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1.
Abstract— A single orthopyroxene crystal from the Martian meteorite Allan Hills (ALH) 84001 was studied by X‐ray diffraction (XRD) and electron microprobe analysis (EMPA) to retrieve information about its thermal history. Both sets of data were used to measure the Fe2+‐Mg order degree between the M1 and M2 sites expressed by the distribution coefficient kD. The 529 ± 30°C closure temperature (Tc) of the Fe2+‐Mg ordering process of ALH 84001 orthopyroxene (Fs28) was calculated using Stimpfl (2005a, 2005b) ln kD versus 1/T equation obtained for intermediate iron sample. At this Tc, the orthopyroxene cooling rate, calculated by Ganguly's (1982) numerical method, was 0.1 °C/day. This study puts new constraints on the last high‐temperature thermal episode recorded by orthopyroxene. With reference to the geological history (Treiman 1998), we ascribe this episode to the I3 event, and we interpret the Tc of 529 °C as a lower limit for this impact heating. Our data confirm that experimentally defined physical conditions for the formation of magnetite from decomposition of carbonates took place on the Martian surface during event I3.  相似文献   

2.
The Jezersko meteorite is a newly confirmed stony meteorite found in 1992 in the Karavanke mountains, Slovenia. The meteorite is moderately weathered (W2), indicating short terrestrial residence time. Chondrules in partially recrystallized matrix are clearly discernible but often fragmented and have mean diameter of 0.73 mm. The meteorite consists of homogeneous olivine (Fa19.4) and low‐Ca pyroxenes (Fs16.7Wo1.2), of which 34% are monoclinic, and minor plagioclase (Ab83An11Or6) and Ca‐pyroxene (Fs6Wo45.8). Troilite, kamacite, zoned taenite, tetrataenite, chromite, and metallic copper comprise about 16.5 vol% of the meteorite. Phosphates are represented by merrillite and minor chlorapatite. Undulatory extinction in some olivine grains and other shock indicators suggests weak shock metamorphism between stages S2 and S3. The bulk chemical composition generally corresponds to the mean H chondrite composition. Low siderophile element contents indicate the oxidized character of the Jezersko parent body. The temperatures recorded by two‐pyroxene, olivine‐chromite, and olivine‐orthopyroxene geothermometers are 854 °C, 737–787 °C, and 750 °C, respectively. Mg concentration profiles across orthopyroxenes and clinopyroxenes indicate relatively fast cooling at temperatures above 700 °C. A low cooling rate of 10 °C Myr?1 was obtained from metallographic data. Considering physical, chemical, and mineralogical properties, meteorite Jezersko was classified as an H4 S2(3) ordinary chondrite.  相似文献   

3.
Abstract— Single crystals of orthopyroxene from small fragments of the Kapoeta, Old Homestead 001, and Hughes 002 howardites were studied by x‐ray diffraction and microprobe analyses. The Fe‐Mg equilibrium distribution coefficients kD of the crystals were used to calculate the closure temperatures (Tc) using the calibration by Stimpfl et al. (1999). The compositions, the presence of exsolved augite lamellae, and the Tc values (from 365 to 385 °C) obtained for Kapoeta orthopyroxene s suggest that our fragment comes from a diogenitic cumulate clast. The more Fe‐rich composition, the absence of exsolved lamellae, and the higher Tc values (from 583 to 605 °C) measured in the Old Homestead 001 orthopyroxenes suggest that this fragment comes from a cumulitic clast affected by fast cooling at high temperature. For the Hughes 002 orthopyroxenes, close in composition to Old Homestead 001, the different Tc values (339, 358, and 607 °C) recorded by the various crystals and the presence of augite lamellae in the crystals with the lowest Tc support the hypothesis that this howardite sample is an unheated breccia containing a mixture of cumulitic orthopyroxenes with different thermal histories.  相似文献   

4.
Mason Gully, the second meteorite recovered using the Desert Fireball Network (DFN), is characterized using petrography, mineralogy, oxygen isotopes, bulk chemistry, and physical properties. Geochemical data are consistent with its classification as an H5 ordinary chondrite. Several properties distinguish it from most other H chondrites. Its 10.7% porosity is predominantly macroscopic, present as intergranular void spaces rather than microscopic cracks. Modal mineralogy (determined via PS‐XRD, element mapping via energy dispersive spectroscopy [EDS], and X‐ray tomography [for sulfide, metal, and porosity volume fractions]) consistently gives an unusually low olivine/orthopyroxene ratio (0.67?0.76 for Mason Gully versus ~1.3 for typical H5 ordinary chondrites). Widespread “silicate darkening” is observed. In addition, it contains a bright green crystalline object at the surface of the recovered stone (diameter ≈ 1.5 mm), which has a tridymite core with minor α‐quartz and a rim of both low‐ and high‐Ca pyroxene. The mineralogy allows the calculation of the temperatures and ?(O2) characterizing thermal metamorphism on the parent body using both the two‐pyroxene and the olivine‐chromite geo‐oxybarometers. These indicate that MG experienced a peak metamorphic temperature of ~900 °C and had a similar ?(O2) to Kernouvé (H6) that was buffered by the reaction between olivine, metal, and pyroxene. There is no evidence for shock, consistent with the observed porosity structure. Thus, while Mason Gully has some unique properties, its geochemistry indicates a similar thermal evolution to other H chondrites. The presence of tridymite, while rare, is seen in other OCs and likely exogenous; however, the green object itself may result from metamorphism.  相似文献   

5.
The crystal structures of orthopyroxene (En86.3Fs8.6Wo5.1, space group Pbca) and pigeonite (En81.7Fs8.8Wo9.5, space group P21/c) from the Almahata Sitta ureilite (fragment#051) have been refined to R1 indices of 3.10% and 2.53%, respectively, using single-crystal X-ray diffraction data. The unit formulas were calculated from electron microprobe analysis, and the occupancies at the M1 and M2 sites were refined for both pyroxenes from the single-crystal diffraction data. The results indicate a rather disordered intracrystalline Fe2+-Mg cation distribution over the M1 and M2 sites, with a closure temperature of 726(±55)°C for orthopyroxene and 704(±110)°C for pigeonite, suggesting fast cooling of these pyroxenes. The Mössbauer spectrum of the Fe-Ni metal particles of Almahata Sitta ureilite (fragment#051) is dominated by two overlapping magnetic sextets that are assigned to Fe atoms in Si-bearing kamacite, and arise from two different nearest-neighbor configurations of Fe* (=Fe+Ni) and Si atoms in the bcc structure of kamacite; (8F*, 0Si) and (7Fe*, 1Si). In addition, the spectrum shows weak absorption peaks that are attributed to the presence of small amounts of cohenite [(Fe,Ni)3C], schreibersite [(Fe,Ni)3P], and an Fe-oxide/hydroxide phase. The fast cooling of pyroxene to the closure temperature (after equilibration at ~1200°C) and the incorporation of Si in kamacite can be interpreted as due to a shock event that took place on the meteorite parent body, consistent with the proposed formation history of ureilites parent body where a fast cooling has occurred at a later stage of its formation.  相似文献   

6.
Abstract— The Cerro los Calvos meteorite is a single stone of 68.5 g found in the Nuevo Mercurio strewn field of Zacatecas, Mexico (24°20′N, 102°8′W). It is an unusual H4 chondrite. Its olivine (Fa12.5) and orthopyroxene (Fs 11.7, Wo 0.8) are reduced relative to typical H chondrites. The La Banderia meteorite of 54.3 g from the same vicinity is an LL5 chondrite of shock classification e.  相似文献   

7.
Abstract— Northwest Africa (NWA) 428 is an L chondrite that was successively thermally metamorphosed to petrologic type‐6, shocked to stage S4–S5, brecciated, and annealed to approximately petrologic type‐4. Its thermal and shock history resembles that of the previously studied LL6 chondrite, Miller Range (MIL) 99301, which formed on a different asteroid. The petrologic type‐6 classification of NWA 428 is based on its highly recrystallized texture, coarse metal (150 ± 150 μm), troilite (100 ± 170 μm), and plagioclase (20–60 μm) grains, and relatively homogeneous olivine (Fa24.4 ± 0.6), low‐Ca pyroxene (Fs20.5 ± 0.4), and plagioclase (Ab84.2 ± 0.4) compositions. The petrographic criteria that indicate shock stage S4–S5 include the presence of chromite veinlets, chromite‐plagioclase assemblages, numerous occurrences of metallic Cu, irregular troilite grains within metallic Fe‐Ni, polycrystalline troilite, duplex plessite, metal and troilite veins, large troilite nodules, and low‐Ca clinopyroxene with polysynthetic twins. If the rock had been shocked before thermal metamorphism, low‐Ca clinopyroxene produced by the shock event would have transformed into orthopyroxene. Post‐shock brecciation is indicated by the presence of recrystallized clasts and highly shocked clasts that form sharp boundaries with the host. Post‐shock annealing is indicated by the sharp optical extinction of the olivine grains; during annealing, the damaged olivine crystal lattices healed. If temperatures exceeded those approximating petrologic type‐4 (?600–700°C) during annealing, the low‐Ca clinopyroxene would have transformed into orthopyroxene. The other shock indicators, likewise, survived the mild annealing. An impact event is the most plausible source of post‐metamorphic, post‐shock annealing because any 26Al that may have been present when the asteroid accreted would have decayed away by the time NWA 428 was annealed. The similar inferred histories of NWA 428 (L6) and MIL 99301 (LL6) indicate that impact heating affected more than 1 ordinary chondrite parent body.  相似文献   

8.
Abstract– To evaluate kinetic parameters for thermal degradation of organic matter, in situ heating experiments of insoluble organic matter (IOM) and bulk of Murchison (CM2) meteorite were conducted under Fourier transform infrared micro‐spectroscopy combined with a heating stage. Decreases of aliphatic C–H band area under Ar flow were well fitted with Ginstling‐Brounshtein three‐dimensional diffusion model, and the rate constants for decreases of aliphatic C–H were determined. Activation energies Ea and frequency factors A obtained from these rate constants at different temperatures using the Arrhenius equation were Ea = 109 ± 3 kJ mol?1 and A = 8.7 × 104 s?1 for IOM, and Ea = 61 ± 6 kJ mol?1 and A = 3.8 s?1 for bulk, respectively. Activation energy values of aliphatic C–H decrease are larger for IOM than bulk. Hence, the mineral assemblage of the Murchison meteorite might have catalytic effects for the organic matter degradation. Using obtained kinetic expressions, the time scale for metamorphism can be estimated for a given temperature with aliphatic C–H band area, or the temperature of metamorphism can be estimated for a given time scale. For example, using the obtained kinetic parameters of IOM, aliphatic C–H is lost approximately within 200 years at 100 °C and 100 Myr at 0 °C. Assuming alteration period of 7.5 Myr, alteration temperatures could be calculated to be <15 ± 12 °C. Aliphatic C–H decrease profiles in a parent body can be estimated using time–temperature history model. The kinetic expression obtained by the infrared spectral band of aliphatic C–H could be used as an alternative method to evaluate thermal processes of organic matter in carbonaceous chondrites.  相似文献   

9.
Abstract— The Carcote meteorite, detected in 1888 in the northern Chilean Andes, is a brecciated, weakly shocked H5 chondrite. It contains a few barred olivine chondrules and, even more rarely, fan-shaped or granular orthopyroxene chondrules. The chondrules are situated in a fine-grained matrix that consists predominantly of olivine and orthopyroxene with accessory clinopyroxene, troilite, chromite, merrillite, and plagioclase. The metal phase is mainly kamacite with subordinate taenite and traces of native Cu. In its bulk rock composition, Carcote compares well with other H5 chondrites so far analysed, except for a distinctly higher C content. Microprobe analyses revealed the following mineral compositions: olivine (Fa16.5–20), orthopyroxene (Fs14–17.5), diopsidic clinopyroxene (FS6–7), plagioclase (An15–20). Troilite is stoichimetric FeS with traces of Ni and Cr; chromite has Cr/(Cr + Al) of 0.86, Fe2+/(Fe2+ + Mg) of 0.80-0.88 and contains considerable amounts of Ti, Mn, and Zn. Merrillite is close to the theoretical formula Ca18(Mg, Fe)2Na2(PO4)14, although with a Na deficiency not compensated for by excess Ca; the Mg/(Mg + Fe2+) ratio of the Carcote merrilite is 0.93-0.95. Kamacite and taenite have Ni contents of 5.6–7.2 and 17.1–23.4 wt%, respectively. Native Cu contains about 3.1–3.3 wt% Fe and 1.6 wt% Ni. Application of different geothermometers to the Carcote H5 chondrite yielded apparently inconsistent results. The highest temperature range of 850–950 °C (at 1 bar) is derived from the Ca-in-opx thermometer. From the cpx-opx solvus geothermometers and the two-pyroxene Fe-Mg exchange geothermometer, a lower temperature range of 750–840 °C is estimated, whereas lower and more variable temperatures of 630–770 °C are obtained from the Ca-in-olivine geothermometer. Recent calibrations of the olivine-spinel geothermometer yielded a still lower temperature range of 570–670 °C, which fits well to the temperature information derived from the Ni distribution between kamacite and taenite. Judging from crystal chemical considerations, we assume that these different temperatures reflect the closure of different exchange equilibria during cooling of the meteorite parent body.  相似文献   

10.
Abstract— Transmission electron microscopy was used to examine pyroxene microstructure in the Northwest Africa (NWA) 856 martian meteorite to construct its cooling and shock histories. All pyroxenes contain strained coherent pigeonite/augite exsolution lamellae on (001). The average width and periodicity of lamellae are 80 and 400 nm, respectively, indicating a cooling rate below 0.1 °C/hr for the parent rock. Pigeonite and augite are topotactic, with strained coherent interfaces parallel to (001). The closure temperature for Ca‐Fe, Mg interdiffusion, estimated from the composition at the augite pigeonite interface, is about 700 °C. Tweed texture in augite reveals that a spinodal decomposition occurred. Locally, tweed evolved toward secondary pigeonite exsolutions on (001). Due to the decreasing diffusion rate with decreasing temperature, “M‐shaped” concentration profiles developed in augite lamellae. Pigeonite contains antiphase boundaries resulting from the C2/c to P21/c space group transition that occurred during cooling. The reconstructive phase transition from P21/c clinopyroxene to orthopyroxene did not occur. The deformation (shock) history of the meteorites is revealed by the presence of dislocations and mechanical twins. Dislocations are found in glide configuration, with the [001](100) glide system preferentially activated. They exhibit strong interaction with the strained augite/pigeonite interfaces and did not propagate over large distances. Twins are found to be almost all parallel to (100) and show moderate interaction with the augite/pigeonite interfaces. These twins are responsible for the plastic deformation of the pyroxene grains. Comparison with microstructure of shocked clinopyroxene (experimentally or naturally shocked) suggests that NWA 856 pyroxenes are not strongly shocked.  相似文献   

11.
The Gao‐Guenie H5 chondrite that fell on Burkina Faso (March 1960) has portions that were impact‐melted on an H chondrite asteroid at ~300 Ma and, through later impact events in space, sent into an Earth‐crossing orbit. This article presents a petrographic and electron microprobe analysis of a representative sample of the Gao‐Guenie impact melt breccia consisting of a chondritic clast domain, quenched melt in contact with chondritic clasts, and an igneous‐textured impact melt domain. Olivine is predominantly Fo80–82. The clast domain contains low‐Ca pyroxene. Impact melt‐grown pyroxene is commonly zoned from low‐Ca pyroxene in cores to pigeonite and augite in rims. Metal–troilite orbs in the impact melt domain measure up to ~2 mm across. The cores of metal orbs in the impact melt domain contain ~7.9 wt% of Ni and are typically surrounded by taenite and Ni‐rich troilite. The metallography of metal–troilite droplets suggest a stage I cooling rate of order 10 °C s?1 for the superheated impact melt. The subsolidus stage II cooling rate for the impact melt breccia could not be determined directly, but was presumably fast. An analogy between the Ni rim gradients in metal of the Gao‐Guenie impact melt breccia and the impact‐melted H6 chondrite Orvinio suggests similar cooling rates, probably on the order of ~5000–40,000 °C yr?1. A simple model of conductive heat transfer shows that the Gao‐Guenie impact melt breccia may have formed in a melt injection dike ~0.5–5 m in width, generated during a sizeable impact event on the H chondrite parent asteroid.  相似文献   

12.
Miller Range 07273 is a chondritic melt breccia that contains clasts of equilibrated ordinary chondrite set in a fine‐grained (<5 μm), largely crystalline, igneous matrix. Data indicate that MIL was derived from the H chondrite parent asteroid, although it has an oxygen isotope composition that approaches but falls outside of the established H group. MIL also is distinctive in having low porosity, cone‐like shapes for coarse metal grains, unusual internal textures and compositions for coarse metal, a matrix composed chiefly of clinoenstatite and omphacitic pigeonite, and troilite veining most common in coarse olivine and orthopyroxene. These features can be explained by a model involving impact into a porous target that produced brief but intense heating at high pressure, a sudden pressure drop, and a slower drop in temperature. Olivine and orthopyroxene in chondrule clasts were the least melted and the most deformed, whereas matrix and troilite melted completely and crystallized to nearly strain‐free minerals. Coarse metal was largely but incompletely liquefied, and matrix silicates formed by the breakdown during melting of albitic feldspar and some olivine to form pyroxene at high pressure (>3 GPa, possibly to ~15–19 GPa) and temperature (>1350 °C, possibly to ≥2000 °C). The higher pressures and temperatures would have involved back‐reaction of high‐pressure polymorphs to pyroxene and olivine upon cooling. Silicates outside of melt matrix have compositions that were relatively unchanged owing to brief heating duration.  相似文献   

13.
Abstract— The Yarle Lakes 001 meteorite was a single stone of 913 g found approximately 20 km north of Watson, South Australia, in 1990 October. It consists of olivine (Fa18.7 ± 0.4, n = 30), low-Ca pyroxene (Fs16.6 ± 0.2 Wo 12 + 0.4, n = 15). feldspar, high-Ca pyroxene, metallic Fe-Ni and troilite. Based on texture and mineral chemistry, Yarle Lakes 001 is classified as a H5 chondrite of shock stage S3.  相似文献   

14.
Abstract— We analyzed the compositional profiles of coexisting orthopyroxenes and spinels in six diogenite samples from the Antarctic meteorite collection and used the data to constrain their thermal histories. The closure temperatures of Fe2+‐Mg exchange between spinel and orthopyroxene in these samples vary between ～630 and 830 °C. However, those in other diogenite samples, for which the compositional data are available in the literature, extend up to ～1125 °C. This wide range of closure temperatures suggests repeated excavation of the diogenites from their original sites over a long time interval during cooling. The orthopyroxene grains were found to be homogeneous in composition while two of the relatively large spinel grains in the samples Elephant Moraine (EET) 87530 and Thiel Mountains (TIL) 82410 showed compositional zoning near the rim. Modeling of the spinel zoning in TIL 82410 suggests that it developed during cooling under a regolith or ejecta blanket, possibly at a depth of ～80–120 m, and that the spinel composition was homogeneous at ～900 °C. A nonlinear cooling model in which the cooling rate is given by ηT(K)2, with η = 5.8 times 10?3 K?1Ma?1, leads to simulated retrograde zoning profile in spinel which match the observed profile in TIL 82410 very well.  相似文献   

15.
A meteorite fall was heard and collected on July 13, 2010 at about 18:00 (local time) in the Shibanjing village of the Huaxi district of Guiyang, Guizhou province, China. The total mass of the fall is estimated to be at least 1.6 kg; some fragments are missing. The meteorite consists mainly of olivine, low‐Ca pyroxene, high‐Ca pyroxene, plagioclase, kamacite, taenite, and troilite. Minor phases include chromite and apatite. Various textural types of chondrules exist in this meteorite: most chondrule textures can be easily defined. The grain sizes of secondary plagioclase in this meteorite range from 2 to 50 μm. The chemical composition of olivine and low‐Ca pyroxene are uniform; Fa in olivine and Fs in low‐Ca pyroxene are, respectively, 19.6 ± 0.2 and 17.0 ± 0.3 (mole%). Huaxi has been classified as an H5 ordinary chondrite, with a shock grade S2, and weathering W0. The weak shock features, rare fractures, and the high porosity (17.6%) indicates that Huaxi is a less compacted meteorite. The preatmospheric radius of Huaxi is ~11 cm, corresponding to ~21 kg. The meteorite experienced a relatively short cosmic‐ray exposure of about 1.6 ± 0.1 Ma. The 4He and 40Ar retention ages are older than 4.6 Ga implying that Huaxi did not degas after thermal metamorphism on its parent body.  相似文献   

16.
On August 19, 2020, at 13:18—UTC, a meteor event ended as a meteorite shower in Santa Filomena, a city in the Pernambuco State, northeast Brazil. The heliocentric orbital parameters resulting from images by cameras of the weather broadcasting system were semimajor axis a = 2.1 ± 0.1 au, eccentricity e = 0.55 ± 0.03, and inclination i = 0.15o ± 0.05. The data identified the body as an Apollo object, an Earth-crossing object with a pericenter interior to the Earth's orbit. The chemical, mineralogical, and petrological evaluations, as well as the physical analysis, followed several traditional techniques. The meteorite was identified as a H5-6 S4 W0 ordinary chondrite genomict breccia. The large amount of metal in the meteorite made a metallographic evaluation based on the opaque phases possible. The monocrystalline kamacite crystals suggest a higher petrological type and the distorted Neumann lines imply at least two different shock events. The absence of the plessite phase shows that the meteorite did not reach the highest shock levels S5 and S6. The well-defined polycrystalline taenite is indicative of petrologic types 4 and 5 due to the conserved internal tetrataenite rim at the boundaries. The presence of polycrystalline taenites and the characteristics of the Agrell Effect suggest that the Santa Filomena meteorite did not reheat above 700°C. The absence of martensite confirms reheating temperatures <800°C and a slow cooling rate. The Ni contents and sizes of the zoned taenite particles indicate a slow cooling rate ranging from 1 to 10 K Myr−1.  相似文献   

17.
We report and describe an L6 ordinary chondrite fall that occurred in Ardón, León province, Spain (longitude 5.5605°W, latitude 42.4364°N) on July 9th, 1931. The 5.5 g single stone was kept hidden for 83 yr by Rosa González Pérez, at the time an 11 yr old who had observed the fall and had recovered the meteorite. According to various newspaper reports, the event was widely observed in Northern Spain. Ardón is a very well‐preserved, fresh, strongly metamorphosed (petrologic type 6), and weakly shocked (S3) ordinary chondrite with well‐equilibrated and recrystallized minerals. The mineral compositions (olivine Fa23.7±0.3, low‐Ca pyroxene Fs20.4±0.2Wo1.5±0.2, plagioclase An10.3±0.5Ab84.3±1.2), magnetic susceptibility (log χ = 4.95 ± 0.05 × 10?9 m3 kg?1), bulk density (3.49 ± 0.05 g   cm?3), grain density (3.58 ± 0.05 g   cm?3), and porosity (2.5 vol%) are typical for L6 chondrites. Short‐lived radionuclides confirm that the meteorite constitutes a recent fall. The 21Ne and 38Ar cosmic ray exposure ages are both about 20–30 Ma, similar to values for many other L chondrites. The cosmogenic 22Ne/21Ne ratio indicates that preatmospheric Ardón was a relatively large body. The fact that the meteorite was hidden in private hands for 83 yr makes one wonder if other meteorite falls may have experienced the same fate, thus possibly explaining the anomalously low number of falls reported in continental Spain in the 20th century.  相似文献   

18.
The Ijopega (Papua New Guinea) meteorite is a new H6 group chondrite fall which contains olivine (Fa 19.9 mole %), bronzite (Fs 17.8 mole %), plagioclase (An 12.1 Or 6.3 Ab 81.6 mole %), diopside, kamacite, taenite, troilite, chromite and whitlockite. The meteorite is extensively recrystallized and brecciated, and shows evidence of moderate shock deformation. Examination of Fe2+ and Mg partitioning between ortho- and clinopyroxene indicates a high equilibration temperature (940° or 880 °C). Chemical analysis shows the meteorite to be rich in S, containing about twice the average H-group abundance. Trace elements, including REE, are in accord with established H-group chondrite abundances.  相似文献   

19.
An assemblage with FeNi metal, troilite, Fe‐Mn‐Na phosphate, and Al‐free chromite was identified in the metal‐troilite eutectic nodules in the shock‐produced chondritic melt of the Yanzhuang H6 meteorite. Electron microprobe and Raman spectroscopic analyses show that a few phosphate globules have the composition of Na‐bearing graftonite (Fe,Mn,Na)3(PO4)2, whereas most others correspond to Mn‐bearing galileiite Na(Fe,Mn)4(PO4)3 and a possible new phosphate phase of Na2(Fe,Mn)17(PO4)12 composition. The Yanzhuang meteorite was shocked to a peak pressure of 50 GPa and a peak temperature of approximately 2000 °C. All minerals were melted after pressure release to form a chondritic melt due to very high postshock heat that brought the chondrite material above its liquidus. The volatile elements P and Na released from whitlockite and plagioclase along with elements Cr and Mn released from chromite are concentrated into the shock‐produced Fe‐Ni‐S‐O melt at high temperatures. During cooling, microcrystalline olivine and pyroxene first crystallized from the chondritic melt, metal‐troilite eutectic intergrowths, and silicate melt glass finally solidified at about 950–1000 °C. On the other hand, P, Mn, and Na in the Fe‐Ni‐S‐O melt combined with Fe and crystallized as Fe‐Mn‐Na phosphates within troilite, while Cr combined with Fe and crystallized as Al‐free chromite also within troilite.  相似文献   

20.
A single piece of meteorite fell on Kamargaon village in the state of Assam in India on November 13, 2015. Based on mineralogical, chemical, and oxygen isotope data, Kamargaon is classified as an L‐chondrite. Homogeneous olivine (Fa: 25 ± 0.7) and low‐Ca pyroxene (Fs: 21 ± 0.4) compositions with percent mean deviation of <2, further suggest that Kamargaon is a coarsely equilibrated, petrologic type 6 chondrite. Kamargaon is thermally metamorphosed with an estimated peak metamorphic temperature of ~800 °C as determined by two‐pyroxene thermometry. Shock metamorphism studies suggest that this meteorite include portions of different shock stages, e.g., S3 and S4 (Stöffler et al. 1991 ); however, local presence of quenched metal‐sulfide melt within shock veins/pockets suggest disequilibrium melting and relatively higher shock stage of up to S5 (Bennett and McSween 1996 ). Based on noble gas isotopes, the cosmic‐ray exposure age is estimated as 7.03 ± 1.60 Ma and nitrogen isotope composition (δ15N = 18‰) also correspond well with the L‐chondrite group. The He‐U, Th, and K‐Ar yield younger ages (170 ± 25 Ma 684 ± 93, respectively) and are discordant. A loss of He during the resetting event is implied by the lower He‐U and Th age. Elemental ratios of trapped Ar, Kr, and Xe can be explained through the presence of a normal Q noble gas component. Relatively low activity of 26Al (39 dpm/kg) and the absence of 60Co activity suggest a likely low shielding depth and envisage a small preatmospheric size of the meteoroid (<10 cm in radius). The Kr isotopic ratios (82Kr/84Kr) further argue that the meteorite was derived from a shallow depth.  相似文献   

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