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1.
Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ～0.4‰ amu?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (～0.0 to ～0.3‰ amu?1) and chondrites (～0.0 to ～0.2‰ amu?1) are similar, whereas the range in pallasite metal (～–0.1 to 0.0‰ amu?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (～0.0 to ～0.3‰ amu?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ～0.4‰ amu?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern.  相似文献   

2.
Abstract— A major revision of the current Saikumar and Goldstein (1988) cooling rate computer model for kamacite growth is presented. This revision incorporates a better fit to the α/α + γ phase boundary and to the γ/α + γ phase boundary particularly below the monotectoid temperature of 400 °C. A reevaluation of the latest diffusivities for the Fe‐Ni system as a function of Ni and P content and temperature is made, particularly for kamacite diffusivity below the paramagnetic to ferromagnetic transition. The revised simulation model is applied to several iron meteorites and several mesosiderites. For the mesosiderites we obtain a cooling rate of 0.2 °C/Ma, about 10x higher than the most recent measured cooling rates. The cooling rate curves from the current model do not accurately predict the central nickel content of taenite halfwidths smaller than ～10 μm. This result calls into question the use of conventional kamacite growth models to explain the microstructure of the mesosiderites. Kamacite regions in mesosiderites may have formed by the same process as decomposed duplex plessite in iron meteorites.  相似文献   

3.
Abstract— Metallographic cooling rates have been calculated for all five members of the iron meteorites group IIF using two different techniques. We have determined cooling rates of ～5 °C/Ma based on Ni profiles through the taenite rim enclosing kamacite spindles. Ni profiles through the kamacite phase are less precise cooling rate indicators, but suggest a cooling rate of ～1 °C/Ma within an order of magnitude at lower temperatures (360–400 °C). Based on the kamacite bandwidth and the Ni profiles through the taenite, we estimate that the kamacite nucleated 130–200 °C below the temperature predicted from the phase diagram. The size of and the distance between the large kamacite spindles is found to be consistent with the thermal history that we have determined on the basis of Ni profiles in kamacite and taenite. We find that previously published kamacite bandwidth cooling rates for the five group IIF members are most likely in error because of the presence of large schreibersite spindles in some kamacite spindles and because undercooling of kamacite was ignored. Contrary to previous workers we find that the metallographic cooling rates are consistent with cooling in a common core.  相似文献   

4.
Abstract— Cooling rate experiments were performed on P‐free Fe‐Ni alloys that are compositionally similar to ordinary chondrite metal to study the taenite ? taenite + kamacite reaction. The role of taenite grain boundaries and the effect of adding Co and S to Fe‐Ni alloys were investigated. In P‐free alloys, kamacite nucleates at taenite/taenite grain boundaries, taenite triple junctions, and taenite grain corners. Grain boundary diffusion enables growth of kamacite grain boundary precipitates into one of the parent taenite grains. Likely, grain boundary nucleation and grain boundary diffusion are the applicable mechanisms for the development of the microstructure of much of the metal in ordinary chondrites. No intragranular (matrix) kamacite precipitates are observed in P‐free Fe‐Ni alloys. The absence of intragranular kamacite indicates that P‐free, monocrystalline taenite particles will transform to martensite upon cooling. This transformation process could explain the metallography of zoneless plessite particles observed in H and L chondrites. In P‐bearing Fe‐Ni alloys and iron meteorites, kamacite precipitates can nucleate both on taenite grain boundaries and intragranularly as Widmanstätten kamacite plates. Therefore, P‐free chondritic metal and P‐bearing iron meteorite/pallasite metal are controlled by different chemical systems and different types of taenite transformation processes.  相似文献   

5.
Abstract— Instrumental neutron activation analysis (INAA) was used to determine Ni, Co, Cu, Ga, As, Au, W, Re and Ir in taenite lamellae isolated by acid dissolution from eight iron meteorites from groups IA, IIIAB and IVA. Taenite is enriched in Ni, Cu, Ga, As, Au, W, Re and Ir relative to kamacite, whereas taenite is depleted in Co. Taenite/kamacite partition ratios in slowly cooled IAB meteorites are farther from unity than those in rapidly cooled IVA meteorites. Taenite/kamacite partition ratios for Cu, Ir, Au and Co may be sensitive cooling rate indicators.  相似文献   

6.
Abstract— Carbon and nitrogen distributions in iron meteorites, their concentrations in various phases, and their isotopic compositions in certain phases were measured by secondary ion mass spectrometry (SIMS). Taenite (and its decomposition products) is the main carrier of C, except for IAB iron meteorites, where graphite and/or carbide (cohenite) may be the main carrier. Taenite is also the main carrier of N in most iron meteorites unless nitrides (carlsbergite CrN or roaldite (Fe, Ni)4N) are present. Carbon and N distributions in taenite are well correlated unless carbides and/or nitrides are exsolved. There seem to be three types of C and N distributions within taenite. (1) These elements are enriched at the center of taenite (convex type). (2) They are enriched at the edge of taenite (concave type). (3) They are enriched near but some distance away from the edge of taenite (complex type). The first case (1) is explained as equilibrium distribution of C and N in Fe-Ni alloy with M-shape Ni concentration profile. The second case (2) seems to be best explained as diffusion controlled C and N distributions. In the third case (3), the interior of taenite has been transformed to the α phase (kamacite or martensite). Carbon and N were expelled from the α phase and enriched near the inner border of the remaining γ phase. Such differences in the C and N distributions in taenite may reflect different cooling rates of iron meteorites. Nitrogen concentrations in taenite are quite high approaching 1 wt% in some iron meteorites. Nitride (carlsbergite and roaldite) is present in meteorites with high N concentrations in taenite, which suggests that the nitride was formed due to supersaturation of the metallic phases with N. The same tendency is generally observed for C (i.e., high C concentrations in taenite correlate with the presence of carbide and/or graphite). Concentrations of C and N in kamacite are generally below detection limits. Isotopic compositions of C and N in taenite can be measured with a precision of several permil. Isotopic analysis in kamacite in most iron meteorites is not possible because of the low concentrations. The C isotopic compositions seem to be somewhat fractionated among various phases, reflecting closure of C transport at low temperatures. A remarkable isotopic anomaly was observed for the Mundrabilla (IIICD anomalous) meteorite. Nitrogen isotopic compositions of taenite measured by SIMS agree very well with those of the bulk samples measured by conventional mass spectrometry.  相似文献   

7.
We report in situ NanoSIMS siderophile minor and trace element abundances in individual Fe‐Ni metal grains in the unequilibrated chondrite Krymka (LL3.2). Associated kamacite and taenite of 10 metal grains in four chondrules and one matrix metal were analyzed for elemental concentrations of Fe, Ni, Co, Cu, Rh, Ir, and Pt. The results show large elemental variations among the metal grains. However, complementary and correlative variations exist between adjacent kamacite‐taenite. This is consistent with the unequilibrated character of the chondrite and corroborates an attainment of chemical equilibrium between the metal phases. The calculated equilibrium temperature is 446 ± 9 °C. This is concordant with the range given by Kimura et al. (2008) for the Krymka postaccretion thermal metamorphism. Based on Ni diffusivity in taenite, a slow cooling rate is estimated of the Krymka parent body that does not exceed ~1K Myr?1, which is consistent with cooling rates inferred by other workers for unequilibrated ordinary chondrites. Elemental ionic radii might have played a role in controlling elemental partitioning between kamacite and taenite. The bulk compositions of the Krymka metal grains have nonsolar (mostly subsolar) element/Ni ratios suggesting the Fe‐Ni grains could have formed from distinct precursors of nonsolar compositions or had their compositions modified subsequent to chondrule formation events.  相似文献   

8.
Abstract— We studied the metallography of Fe‐Ni metal particles in 17 relatively unshocked ordinary chondrites and interpreted their microstructures using the results of P‐free, Fe‐Ni alloy cooling experiments (described in Reisener and Goldstein 2003). Two types of Fe‐Ni metal particles were observed in the chondrites: zoned taenite + kamacite particles and zoneless plessite particles, which lack systematic Ni zoning and consist of tetrataenite in a kamacite matrix. Both types of metal particles formed during metamorphism in a parent body from homogeneous, P‐poor taenite grains. The phase transformations during cooling from peak metamorphic temperatures were controlled by the presence or absence of grain boundaries in the taenite particles. Polycrystalline taenite particles transformed to zoned taenite + kamacite particles by kamacite nucleation at taenite/taenite grain boundaries during cooling. Monocrystalline taenite particles transformed to zoneless plessite particles by martensite formation and subsequent martensite decomposition to tetrataenite and kamacite during the same cooling process. The varying proportions of zoned taenite + kamacite particles and zoneless plessite particles in types 4–6 ordinary chondrites can be attributed to the conversion of polycrystalline taenite to monocrystalline taenite during metamorphism. Type 4 chondrites have no zoneless plessite particles because metamorphism was not intense enough to form monocrystalline taenite particles. Type 6 chondrites have larger and more abundant zoneless plessite particles than type 5 chondrites because intense metamorphism in type 6 chondrites generated more monocrystalline taenite particles. The distribution of zoneless plessite particles in ordinary chondrites is entirely consistent with our understanding of Fe‐Ni alloy phase transformations during cooling. The distribution cannot be explained by hot accretion‐autometamorphism, post‐metamorphic brecciation, or shock processing.  相似文献   

9.
Abstract– The microstructures of six reheated iron meteorites—two IVA irons, Maria Elena (1935), Fuzzy Creek; one IVB iron, Ternera; and three ungrouped irons, Hammond, Babb’s Mill (Blake’s Iron), and Babb’s Mill (Troost’s Iron)—were characterized using scanning and transmission electron microscopy, electron‐probe microanalysis, and electron backscatter diffraction techniques to determine their thermal and shock history and that of their parent asteroids. Maria Elena and Hammond were heated below approximately 700–750 °C, so that kamacite was recrystallized and taenite was exsolved in kamacite and was spheroidized in plessite. Both meteorites retained a record of the original Widmanstätten pattern. The other four, which show no trace of their original microstructure, were heated above 600–700 °C and recrystallized to form 10–20 μm wide homogeneous taenite grains. On cooling, kamacite formed on taenite grain boundaries with their close‐packed planes aligned. Formation of homogeneous 20 μm wide taenite grains with diverse orientations would have required as long as approximately 800 yr at 600 °C or approximately 1 h at 1300 °C. All six irons contain approximately 5–10 μm wide taenite grains with internal microprecipitates of kamacite and nanometer‐scale M‐shaped Ni profiles that reach approximately 40% Ni indicating cooling over 100–10,000 yr. Un‐decomposed high‐Ni martensite (α2) in taenite—the first occurrence in irons—appears to be a characteristic of strongly reheated irons. From our studies and published work, we identified four progressive stages of shock and reheating in IVA irons using these criteria: cloudy taenite, M‐shaped Ni profiles in taenite, Neumann twin lamellae, martensite, shock‐hatched kamacite, recrystallization, microprecipitates of taenite, and shock‐melted troilite. Maria Elena and Fuzzy Creek represent stages 3 and 4, respectively. Although not all reheated irons contain evidence for shock, it was probably the main cause of reheating. Cooling over years rather than hours precludes shock during the impacts that exposed the irons to cosmic rays. If the reheated irons that we studied are representative, the IVA irons may have been shocked soon after they cooled below 200 °C at 4.5 Gyr in an impact that created a rubblepile asteroid with fragments from diverse depths. The primary cooling rates of the IVA irons and the proposed early history are remarkably consistent with the Pb‐Pb ages of troilite inclusions in two IVA irons including the oldest known differentiated meteorite ( Blichert‐Toft et al. 2010 ).  相似文献   

10.
Abstract— The Ulasitai iron was recently found about 130 km southeast to the find site of the Armanty (Xinjiang, IIIE) meteorite. It is a coarse octahedrite with a kamacite bandwidth of 1.2 ± 0.2 (0.9–1.8) mm. Plessite is abundant, as is taenite, kamacite, cohenite, and schreibersite with various microstructures. Schreibersite is Ni‐rich (30.5–55.5 wt%) in plessite or coexisting with troilite and daubreelite, in comparison with the coarse laths (20.6–21.2 wt%) between the Widmanstätten pattern plates. The correlation between the center Ni content and the half bandwidth of taenite suggest a cooling rate of ?20 °C/Myr based on simulations. The petrography and mineral chemistry of Ulasitai are similar to Armanty. The bulk samples of Ulasitai were measured, together with Armanty, Nandan (IIICD), and Mundrabilla (IIICD), by inductively coupled plasma atomic emission spectrometry (ICP‐AES) and mass spectrometry (ICP‐MS). The results agree with literature data of the same meteorites, and our analyses of four samples of Armanty (L1, L12, L16, L17) confirm a homogeneous composition (Wasson et al. 1988). The bulk composition of Ulasitai is identical to that of Armanty, both plotting within the IIIE field. We classify Ulasitai as a new IIIE iron and suggest that it pairs with Armanty.  相似文献   

11.
K.L. Rasmussen 《Icarus》1981,45(3):564-576
Measurements of Ni concentration profiles of a large number of neighboring kamacite and taenite lamellae in the iron meteorite Cape York (IIIA) have revealed that the kamacite plates have nucleated in a taenite of varying Ni concentration, equal to or above the bulk Ni concentration of the meteorite. This variation indicates that the kamacite plates nucleated stepwise (i.e., independently) during cooling through a certain temperature interval, rather than simultaneously after more or less undercooling of the meteorite. The latter is assumed in most previous cooling rate determinations (e.g., Moren and Goldstein, 1978). In this paper the measured local bulk Ni concentrations are used in the computer simulation of the evolution of the Widmannstaetten pattern in order to calculate the cooling rate of the meteorite. The cooling rate obtained for Cape York is 1.3°K/my. In most previous work, a correlation is seen between the resulting taenite width and the cooling rate in one and the same meteorite. No such correlation is seen using the present method.  相似文献   

12.
Abstract— Electron microprobe studies of several H5 and H6 chondrites reveal that olivine crystals exhibit systematic Fe‐Mg zoning near olivine‐metal interfaces. Olivine Fa concentrations decrease by up to 2 mol% toward zoned taenite + kamacite particles (formed after relatively small amounts of taenite undercooling) and increase by up to 2 mol% toward zoneless plessite particles (formed after ?200 °C of taenite undercooling). The olivine zoning can be understood in terms of localized olivine‐orthopyroxene‐metal reactions during cooling from the peak metamorphic temperature. The silicate‐metal reactions were influenced by solid‐state metal phase transformations, and the two types of olivine zoning profiles resulted from variable amounts of taenite undercooling at temperatures <700 °C. The relevant silicate‐metal reactions are modeled using chemical thermodynamics. Systematic olivine Fe‐Mg zoning adjacent to metal is an expected consequence of retrograde silicate‐metal reactions, and the presence of such zoning provides strong evidence that the silicate and metallic minerals evolved in situ during cooling from the peak metamorphic temperature.  相似文献   

13.
Fe‐Ni metal is a common constituent of most meteorites and is an indicator of the thermal history of the respective meteorites, it is a diagnostic tool to distinguish between groups/subgroups of meteorites. In spite of over a million micrometeorites collected from various domains, reports of pure metallic particles among micrometeorites have been extremely rare. We report here the finding of a variety of cosmic metal particles such as kamacite, plessite, taenite, and Fe‐Ni beads from deep‐sea sediments of the Indian Ocean, a majority of which have entered the Earth unaffected by frictional heating during atmospheric entry. Such particles are known as components of meteorites but have never been found as individual entities. Their compositions suggest precursors from a variety of meteorite groups, thus providing an insight into the metal fluxes on the Earth. Some particles have undergone heating and oxidation to different levels during entry developing features similar to I‐type cosmic spherules, suggesting atmospheric processing of individual kamacites/taenite grains as another hitherto unknown source for the I‐type spherules. The particles have undergone postdepositional aqueous alteration transforming finally into the serpentine mineral cronstedtite. Aqueous alteration products of kamacite reflect the local microenvironment, therefore they have the potential to provide information on the composition of water in the solar nebula, on the parent bodies or on surfaces of planetary bodies. Our observations suggest it would take sustained burial in water for tens of thousands of years under cold conditions for kamacites to alter to cronstedtite.  相似文献   

14.
Abstract— We studied the texture, mineralogy, and bulk chemical composition of Dhofar 007, a basaltic achondrite. Dhofar 007 is a polymict breccia that is mostly composed of coarse‐grained granular (CG) clasts with a minor amount of xenolithic components, such as a fragment of Mg‐rich pyroxene. The coarse‐grained, relict gabbroic texture, mineral chemistry, and bulk chemical data of the coarse‐grained clast indicate that the CG clasts were originally a cumulate rock crystallized in a crust of the parent body. However, in contrast to monomict eucrites, the siderophile elements are highly enriched and could have been introduced by impact events. Dhofar 007 appears to have experienced a two‐stage postcrystallization thermal history: rapid cooling at high temperatures and slow cooling at lower temperatures. The presence of pigeonite with closely spaced, fine augite lamellae suggests that this rock was cooled rapidly from higher temperatures (>0.5 °C/yr at ˜1000 °C) than typical cumulate eucrites. However, the presence of the cloudy zone in taenite and the Ni profile across the kamacite‐taenite boundaries indicates that the cooling rate was very slow at lower temperatures (˜1–10 °C/Myr at <600–700 °C). The slow cooling rate is comparable to those in mesosiderites and pallasites. The two‐stage thermal history and the relative abundance of siderophile elements similar to those for metallic portions in mesosiderites suggest that Dhofar 007 is a large inclusion of mesosiderite. However, we cannot rule out a possibility that Dhofar 007 is an anomalous eucrite.  相似文献   

15.
Abstract— We have measured the size of the high‐Ni particles in the cloudy zone and the width of the outer taenite rim in eight low shocked and eight moderately to heavily shocked IVA irons using a transmission electron microscope (TEM). Thin sections for TEM analysis were produced by a focused ion beam instrument. Use of the TEM allowed us to avoid potential artifacts which may be introduced during specimen preparation for SEM analysis of high Ni particles <30 nm in size and to identify microchemical and microstructural changes due to the effects of shock induced reheating. No cloudy zone was observed in five of the eight moderately to highly shocked (>13 GPa) IVA irons that were examined in the TEM. Shock induced reheating has allowed for diffusion from 20 nm to 400 nm across kamacite/taenite boundaries, recrystallization of kamacite, and the formation, in Jamestown, of taenite grain boundaries. In the eleven IVA irons with cloudy zone microstructures, the size of the high‐Ni particles in the cloudy zone increases directly with increasing bulk Ni content. Our data and the inverse correlation between cooling rate and high‐Ni particle size for irons and stony‐irons show that IVA cooling rates at 350‐200 °C are inversely correlated with bulk Ni concentration and vary by a factor of about 15. This cooling rate variation is incompatible with cooling in a metallic core that was insulated with a silicate mantle, but is compatible with cooling in a metallic body of radius 150 ± 50 km. The widths of the tetrataenite regions next to the cloudy zone correlate directly with high‐Ni particle size providing another method to measure low temperature cooling rates.  相似文献   

16.
Room temperature Mossbauer spectra have been obtained for several iron bearing phases in the octahedrite Toluca. The spectrum for kamacite contains six lines, as expected for a ferromagnetic material. That for taenite contains a strong six-line pattern, closely similar to that for kamacite, plus a weak singlet. The former is due to the ferromagnetic form of taenite, which predominates, and the latter to the non-equilibrium paramagnetic form. The spectra for troilite, schreibersite and cohenite are similar to those for terrestrial troilite, synthetic schreibersite and cementite, respectively. With some troilite samples, a weak doublet due to some non-magnetic phase was obtained. This was found to match the doublet reported for terrestrial pyrite, but the results are not such as to make a positive identification possible. This exploratory study of the Mossbauer spectra of some of the principal phases found in iron-nickel meteorites suggests that the main value of Mossbauer spectroscopy in the study of meteorites lies in its ability to detect relatively small amounts of paramagnetic phases such as the paramagnetic form of taenite.  相似文献   

17.
The combined SEM and TEM studies on the metal (Fe-Ni alloy ±C) portion of the Vaca Muerta mesosiderite reveal structural and compositional evidence at micro to nanoscale, which sheds light on the solidification of taenite + graphite as a cement, and later solid-state precipitation process for the kamacite formation as grain boundary allotriomorph. Besides, it is proposed that the graphite veinlets formed through a complex partial melting process followed by a solidification toward the final eutectic transient coupled with the solid-state precipitation and later decomposition ordering of taenite. The presence of defects and taenite in graphite signal formation in a liquid environment. The δ13C values of graphite in the graphite-rich areas (e.g., ranging from −0.8 ± 1.7‰ to +15.3 ± 2.5‰) suggest a short-circuit diffusion path for C isotope fractionation.  相似文献   

18.
Abstract— The radiogenic 207Pb/206Pb ratio is the only extant nuclide chronometer with sufficient time resolution for studies of the solar nebula accretion and early asteroidal differentiation and metamorphism. Pb isotopic dates can be used to link the dates obtained from extinct nuclide chronometers to the absolute time scale. The factors that control precision and accuracy of Pb isotopic dates of meteorites: instrumental mass fractionation in isotopic analysis, mass spectrometer sensitivity, removal of common Pb, multi‐stage evolution of U‐Pb systems, disturbances caused by diffusion, alteration, and shock metamorphism, and uncertainties in decay constants and the natural ratio of the U isotopes are reviewed. The precision of Pb isotopic dates of meteorites attained with currently available techniques and methodology is ±0.5–1.0 Myr in favorable cases. The accuracy of time interval measurements is approximately the same. The most serious limitation on precision and accuracy of Pb isotopic dates is placed by the presence of common Pb of uncertain and/or variable isotopic composition. Improvement in precision and accuracy of Pb isotopic dates would be possible through combined advancement of techniques of isotopic analysis (most importantly, better control over instrumental mass fractionation) and more effective techniques for the removal of common Pb, together with a better understanding of the effects of thermal metamorphism, shock metamorphism, and aqueous alteration on the U‐Pb system in meteorites.  相似文献   

19.
Abstract— The purpose of this study is to examine, using light optical and electron optical techniques, the microstructure and composition of metal particles in ordinary chondritic meteorites. This examination will lead to the understanding of the low temperature thermal history of metal particles in their host chondrites. Two type 6 falls were chosen for study: Kernouvé (H6) and Saint Severin (LL6). In both meteorites, the taenite particles consisted of a narrow rim of high Ni taenite and a central region of cloudy zone similar to the phases observed in iron meteorites. The cloudy zone microstructure was coarser in Saint Severin than in Kernouvé due to the higher bulk Ni content of the taenite and the slower cooling rate, 3 K Ma?1 vs. 17 K Ma?1. Three microstructural zones were observed within the high Ni taenite region in both meteorites. The origin of the multiple zones is unknown but is most likely due to the high Ni taenite cooling into the two phase γ″ (FeNi) + γ′ (FeNi3) region of the low temperature Fe-Ni phase diagram. Another explanation may be the presence of uniform size antiphase boundaries within the high Ni taenite. Finally, abnormally wide high Ni taenite regions are observed bordering troilite. The wide zones are probably caused by the diffusion of Ni from troilite into the high Ni taenite borders at low cooling temperatures.  相似文献   

20.
The Agoudal IIAB iron meteorite exhibits only kamacite grains (~6 mm across) without any taenite. The kamacite is homogeneously enriched with numerous rhabdite inclusions of different size, shape, and composition. In some kamacite domains, this appears frosty due to micron‐scale rhabdite inclusions (~5 to 100 μm) of moderate to high Ni content (~26 to 40 wt%). In addition, all the kamacite grains in matrix are marked with a prominent linear crack formed during an atmospheric break‐up event and subsequently oxidized. This feature, also defined by trails of lowest Ni‐bearing (mean Ni: 23 wt%) mm‐scale rhabdite plates (fractured and oxidized) could be a trace of a pre‐existing γ–α interface. Agoudal experienced a very slow rate of primary cooling ~4 °C Ma?1 estimated from the binary plots of true rhabdite width against corresponding Ni wt% and the computed cooling rate curves after Randich and Goldstein (1978). Chemically, Agoudal iron (Ga: 54 ppm; Ge: 140 ppm; Ir: 0.03 ppm) resembles the Ainsworth iron, the coarsest octahedrite of the IIAB group. Agoudal contains multiple sets of Neumann bands that are formed in space and time at different scales and densities due to multiple impacts with shock magnitude up to 130 kb. Signatures of recrystallization due to postshock low temperature mild reheating at about 400 °C are also locally present.  相似文献   

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