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1.
Abstract— The polycyclic aromatic hydrocarbon (PAH) naphthalene was exposed to ultraviolet radiation in H2O ice under astrophysical conditions, and the products were analyzed using infrared spectroscopy and high‐performance liquid chromatography. As we found in our earlier studies on the photoprocessing of coronene in H2O ice, aromatic alcohols and ketones (quinones) were formed. The regiochemistry of the reactions is described and leads to specific predictions of the relative abundances of various oxidized naphthalenes that should exist in meteorites if interstellar ice photochemistry influenced their aromatic inventory. Since oxidized PAHs are present in carbon‐rich meteorites and interplanetary dust particles (IDPs), and ubiquitous in and fundamental to biochemistry, the delivery of such extraterrestrial molecules to the early Earth may have played a role in the origin and evolution of life.  相似文献   

2.
The Ko?ice meteorite was observed to fall on 28 February 2010 at 23:25 UT near the city of Ko?ice in eastern Slovakia and its mineralogy, petrology, and geochemistry are described. The characteristic features of the meteorite fragments are fan‐like, mosaic, lamellar, and granular chondrules, which were up to 1.2 mm in diameter. The fusion crust has a black‐gray color with a thickness up to 0.6 mm. The matrix of the meteorite is formed mainly by forsterite (Fo80.6); diopside; enstatite (Fs16.7); albite; troilite; Fe‐Ni metals such as iron and taenite; and some augite, chlorapatite, merrillite, chromite, and tetrataenite. Plagioclase‐like glass was also identified. Relative uniform chemical composition of basic silicates, partially brecciated textures, as well as skeletal taenite crystals into troilite veinlets suggest monomict breccia formed at conditions of rapid cooling. The Ko?ice meteorite is classified as ordinary chondrite of the H5 type which has been slightly weathered, and only short veinlets of Fe hydroxides are present. The textural relationships indicate an S3 degree of shock metamorphism and W0 weathering grade. Some fragments of the meteorite Ko?ice are formed by monomict breccia of the petrological type H5. On the basis of REE content, we suggest the Ko?ice chondrite is probably from the same parent body as H5 chondrite Morávka from Czech Republic. Electron‐microprobe analysis (EMPA) with focused and defocused electron beam, whole‐rock analysis (WRA), inductively coupled plasma mass and optical emission spectroscopy (ICP MS, ICP OES), and calibration‐free laser induced breakdown spectroscopy (CF‐LIBS) were used to characterize the Ko?ice fragments. The results provide further evidence that whole‐rock analysis gives the most accurate analyses, but this method is completely destructive. Two other proposed methods are partially destructive (EMPA) or nondestructive (CF‐LIBS), but only major and minor elements can be evaluated due to the significantly lower sample consumption.  相似文献   

3.
Abstract— High‐performance liquid chromatography (HPLC) based amino acid analysis of a Tagish Lake meteorite sample recovered 3 months after the meteorite fell to Earth have revealed that the amino acid composition of Tagish Lake is strikingly different from that of the CM and CI carbonaceous chondrites. We found that the Tagish Lake meteorite contains only trace levels of amino acids (total abundance = 880 ppb), which is much lower than the total abundance of amino acids in the CI Orgueil (4100 ppb) and the CM Murchison (16 900 ppb). Because most of the same amino acids found in the Tagish Lake meteorite are also present in the Tagish Lake ice melt water, we conclude that the amino acids detected in the meteorite are terrestrial contamination. We found that the exposure of a sample of Murchison to cold water lead to a substantial reduction over a period of several weeks in the amount of amino acids that are not strongly bound to the meteorite matrix. However, strongly bound amino acids that are extracted by direct HCl hydrolysis are not affected by the leaching process. Thus even if there had been leaching of amino acids from our Tagish Lake meteorite sample during its 3 month residence in Tagish Lake ice and melt water, a Murchison type abundance of endogenous amino acids in the meteorite would have still been readily detectable. The low amino acid content of Tagish Lake indicates that this meteorite originated from a different type of parent body than the CM and CI chondrites. The parent body was apparently devoid of the reagents such as aldehyldes/ketones, HCN and ammonia needed for the effective abiotic synthesis of amino acids. Based on reflectance spectral measurements, Tagish Lake has been associated with P‐ or D‐type asteroids. If the Tagish Lake meteorite was indeed derived from these types of parent bodies, our understanding of these primitive asteroids needs to be reevaluated with respect to their potential inventory of biologically important organic compounds.  相似文献   

4.
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5.
Meteorites are delivered from the asteroid belt by way of chaotic zones (Wisdom 1985a). The dominant sources are believed to be the chaotic zones associated with the ν6 secular resonance, the 3:1 mean motion resonance, and the 5:2 mean motion resonance. Though the meteorite transport process has been previously studied, those studies have limitations. Here I reassess the meteorite transport process with fewer limitations. Prior studies have not been able to reproduce the afternoon excess (the fact that approximately twice as many meteorites fall in the afternoon as in the morning) and suggested that the afternoon excess is an observational artifact; here it is shown that the afternoon excess is in fact consistent with the transport of meteorites by way of chaotic zones in the asteroid belt. By studying models with and without the inner planets it is found that the inner planets significantly speed up the transport of meteorites.  相似文献   

6.
The Jezersko meteorite is a newly confirmed stony meteorite found in 1992 in the Karavanke mountains, Slovenia. The meteorite is moderately weathered (W2), indicating short terrestrial residence time. Chondrules in partially recrystallized matrix are clearly discernible but often fragmented and have mean diameter of 0.73 mm. The meteorite consists of homogeneous olivine (Fa19.4) and low‐Ca pyroxenes (Fs16.7Wo1.2), of which 34% are monoclinic, and minor plagioclase (Ab83An11Or6) and Ca‐pyroxene (Fs6Wo45.8). Troilite, kamacite, zoned taenite, tetrataenite, chromite, and metallic copper comprise about 16.5 vol% of the meteorite. Phosphates are represented by merrillite and minor chlorapatite. Undulatory extinction in some olivine grains and other shock indicators suggests weak shock metamorphism between stages S2 and S3. The bulk chemical composition generally corresponds to the mean H chondrite composition. Low siderophile element contents indicate the oxidized character of the Jezersko parent body. The temperatures recorded by two‐pyroxene, olivine‐chromite, and olivine‐orthopyroxene geothermometers are 854 °C, 737–787 °C, and 750 °C, respectively. Mg concentration profiles across orthopyroxenes and clinopyroxenes indicate relatively fast cooling at temperatures above 700 °C. A low cooling rate of 10 °C Myr?1 was obtained from metallographic data. Considering physical, chemical, and mineralogical properties, meteorite Jezersko was classified as an H4 S2(3) ordinary chondrite.  相似文献   

7.
Abstract— The polycyclic aromatic nitrogen heterocycle (PANH) quinoline (C9H7N) was frozen at 20 K in interstellar ice analogs containing either pure water or water mixed with methanol or methane and exposed to ultraviolet (UV) radiation. Upon warming, the photolysis products were analyzed by high‐performance liquid chromatography and nanoscale liquid chromatography‐electrospray ionization mass spectrometry. A suite of hydroxyquinolines, which were formed by the addition of oxygen atoms to quinoline, was observed as the primary product in all the ices. Quinoline N oxide was not formed, but five hydroxyquinoline isomers were produced with no clear dominance of one isomer. Reduction products, formed by hydrogen atom addition, were also created. Ices created at 20 K with H2O: quinoline ratios of 10:1 to 100:1 showed similar product distributions to those at 122 K, with no apparent temperature or concentration dependence. Increasing the UV dose led to a decrease in overall yield, indicating that quinoline and its products may be photo‐destroyed. Methylquinolines were formed upon photolysis of the methanol‐ and methane‐containing ices. In addition, possible methoxyquinolines or quinoline methylene alcohols were formed in the methanol‐containing ice, while methylhydroxyquinolines were created in the methane‐containing ice. This work indicates that oxidation of PANHs could occur in icy extraterrestrial environments and suggests that a search for such compounds in carbonaceous meteorites could illuminate the possible link between interstellar ice chemistry and meteoritic organics. Given the importance of oxidized and alkylated PANHs to biochemistry, the formation and delivery of such molecules to the early Earth may have played a role in the origin and evolution of life.  相似文献   

8.
A rich population of low‐mass planets orbiting solar‐type stars on tight orbits has been detected by Doppler spectroscopy. These planets have masses in the domain of super‐Earths and Neptune‐type objects, and periods less than 100 days. In numerous cases these planets are part of very compact multiplanetary systems. Up to seven planets have been discovered orbiting one single star. These low‐mass planets have been detected by the HARPS spectrograph around 30 % of solar‐type stars. This very high occurrence rate has been recently confirmed by the results of the Kepler planetary transit space mission. The large number of planets of this kind allows us to attempt a first characterization of their statistical properties, which in turn represent constraints to understand the formation process of these systems. The achieved progress in the sensitivity and stability of spectrographs have already led to the discovery of planets with masses as small as 1.5 M⊕ (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

9.
Abstract— –We have analyzed ice samples and meteorites from the LaPaz region of Antarctica to investigate the composition of polycyclic aromatic hydrocarbons (PAHs) and amino acids with the goal to understand whether or not there is a compositional relationship between the two reservoirs. Four LL5 ordinary chondrites (OCs) and one CK carbonaceous chondrite were collected as part of the 2003/2004 ANSMET season. Ice samples collected from directly underneath the meteorites were extracted. In addition, exhaust particles from the snowmobiles used during the expedition were collected to investigate possible contributions from this source. The meteorite samples, the particulate matter and solid‐state extracts of the ice samples and the exhaust filters were subjected to two‐step laser mass spectrometry (L2MS) to investigate the PAH composition. For amino acids analysis, the meteorites were extracted with water and acid hydrolyzed, and the extracts were analyzed with offline OPA/NAC derivatization combined with liquid chromatography with UV fluorescence detection and time of flight mass spectrometry (LC‐FD/ToF‐MS). PAHs in the particulate matter of the ice were found to be qualitatively similar to the meteorite samples, indicating that micron‐sized grains of the meteorite may be embedded in the ice samples. The concentration levels of dissolved PAHs in all the ice samples were found to be below the detection limit of the L2MS. The PAH composition of the snowmobile exhaust is significantly different to the one in particulate matter, making it an unlikely source of contamination for Antarctic meteorites. The amino acids glycine, β‐alanine and γ‐amino‐n‐butyric acid that were detected at concentrations of 3 to 19 parts per billion (ppb) are probably indigenous to the Antarctic meteorites. Some of the LaPaz ice samples were also found to contain amino acids at concentration levels of 1 to 33 parts per trillion (ppt), in particular α‐aminoisobutyric acid (AIB), an abundant non‐protein amino acid of extraterrestrial origin found in some carbonaceous chondrites. We hypothesize that this amino acid could have been extracted from Antarctic micrometeorites and the particulate matter of the meteorites during the concentration procedure of the ice samples.  相似文献   

10.
No meteorites from Mercury and Venus have been conclusively identified so far. In this study, we develop an original approach based on extensive Monte Carlo simulations and diffusion models to explore the radiogenic argon (40Ar*) and helium (4He*) loss behavior and the range of 40Ar/39Ar and (U‐Th)/He age signatures expected for a range of crystals if meteorites from these planets were ever to be found. We show that we can accurately date the crystallization age of a meteorite from both Mercury and Venus using the 40Ar/39Ar technique on clinopyroxene (± orthopyroxene) and that its 40Ar/39Ar age should match the Pb‐Pb age. At the surface of Mercury, phases like albite and anorthite will exhibit a complete range of 40Ar* loss ranging from 0% to 100%, whereas merrillite and apatite will show 100% 4He* loss. By measuring the crystal size and diffusion parameters of a series of plagioclase crystals, one can inverse the 40Ar* loss value to estimate the maximum temperature experienced by a rock, and narrow down the possible pre‐ejection location of the meteorite at the surface of Mercury. At the surface of Venus, plagioclase and phosphate phases will only record the age of ejection. The (U‐Th)/He systematics of merrillite and apatite will be, respectively, moderately and strongly affected by 4He* loss during the transit of the meteorite from its host planet to Earth. Finally, meteorites from Mercury or Venus will each have their own 40Ar/39Ar and (U‐Th)/He isotopic age and 38Arc cosmic ray exposure age signatures over a series of different crystal types, allowing to unambiguously recognize a meteorite for any of these two planets using radiogenic and cosmogenic noble gases.  相似文献   

11.
CV (Vigarano type) carbonaceous chondrites, comprising Allende‐like (CVoxA) and Bali‐like (CVoxB) oxidized and reduced (CVred) subgroups, experienced differing degrees of fluid‐assisted thermal and shock metamorphism. The abundance and speciation of secondary minerals produced during asteroidal alteration differ among the subgroups: (1) ferroan olivine and diopside–hedenbergite solid solution pyroxenes are common in all CVs; (2) nepheline and sodalite are abundant in CVoxA, rare in CVred, and absent in CVoxB; (3) phyllosilicates and nearly pure fayalite are common in CVoxB, rare in CVred, and virtually absent in CVoxA; (4) andradite, magnetite, and Fe‐Ni‐sulfides are common in oxidized CVs, but rare in reduced CVs; the latter contain kirschsteinite instead. Thus, a previously unrecognized correlation exists between meteorite bulk permeabilities and porosities with the speciation of the Ca‐, Fe‐rich silicates (pyroxenes, andradite, kirschsteinite) among the CVox and CVred meteorites. The extent of secondary mineralization was controlled by the distribution of water ices, permeability, and porosity, which in turn were controlled by impacts on the asteroidal parent body. More intense shock metamorphism in the region where the reduced CVs originated decreased their porosity and permeability while simultaneously expelling intergranular ices and fluids. The mineralogy, petrography, and bulk chemical compositions of both the reduced and oxidized CV chondrites indicate that mobile elements were redistributed between Ca,Al‐rich inclusions, dark inclusions, chondrules, and matrices only locally; there is no evidence for large‐scale (>several cm) fluid transport. Published 53Mn‐53Cr ages of secondary fayalite in CV, CO, and unequilibrated ordinary chondrites, and carbonates in CI, CM, and CR chondrites are consistent with aqueous alteration initiated by heating of water ice‐bearing asteroids by decay of 26Al, not shock metamorphism.  相似文献   

12.
Chinese and Japanese historical records of daytime fireballs, and world-wide daytime meteorite falls in the catalogue have been investigated. Among them, there are 253 and 104 records of great daytime fireballs in China and in Japan respectively, and 506 meteorite falls in the daytime are recorded in the Catalogue of Meteorites (1985). The same trends of seasonal and daily variations in the flux of daytime fireballs are clearly seen in both Chinese and Japanese records, and then the distributions of the daytime fireballs seem to suggest the association with meteorites and near-earth minor planets rather than with comets. Possible relations with minor planets, such as (1566) Icarus, (3671) Dionysius, (4450) Pan, (4486) Mithra and others are suggested.  相似文献   

13.
Chinese and Japanese historical records of daytime fireballs, and world-wide daytime meteorite falls in the catalogue have been investigated. Among them, there are 253 and 104 records of great daytime fireballs in China and in Japan respectively, and 506 meteorite falls in the daytime are recorded in the Catalogue of Meteorites (1985).The same trends of seasonal and daily variations in the flux of daytime fireballs are clearly seen in both Chinese and Japanese records, and then the distributions of the daytime fireballs seem to suggest the association with meteorites and near-earth minor planets rather than with comets.Possible relations with minor planets, such as (1566) Icarus, (3671) Dionysius, (4450) Pan, (4486) Mithra and others are suggested.  相似文献   

14.
Abstract— Antarctic meteorites have been and are being well studied but the potential for glaciological and climatological information in the sites where they are found is only beginning to be realized. To date, meteorite stranding surfaces have been identified only in East Antarctica: (1) The MacKay Glacier/David Glacier region contains the Allan Hills and the Reckling Moraine/Elephant Moraine stranding surfaces. Because the Allan Hills Main Icefield has a large proportion of meteorites with long terrestrial ages, these concentrations of meteorites must have had catchment areas extending well inland, in contrast to the present. Where known, bedrock topography is mesa-like in form and influences ice flow directions. Ice levels at the Allan Hills may have been higher by 50–100 m in the past. Reckling Moraine and Elephant Moraine are located on a long patch of ice running westward from Reckling Peak; the ice appears to be pouring over a bedrock escarpment. (2) In North Victoria Land, ice diverges around Frontier Mountain and flows into a site behind the barrier where ablation occurs extensively. It is proposed that meteorites and rocks were dumped by ice flow at the mouth of a valley in the lee of the mountain at the site where a meltwater pond existed, in a depression produced by ablation. Later, the pond migrated headward along the valley to a point where it is today, leaving a morainal deposit with the meteorites at a higher level. (3) Between the Beardmore and Law Glaciers, ice flows sluggishly into the southwestern margin of the Walcott Névé. Northeastern sections of the Walcott are virtually barren of meteorites. The entering Plateau ice is diverted northward to flow along the base of Lewis Cliff. This flow apparently terminates in an ice tongue protruding into a vast moraine, where a very large concentration of meteorites was found on the ice. This final segment of flowing ice is called the Lewis Cliff Ice Tongue. Meteorite Moraine, a subsidiary occurrence 2 km to the northeast, is also found against morainal deposits. The origin of the moraines and the history of meteorite concentration at this site is the subject of some debate. (4) The Transantarctic Mountains are submerged along one segment many hundreds of km in length by ice flowing off the Polar Plateau. The Thiel Mountains, Pecora Escarpment and Patuxent Range are the only surface indications of the underlying mountains along this interval, and meteorite stranding surfaces are found at each of these sites. Little is yet known about ice dynamics at these sites. (5) The immense Yamato Mountains meteorite stranding surface covers an area of about 4000 km2. So far, most meteorites have been recovered in the upper reaches of this blue ice field, where ice flow is slowed by outlying subice barriers of the Yamato Mountains. Individual massifs in this range extend northward over 50 km, and the Yamato Meteorite Icefield loses 1100 m in elevation over this distance. (6) The Sør Rondane Mountains form a barrier to ice flow off the Polar Plateau. The major meteorite stranding surface associated with this barrier is the Nansenisen Icefield, a large ablation area about 50 km upstream of the mountains. The existence of a meteorite stranding surface at this site has not been explained so far. Most meteorite stranding surfaces have been functioning for a long time. They are sites where net ablation of the surface is occurring; the ice at these sites is stagnant or flowing only slowly, and the numbers of meteorites with great terrestrial ages decrease exponentially. Concentration mechanisms operating at these sites involve ablation, direct infall, time, low temperatures, moderate weathering and wind ablation. Detrimental to concentration are ice flow out of the area and extreme weathering. In spite of the fact that the Antarctic Ice Sheet is thought to be over 10 Ma old, we do not find stranding surfaces with meteorites having greater terrestrial ages than 1 Ma. This suggests that stranding surfaces are transient features, affected on a continental scale by possible extreme warming during late Pliocene and on a smaller scale by regional changes that produce differential effects between icefields. The latter effect is suggested by differences in the average terrestrial age of meteorites at different stranding surfaces. In either case, these sites seem to appear as a result of thinning near the edges of the ice sheet, and stratigraphic sequences may be exposed in the ice at stranding surfaces. We review five models for the production of meteorite stranding surfaces: (1) simple deflation of the ice sheet, in which ablation removes great thicknesses of overlying ice, exposing the contained meteorites while allowing direct falls to accumulate, (2) simple accumulation of direct falls on a bare ice surface that is not deflating, (3) ablation of ice trapped against a barrier, in which meteorites accumulate by direct infall while inflowing ice contributes meteorites by ablation discovery, (4) deceleration of ice by a subice barrier, which allows ablation discovery of meteorites in incoming ice and accumulation of other meteorites on the surface by direct infall and (5) stagnation of ice by encounter with an ice mass able to produce an opposing flow vector, in which ablation discovery and direct infall accumulation processes operate to build the meteorite concentration.  相似文献   

15.
Abstract— The Brunflo fossil meteorite was found in the 1950s in mid‐Ordovician marine limestone in the Gärde quarry in Jämtland. It originates from strata that are about 5 million years younger than similar limestone that more recently has yielded >50 fossil meteorites in the Thorsberg quarry at Kinnekulle, 600 km to the south. Based primarily on the low TiO2 content (about 1.8 wt%) of its relict chromite the Brunflo meteorite had been tentatively classified as an H chondrite. The meteorite hence appears to be an anomaly in relation to the Kinnekulle meteorites, in which chromite composition, chondrule mean diameter and oxygen isotopic composition all indicate an L‐chondritic origin, reflecting an enhanced flux of meteorites to Earth following the disruption of the L chondrite parent body 470 Ma. New chondrule‐size measurements for the Brunflo meteorite indicate that it too is an L chondrite, related to the same parent‐body breakup. Chromite maximum diameters and well‐defined chondrule structures further show that Brunflo belongs to the L4 or L5 type. Chromites in recently fallen L4 chondrites commonly have low TiO2 contents similar to the Brunflo chromites, adding support for Brunflo being an L4 chondrite. The limestone in the Gärde quarry is relatively rich (about 0.45 grain kg−1) in sediment‐dispersed extraterrestrial chromite grains (>63 μm) with chemical composition similar to those in L chondrites and the limestone (1–3 grains kg−1) at Kinnekulle, suggesting that the enhanced flux of L chondrites prevailed, although somewhat diminished, at the time when the Brunflo meteorite fell.  相似文献   

16.
Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   

17.
Light and cold extrasolar planets such as OGLE 2005‐BLG‐390Lb, a 5.5 Earth masses planet detected via microlensing, could be frequent in the Galaxy according to some preliminary results from microlensing experiments. These planets can be frozen rocky‐ or ocean‐planet, situated beyond the snow line and, therefore, beyond the habitable zone of their system. They can nonetheless host a layer of liquid water, heated by radiogenic energy, underneath an ice shell surface for billions of years, before freezing completely. These results suggest that oceans under ice, like those suspected to be present on icy moons in the Solar system, could be a common feature of cold low‐mass extrasolar planets. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

18.
On February 24, 1979, a deeply oxidized mass of iron meteorite was excavated from bauxite at an open cut mine on the Gove Peninsula, Northern Territory, Australia. The meteorite, measuring 0.75–1 m in diameter and of unknown total weight, was found at coordinates 12°15.8′S, 136°50.3′E. On removal from the ground, the meteorite is reported to have disintegrated rapidly. A preliminary analysis at the mine laboratory reportedly gave 8.5 wt% Ni. A modern analysis of oxidized material gave Ni = 32.9, Co = 3.67 (both mg g?1), Cr = 168, Cu = 195, Ga = 22.5, Ge = <70, As = 4.16, W = 1.35, Ir = 10.5, Pt = 21.2, Au = 0.672 (all μg g?1), Sb = <150, and Re = 844 (both ng g?1). Competent fragments of oxidized material retain a fine to medium Widmanstätten pattern with an apparent average bandwidth of 0.5 mm (range 0.2–0.9 mm in plane section). Primary mineralogy includes rare γ–taenite and daubréelite, and secondary minerals produced by weathering include awaruite (with up to 78.5 wt% Ni) and an, as yet, unnamed Cu‐Cr‐bearing sulfide with the ideal formula CuCrS2 that is hitherto unknown in nature. Deep weathering has masked many of the features of the meteorite; however, the analysis normalized to the analyses of fresh iron meteorites favors chemical group IIIAB. The terrestrial age of the meteorite is unknown, although it is likely to be in the Neogene (2.5–23 Ma), which is widely accepted as the major period of bauxite formation in the Northern Territory of Australia. Gove is the second authenticated relict meteorite found in Australia.  相似文献   

19.
Compound‐specific carbon isotope analysis (δ13C) of meteoritic organic compounds can be used to elucidate the abiotic chemical reactions involved in their synthesis. The soluble organic content of the Murchison carbonaceous chondrite has been extensively investigated over the years, with a focus on the origins of amino acids and the potential role of Strecker‐cyanohydrin synthesis in the early solar system. Previous δ13C investigations have targeted α‐amino acid and α‐hydroxy acid Strecker products and reactant HCN; however, δ13C values for meteoritic aldehydes and ketones (Strecker precursors) have not yet been reported. As such, the distribution of aldehydes and ketones in the cosmos and their role in prebiotic reactions have not been fully investigated. Here, we have applied an optimized O‐(2,3,4,5,6‐pentafluorobenzyl)hydroxylamine (PFBHA) derivatization procedure to the extraction, identification, and δ13C analysis of carbonyl compounds in the Murchison meteorite. A suite of aldehydes and ketones, dominated by acetaldehyde, propionaldehyde, and acetone, were detected in the sample. δ13C values, ranging from ?10.0‰ to +66.4‰, were more 13C‐depleted than would be expected for aldehydes and ketones derived from the interstellar medium, based on interstellar 12C/13C ratios. These relatively 13C‐depleted values suggest that chemical processes taking place in asteroid parent bodies (e.g., oxidation of the IOM) may provide a secondary source of aldehydes and ketones in the solar system. Comparisons between δ13C compositions of meteoritic aldehydes and ketones and other organic compound classes were used to evaluate potential structural relationships and associated reactions, including Strecker synthesis and alteration‐driven chemical pathways.  相似文献   

20.
Abstract— We investigated the ballistically dispersed melts from Meteor Crater, Arizona, USA to determine the stratigraphic extent of its melt zone from the compositional relationship of melts and target rocks. Most melt particles are crystallized, hydrated, and oxidized; pristine glasses are rare. Hydration and oxidation occurred at ambient temperatures long after the impact. The preserved glasses are generally clear and texturally homogeneous, but unlike typical impact melts, they have unusually heterogeneous compositions, both within individual particles and from sample to sample. For example, the average SiO2 for individual particles ranges from 43 to 65%. The projectile content is unusually high and it is distributed bimodally, with specific samples containing either 5–10% or 20–30% FeO. These compositional heterogeneities most likely reflect the high carbonate content of the target rocks and the release of copious CO2 that dispersed the melts, thereby terminating melt flow and mixing. The high projectile content and the CO2 depleted residue of purely sedimentary rocks produced mafic melts that crystallized fine‐grained olivine and pyroxene. The melts fall into three compositional groups reflecting variable proportions of the major target formations, Moenkopi, Kaibab, and Coconino. Least‐square mixing calculations revealed one group to contain 55% Moenkopi, 40% quartz‐rich, upper Kaibab, and 5% meteorite, suggesting a source depth of <30 m from the pre‐impact surface. The other two melt groups have higher contents of meteorite (15–20%) and Kaibab (50–70%) and contain more SiO2 than average Kaibab. The additional quartz may have been derived from Coconino or the upper Kaibab, implying melt depths >90 m or <30 m, respectively. Additional studies, especially hydrocode calculations, are needed to better understand the source depth of these melts and their exceptionally high projectile content.  相似文献   

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