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1.
The sediment geochemistry, including REE, of surface and core samples from Mansar Lake, along with mineralogical investigations, have been carried out in order to understand the provenance, source area weathering, hydrolic sorting and tectonic setting of the basin. The geochemical signatures preserved in these sediments have been exploited as proxies in order to delineate these different parameters.The major element log values (Fe2O3/K2O) vs (SiO2/Al2O3) and (Na2O/K2O) vs (SiO2/Al2O3) demarcate a lithology remarkably similar to that exposed in the catchment area. The chondrite normalized REE patterns of lake samples are similar to Post Archaean Australian Shale (PAAS) with LREE enrichment, a negative Eu anomaly and almost flat HREE pattern similar to a felsic and/or cratonic sedimentary source. However, the La–Th–Sc plot of samples fall in a mixed sedimentary domain, close to Upper Continental Crust (UCC) and PAAS, suggesting sedimentary source rocks for the Mansar detritus. It also indicates that these elements remained immobile during weathering and transportation. The mineralogical characteristic, REEs, and high field strength elements (HFSE), together with the high percentage of metamorphic rock fragments in the Siwalik sandstone, support a metamorphic source for lower Siwalik sediments. A very weak positive correlation between Zr and SiO2, poor negative correlation with Al2O3, negative correlation of (La/Yb)N and (Gd/Yb)N ratios with SiO2 and positive correlation with Al2O3, suggest that Zr does not dominantly control the REE distribution in Mansar sediments. The petrographic character and textural immaturity indicate a short distance transport for the detritus. The distribution of elements in core samples reflect fractionation. The higher Zr/Th and Zr/Yb ratios in coarse sediments and PAAS compared to finer grained detritus indicate sedimentary sorting. Plots of the geochemical data on tectonic discrimination diagrams suggest that the sediments derived from the lower Siwalik were originated within a cratonic interior and later deposited along a passive margin basinal setting. It therefore reveals lower Siwalik depositional history.  相似文献   

2.
Geochemical and mineralogical data from a Pliocene to Pleistocene alluvial sequence are integrated to access the factors that control rare earth elements (REE) geochemistry and the evolution and spatial differences in provenance. The studied alluvial system is situated in a tectonic active setting at the contact between the Variscan Massif, with several Paleozoic and Precambrian units that support a coastal range, and the Atlantic margin. REE and HREE abundances are generally higher in swamp-lake than in floodplain sediments. The majority of the REE in floodplain sediments is hosted by Y and Th-bearing minerals and illite; in swamp-lake sediments is also probable an association with organic matter. The high Gd/Yb, Eu/Eu* and kaolinite content in older sediments suggest that during the earlier phases provenance was mainly from the hinterland (weathered granitic rocks and its sediment cover). The subsequent illite (Mg-rich) clay assemblages and REE patterns indicate mainly lateral input from the eastern basin edge (Palaeozoic and Precambrian metapelitic rocks). These sediments tend to have lower Gd/Yb and La/Sm than their source rocks. The analysis of the chemical index of alteration (CIA) indicates that although a north-directed fluvial axis existed at that time the “mature” basin edge units found to the south (Silurian) had a limited role in supplying sediments. This shift in provenance is attributed to the uplift of the coastal range. Afterwards, the contribution of recycled Cretaceous and Cenozoic sedimentary units increased progressively. This is demonstrated by the increase is SiO2/TiO2, CIA and kaolinite/illite when the climatic conditions are expected to have become less chemically aggressive.  相似文献   

3.
《Quaternary Science Reviews》2007,26(9-10):1362-1368
Sediments deposited on the bottom of Lake Baikal have contributed to the understanding of a long-term environmental history of continents. Rare earth elements (REEs) along with major elements and loss on ignition (LOI) of Baikal sediments were determined with the aim of evaluating their suitability for a new paleoenvironmental proxy. Our interest is concentrated on paleoenvironmental change during the Last Glacial/Interglacial transition (LGIT). Chondrite-normalized REE patterns for Baikal sediments show a similar variation to those for typical upper continental crustal materials. Three parameters of (La/Yb)n (n: chondrite-normalized value) ratio, ΣREE/TiO2 and Eu anomaly were used to express detailed characteristics of Baikal sediments. Depth profile of (La/Yb)n ratio shows abrupt change, whose timing corresponds to the beginning of climatic warming inferred from the profiles of SiO2/TiO2 and LOI. In addition, (La/Yb)n ratio, ΣREE/TiO2 and the degree of Eu anomaly correlate with each other. This suggests that inflow process of particulate materials into the lake may have changed during the LGIT. The analytical results of this study lead to the conclusion that REE is a useful paleoenvironmental proxy in the Baikal region.  相似文献   

4.
对于青藏高原北部羌塘盆地中央隆起带晚古生代的构造演化历史,学术界目前仍存在不同观点。位于盆地中央隆起带角木日地区的羌资5井揭示出的下二叠统展金组细碎屑岩,对于该地区古地理研究和构造背景约束具有重要意义。通过对该井中17个展金组粉砂质泥岩和泥质粉砂岩样品的稀土元素地球化学研究表明:样品 ω(ΣREE) 整体较高,ω(ΣLREE)/ω(ΣHREE)及(La/Yb)N等比值显示其具有较弱的轻、重稀土元素分异;Ceanom,Ce/Ce*,Eu/Eu*等参数反映样品主要形成于具有一定深度的浅海还原环境;(La/Yb)N值自下而上呈降低趋势,表明下部的沉积速率低于上部。稀土元素组合及其比值特征指示展金组物源以玄武岩和沉积岩混合为主。根据La-Th-Sc构造背景判别图解分析,并与不同构造背景下的杂砂岩稀土元素特征比较,认为展金组沉积岩的物源可能来自于具有类似岛弧构造特征的环境。  相似文献   

5.
渝东南地区的下志留统石牛栏组作为重要的油气储集层,研究其古环境变化、物质来源及物源区构造背景具有重要意义。本文采用稀土元素总量w(ΣREE)、REE配分模式、以及w(ΣLREE)/w(ΣHREE)、w(La)_N/w(Yb)_N、w(Ce)_N/w(Yb)_N、w(La)_N/w(Sm)_N、w(Gd)_N/w(Yb)_N、δEu、δCe、Ce_(anom)等特征值研究方法,对渝东南下志留统石牛栏组典型剖面的稀土元素特征及古海洋环境和物源进行深入研究。结果表明:石牛栏组灰岩稀土元素总量略低于大陆地壳平均值,轻稀土较为富集,重稀土亏损,铕明显负异常,铈负异常较微弱。w(ΣREE)证实了石牛栏组的沉积水体由浅缓慢变深再急剧变浅的变化过程。Eu负异常、Ce负异常和C_(eanom)值均揭示石牛栏组沉积时期海水具有弱还原性。REE的分异程度反映了石牛栏组从沉积早期到沉积晚期,沉积速率总体降低。稀土元素的比值特征及w(ΣREE)—w(La)/w(Yb)图解表明其物源源自雪峰山隆起,源岩主要为沉积岩。  相似文献   

6.
The Neoproterozoic Bhander Group in the Son Valley, central India conformably overlying the Rewa Group, is the uppermost subdivision of the Vindhyan Supergroup dominantly composed of arenites, carbonates and shales. In Maihar-Nagod area, a thick pile of unmetamorphosed clastic sedimentary rocks of Bhander Group is exposed, which provides a unique opportunity to study Neoproterozoic basin development through provenance and tectonic interpretations. The provenance discrimination and tectonic setting interpretations are based on modal analysis and whole rock geochemistry. The average framework composition of the detrital sediments composed of quartz and sedimentary lithic fragments are classified as quartz arenite to sublitharenite. The sandstone geochemically reflects high SiO2, moderate Al2O3 and low CaO and Na2O type arenite. The high concentration of HFSE such as Zr, Hf, and Th/Sc, Th/U ratios in these sandstones indicate a mixed provenance. The chondrite normalized REE pattern shows moderate to strong negative Eu anomaly which suggests that major part of the sediments were derived from the granitic source area. The sandstone tectonic discrimination diagrams and various geochemical plots suggest that the provenance of the lower and upper Bhander sandstone formations was continental interior to recycled orogen.  相似文献   

7.
Sandstones of Jhuran Formation from Jara dome, western Kachchh, Gujarat, India were studied for major, trace and rare earth element (REE) geochemistry to deduce their paleo-weathering, tectonic setting, source rock characteristics and provenance. Petrographic analysis shows that sandstones are having quartz grains with minor amount of K-feldspar and lithic fragments in the modal ratio of Q 89:F 7:L 4. On the basis of geochemical results, sandstones are classified into arkose, sub-litharenite, wacke and quartz arenite. The corrected CIA values indicate that the weathering at source region was moderate to intense. The distribution of major and REE elements in the samples normalized to upper continental crust (UCC) and chondrite values indicate similar pattern of UCC. The tectonic discrimination diagram based on the elemental concentrations and elemental ratios of Fe2O3 + MgOvs. TiO2, SiO2 vs. log(K2O/Na2O), Sc/Cr vs. La/Y, Th–Sc–Zr/10, La–Th–Sc plots Jhuran Formation samples in continental rift and collision settings. The plots of Ni against TiO2, La/Sc vs. Th/Co and V–Ni–Th ?10 reveals that the sediments of Jhuran Formation were derived from felsic rock sources. Additionally, the diagram of (Gd/Yb) N against Eu/Eu ? suggest the post-Archean provenance as source possibly Nagar Parkar complex for the studied samples.  相似文献   

8.
萤石经常以脉石矿物存在于各类金属矿床中,但以矿石矿物与金属矿物共存较为少见。布拖小洞子铅锌矿体和萤石矿体是赋存在震旦系灯影组不同部位的典型矿床,受四开-交际河断裂的次级断层带控制,是该区较为特殊,研究程度较低的一类矿床。其中萤石矿床产于与黑色燧石条带白云岩相关的断裂构造,矿石矿物以萤石为主。本文通过对震旦系灯影组下部萤石矿床开展稀土元素地球化学研究,结果表明轻稀土元素富集,重稀土元素略亏损,LREE/HREE介于0.96~1.61,(La/Yb)_N为1.19~3.23,稀土元素配分图表现出略微右倾的特征,具Eu正异常和Ce负异常特征。Tb/Ca-Tb/La、Y/Ho-La/Ho及La/Yb-∑REE等图解表明小洞子萤石矿床主要为同一体系不同阶段的热液产物,破碎带充填交代型矿床成因,其成矿物质来源与灯影组地层和峨眉山玄武岩热液有关。  相似文献   

9.
苏扣林  丁兴  郭宇  石晓龙 《中国地质》2021,48(1):161-172
广州市增城地质公园发育有大量的燕山期安山岩和流纹岩,由于缺少详细的岩石地球化学研究,这些火山岩的成因和所代表的大地构造意义一直未明确。文章对上述火山岩进行了较为系统的全岩地球化学以及同位素地球化学分析。研究结果显示,安山岩具有安第斯型火山岩特点,显示Nb、Ta、Sr和Ti的亏损,Isr值介于0.70332~0.7144,平均值0.7092,岩石稀土总量较低(ΣREE=158.9×10^-6~215.0×10^-6),平均值186.8×10^-6,轻重稀土元素分异较弱((La/Yb)N5.06~9.87),平均值7.01,Eu负异常不明显(δEu=0.80~1.38),平均值δEu=0.94。流纹岩具有高钾特点,有明显的Ba、Sr、P、Eu、Ti负异常和Pb、Yb正异常,其Isr值介于0.71393~0.73650,平均值0.72615,岩石稀土总量较低(ΣREE=93.4×10^-6~481.5×10^-6),平均值285.7×10^-6,轻重稀土元素分异弱((La/Yb)N=0.65~9.51),平均值4.35,Eu负异常很明显(δEu=0.01~0.03),平均值δEu=0.02,全岩Rb-Sr同位素年龄为(112±12)Ma。综合的地球化学研究表明,增城地质公园安山质-流纹质火山岩均属壳幔混合成因,其中安山岩以幔源为主,而流纹岩则以壳源为主,分别形成于早侏罗世和早白垩世太平洋板块俯冲碰撞挤压的构造背景下。这对华南地区中生代构造演化的深入认识具有重要的地质意义。  相似文献   

10.
《China Geology》2018,1(2):225-235
For the first time, we present the rare earth element (REE) and sulfur isotopic composition of hydrothermal precipitates recovered from the Tangyin hydrothermal field (THF), Okinawa Trough at a water depth of 1206 m. The natural sulfur samples exhibit the lowest ΣREE concentrations (ΣREE= 0.65×10–6–4.580×10–6) followed by metal sulfides (ΣREE=1.71×10–6–11.63×10–6). By contrast, the natural sulfur-sediment samples have maximum ΣREE concentrations (ΣREE=11.54×10–6–33.06×10–6), significantly lower than those of the volcanic and sediment samples. Nevertheless, the δEu, δCe, (La/Yb)N, La/Sm, (Gd/Yb)N and normalized patterns of the natural sulfur and metal sulfide show the most similarity to the sediment. Most hydrothermal precipitate samples are characterized by enrichments of LREE (LREE/HREE=10.09–24.53) and slightly negative Eu anomalies or no anomaly (δEu=0.48–0.99), which are different from the hydrothermal fluid from sediment-free mid-oceanic ridges and back-arc basins, but identical to the sulfides from the Jade hydrothermal field. The lower temperature and more oxidizing conditions produced by the mixing between seawater and hydrothermal fluids further attenuate the leaching ability of hydrothermal fluid, inducing lower REE concentrations for natural sulfur compared with metal sulfide; meanwhile, the negative Eu anomaly is also weakened or almost absent. The sulfur isotopic compositions of the natural sulfur (δ34S=3.20‰–5.01‰, mean 4.23‰) and metal sulfide samples (δ34S=0.82‰–0.89‰, mean 0.85‰) reveal that the sulfur of the chimney is sourced from magmatic degassing.  相似文献   

11.
Late Paleozoic sedimentary strata outcrop extensively in central Inner Mongolia, and are a key to understanding the tectonic evolution of the southeastern Central Orogenic Belt. A combined analysis of petrography, whole-rock major and trace element, and Nd isotope is carried out on representative sandstones from the Late Paleozoic sedimentary strata (420–270 Ma). The sandstones are mainly wackes and litharenites in lithology, with low SiO2/Al2O3 of 2.85–9.47 (averagely 5.22) and poor textural and compositional maturities, implying short sediment transportation between the depositional basins and provenances. The trace element compositions are generally comparable to that of the average upper continent crust (UCC), with negatively-sloping chondrite-normalized rare earth element distribution patterns ((La/Yb)N = 3.43–11; averagely 6.94) and flat UCC-normalized trace element distribution patterns. The Nd isotopic compositions show great variation (ԐNd(t) = −5.01 to 5.35) with depositional time of the sandstones, and coincide well with the arc magmatic phases in central Inner Mongolia. The geochemical signatures of the sandstones indicate that the dominant provenances are intermediate to felsic arc magmatic rocks that have ages approximating the deposition, although old, recycled sediments may have made a minor contribution. An active continental arc setting during the Late Paleozoic in central Inner Mongolia, controlled by the northward subduction of the Paleo-Asian oceanic slab, was the most likely depositional tectonic setting of the sandstones. This active continental arc setting continued to at least 270 Ma, implying that the final closure of the Paleo-Asian Ocean along the Solonker suture zone most likely occurred sometime during the Late Permian to Early Triassic. The northward subduction of the Paleo-Asian Ocean is likely of West Pacific-style, in which the present-day Baolidao arc has a close genetic link with the South Mongolian microcontinent and, likely, the former originally formed as the arc margin of the latter.  相似文献   

12.
北羌塘盆地那底岗日剖面中上侏罗统碳酸盐岩发育,其中以布曲组和索瓦组最为发育,对研究该区中上侏罗统沉积环境具重要意义。通过对稀土元素分布规律、分布特征及地球化学特征值分析,表明该套碳酸盐岩中稀土元素平均总含量(ΣREE)较低,为35.305μg/g;ΣLREE/ΣHREE比值为7.769～9.046,轻重稀土分馏明显,且稀土总含量(ΣREE)与SiO2和Al2O3含量呈正相关,与CaO含量呈负相关,说明沉积期有大量陆源碎屑注入。δCe平均值为0.966,基本无异常,但不同地层中有一定变化,布曲组到索瓦组一段、二段沉积水体氧化性显示为强-弱-强演化过程。LaN/YbN比值为1.124～1.493,其中索瓦组二段数值最小,沉积时期水体酸性最弱。表明研究区沉积水体具弱还原性,沉积时期有大量陆源碎屑注入,为近岸碳酸盐岩沉积。  相似文献   

13.
元素地球化学是沉积物源判别和环境研究的重要手段,但河口海岸地区沉积动力环境复杂多变,人类活动影响强烈,全岩沉积地球化学的示踪研究存在局限性和多解性。选择长江下游干流悬浮物、东海陆架表层沉积物以及长江口具有一百多年沉积记录的ZK6孔,通过化学相态分析（1 N HCl处理）,探究酸溶态微量元素组成特征及其对河口环境变迁的指示。相较于钻孔全岩样品,酸溶态Sr/Ba比能更可靠地反映河口古盐度和海陆相沉积环境的变化。ZK6孔沉积物酸溶态稀土元素（REE）主要赋存于Mn氧化物中,Mn、ΣREE含量、Ce/Ce*以及Sr/Ba比在1899—2007年间呈三段式变化,主要反映长江河口流路分汊和主泓位置改变引起的河口沉积环境变化,进而影响河口环境中活跃元素和次生组分在沉积地层中的保存记录。该研究对今后深化认识复杂河口环境下微量元素地球化学行为以及微量元素示踪海洋环境变化具有借鉴意义。  相似文献   

14.
The early Proterozoic metasedimentary sequence of the Alligator Rivers Region (a part of the Pine Creek Geosyncline) in the Northern Territory, Australia, overlies an Archaean granitoid basement. Early Proterozoic sedimentary sequences, in general, record important changes in the composition of the upper continental crust about the Archaean-Proterozoic boundary. However, the geochemistry of only a few of these sequences has been documented. The geochemistry of the early Proterozoic succession in the Alligator Rivers Region is reported here and the results are interpreted in terms of differences between the stratigraphic units, their provenance—particularly in relation to crustal evolution, and their subsequent metamorphism and weathering.Clastic metasedimentary rocks throughout the Alligator Rivers Region have a remarkably uniform major and trace element geochemistry. The Kakadu Group and upper member of the Cahill Formation are relatively more enriched in SiO2 and correspondingly more depleted in Al2O3 than the rest of the sequence, reflecting the greater dominance of metapsammitic assemblages. The lower member of the Cahill Formation, which hosts the major U deposits of the Alligator Rivers Region, and the metasedimentary sequence in general, exhibit no significant enrichment in U above normal background values. Rare earth element (REE) concentrations in the metasedimentary units within the Alligator Rivers Region are uniform, though in detail there are some important differences within and between formations.The composition of the early Proterozoic clastic metasediments in the Alligator Rivers Region is consistent with the composition of similar material of the same age from other areas, and supports current ideas on crustal evolution. The Alligator Rivers metasediments are enriched in Si and K, and depleted in Mg, Ca, and Na relative to the Archaean average for clastic sedimentary rocks, and their REE geochemistry resembles typical post-Archaean sedimentary rocks having a light REE enriched pattern and a distinct Eu/Eu1 depletion compared to typical Archaean sediments. However, the REE data indicate that two compositionally distinct sources are involved in the provenance of the Kakadu Group, and possibly the lower member of the Cahill Formation, where two types of REE patterns can be distinguished on their HREE concentration and Eu/Eu1 anomaly.  相似文献   

15.
大同盆地是典型的干旱-半干旱内陆盆地,盆地中部地下水碘含量异常,对当地饮用水安全造成了严重威胁.对盆地高碘地下水分布区沉积物组成及稀土元素(REE) 进行了地球化学研究,结果表明,地下水系统呈弱碱性(pH值为7.18~9.64) 的偏还原环境,沉积物多为Ce正常或轻微负异常及Eu负异常;沉积物中碘含量为0~1.78×10-6;ΣREE含量较高,ΣLREE/ΣHREE比值为2.79~4.14,即富集轻稀土元素(LREE) 而亏损重稀土元素(HREE).ΣREE与碘含量呈负相关关系,虽然铁氧化物/氢氧化物矿物的还原性溶解可导致二者的释放,但由于沉积物有机质产生的低结晶矿物对碘的强吸附性,使沉积物中碘含量较高;弱碱性环境中REE的再吸附过程会导致沉积物中富集LREE;沉积物中碘含量与氧化还原敏感组分TOC、U、V及[Eu]N的关系也表明,地下水系统的氧化还原条件及有机质含量是影响碘富集的重要因素.   相似文献   

16.
总结了内蒙古大石寨地区1∶25万区域地球化学调查获得的1点/4km2的水系沉积物组合样品中的La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y等15种稀土元素的区域地球化学分布特征。稀土元素分布与研究区中部的黑云母花岗岩密切相关,轻稀土主要分布在该岩体外围的二叠系地层中,重稀土主要分布在该岩体上方。该岩体上方和外围地层的稀土元素分布、稀土元素总量、轻重稀土比及δCe、δEu、(La/Sm)N、(La/Tb)N、(La/Lu)N、(Ce/Yb)N、(Gd/Lu)N等稀土元素分馏特征的差异明显。利用区域地球化学调查水系沉积物样品中的稀土元素含量,可获得研究区可靠的稀土元素区域地球化学分布特征,也可反映研究区地质特点,并为区域地球化学异常解译提供参考资料。  相似文献   

17.
对柴达木盆地北缘(简称柴北缘)鱼卡地区鱼油页1井(YYY-1)页岩段稀土元素地球化学分析,揭示了其对古环境、古物源和古气候的响应,并探讨了对油页岩成矿的影响。分析结果表明:石门沟组页岩段稀土元素总量(ΣREE)为(139.16~342.59)×10~(-6),平均值为236.66×10~(-6),高于北美页岩(NASC)和后太古宙页岩(PASS)。ΣLREE/ΣHREE和(La/Yb)_N等地球化学参数表明,轻重稀土元素分异明显;分布模式为轻稀土元素富集、重稀土元素相对亏损。地球化学参数以及La/Yb-ΣREE图解表明,研究区物源主要为上地壳沉积岩和火山岩的混合来源。元素Eu具有明显的负异常,指示沉积水体为缺氧的还原环境,为油页岩中有机质的富集提供良好的保存条件。根据高含量的ΣREE值以及δEu异常值,结合前人对该地区的孢粉研究成果,石门沟组页岩段形成于暖湿的气候条件,为油页岩的形成提供良好的物质来源和保存条件。  相似文献   

18.
The major, trace and rare earth element (REE) contents of metapelite (MPL), metapsammite (MPS) and metamarl (MM) samples from the Cambro-Ordovician Seydi?ehir Formation were analyzed to investigate their provenance and tectonic setting. The MPS, MPL, and MM samples have variable SiO2 concentrations, with average values of 72.36, 55.54, and 20.95 wt%, moderate SiO2/Al2O3 ratios (means of 6.88, 3.23, and 3.80), moderate to high Fe2O3 + MgO contents (means of 5.14, 9.55, 3.56 wt%), and high K2O/Na2O ratios (means of 3.26, 3.64, 2.90), respectively. On average, the chemical index of alteration (CIA) values of the MPS and the MPL are 65.87 and 71.96, respectively, while the chemical index of weathering (CIW) values are 74.54 and 85.09, respectively. These data record an intermediate to high degree of alteration (weathering) of plagioclase to illite/kaolinite in the samples’ provenance. The chondrite-normalized REE patterns of all the sample groups are similar and are characterized by subparallel light rare earth elements (LREE)-enriched, relatively flat heavy rare earth elements (HREE) patterns with pronounced Eu anomalies (mean of 0.69) and moderate fractionation [average (La/Yb)N = 8.7]. Plots of sediments in ternary diagrams of La, Th, Sc and elemental ratios (La/Sc, Th/Sc, Cr/Th, Eu/Eu*, La/Lu, Co/Th, La/Sc and Sc/Th), which are critical for determining provenance, and REE patterns indicate that the metaclastic units of the Seydi?ehir Formation were derived dominantly from felsic to intermediate magmatic rocks and not from a mafic source. The La–Sc–Th and Th–Sc–Zr/10 ternary diagrams of the Seydi?ehir Formation are typical of continental island arc/active continental margin tectonic settings. The geologic location and geochemistry of the Seydi?ehir Formation suggest that it was deposited in an Andean-type retroarc foreland basin during the Late Cambrian–Early Ordovician period. The Neoproterozoic intermediate to felsic magmatic rocks and metaclastic sediments with felsic origins of the Sand?kl?–Afyon Basement Complex (SBC) and their equivalent units, which are thought to be overlain by the younger units in the study area, may be the dominant source rocks for the Seydi?ehir Formation.  相似文献   

19.
The Metasedimentary rocks from the Adola metamorphic belt has been analysed for major, minor, and trace elements, including REEs, in order to investigate the provenance and tectonic setting of these rocks.On the basis of filed work, petrographic data and major element geochemistry the Adola sedimentary rocks are essentially greywackes with subordinate lithic arenite. Among the 27 samples analysed, only two samples are quartz arenite with SiO2 values above 89%. CaO-Na2O-K2O diagrams showed that most sample cluster around the average plots of granites and granodiorites. In order to determine the tectonic setting and provenance of the rocks, the samples are plotted on various binary and ternary diagrams. The plots on Fe2O3T+MgO versus TiO2, K2O/Na2O, Al2O3/SiO2 and Al2O3/(CaO+Na2O) plots show that the Adola sediments have Oceanic Island Arc(OIC), Continental Island Arc(CIA), Active Continental Margin(ACM) and Passive Margin(PM) characteristics. Most samples, however, show island arc affinity. Only two samples (the quartz arenites) fall in the Passive Margin (PM) field.The trace element characteristics of these rocks discriminate the rocks only into oceanic and continental arc fields. The relatively high abundance of the transition metals, mainly Co, Ni, Cr and the low concentration of TiO2 correlates well with the previously determined geochemical affinity of the basic rocks of Adola suggesting the dominance of the low- Ti oceanic tholeiites and even boninites in the source region.The REE patterns show three distinct groupings; a)With strong LREE enrichment, flat HREE and with out Eu anomaly, shows similar patterns with that of the oceanic island arc rocks; b) samples with strong Light REE enrichment, flat HREE pattern and strong negative Eu anomaly showing similar patterns to the Andean type andesites, probably derived from granitic gneisses and are affiliated to Active Continental Margin settings; c) this group is represented by a single plot having an enriched LREE pattern, flat HREE pattern and strong positive Eu anomaly. It is most likely that this pattern is related to a high normative plagioclase content due to local accumulation of feldspar during sedimentation rather than representing excessive Eu content of the precursor rock. The REE pattern represented by this sample is roughly similar to that of the Devonian greywackes of Australia.In conclusion, the use of geochemical characteristics of the sediments coupled with the geological information from the area strengthens the suprasubduction zone (SSZ) ophiolitic tectonic setting interpretation suggested (Yibas 1993) for the Adola belt. The trace element plots and their absolute abundance, and the REE patterns strongly constrain the tectonic setting and the provenance of the metasediments to an arc related setting.  相似文献   

20.
寻乌岩组变沉积岩发育在江西南部新元古代—早古生代南城—寻乌盆地内,时代为震旦—寒武纪。寻乌岩组的Si O2含量变化较大,除1个含量较低的样品外,平均为63.01%,具有相对较高的K2O、Al2O3及(TFe O+Mg O)值,较低的Na2O、Ca O。相容元素含量与后太古代澳大利亚页岩(PAAS)十分接近,高于中国东部上地壳,与其较高的(TFe O+Mg O)特征相吻合,说明源区具有一定数量的中基性组分。稀土元素总量高于上地壳及PAAS,但其球粒陨石标准化配分模式与典型的上地壳及PAAS相似,表现为明显向右倾斜,轻稀土富集,重稀土平坦,铕负异常显著,铈负异常不明显。岩石地球化学特征显示其原岩属于一种中等成熟度的陆源碎屑岩,物源主要为被改造的上地壳长英质和花岗质物源区,少部分物源为中基性火山岩。高场强元素及稀土元素等不活动元素地球化学特征表明其沉积环境为浅海—半深海,其构造环境属于发育有裂谷系的被动大陆边缘,该认识从沉积岩地球化学方面为华南早古生代构造属性提供了新资料。  相似文献   

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