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1.
Abstract— Spherical carbonate globules of similar composition, size, and radial Ca‐, Mg‐, and Fe‐zonation to those in martian meteorite Allan Hills (ALH) 84001 were precipitated from Mg‐rich, supersaturated solutions of Ca‐Mg‐Fe‐CO2‐H2O at 150 °C. The supersaturated solutions (pH ? 6–7) were prepared at room temperature and contained in TeflonTM‐lined stainless steel vessels, which were sealed and heated to 150 °C for 24 h. Experiments were also conducted at 25 °C and no globules comparable to those of ALH 84001 were precipitated. Instead, amorphous Fe‐rich carbonates were formed after 24 h and Mg‐Fe calcites formed after 96 h. These experiments suggest a possible low‐temperature inorganic origin for the carbonates in martian meteorite ALH 84001.  相似文献   

2.
Abstract— We present a new single‐crystal X‐ray diffraction (XRD) study performed on a suite of six orthopyroxene grains from the low‐shocked H6 Trenzano meteorite. The quenched intracrystalline Fe2+‐Mg ordering state in orthopyroxene preserves the memory of the cooling rate near closure temperature Tc, thus yielding useful constraints on the last thermal event undergone by the host rock. The orthopyroxene Tc of 522 ± 13 °C, calculated using a new calibration equation obtained by Stimpfl (2005b), is higher than in previously published H chondrite data. The orthopyroxene cooling rate at this Tc is about 100 °C/kyr. This fast rate is inconsistent with the much slower cooling rate expected for H6 in the onion shell structural and thermal model of chondrite parent bodies. A petrographic study carried out at the same time indicated that the Trenzano meteorite is an H5 chondrite and not an H6 chondrite, as it is officially classified. Furthermore, the two‐pyroxene equilibrium temperature of Trenzano (824 ± 24 °C), calculated with QUILF95, is similar to the two‐pyroxene temperature of 750–840 °C obtained for the Carcote (H5) chondrite (Kleinschrot and Okrusch 1999).  相似文献   

3.
Abstract Shock recovery experiments to determine whether magnetite could be produced by the decomposition of iron‐carbonate were initiated. Naturally occurring siderite was first characterized by a variety of techniques to be sure that the starting material did not contain detectable magnetite. Samples were shocked in tungsten‐alloy holders (W = 90%, Ni = 6%, Cu = 4%) to further ensure that any iron phases in the shock products were contributed by the siderite rather than the sample holder. Each sample was shocked to a specific pressure between 30 to 49 GPa. Transformation of siderite to magnetite as characterized by TEM was found in the 49 GPa shock experiment. Compositions of most magnetites are >50% Fe+2 in the octahedral site of the inverse spinel structure. Magnetites produced in shock experiments display the same range of sizes (?50–100 nm), compositions (100% magnetite to 80% magnetite‐20% magnesioferrite), and morphologies (equant, elongated, euhedral to subhedral) as magnetites synthesized by Golden et al. (2001) and as the magnetites in Martian meteorite Allan Hills (ALH) 84001. Fritz et al. (2005) previously concluded that ALH 84001 experienced ?32 GPa pressure and a resultant thermal pulse of ?100–110°C. However, ALH 84001 contains evidence of local temperature excursions high enough to melt feldspar, pyroxene, and a silica‐rich phase. This 49 GPa experiment demonstrates that magnetite can be produced by the shock decomposition of siderite as a result of local heating to > 470°C. Therefore, magnetite in the rims of carbonates in Martian meteorite ALH 84001 could be a product of shock devolatilization of siderite as well.  相似文献   

4.
Abstract— The abundances and isotopic compositions of N and Ar have been measured by stepped combustion of the Allan Hills 84001 (ALH 84001) Martian orthopyroxenite. Material described as shocked is N-poor ([N] ～ 0.34 ppm; δ15N ～ +23%); although during stepped combustion, 15N-enriched N (δ15N ～ +143%) is released in a narrow temperature interval between 700 °C and 800 °C (along with 13C-enriched C (δ13C ～ +19%) and 40Ar). Cosmogenic species are found to be negligible at this temperature; thus, the iso-topically heavy component is identified, in part, as Martian atmospheric gas trapped relatively recently in the history of ALH 84001. The N and Ar data show that ALH 84001 contains species from the Martian lithosphere, a component interpreted as ancient trapped atmosphere (in addition to the modern atmospheric species), and excess 40Ar from K decay. Deconvolution of radiogenic 40Ar from other Ar components, on the basis of end-member 36Ar/14N and 40Ar/36Ar ratios, has enabled calculation of a K-Ar age for ALH 84001 as 3.5–4.6 Ga, depending on assumed K abundance. If the component believed to be Martian palaeoatmos-phere was introduced to ALH 84001 at the time the K-Ar age was set, then the composition of the atmosphere at this time is constrained to: δ15N ≥ +200%, 40Ar/36Ar ≤ 300 and 36Ar/14N ≥ 17 × 10?5. In terms of the petrogenetic history of the meteorite, ALH 84001 crystallised soon after differentiation of the planet, may have been shocked and thermally metamorphosed in an early period of bombardment, and then subjected to a second event. This later process did not reset the K-Ar system but perhaps was responsible for introducing (recent) atmospheric gases into ALH 84001; and it might mark the time at which ALH 84001 suffered fluid alteration resulting in the formation of the plagioclase and carbonate mineral assemblages.  相似文献   

5.
Clay minerals, although ubiquitous on the ancient terrains of Mars, have not been observed in Martian meteorite Allan Hills (ALH) 84001, which is an orthopyroxenite sample of the early Martian crust with a secondary carbonate assemblage. We used a low‐temperature (20 °C) one‐dimensional (1‐D) transport thermochemical model to investigate the possible aqueous alteration processes that produced the carbonate assemblage of ALH 84001 while avoiding the coprecipitation of clay minerals. We found that the carbonate in ALH 84001 could have been produced in a process, whereby a low‐temperature (~20 °C) fluid, initially equilibrated with the early Martian atmosphere, moved through surficial clay mineral and silica‐rich layers, percolated through the parent rock of the meteorite, and precipitated carbonates (thereby decreasing the partial pressure of CO2) as it evaporated. This finding requires that before encountering the unweathered orthopyroxenite host of ALH 84001, the fluid permeated rock that became weathered during the process. We were able to predict the composition of the clay minerals formed during weathering, which included the dioctahedral smectite nontronite, kaolinite, and chlorite, all of which have been previously detected on Mars. We also calculated host rock replacement in local equilibrium conditions by the hydrated silicate talc, which is typically considered to be a higher temperature hydrothermal phase on Earth, but may have been a common constituent in the formation of Martian soils through pervasive aqueous alteration. Finally, goethite and magnetite were also found to precipitate in the secondary alteration assemblage, the latter associated with the generation of H2. Apparently, despite the limited water–rock interaction that must have led to the formation of the carbonates ~ 3.9 Ga ago, in the vicinity of the ALH 84001 source rocks, clay formation would have been widespread.  相似文献   

6.
Abstract— Olivine from Martian meteorite Allan Hills (ALH) 84001 occurs as clusters within orthopyroxene adjacent to fractures containing disrupted carbonate globules and feldspathic shock glass. The inclusions are irregular in shape and range in size from ～40 μm to submicrometer. Some of the inclusions are elongate and boudinage-like. The olivine grains are in sharp contact with the enclosing orthopyroxene and often contain small inclusions of chromite. The olivine exhibits a very limited range of composition from Fo65 to Fo66 (n = 25). The δ18O values of the olivine and orthopyroxene analyzed by ion microprobe range from +4.3 to +5.3‰ and are indistinguishable from each other within analytical uncertainty. The mineral chemistries, O-isotopic data, and textural relationships indicate that the olivine inclusions were produced at a temperature >800 °C. It is unlikely that the olivines formed during the same event that gave rise to the carbonates in ALH 84001, which have more elevated and variable δ18O values, and were probably formed from fluids that were not in isotopic equilibrium with the orthopyroxene or olivine. The reactions most likely instrumental in the formation of olivine could be either the dehydration of hydrous silicates that formed during carbonate precipitation or the reduction of orthopyroxene and spinel. If the olivine was formed by either reaction during a postcarbonate heating event, the implications are profound with regards to the interpretations of McKay et al. (1996). Due to the low diffusion rates in carbonates, this rapid, high-temperature event would have resulted in the preservation of the fine-scale carbonate zoning, while partially devolatilizing select carbonate compositions on a submicrometer scale (Brearley, 1998a). This may have resulted in the formation of the minute magnetite grains that McKay et al. (1996) attributed to biogenic activity.  相似文献   

7.
Abstract— Crystallographic relationships between magnetite, sulfides, and carbonate rosettes in fracture zones of the Allan Hills (ALH) 84001 Martian meteorite have been studied using analytical electron microscopy. We have focused on those magnetite grains whose growth mechanisms can be rigorously established from their crystallographic properties. Individual magnetite nanocrystals on the surfaces of carbonates are epitaxially intergrown with one another in “stacks” of single-domain crystals. Other magnetite nanocrystals are epitaxially intergrown with the surfaces of the carbonate substrates. The observed magnetite/carbonate (hkl) Miller indices orientation relationships are (?, ?, 3)m ‖ (1, ?, 0)c and (1, ?, 1)m ‖ (0,0, 3)c with lattice mismatches of ～13% and ～11%, respectively. Epitaxy is a common mode of vapor-phase growth of refractory oxides like magnetite, as is the spiral growth about axial screw dislocations previously observed in other magnetite nanocrystals in ALH 84001. Epitaxy rules out intracellular precipitation of these magnetites by (Martian) organisms, provides further evidence of the high-temperature (>120 °C) inorganic origins of magnetite in ALH 84001, and indicates that the carbonates also have been exposed to elevated temperatures.  相似文献   

8.
Abstract— Single crystals of orthopyroxene from small fragments of the Kapoeta, Old Homestead 001, and Hughes 002 howardites were studied by x‐ray diffraction and microprobe analyses. The Fe‐Mg equilibrium distribution coefficients kD of the crystals were used to calculate the closure temperatures (Tc) using the calibration by Stimpfl et al. (1999). The compositions, the presence of exsolved augite lamellae, and the Tc values (from 365 to 385 °C) obtained for Kapoeta orthopyroxene s suggest that our fragment comes from a diogenitic cumulate clast. The more Fe‐rich composition, the absence of exsolved lamellae, and the higher Tc values (from 583 to 605 °C) measured in the Old Homestead 001 orthopyroxenes suggest that this fragment comes from a cumulitic clast affected by fast cooling at high temperature. For the Hughes 002 orthopyroxenes, close in composition to Old Homestead 001, the different Tc values (339, 358, and 607 °C) recorded by the various crystals and the presence of augite lamellae in the crystals with the lowest Tc support the hypothesis that this howardite sample is an unheated breccia containing a mixture of cumulitic orthopyroxenes with different thermal histories.  相似文献   

9.
Abstract— Rare earth element (REE) and other selected trace and minor element concentrations were measured in individual grains of orthopyroxene, feldspathic glass (of plagioclase composition) and merrillite of the ALH 84001 Martian meteorite. Unlike in other Martian meteorites, phosphate is not the main REE carrier in ALH 84001. The REE pattern of ALH 84001 bulk rock is dependent on the modal abundances of three REE-bearing phases, namely, orthopyroxene, which contains most of the heavy rare earth elements (HREEs); feldspathic glass, which dominates the Eu abundances; and merrillite, which contains the majority of the light rare earth elements (LREEs). Variations in the REE abundances previously observed in different splits of ALH 84001 can easily be explained in terms of small variations in the modal abundances of these three minerals without the need to invoke extensive redistribution of LREEs. At least some orthopyroxenes (i.e., those away from contacts with feldspathic glass) in ALH 84001 appear to have preserved their original REE zonation from igneous fractionation. An estimate of the ALH 84001 parent magma composition from that of the unaltered orthopyroxene “core” (i.e., zoned orthopyroxene with the lowest REE abundances) indicates that it is LREE depleted. This implies that the Martian mantle was already partly depleted within ～100 Ma of solar system formation, which is consistent with rapid accretion and differentiation of Mars. Although equilibration and exchange of REEs between phases (in particular, transport of LREEs into the interstitial phases, feldspathic glass and merrillite) cannot be ruled out, our data suggest that the LREE enrichment in melts “in equilibrium” with these interstitial phases is most likely the result of late-stage infiltration of the cumulate pile by a LREE-enriched melt.  相似文献   

10.
Recently it has been shown that the relatively low closure temperature (Tc) of 500 (100)°C calculated for augite from Miller Range nakhlite (MIL 03346,13) using the available geothermometers would correspond to a slow cooling rate inconsistent with the petrologic evidence for an origin from a fast‐cooled lava flow. Moreover, previous annealing experiments combined with HR‐SC‐XRD on an augite crystal from MIL 03346 clearly showed that at 600 °C, the Fe2+‐Mg degree of order remained unchanged, thus suggesting that the actual Tc is close to this temperature. In order to clarify this discrepancy, we undertook an ex situ annealing experimental study at 700, 800, and 900 °C, until the equilibrium in the intracrystalline Fe2+‐Mg exchange is reached, using an augite crystal from Miller Range nakhlite (MIL 03346,13) with a composition of about En36Fs24Wo40. These data allowed us to calculate the following new geothermometer calibration for Martian nakhlites: where The application of this new equation to other Martian nakhlites (NWA 988 and Nakhla) suggests that for augite with composition close to that of MIL 03346, the Tc is up to 170 °C higher with respect to the one calculated using the previous available geothermometer equation, thus suggesting a significantly faster cooling in agreement with petrologic evidence.  相似文献   

11.
Abstract— ALH84001, originally classified as a diogenite, is a coarse-grained, cataclastic, orthopyroxenite meteorite related to the martian (SNC) meteorites. The orthopyroxene is relatively uniform in composition, with a mean composition of Wo3.3En69.4Fs27.3. Minor phases are euhedral to subhedral chromite and interstitial maskelynite, An31.1Ab63.2Or5.7, with accessory augite, Wo42.2En45.1Fs12.7, apatite, pyrite and carbonates, Cc11.5Mg58.0Sd29.4Rd1.1. The pyroxenes and chromites in ALH84001 are similar in composition to these phases in EETA79001 lithology A megacrysts but are more homogeneous. Maskelynite is similar in composition to feldspars in the nakhlites and Chassigny. Two generations of carbonates are present, early (pre-shock) strongly zoned carbonates and late (post-shock) carbonates. The high Ca content of both types of carbonates indicates that they were formed at moderately high temperature, possibly ～700 °C. ALH84001 has a slightly LREE-depleted pattern with La 0.67x and Lu 1.85x CI abundances and with a negative Eu anomaly (Eu/Sm 0.56x CI). The uniform pyroxene composition is unusual for martian meteorites, and suggests that ALH84001 cooled more slowly than did the shergottites, nakhlites or Chassigny. The nearly monomineralic composition, coarse-grain size, homogenous orthopyroxene and chromite compositions, the interstitial maskelynite and apatite, and the REE pattern suggest that ALH84001 is a cumulate orthopyroxenite containing minor trapped, intercumulus material.  相似文献   

12.
Abstract— In a study of the isotopic signatures of trapped Xe in shock-produced glass of shergottites and in ALH 84001, we observe three components: (1) modern Martian atmospheric Xe that is isotopically mass fractionated relative to solar Xe, favoring the heavy isotopes, (2) solar-like Xe, as previously observed in Chassigny, and (3) an isotopically fractionated (possibly ancient) component with little or no radiogenic 129Xerad. In situ-produced fission and spallation components are observed predominantly in the high-temperature steps. Heavy N signatures in ALH 84001, EET 79001 and Zagami reveal Martian atmospheric components. The low-temperature release of ALH 84001 shows evidence for the presence of a light N component (δ15N ≤ -21%), which is consistent with the component observed in the other Shergotty, Nakhla and Chassigny (SNC) group meteorites. The highest observed 129Xe/130Xe ratio of 15.60 in Zagami and EET 79001 is used here to represent the present Martian atmospheric component, and the isotopic composition of this component is compared with other solar system Xe signatures. The 129Xe/130Xe ratios in ALH 84001 are lower but appear to reflect varying mixing ratios with other components. The consistently high 129Xe/130Xe ratios in rocks of different radiometric ages suggest that Martian atmospheric Xe evolved early on. As already concluded in earlier work, only a small fission component is observed in the Martian atmospheric component. Assuming that a chondritic 244Pu/129I initial ratio applies to Mars, this implies that either Pu-derived fission Xe is retained in the solid planet (in fact, in situ-produced fission Xe is observed in ALH 84001) or may reflect a very particular degassing history of the planet.  相似文献   

13.
Abstract— We report a comprehensive imaging study including confocal microRaman spectroscopy, scanning electron microscopy (SEM), and 3‐D extended focal imaging light microscopy of carbonate globules throughout a depth profile of the Martian meteorite Allan Hills (ALH) 84001 and similar objects in mantle peridotite xenoliths from the Bockfjorden volcanic complex (BVC), Svalbard. Carbonate and iron oxide zoning in ALH 84001 is similar to that seen in BVC globules. Hematite appears to be present in all ALH 84001 carbonate‐bearing assemblages except within a magnesite outer rim found in some globules. Macromolecular carbon (MMC) was found in intimate association with magnetite in both ALH 84001 and BVC carbonates. The MMC synthesis mechanism appears similar to established reactions within the Fe‐C‐O system. By inference to a terrestrial analogue of mantle origin (BVC), these results appear to represent the first measurements of the products of an abiotic MMC synthesis mechanism in Martian samples. Furthermore, the ubiquitous but heterogeneous distribution of hematite throughout carbonate globules in ALH 84001 may be partly responsible for some of the wide range in measured oxygen isotopes reported in previous studies. Using BVC carbonates as a suitable analogue, we postulate that a low temperature hydrothermal model of ALH 84001 globule formation is most likely, although alteration (decarbonation) of a subset of globules possibly occurred during a later impact event.  相似文献   

14.
Abstract— In martian orthopyroxenite ALH 84001, pockets of feldspathic glass frequently contain carbonate masses that have been disrupted and dispersed within feldspathic shock melt as a result of impact(s). Transmission electron microscope studies of carbonate fragments embedded within feldspathic glass show that the fragments contain myriad, nanometer‐sized magnetite particles with cuboid, irregular, and teardrop morphologies, frequently associated with voids. The fragments of carbonate must have been incorporated into the melt at temperatures of ?900°C, well above the upper thermal stability of siderite (FeCO3), which decomposes to produce magnetite and CO2 below ?450°C. These observations suggest that most, if not all, of the fine‐grained magnetite associated with Fe‐bearing carbonate in ALH 84001 could have been formed as result of the thermal decomposition of the siderite (FeCO3) component of the carbonate and is not due to biological activity.  相似文献   

15.
Abstract— Understanding the origin of carbonate minerals in the Martian meteorite Allan Hills (ALH) 84001 is crucial to evaluating the hypothesis that they contain traces of ancient Martian life. Using arguments based on chemical equilibria among carbonates and fluids, an origin at >650 °C (inimical to life) has been proposed. However, the bulk and stable isotopic compositions of the carbonate minerals are open to multiple interpretations and so lend no particular support to a high-temperature origin. Other methods (possibly less direct) will have to be used to determine the formation temperature of the carbonates in ALH 84001.  相似文献   

16.
Abstract— Argon-isotopic abundances were measured in neutron-irradiated samples of Martian meteorites Chassigny, Allan Hills (ALH) 84001, ALH 77005, Elephant Moraine (EET) 79001, Yamato (Y) 793605, Shergotty, Zagami, and Queen Alexandra Range (QUE) 94201, and in unirradiated samples of ALH 77005. Chassigny gives a 39Ar-40Ar age of 1.32 ± 0.07 Ga, which is similar to radiometric ages of the nakhlites. Argon-39-Argon-40 data for ALH 84001 indicate ages between 3.9 and 4.3 Ga. A more precise definition of this age requires detailed characterization of the multiple trapped Ar components in ALH 84001 and of 39Ar recoil distribution. All six shergottite samples show apparent 39Ar-40Ar ages substantially older than the ～165–200 Ma range in ages given by other isotope dating techniques. Shergottites appear to contain ubiquitous Ar components acquired from the Martian atmosphere, the Martian mantle, and commonly terrestrial atmospheric contamination. Zagami feldspar also suggests inherited radiogenic 40Ar. These data analyses indicate that the recent Martian atmospheric component trapped in shergottites has a 40Ar/36Ar ratio possibly as low as ～1750 and no greater than ～1900. These ratios are less than the value of 3000 ± 500 reported by Viking. The 40Ar/36Ar ratio for the Martian mantle component is probably <500 but is poorly constrained. The correlation between trapped 40Ar/36Ar and 129Xe/132Xe ratios in shergottite impact glasses and unirradiated samples of ALH 77005 shows considerable scatter and suggests that the 36Ar/132Xe ratio in the Martian components may vary. Resolution of Martian atmospheric 40Ar/36Ar ratio at different time periods (i.e., at ～4.0 and 0.2 Ga) is also difficult without an understanding of the composition of various trapped components.  相似文献   

17.
Abstract— The objective of this study was to identify and map possible source regions for all 5 known martian meteorite lithologies (basalt, lherzolite, clinopyroxenite, orthopyroxenite, and dunite) using data from the Mars Global Surveyor Thermal Emission Spectrometer (MGS TES). We deconvolved the TES data set using laboratory spectra of 6 martian meteorites (Los Angeles, Zagami, ALH A77005, Nakhla, ALH 84001, and Chassigny) as end members, along with atmospheric and surface spectra previously derived from TES data. Global maps (16 pixels/degree) of the distribution of each meteorite end member show that meteorite‐like compositions are not present at or above TES detectability limits over most of the planet's dust‐free regions. However, we have confidently identified local‐scale (100s‐1000s km2) concentrations of olivine‐ and orthopyroxene‐bearing materials similar to ALH A77005, Chassigny, and ALH 84001 in Nili Fossae, in and near Ganges Chasma, in the Argyre and Hellas basin rims, and in Eos Chasma. Nakhla‐like materials are identified near the detection limit throughout the eastern Valles Marineris region and portions of Syrtis Major. Basaltic shergottites were not detected in any spatially coherent areas at the scale of this study. Martian meteorite‐like lithologies represent only a minor portion of the dust‐free surface and, thus, are not representative of the bulk composition of the ancient crust. Meteorite‐like spectral signatures identified above TES detectability limits in more spatially restricted areas (<tens of km) are targets of ongoing analysis.  相似文献   

18.
Abstract— The microtextures of pigeonite in four ureilites, Allan Hills (ALH) 77257, Reckling Peak (RKP) A80239, Yamato (Y‐) 791538, and Allan Hills A81101, chosen to span a range of composition and shock level, were investigated by transmission electron microscopy (TEM); two of the samples were also investigated by single crystal X‐ray diffraction to determine Fe2+‐Mg cation site partitioning. The low‐shock and compositionally homogeneous pigeonites in ALHA77257 and RKPA80329 (Wo 6.4 for both, mg 86.3 and 84.3 respectively) display irregularly spaced, shock‐induced stacking faults oriented parallel to (100), and large antiphase domains (50–100 nm). Antiphase domains have no preferential orientation. No evidence of exsolution was observed. The low‐shock Y‐791538 pigeonite is homogeneous and has higher Ca and mg (Wo 9.4, mg 91.2). TEM investigation showed spinodal decomposition, indicative of incipient exsolution; small antiphase domains were observed (～5 nm). Single crystal refinement yielded R4s? = 5.71%, with Fe2+‐Mg partitioning coefficient kd = 0.077(8) and Tc = 658(35) °C. ALHA81101 has compositionally heterogeneous pyroxenes, with large local variations in Wo and mg (Wo = 4–13, mg = 86–68). No compositional gradients from core to rim of grains were observed, and the heterogeneity is interpreted as related to cation migration during shock. In one relatively Ca‐rich region (Wo～12), TEM analysis showed augite‐pigeonite exsolution lamellae, with spacing 145(20) nm. Results for ALHA77257, RKPA80239, and Y‐791538 support a model of rapid cooling following breakup of the ureilite parent body. The presence of exsolution lamellae in ALHA81101 can be related to a local shock‐induced Ca enrichment and provides no constraint on the late cooling history.  相似文献   

19.
Abstract— Pyroxene structural data, along with analyses of titanomagnetite, fayalite and mesostasis of the new nakhlite Miller Range (MIL) 03346, define equilibration near 1 bar, 1100 °C, and oxygen fugacity near the FMQ buffer. There is a clear progression of oxygen fugacity (fO2) in Martian meteorites from reduced Allan Hills (ALH) 84001 to intermediate shergottites to oxidized nakhlites. This trend can be explained by polybaric graphite‐CO‐CO2 equilibria in the Martian mantle. Shergottites would have formed at pressures between 1.2 and 3.0 GPa, and nakhlite parent liquids formed at pressures >3.0 GPa, consistent with geochemical and petrologic data for the shergottites and nahklites. Carbon buffering in the Martian mantle could be responsible for variation in fO2 in Martian meteorites (rather than assimilation or crustal interaction), as well as C‐H‐O fluids that could be the source of ˜30 ppb CH4 detected by recent spacecraft missions. The conundrum of an oxidized current mantle and basalts, but reduced early mantle during core‐mantle equilibrium exists for both the Earth and Mars. A polybaric buffering role for graphite can explain this discrepancy for Mars, and thus it may not be necessary to have an oxidation mechanism like the dissociation of MgFe‐perovskite to account for the oxidized terrestrial mantle.  相似文献   

20.
Abstract— Isotopic abundances of the noble gases were measured in the following Martian meteorites: two shock glass inclusions from Elephant Moraine (EET) 79001, shock vein glass from Shergotty and Yamato (Y) 793605, and whole-rock samples of Allan Hills (ALH) 84001 and Queen Alexandra Range (QUE) 94201. These glass samples, when combined with literature data on a separate single glass inclusion from EET 79001 and a glass vein from Zagami, permit examination in greater detail of the isotopic composition of Ne, Ar, Kr, and Xe trapped from the Martian atmosphere. The isotopic composition of Martian Ne, if actually present in these glasses, remains poorly defined. The 40Ar/36Ar ratio of trapped Martian atmospheric Ar is probably considerably lower than the nominal ratio of 3000 measured by Viking, and data on impact glasses suggest a value of ～1900. The atmospheric 36Ar/38Ar ratio is ≤4.0. Martian atmospheric Kr may be enriched in lighter isotopes by ～0.5%/amu compared to both solar-wind Kr and to the Martian composition previously reported. The isotopic composition of Xe in these glasses agrees with that previously reported in the literature. The Martian atmospheric 36Ar/132Xe and 84Kr/132Xe elemental ratios are higher than those reported by Viking by factors of ～2.5–1.6 (depending on the 40Ar/36Ar ratio adopted) and ～1.8, respectively, and are discussed in a separate paper. Cosmogenic gases indicate space exposure ages of 2.7 ± 0.6 Ma for QUE 94201 and Shergotty and 14 ± 1 Ma for ALH 84001. Small amounts of 21Ne produced by energetic solar protons may be present in QUE 94201 but are not present in ALH 84001 or Y-793605. The space exposure age for Y-793605 is 4.9 ± 0.6 Ma and appears to be distinctly older than the ages for basaltic shergottites. However, uncertainties in cosmogenic production rates still makes somewhat uncertain the number of Martian impact events required to produce the exposure ages of Martian meteorites.  相似文献   

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