物检出;检出点多分布于工矿企业的下游地段,排污河渠两侧;污染物多来源于中小型工矿企业,以污染物通过落水洞、天窗等进入含水层为主要污染途径;地下水系统排泄区的近源污染多发,危害程度大。针对上述污染特征,提出加强对中小企业污染源的集中管理,加大污水管网建设力度等对策建议。 相似文献
10.
Barbara L. Nowicki Edwin Requintina Donna Van Keuren John Portnoy 《Estuaries and Coasts》1999,22(2):245-259
The Nauset Marsh estuary is the most extensive (9.45 km2) and least disturbed salt marsh/estuarine system within the Cape Cod National Seashore, even though much of the 19 km2 watershed area of the estuary is developed for residential or commercial purposes. Because all of the Nauset watershed is serviced by on-site individual sewage disposal systems, there is concern over the potential impact of groundwater-derived nutrients passing from these systems to the shallow receiving waters of the estuary. The purpose of this study was to determine whether denitrification (the bacterial conversion of nitrate to gaseous nitrogen) in estuarine sediments could effectively remove the nitrate from contaminated groundwater before it passed from the watershed to the estuary. Rates of denitrification were measured both in situ and in sediment cores, in areas of active groundwater discharge, in relatively pristine locations, and in areas situated down-gradient of moderate to heavily developed regions of the watershed. Denitrification rates for 47 sediment cores taken over an annual cycle at 5 stations ranged from non-detectable to 47 μmol N2 m−2 h−. Mean denitrification rates were positively correlated with sediment organic content, and varied seasonally due to changes in sediment organic content and to the effect of water temperatures on sediment oxygen penetration depths. There was no correlation between observed denitrification rates and corresponding nitrate concentrations in groundwater. A comparison of in situ denitrification rates (supported by groundwater nitrate) with denitrification rates observed in sediment cores (supported by remineralized nitrate) showed that groundwater-driven denitrification rates were small, and not in excess of denitrification rates supported by remineralized nitrate. Most of the denitrification in Nauset sediments was apparently fueled by remineralized nitrate through coupled nitrification/denitrification. Denitrification did not contribute significantly to the direct loss of nitrate from incoming groundwater at Nauset Marsh estuary. Groundwater flow was rapid, and much of it occurred in freshwater springs and seeps through very coarse, sandy, well-oxygenated sediments of limited organic content. There was little opportunity for denitrification to occur during groundwater passage through these sediments. These results have important management implications because they suggest that the majority of nitrogen from contaminated groundwater crosses the sediment/water interface and arrives at Nauset Estuary, where it is available to primary producers. Preliminary budget calculations suggest that while denitrification was not an effective mechanism for the direct removal of nitrate in contaminated groundwater flowing to Nauset Marsh estuary, it may contribute to significant nitrogen losses from the estuary itself. 相似文献
11.
Temporal variations in arsenic concentration in the groundwater of Murshidabad District,West Bengal,India 总被引：1，自引：0，他引：1
S. H. Farooq D. Chandrasekharam S. Norra Z. Berner E. Eiche P. Thambidurai D. Stüben 《Environmental Earth Sciences》2011,62(2):223-232
Systematic investigations on seasonal variations in arsenic (As) concentrations in groundwater in both space and time are
scarce for most parts of West Bengal (India). Hence, this study has been undertaken to investigate the extent of As pollution
and its temporal variability in parts of Murshidabad district (West Bengal, India). Water samples from 35 wells were collected
during pre-monsoon, monsoon and post-monsoon seasons and analyzed for various elements. Based on the Indian permissible limit
for As (50 μg/L) in the drinking water, water samples were classified into contaminated and uncontaminated category. 18 wells
were reported as uncontaminated (on average 12 μg/L As) and 12 wells were found contaminated (129 μg/L As) throughout the
year, while 5 wells could be classified as either contaminated or uncontaminated depending on when they were sampled. Although
the number of wells that alternate between the contaminated and uncontaminated classification is relatively small (14%), distinct
seasonal variation in As concentrations occur in all wells. This suggests that investigations conducted within the study area
for the purpose of assessing the health risk posed by As in groundwater should not rely on a single round of water samples.
In comparison to other areas, As is mainly released to the groundwater due to reductive dissolution of Fe-oxyhydroxides, a
process, which is probably enhanced by anthropogenic input of organic carbon. The seasonal variation in As concentrations
appear to be caused mainly by dilution effects during monsoon and post-monsoon. The relatively high concentrations of Mn (mean
0.9 mg/L), well above the WHO limit (0.4 mg/L), also cause great concern and necessitate further investigations. 相似文献
12.
Cesar Falcão Barella Luís de Almeida Prado Bacellar Hermínio Arias Nalini Jr 《Environmental Earth Sciences》2013,70(5):2283-2292
The objective of this work was to evaluate the influence of the natural degradation of the leachate organic fraction from the Belo Horizonte landfill on groundwater chemical evolution. The work focused on the modifications introduced by redox reactions in the presence of terminal electron acceptors. Twenty-one sampling points distributed along 13 monitoring wells were selected for the analysis of the chemical indicators of interest (TDS, SO 4 ?2 , Fe+2, Ba, pH and Eh). The behaviour of the variables involved in the alteration of the water quality was assessed by the spatial distribution of target parameters, elaboration of redox diagrams and chemical modelling that focused on the determination of mineral saturation indexes. The study showed a trend toward pyrite precipitation, which leads to the removal of chemical species such as divalent iron and sulphur as sulphide from the system. This removal disturbs the chemical equilibrium, typically by moving the reactions to replenish the sulphate concentration present in the groundwater. This process occurs primarily through the dissolution of compounds that have sulphate in their chemical composition, such as barite, suggesting that part of the barium concentration in the subsurface can be of geogenic origin. This study demonstrated the importance of knowing the nature of the geochemical processes in groundwater contaminated by urban solid waste. 相似文献
13.
Groundwater samples collected from both open and bore wells in an area of about 270 km2 from Madras City, India, have been analyzed for major ions (HCO3, Cl, Si, Na, Ca, and Mg) and trace elements (As, Se, B, V, Cr, Fe, Co, Pb, Cu, Zn, Cd, Mn, Ni, Mo, and Ba). The study reveals that the quality of potable water has deteriorated to a large extent. Seawater intrusion into the aquifer has been observed in nearly 50 percent of the study area. The toxic elements (As and Se) have already exceeded the maximum permissible limits of drinking water in almost the entire city. A positive correlation of As and Se with other toxic metals such as V, Cr, Fe, B, etc., indicates that all these elements are anthropogenic in origin. Applying multivariate analysis, the source for trace elements in groundwater has been grouped into two major factors: pollution and mobilization factors. The groundwater in the study area is largely contaminated by organic effluents and reflects the intensity of pollution caused by the overlying soil sediment and rapid infiltration of the pollutants. 相似文献
14.
当地下水邂逅DNA:石油类有机污染及其生物降解 总被引：1，自引：0，他引：1
地下水科学与工程研究发展到今日,已经成为一门涉及多个领域的综合性学科。地下水污染的控制和修复研究更需要跨学科的技术和知识支持,而生物修复作为一种高效低耗修复的技术成为环境领域的研究热点。微生物因其自身特性及其对污染的降解主导特征对确定有机物污染场地的永续修复具有重要意义。简要地综述了地下水有机污染及其原位修复、有机污染物和地下环境微生物的交互作用,进一步聚焦生物降解机制、生物修复和细菌研究。在此基础上以某石油污染场地地下水为例,进行了地下水中分离微生物菌株及其降解特征的实验研究。结果表明:放线菌降解效果最好,细菌和真菌次之;两两组合降解效果好于单菌,表明存在协同作用;不同菌株混合降解率较低,表明具有拮抗作用。通过动力学实验得出对TPH的降解符合一级反应动力学方程及其降解速度和降解半衰期。就微生物对有机组分降解而言,烷烃和总石油烃降解规律相似;难降解组分降解率低,后期因烷烃转化使其浓度升高;苯浓度变化不大。微生物活性实验表明:活菌总数和脱氢酶活性与降解率呈正相关变化。运用生理生化及分子生物学方法鉴定得出了具体的菌种。 相似文献
15.
某石化污染场地含水层自然降解BTEX能力评估 总被引：1，自引：0，他引：1
地下水污染问题是国家关注的重要环境问题之一,监测与评估含水层自然降解污染物能力是防治地下水污染的基本手段,也是国外地下水中修复技术研究热点课题。以华北平原某石油化工类场地为案例,通过调查场地水文地质条件、土壤及地下水污染现状,监测场地地下水中苯系物(BTEX)浓度及相关化学参数变化,运用微生物水文地球化学方法和水文地质方法,估算了该场地含水层自然降解苯系物量。这一研究成果为评估我国石油类场地地下水污染的自然修复能力提供了实证和基础数据。 相似文献
16.
污染造成的环境损害和土壤与地下水质量降低,直接影响生命健康与环境安全。污染企业搬迁后遗留场地的调查检测与修复治理,是土地资源开发利用与管理的重要环节。结合两个炼油厂污染地块在土地再开发期间所进行的土壤环境调查和治理修复案例,阐述了石油类污染地基土的环境调查方法、评价方式和治理修复措施,以期为污染土壤的调查与治理修复提供借鉴。 相似文献
17.
N. P. Laverov V. I. Velichkin V. I. Malkovsky N. N. Tarasov Yu. P. Dikov 《Geology of Ore Deposits》2010,52(1):5-13
The spread of radioactive contamination in the subsurface medium near Lake Karachai is considered. The complexity of this
process requires a comprehensive approach to its study. The source of radioactive contamination is overviewed. The map of
faults in subsurface medium is considered in order to determine the prevailing direction of contaminated groundwater flow.
Photometry in observation wells has been used for structural geological estimation of transport properties of the shallow
aquifer, where contaminated groundwater is moving. This study was carried out along with hydrochemical logging, which makes
it possible to estimate the dynamics of contamination of subsurface medium and vertical distribution of groundwater contamination.
Special attention is paid to transport of radionuclides in the form of radiocolloid particles. Groundwater samples were taken
from various depths corresponding to different contamination levels near Lake Karachai. The depth intervals of sampling were
determined from the data of hydrochemical logging. Ultrafiltration through membranes with a specific pore size in combination
with gamma spectrometry was used to characterize radionuclide transfer with colloidal particles differing in size. The local
elemental composition of the radiocolloid surface was studied by Auger spectroscopy. The chemical composition and structure
of radiocolloid particles were determined by X-ray photoelectron spectroscopy with consecutive etching of the particle surface
by argon ions for a certain depth. The data obtained indicate that radiocolloid particles are heterogeneous and an organic
shell consisting of humic and fulvic acids and technogenic organic compounds coat their surface. 相似文献
18.
分析了有机污染物在土壤中的迁移转化机理，建立了非平衡吸附作用下渗滤液中有机污染物在土壤中迁移转化的动力学模型，给出了模型的数值解法，模拟出渗滤液在非平衡吸附作用下的污染过程；同时还探讨了模型参数降雨量p，垃圾土土层的厚度h，含水率θ等对有机污染物运移的影响。结果表明：在总的污染源一定的情况下，降雨量的增大和污染土层厚度的增大会使得下层土壤中有机物的浓度降低，为定量研究有机污染物在土壤-水环境系统中分配与归宿提供理论依据，同时也可为监测、治理和恢复地下水污染提供一定的科学根据。 相似文献
19.
Rakia S’habou Moncef Zairi Amjed Kallel Abdelwaheb Aydi Hamed Ben Dhia 《Environmental Geology》2009,58(3):679-686
Olive oil is a typical and valuable agro-industrial product in Mediterranean countries. In Tunisia, olive mill wastewaters
(OMW) reach an amount of about 1,000,000 t year−1 and constitute a serious organic pollution risk because of the high chemical oxygen demand values and the presence of phytotoxic
and antibacterial polyphenols. OMW have been generally stored in pond sites to be eliminated by natural evaporation or valorised
by spreading on cultivated soils or by composting. Many researches on the interactions of OMW with soils at laboratory scale
(columns) have been reported, but less attention have been paid to the effect of OMW on soils at field scale. The aim of this
work is to investigate an area used for >15 years as an uncontrolled OMW pond site. The transformations of soil properties
and groundwater occurring during OMW storage were characterised by the pH, phenolic contents, electrical conductivity (EC),
moisture content and organic contents. The soil samples were taken from two borings and compared to those of a control one
located near the pond site. Groundwater samples were taken on the accessible and nearest water wells to the evaporation ponds.
The permeable silty and sandy layers in the site support the infiltration of OMW near the evaporation ponds. This infiltration
has reached a depth of 6 m at a distance of almost 50 m laterally. The results show that the OMW infiltration in the subsoil
has affected the pH, EC, organic content, phenolic compounds and the moisture. 相似文献
20.
S. Sankaran R. Rangarajan K. Krishna Kumar S. Saheb Rao Smita Vishwasrao Humbarde 《Environmental Earth Sciences》2010,60(4):757-764
A chemical factory near Ranipet town in Vellore district, in the state of Tamil Nadu, India produced chromium-based inorganic
chemicals. The factory area in granite gnessic terrain receives an average annual rainfall of 1,000 mm. About 1.5 lakh tons
of solid wastes rich in hexavalent chromium (Cr6+), spreading over an area of 14,000 m2 (about 3.5 acres), having about 4 m thickness, is accumulated in an open yard within the factory premises. The soil and groundwater
in and around the factory area are contaminated with Cr6+ leached from dump site. Cr6+ is carcinogenic in nature and when leached in water can lead to respiratory disorders. Resistivity surveys comprising vertical
electrical sounding, multielectrode resistivity imaging, drilling of bore wells, chemical analysis of soil, formation and
groundwater samples and bore hole tracer studies were carried out within the factory and adjoining areas to decipher subsurface
geology, hydraulic behavior of dyke as natural barrier and lateral and vertical extent of pollution zone in and around the
chromium dump site. The data obtained were integrated and interpreted for understanding the pollution migration and its impact
on environment. Remedial measures are suggested for containing the contamination. 相似文献