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1.
Abstract— The Frontier Mountain (FRO) 93001 meteorite is a 4.86 g fragment of an unshocked, medium‐ to coarse‐grained rock from the acapulcoite‐lodranite (AL) parent body. It consists of anhedral orthoenstatite (Fs13.3 ± 0.4Wo3.1 ± 0.2), augite (Fs6.1 ± 0.7Wo42.3 ± 0.9; Cr2O3 = 1.54 ± 0.03), and oligoclase (Ab80.5 ± 3.3Or3.1 ± 0.6) up to >1 cm in size enclosing polycrystalline aggregates of fine‐grained olivine (average grain size: 460 ± 210 μm) showing granoblastic textures, often associated with Fe,Ni metal, troilite, chromite (cr# = 0.91 ± 0.03; fe# = 0.62 ± 0.04), schreibersite, and phosphates. Such aggregates appear to have been corroded by a melt. They are interpreted as lodranitic xenoliths. After the igneous (the term “igneous” is used here strictly to describe rocks or minerals that solidified from molten material) lithology intruding an acapulcoite host in Lewis Cliff (LEW) 86220, FRO 93001 is the second‐known silicate‐rich melt from the AL parent asteroid. Despite some similarities, the silicate igneous component of FRO 93001 (i.e., the pyroxene‐plagioclase mineral assemblage) differs in being coarser‐grained and containing abundant enstatite. Melting‐crystallization modeling suggests that FRO 93001 formed through high‐degree partial melting (≥35 wt%; namely, ≥15 wt% silicate melting and ?20 wt% metal melting) of an acapulcoitic source rock, or its chondritic precursor, at temperatures ≥1200 °C, under reducing conditions. The resulting magnesium‐rich silicate melt then underwent equilibrium crystallization; prior to complete crystallization at ?1040 °C, it incorporated lodranitic xenoliths. FRO 93001 is the highest‐temperature melt from the AL parent‐body so far available in laboratory. The fact that FRO 93001 could form by partial melting and crystallization under equilibrium conditions, coupled with the lack of quench‐textures and evidence for shock deformation in the xenoliths, suggests that FRO 93001 is a magmatic rock produced by endogenic heating rather than impact melting.  相似文献   

2.
Hayabusa‐returned samples offer a unique perspective for understanding the link between asteroids and cosmomaterials available in the laboratory, and provide insights on the early stages of surface space weathering. This study characterizes the mineralogy and the extent of space weathering of the three Itokawa particles RA‐QD02‐0163, RA‐QD02‐0174, and RA‐QD02‐0213 provided by JAXA to our consortium. We report here a series of results based on nondestructive analyses through visible‐near‐infrared reflectance and Raman spectroscopy. Results were obtained on the raw particles, both in their original containers and deposited on diamond windows. Identification of the minerals, characterization of their elemental compositions, and measurements of their relative abundances were led through Raman spectroscopy in punctual and automatic mode. Reflectance spectra in the visible and near‐IR wavelengths constrain the mineralogy of the grains and allow direct comparison with the surface of Itokawa. The spectra reflect the extent of space weathering experienced by the three particles. Particle RA‐QD02‐0163 consists of a heterogeneous mixture of minerals: olivine (Fo76) dominates an assemblage with both Ca‐rich (En50, Wo50) and Ca‐poor (En85) pyroxenes. The elemental compositions of the silicates are consistent with those previously reported for distinct Hayabusa particles. Particles RA‐QD‐0174 and RA‐QD02‐0213 are solely composed of olivine, whose chemical composition is similar to that observed in RA‐QD02‐0163. It has been previously shown that the S‐type asteroid 25143 Itokawa is a breccia of poorly equilibrated LL4 and highly equilibrated LL5 and LL6 materials. The three particles studied here can be related to the least metamorphosed lithology (LL4) based on the high forsterite content of the olivine. Neither carbonaceous matter nor hydrated minerals were detected through Raman on the three allocated particles. The NIR‐VIS reflectance (incidence = 45°, light collection at e = 0°) spectra of the three particles, in particular the 1 μm band, are consistent with the presence of both olivine and pyroxene detected via Raman. The spectra of particles RA‐QD02‐0163 and RA‐QD02‐0213 are also fully compatible with the ground‐based observations of asteroid (25143) Itokawa in terms of both spectral features and slope. By contrast, particle RA‐QD02‐0174 has a similar 1 μm band depth but higher (redder) spectral slope than the surface of Itokawa. This probably reveals a variable extent of space weathering among the regolith particles. RA‐QD02‐0174 may contain a higher amount of nanophase metallic iron and nanophase FeS. Such phases are products by space weathering induced by solar wind, previously detected on other Itokawa particles.  相似文献   

3.
Terrestrial weathering of hot desert achondrite meteorite finds and heterogeneous phase distributions in meteorites can complicate interpretation of petrological and geochemical information regarding parent‐body processes. For example, understanding the effects of weathering is important for establishing chalcophile and siderophile element distributions within sulfide and metal phases in meteorites. Heterogeneous mineral phase distribution in relatively coarsely grained meteorites can also lead to uncertainties relating to compositional representativeness. Here, we investigate the weathering and high‐density (e.g., sulfide, spinel, Fe‐oxide) phase distribution in sections of ultramafic achondrite meteorite Northwest Africa (NWA) 4872. NWA 4872 is an olivine‐rich brachinite (Fo63.6 ± 0.5) with subsidiary pyroxene (Fs9.7 ± 0.1Wo46.3 ± 0.2), Cr‐spinel (Cr# = 70.3 ± 1.1), and weathered sulfide and metal. Raman mapping confirms that weathering has redistributed sulfur from primary troilite, resulting in the formation of Fe‐oxide (‐hydroxide) and marcasite (FeS2). From Raman mapping, NWA 4872 is composed of olivine (89%), Ca‐rich pyroxene (0.4%), and Cr‐spinel (1.1%), with approximately 7% oxidized metal and sulfide and 2.3% marcasite‐dominated sulfide. Microcomputed tomography (micro‐CT) observations reveal high‐density regions, demonstrating heterogeneities in mineral distribution. Precision cutting of the largest high‐density region revealed a single 2 mm Cr‐spinel grain. Despite the weathering in NWA 4872, rare earth element (REE) abundances of pyroxene determined by laser‐ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) indicate negligible modification of these elements in this mineral phase. The REE abundances of mineral grains in NWA 4872 are consistent with formation of the meteorite as the residuum of the partial melting process that occurred on its parent body. LA‐ICP‐MS analyses of sulfide and alteration products demonstrate the mobility of Re and/or Os; however, highly siderophile element (HSE) abundance patterns remain faithful recorders of processes acting on the brachinite parent body(ies). Detailed study of weathering and phase distribution offers a powerful tool for assessing the effects of low‐temperature alteration and for identifying robust evidence for parent‐body processes.  相似文献   

4.
Abstract– Queen Alexandra Range (QUE) 94204, an enstatite achondrite, is a coarse‐grained, highly recrystallized, chondrule‐free and unbrecciated rock dominated (about 70 vol%) by anhedral, equigranular crystals of orthoenstatite of nearly endmember composition (Fs0.1–0.4, Wo0.3–0.4) with interstitial plagioclase, kamacite, and troilite. Abundance of approximately 120° triple junctions and the close association of metal–sulfide and plagioclase‐rich melts indicate that QUE 94204 has undergone limited partial melting with inefficient melt extraction. Mineral chemistry indicates a high degree of thermal metamorphism. Kamacite in QUE 94204 contains between 2.09 and 2.55 wt% Si, similar to highly metamorphosed EL chondrites. Plagioclase has between 4.31 and 6.66 wt% CaO, higher than other E chondrites but closer in composition to plagioclase from metamorphosed EL chondrites. QUE 94204 troilite contains up to 2.55 wt% Ti, consistent with extensive thermal metamorphism of an E chondrite‐like precursor. Results presented in this study indicate that QUE 94204 is the result of low degree, (about 5–20 vol%, probably toward the lower end of this range) partial melting of an E chondrite protolith. Textural and chemical evidence suggests that during the metamorphism of QUE 94204, melts formed first at the Fe,Ni‐FeS cotectic near approximately 900 °C, followed by plagioclase‐pyroxene silicate partial melts near approximately 1100 °C. Neither the Fe,Ni‐FeS nor the plagioclase‐pyroxene melts were efficiently segregated or extracted. QUE 94204 belongs to a grouplet of similar “primitive enstatite achondrites” that are analogous to the acapulcoites‐lodranites, but that have resulted from the partial melting of an E chondrite‐like protolith.  相似文献   

5.
We report on the petrography and mineralogy of three types of silicate veinlets in the brecciated eucrite Northwest Africa (NWA) 1109. These include Fe‐rich olivine, Mg‐rich olivine, and pyroxene veinlets. The Fe‐rich olivine veinlets mainly infill fractures in pyroxene and also occur along grain boundaries between pyroxene and plagioclase crystals, in both nonequilibrated and equilibrated lithic clasts. The host pyroxene of Fe‐rich olivine veinlets shows large chemical variations between and within grains. The Fe‐rich olivine veinlets also contain fine‐grained Fe3+‐bearing chromite, highly calcic plagioclase, merrillite, apatite, and troilite. Based on texture and mineral chemistry, we argue that the formation of Fe‐rich olivine was related to fluid deposition at relatively high temperatures. However, the source of Fe‐rich olivine in the veinlets remains unclear. Magnesium‐rich olivine veinlets were found in three diogenitic lithic clasts. In one of these, the Mg‐rich olivine veinlets only occur in one of the fine‐grained interstitial regions and extend into fractures within surrounding coarse‐grained orthopyroxene. Based on the texture of the interstitial materials, we suggest that the Mg‐rich olivine veinlets formed by shock‐induced localized melting and recrystallization. Pyroxene veinlets were only observed in one clast where they infill fractures within large plagioclase grains and are associated with fine‐grained pyroxene surrounding coarse‐grained pyroxene. The large chemical variations in pyroxene and the fracture‐filling texture indicate that the pyroxene veinlets might also have formed by shock‐induced localized melting and rapid crystallization. Our study demonstrates that silicate veinlets formed by a range of different surface processes on the surface of Vesta.  相似文献   

6.
Abstract— Dar al Gani 476, the 13th martian meteorite, was recovered from the Sahara in 1998. It is a basaltic shergottitic rock composed of olivine megacrysts reaching 5 mm (24 vol%) set in a finegrained groundmass of pyroxene (59 vol%) and maskelynitized plagioclase (12 vol%) with minor amounts of accessory phases (spinel, merrillite, ilmenite). Dar al Gani 476 is similar to lithology A of Elephant Moraine A79001 (EETA79001) in petrography and mineralogy, but is distinct in several aspects. Low‐Ca pyroxenes in the Dar al Gani 476 groundmass are more magnesian (En76Fs21 Wo3～En58Fs30Wo12) than those in lithology A of EETA79001 (En73Fs22Wo5～En45Fs43Wo12), rather similar to pyroxenes in lherzolitic martian meteorites (En76Fs21 Wo3～En63Fs22Wo15). Dar al Gani 476 olivine is less magnesian and shows a narrower compositional range (Fo76‐58) than EETA79001 olivine (Fo81‐53), and is also similar to olivines in lherzolitic martian meteorites (Fo74‐65). The orthopyroxene‐olivine‐chromite xenolith typical in the lithology A of EETA79001 is absent in Dar al Gani 476. It seems that Dar al Gani 476 crystallized from a slightly more primitive mafic magma than lithology A of EETA79001 and several phases (olivine, pyroxene, chromite, and ilmenite) in Dar al Gani 476 may have petrogenetic similarities to those of lherzolitic martian meteorites. Olivine megacrysts in Dar al Gani 476 are in disequilibrium with the bulk composition. The presence of fractured olivine grains in which the most Mg‐rich parts are in contact with the groundmass suggests that little diffusive modification of original olivine compositions occurred during cooling. This observation enabled us to estimate the cooling rates of Dar al Gani 476 and EETA79001 olivines, giving similar cooling rates of 0.03‐3 °C/h for Dar al Gani 476 and 0.05‐5 °C/h for EETA79001. This suggests that they were cooled near the surface (burial depth shallower than about 3 m at most), probably in lava flows during crystallization of groundmass. As is proposed for lithology A of EETA79001, it may be possible to consider that Dar al Gani 476 has an impact melt origin, a mixture of martian lherzolite and other martian rock (Queen Alexandra Range 94201, nakhlites?).  相似文献   

7.
Abstract– Metamorphosed clasts in the CV carbonaceous chondrite breccias Mokoia and Yamato‐86009 (Y‐86009) are coarse‐grained, granular, polymineralic rocks composed of Ca‐bearing (up to 0.6 wt% CaO) ferroan olivine (Fa34–39), ferroan Al‐diopside (Fs9–13Wo47–50, approximately 2–7 wt% Al2O3), plagioclase (An37–84Ab63–17), Cr‐spinel (Cr/(Cr + Al) = 0.19–0.45, Fe/(Fe + Mg) = 0.60–0.79), nepheline, pyrrhotite, pentlandite, Ca‐phosphate, and rare grains of Ni‐rich taenite; low‐Ca pyroxene is absent. Most clasts have triple junctions between silicate grains, indicative of prolonged thermal annealing. Based on the olivine‐spinel and pyroxene thermometry, the estimated metamorphic temperature recorded by the clasts is approximately 1100 K. Few clasts experienced thermal metamorphism to a lower degree and preserved chondrule‐like textures. The Mokoia and Y‐86009 clasts are mineralogically unique and different from metamorphosed chondrites of known groups (H, L, LL, R, EH, EL, CO, CK) and primitive achondrites (acapulcoites, brachinites, lodranites). On a three‐isotope oxygen diagram, compositions of olivine in the clasts plot along carbonaceous chondrite anhydrous mineral line and the Allende mass‐fractionation line, and overlap with those of the CV chondrule olivines; the Δ17O values of the clasts range from about ?4.3‰ to ?3.0‰. We suggest that the clasts represent fragments of the CV‐like material that experienced metasomatic alteration, high‐temperature metamorphism, and possibly melting in the interior of the CV parent asteroid. The lack of low‐Ca pyroxene in the clasts could be due to its replacement by ferroan olivine during iron‐alkali metasomatic alteration or by high‐Ca ferroan pyroxene during melting under oxidizing conditions.  相似文献   

8.
Abstract— In this paper we reconstruct the heterogeneous lithology of an unusual intrusive rock from the acapulcoite‐lodranite (AL) parent asteroid on the basis of the petrographic analysis of 5 small (<8.3 g) meteorite specimens from the Frontier Mountain ice field (Antarctica). Although these individual specimens may not be representative of the parent‐rock lithology due to their relatively large grain size, by putting together evidence from various thin sections and literature data we conclude that Frontier Mountain (FRO) 90011, FRO 93001, FRO 99030, and FRO 03001 are paired fragments of a medium‐ to coarse‐grained igneous rock which intrudes a lodranite and entrains xenoliths. The igneous matrix is composed of enstatite (Fs13.3 ± 0.4 Wo3.1 ± 0.2), Cr‐rich augite (Fs6.1 ± 0.7 Wo42.3 ± 0.9), and oligoclase (Ab80.5 ± 3.3 Or3.2 ± 0.6). The lodranitic xenoliths show a fine‐grained (average grain size 488 ± 201 μm) granoblastic texture and consist of olivine Fa9.5 ± 0.4 and Fe,Ni metal and minor amounts of enstatite Fs12.7 ± 0.4 Wo1.8 ± 0.1, troilite, chromite, schreibersite, and Ca‐phosphates. Crystals of the igneous matrix and lodranitic xenoliths are devoid of shock features down to the scanning electron microscope scale. From a petrogenetic point of view, the lack of shock evidence in the lodranitic xenoliths of all the studied samples favors the magmatic rather than the impact melting origin of this rock. FRO 95029 is an acapulcoite and represents a separate fall from the AL parent asteroid, i.e., it is not a different clast entrained by the FRO 90011, FRO 93001, FRO 99030, and FRO 03001 melt, as in genomict breccias common in the meteoritic record. The specimen‐to‐meteorite ratio for the AL meteorites so far found at Frontier Mountain is thus 2.5.  相似文献   

9.
Abstract– Northwest Africa (NWA) 4797 is an ultramafic Martian meteorite composed of olivine (40.3 vol%), pigeonite (22.2%), augite (11.9%), plagioclase (9.1%), vesicles (1.6%), and a shock vein (10.3%). Minor phases include chromite (3.4%), merrillite (0.8%), and magmatic inclusions (0.4%). Olivine and pyroxene compositions range from Fo66–72,En58–74Fs19–28Wo6–15, and En46–60Fs14–22Wo34–40, respectively. The rock is texturally similar to “lherzolitic” shergottites. The oxygen fugacity was QFM?2.9 near the liquidus, increasing to QFM?1.7 as crystallization proceeded. Shock effects in olivine and pyroxene include strong mosaicism, grain boundary melting, local recrystallization, and pervasive fracturing. Shock heating has completely melted and vesiculated igneous plagioclase, which upon cooling has quench‐crystallized plagioclase microlites in glass. A mm‐size shock melt vein transects the rock, containing phosphoran olivine (Fo69–79), pyroxene (En44–51Fs14–18Wo30–42), and chromite in a groundmass of alkali‐rich glass containing iron sulfide spheres. Trace element analysis reveals that (1) REE in plagioclase and the shock melt vein mimics the whole rock pattern; and (2) the reconstructed NWA 4797 whole rock is slightly enriched in LREE relative to other intermediate ultramafic shergottites, attributable to local mobilization of melt by shock. The shock melt vein represents bulk melting of NWA 4797 injected during pressure release. Calculated oxygen fugacity for NWA 4797 indicates that oxygen fugacity is decoupled from incompatible element concentrations. This is attributed to subsolidus re‐equilibration. We propose an alternative nomenclature for “lherzolitic” shergottites that removes genetic connotations. NWA 4797 is classified as an ultramafic poikilitic shergottite with intermediate trace element characteristics.  相似文献   

10.
Tissint, a new unaltered piece of Martian volcanic materials, is the most silica‐poor and Mg‐Fe‐rich igneous rock among the “depleted” olivine‐phyric shergottites. Fe‐Mg zoning of olivine suggests equilibrium growth (<0.1 °C h?1) in the range of Fo80–56 and olivine overgrowth (Fo55–18) through a process of rapid disequilibrium (~1.0–5.0 °C h?1). The spatially extended (up to 600 μm) flat‐top Fe‐Mg profiles of olivine indicates that the early‐stage cooling rate of Tissint was slower than the other shergottites. The chemically metastable outer rim of olivine (55) consists of oscillatory phosphorus zoning at the impact‐induced melt domains and grew rapidly compared to the early to intermediate‐stage crystallization of the Tissint bulk. High‐Ca pyroxene to low‐Ca pyroxene and high‐Ca pyroxene to plagioclase ratios of Tissint are more comparable to the enriched basaltic and enriched olivine‐phyric shergottites. Dominance of augite over plagioclase induced augite to control the Ca‐buffer in the residual melt suppressing the plagioclase crystallization, which also caused a profound effect on the Al‐content in the late‐crystallized pyroxenes. Mineral chemical stability, phase‐assemblage saturation, and pressure–temperature path of evolution indicates that the parent magma entered the solidus and left the liquidus field at a depth of 40–80 km in the upper mantle. Petrogenesis of Tissint appears to be similar to LAR 06319, an enriched olivine‐phyric shergottite, during the early to intermediate stage of crystallization. A severe shock‐induced deformation resulted in remelting (10–15 vol%), recrystallization (most Fe‐rich phases), and exhumation of Tissint in a time scale of 1–8 yr. Tissint possesses some distinct characteristics, e.g., impact‐induced melting and deformation, forming phosphorus‐rich recrystallization rims of olivine, and shock‐induced melt domains without relative enrichment of LREEs compared to the bulk; and shared characteristics, e.g., modal composition and magmatic evolution with the enriched basaltic shergottites, evidently reflecting unique mantle source in comparison to the clan of the depleted members.  相似文献   

11.
Abstract— Queen Alexandra Range (QUE) 93148 is a small (1.1 g) olivine‐rich achondrite (mg 86) that contains variable amounts of orthopyroxene (mg 87) and kamacite (6.7 wt% Ni), with minor augite. Olivine in QUE 93148 contains an unusual suite of inclusions: (1) 5 × 100 μm sized lamellae with a CaO‐ and Cr2O3‐rich (～10 and 22 wt%, respectively) composition that may represent a submicrometer‐scale intergrowth of chromite and pyroxene(s); (2) 75 × 500 μm sized lamellar symplectites composed of chromite and two pyroxenes, with minor metal; (3) 15–20 μm sized, irregularly‐shaped symplectites composed of chromite and pyroxene(s); (4) 100–150 μm sized, elliptical inclusions composed of chromite, two pyroxenes, metal, troilite, and rare whitlockite. Type 1, 2, and 3 inclusions probably formed by exsolution from the host olivine during slow cooling, whereas type 4 more likely resulted from early entrapment of silicate and metallic melts followed by closed‐system oxidation. Queen Alexandra Range 93148 can be distinguished from most other olivine‐rich achondrites (ureilites, winonaites, lodranites, acapulcoites, brachinites, Eagle‐Station‐type pallasites, and pyroxene pallasites), as well as from mesosiderites, by some or all of the following properties: O‐isotopic composition, Fe‐Mn‐Mg relations of olivine, CaO and Cr2O3 contents of olivine, orthopyroxene compositions, molar Cr/(Cr + Al) ratios of chromite, metal composition, texture, and the presence of the inclusions. In terms of many of these properties, it shows an affinity to main‐group pallasites. Nevertheless, it cannot be identified as belonging to this group. Meteorite QUE 93148 appears to be a unique achondrite. Possibly it should be considered to be a pyroxene pallasite that is genetically related to main‐group pallasites. Alternatively, it may be derived from the mantle of the pallasite (howardite‐eucrite‐diogenite?) parent body.  相似文献   

12.
We performed a petrologic, geochemical, and oxygen isotopic study of the lowest FeO ordinary chondrite (OC), Yamato (Y) 982717. Y 982717 shows a chondritic texture composed of chondrules and chondrule fragments, and mineral fragments set in a finer grained, clastic matrix, similar to H4 chondrites. The composition of olivine (Fa11.17 ± 0.48 (1σ)) and low‐Ca pyroxene (Fs11.07 ± 0.98 (1σ)Wo0.90 ± 0.71(1σ)) is significantly more magnesian than those of typical H chondrites (Fa16.0‐20, Fs14.5‐18.0), as well as other known low‐FeO OCs (Fa12.8‐16.7; Fs13‐16). However, the bulk chemical composition of Y 982717, in particular lithophile and moderately volatile elements, is within the range of OCs. The bulk siderophile element composition (Ni, Co) is within the range of H chondrites and distinguishable from L chondrites. The O‐isotopic composition is also within the range of H chondrites. The lack of reduction textures indicates that the low olivine Fa content and low‐Ca pyroxene Fs content are characteristics of the precursor materials, rather than the result of reduction during thermal metamorphism. We suggest that the H chondrites are more compositionally diverse than has been previously recognized.  相似文献   

13.
Abstract— Antarctic meteorite Miller Range (MIL) 03346 is a nakhlite composed of 79% clinopyroxene, ?1% olivine, and 20% vitrophyric intercumulus material. We have performed a petrological and geochemical study of MIL 03346, demonstrating a petrogenetic history similar to previously discovered nakhlites. Quantitative textural study of MIL 03346 indicates long (>1 × 101 yr) residence times for the cumulus augite, whereas the skeletal Fe‐Ti oxide, fayalite, and sulfide in the vitrophyric intercumulus matrix suggest rapid cooling, probably as a lava flow. From the relatively high forsterite contents of olivine (up to Fo43) compared with other nakhlites and compositions of augite cores (Wo38–42En35–40Fs22–28) and their hedenbergite rims, we suggest that MIL 03346 is part of the same or a similar Martian cumulate‐rich lava flow as other nakhlites. However, MIL 03346 has experienced less equilibration and faster cooling than other nakhlites discovered to date. Calculated trace element concentrations based upon modal abundances of MIL 03346 and its constituent minerals are identical to whole rock trace element abundances. Parental melts for augite have REE patterns that are approximately parallel with whole rock and intercumulus melt using experimentally defined partition coefficients. This parallelism reflects closed‐system crystallization for MIL 03346, where the only significant petrogenetic process between formation of augite and eruption and emplacement of the nakhlite flow has been fractional crystallization. A model for the petrogenesis of MIL 03346 and the nakhlites (Nakhla, Governador Valadares, Lafayette, Yamato‐000593, Northwest Africa (NWA) 817, NWA 998) would include: 1) partial melting and ascent of melt generated from a long‐term LREE depleted mantle source, 2) crystallization of cumulus augite (± olivine, ± magnetite) in a shallow‐level Martian magma chamber, 3) eruption of the crystal‐laden nakhlite magma onto the surface of Mars, 4) cooling, crystal settling, overgrowth, and partial equilibration to different extents within the flow, 5) secondary alteration through hydrothermal processes, possibly immediately succeeding or during emplacement of the flow. This model might apply to single—or multiple—flow models for the nakhlites. Ultimately, MIL 03346 and the other nakhlites preserve a record of magmatic processes in volcanic rocks on Mars with analogous petrogenetic histories to pyroxene‐rich terrestrial lava flows and to komatiites.  相似文献   

14.
Abstract— The lherzolitic Martian meteorite Northwest Africa (NWA) 1950 consists of two distinct zones: 1) low‐Ca pyroxene poikilically enclosing cumulate olivine (Fo70–75) and chromite, and 2) areas interstitial to the oikocrysts comprised of maskelynite, low‐ and high‐Ca pyroxene, cumulate olivine (Fo68–71) and chromite. Shock metamorphic effects, most likely associated with ejection from the Martian subsurface by large‐scale impact, include mechanical deformation of host rock olivine and pyroxene, transformation of plagioclase to maskelynite, and localized melting (pockets and veins). These shock effects indicate that NWA 1950 experienced an equilibration shock pressure of 35–45 GPa. Large (millimeter‐size) melt pockets have crystallized magnesian olivine (Fo78–87) and chromite, embedded in an Fe‐rich, Al‐poor basaltic to picro‐basaltic glass. Within the melt pockets strong thermal gradients (minimum 1 °C/μm) existed at the onset of crystallization, giving rise to a heterogeneous distribution of nucleation sites, resulting in gradational textures of olivine and chromite. Dendritic and skeletal olivine, crystallized in the melt pocket center, has a nucleation density (1.0 × 103 crystals/mm2) that is two orders of magnitude lower than olivine euhedra near the melt margin (1.6 × 105 crystals/mm2). Based on petrography and minor element abundances, melt pocket formation occurred by in situ melting of host rock constituents by shock, as opposed to melt injected into the lherzolitic target. Despite a common origin, NWA 1950 is shocked to a lesser extent compared to Allan Hills (ALH) 77005 (45–55 GPa). Assuming ejection in a single shock event by spallation, this places NWA 1950 near to ALH 77005, but at a shallower depth within the Martian subsurface. Extensive shock melt networks, the interconnectivity between melt pockets, and the ubiquitous presence of highly vesiculated plagioclase glass in ALH 77005 suggests that this meteorite may be transitional between discreet shock melting and bulk rock melting.  相似文献   

15.
Abstract— On the night of March 26, 2003, a large meteorite broke up and fell upon the south suburbs of Chicago. The name Park Forest, for the village that is at the center of the strewnfield, has been approved by the nomenclature committee of the Meteoritical Society. Satellite data indicate that the bolide traveled from the southwest toward the northeast. The strewnfield has a southeast‐northwest trend; however, this is probably due to the effects of strong westerly winds at high altitudes. Its very low 56Co and very high 60Co activities indicate that Park Forest had a preatmospheric mass that was at least ～900 kg and could have been as large as ～7 times 103 kg, of which only ～30 kg have been recovered. The average compositions of olivine and low‐Ca pyroxene, Fa24.7 ± 1.1 and Fs20.8 ± 0.7, respectively, and its bulk oxygen isotopic composition, δ18O = +4.68%o, δ17O = +3.44%o, show that Park Forest is an L chondrite. The ferromagnesian minerals are well equilibrated, chondrules are easily recognized, and maskelynite is mostly ≤50 μm across. Based on these observations, we classify Park Forest as type 5. The meteorite has been strongly shocked, and based on the presence of maskelynite, mosaicism and planar deformation features in olivine, undulatory extinction in pyroxene, and glassy veins, the shock stage is S5. The meteorite is a monomict breccia, consisting of light‐colored, angular to rounded clasts in a very dark host. The light and dark lithologies have essentially identical mineral and oxygen isotopic compositions. Their striking difference in appearance is due to the presence of a fine, pervasive network of sulfide veins in the dark lithology, resulting in very short optical path lengths. The dark lithology probably formed from the light lithology in an impact that formed a sulfide‐rich melt and injected it into cracks.  相似文献   

16.
Abstract— The CV (Vigarano‐type) chondrites are a petrologically diverse group of meteorites that are divided into the reduced and the Bali‐like and Allende‐like oxidized subgroups largely based on secondary mineralogy (Weisberg et al., 1997; Krot et al., 1998b). Some chondrules and calcium‐aluminum‐rich inclusions (CAIs) in the reduced CV chondrite Vigarano show alteration features similar to those in Allende: metal is oxidized to magnetite; low‐Ca pyroxene, forsterite, and magnetite are rimmed and veined by ferrous olivine (Fs40–50); and plagioclase mesostases and melilite are replaced by nepheline and sodalite (Sylvester et al., 1993; Kimura and Ikeda, 1996, 1997, 1998). Our petrographic observations indicate that Vigarano also contains individual chondrules, chondrule fragments, and lithic clasts of the Bali‐like oxidized CV materials. The largest lithic clast (about 1 times 2 cm in size) is composed of opaque matrix, type‐I chondrules (400–2000 μm in apparent diameter) surrounded by coarse‐grained and fine‐grained rims, and rare CAIs. The matrix‐chondrule ratio is about 1.1. Opaque nodules in chondrules in the clast consist of Cr‐poor and Cr‐rich magnetite, Ni‐ and Co‐rich metal, Ni‐poor and Ni‐rich sulfide; low‐Ni metal nodules occur only inside chondrule phenocrysts. Chromium‐poor magnetite is preferentially replaced by fayalite. Chondrule mesostases are replaced by phyllosilicates; low‐Ca pyroxene and olivine phenocrysts appear to be unaltered. Matrix in the clast consists of very fine‐grained (<1 μm) ferrous olivine, anhedral fayalite grains (Fa80–100), rounded objects of porous Ca‐Fe‐rich pyroxenes (Fs10–50Wo50), Ni‐poor sulfide, Ni‐ and Co‐rich metal, and phyllosilicates; magnetite is rare. On the basis of the presence of the Bali‐like lithified chondritic clast—in addition to individual chondrules and CAIs of both Bali‐like and Allende‐like materials—in the reduced CV chondrite Vigarano, we infer that (1) all three types of materials were mixed during regolith gardening on the CV asteroidal body, and (2) the reduced and oxidized CV materials may have originated from a single, heterogeneously altered asteroid.  相似文献   

17.
Abstract— We describe the mineralogy, petrology, oxygen, and magnesium isotope compositions of three coarse‐grained, igneous, anorthite‐rich (type C) Ca‐Al‐rich inclusions (CAIs) (ABC, TS26, and 93) that are associated with ferromagnesian chondrule‐like silicate materials from the CV carbonaceous chondrite Allende. The CAIs consist of lath‐shaped anorthite (An99), Cr‐bearing Al‐Ti‐diopside (Al and Ti contents are highly variable), spinel, and highly åkermanitic and Na‐rich melilite (Åk63–74, 0.4–0.6 wt% Na2O). TS26 and 93 lack Wark‐Lovering rim layers; ABC is a CAI fragment missing the outermost part. The peripheral portions of TS26 and ABC are enriched in SiO2 and depleted in TiO2 and Al2O3 compared to their cores and contain relict ferromagnesian chondrule fragments composed of forsteritic olivine (Fa6–8) and low‐Ca pyroxene/pigeonite (Fs1Wo1–9). The relict grains are corroded by Al‐Ti‐diopside of the host CAIs and surrounded by haloes of augite (Fs0.5Wo30–42). The outer portion of CAI 93 enriched in spinel is overgrown by coarse‐grained pigeonite (Fs0.5–2Wo5–17), augite (Fs0.5Wo38–42), and anorthitic plagioclase (An84). Relict olivine and low‐Ca pyroxene/pigeonite in ABC and TS26, and the pigeonite‐augite rim around 93 are 16O‐poor (Δ17O ～ ?1‰ to ?8‰). Spinel and Al‐Ti‐diopside in cores of CAIs ABC, TS26, and 93 are 16O‐enriched (Δ17O down to ?20‰), whereas Al‐Ti‐diopside in the outer zones, as well as melilite and anorthite, are 16O‐depleted to various degrees (Δ17O = ?11‰ to 2‰). In contrast to typical Allende CAIs that have the canonical initial 26Al/27Al ratio of ～5 × 10?5 ABC, 93, and TS26 are 26Al‐poor with (26Al/27Al)0 ratios of (4.7 ± 1.4) × 10?6 (1.5 ± 1.8) × 10?6 <1.2 × 10?6 respectively. We conclude that ABC, TS26, and 93 experienced remelting with addition of ferromagnesian chondrule silicates and incomplete oxygen isotopic exchange in an 16O‐poor gaseous reservoir, probably in the chondrule‐forming region. This melting episode could have reset the 26Al‐26Mg systematics of the host CAIs, suggesting it occurred ～2 Myr after formation of most CAIs. These observations and the common presence of relict CAIs inside chondrules suggest that CAIs predated formation of chondrules.  相似文献   

18.
Abstract— Amoeboid olivine aggregates (AOAs) from the reduced CV chondrites Efremovka, Leoville and Vigarano are irregularly‐shaped objects, up to 5 mm in size, composed of forsteritic olivine (Fa<10) and a refractory, Ca, Al‐rich component. The AOAs are depleted in moderately volatile elements (Mn, Cr, Na, K), Fe, Ni‐metal and sulfides and contain no low‐Ca pyroxene. The refractory component consists of fine‐grained calcium‐aluminum‐rich inclusions (CAIs) composed of Al‐diopside, anorthite (An100), and magnesium‐rich spinel (～1 wt% FeO) or fine‐grained intergrowths of these minerals; secondary nepheline and sodalite are very minor. This indicates that AOAs from the reduced CV chondrites are more pristine than those from the oxidized CV chondrites Allende and Mokoia. Although AOAs from the reduced CV chondrites show evidence for high‐temperature nebular annealing (e.g., forsterite grain boundaries form 120° triple junctions) and possibly a minor degree of melting of Al‐diopside‐anorthite materials, none of the AOAs studied appear to have experienced extensive (>50%) melting. We infer that AOAs are aggregates of high‐temperature nebular condensates, which formed in CAI‐forming regions, and that they were absent from chondrule‐forming regions at the time of chondrule formation. The absence of low‐Ca pyroxene and depletion in moderately volatile elements (Mn, Cr, Na, K) suggest that AOAs were either removed from CAI‐forming regions prior to condensation of these elements and low‐Ca pyroxene or gas‐solid condensation of low‐Ca‐pyroxene was kinetically inhibited.  相似文献   

19.
Abstract— We have investigated the mineralogy, petrography, bulk chemistry, and light element isotope composition of the ungrouped chondrites North West Africa (NWA) 1152 and Sahara 00182. NWA 1152 contains predominantly type 1 porphyritic olivine (PO) and porphyritic olivinepyroxene (POP) chondrules. Chondrule silicates are magnesium‐rich (Fo98.8 ± 1.2, n = 36; Fs2.3 ± 2.1 Wo1.2 ± 0.3, n = 23). Matrix comprises ?40 vol% of the sample and is composed of a micron sized silicate groundmass with larger silicate, sulfide, magnetite, and Fe‐Ni metal (Ni ?50 wt%) grains. Phyllosilicates were not observed in the matrix. Refractory inclusions are rare (0.3 vol%) and are spinel pyroxene aggregates or amoeboid olivine aggregates; melilite is absent from the refractory inclusions. Sahara 00182 contains predominantly type 1 PO chondrules, POP chondrules are less common. Most chondrules contain blebs of, and are often rimmed with, Fe‐Ni metal and sulfide. Chondrule phenocrysts are magnesium‐rich (Fo92.2 ± 0.6, n = 129; Fs4.4 ± 1.8 Wo1.3 ± 1.1, n = 16). Matrix comprises ?30 vol% of the meteorite and is predominantly sub‐micron silicates, with rare larger silicate gains. Matrix Fe‐Ni metal (mean Ni = 5.8 wt%) and sulfide grains are up to mm scale. No phyllosilicates were observed in the matrix. Refractory inclusions are rare (1.1 vol%) and melilite is absent. The oxygen isotope composition of NWA 1152 falls within the range of the CV chondrites with δ17O = ?3.43%0 δ18O = 0.70%0 and is similar to Sahara 00182, δ17O = ?3.89%0, δ18O = ?0.19%0 (Grossman and Zipfel 2001). Based on mineralogical and petrographic characteristics, we suggest NWA 1152 and Sahara 00182 show many similarities with the CR chondrites, however, oxygen isotopes suggest affinity with the CVs. Thus, neither sample can be assigned to any of the currently known carbonaceous chondrite groups based on traditionally recognized characteristics. Both samples demonstrate the complexity of inter‐ and intra‐group relationships of the carbonaceous chondrites. Whatever their classification, N WA 1152 and Sahara 00182 represent a source of relatively pristine solar system material.  相似文献   

20.
Abstract— Queen Alexandra Range (QUE) 97990 (CM2.6) is among the least‐altered CM chondrites known. It contains 1.8 vol% refractory inclusions; 40 were studied from a single thin section. Inclusion varieties include simple, banded and nodular structures as well as simple and complex distended objects. The inclusions range in mean size from 30 to 530 μm and average 130 ± 90 μm. Many inclusions contain 25 ± 15 vol% phyllosilicate (predominantly Mg‐Fe serpentine); several contain small grains of perovskite. In addition to phyllosilicate, the most abundant inclusions in QUE 97990 consist mainly of spinel‐pyroxene (35%), followed by spinel (20%), spinel‐pyroxene‐olivine (18%), pyroxene (12%), pyroxene‐olivine (8%) and hibonite ± spinel (8%). Four pyroxene phases occur: diopside, Al‐rich diopside (with ≥ 8.0 wt% Al2O3), Al‐Ti diopside (i.e., fassaite), and (in two inclusions) enstatite. No inclusions contain melilite. Aqueous alteration of refractory inclusions transforms some phases (particularly melilite) into phyllosilicate; some inclusions broke apart during alteration. Melilite‐free, phyllosilicate‐bearing, spinel inclusions probably formed from pristine, phyllosilicate‐free inclusions containing both melilite and spinel. Sixty‐five percent of the refractory inclusions in QUE 97990 appear to be largely intact; the major exception is the group of spinel inclusions, all of which are fragments. Whereas QUE 97990 contains about 50 largely intact refractory inclusions/cm2, estimates from literature data imply that more‐altered CM chondrites have lower modal abundances (and lower number densities) of refractory inclusions: Mighei (CM ? 2.3) contains roughly 0.3–0.6 vol% inclusions (?10 largely intact inclusions/cm2); Cold Bokkeveld (CM2.2) contains ?0.01 vol% inclusions (on the order of 6 largely intact inclusions/cm2).  相似文献   

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