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1.
A start‐up study for biohydrogen production from palm oil mill effluent (POME) is carried out in a pilot‐scale up‐flow anaerobic sludge blanket fixed‐film reactor (UASFF). A substrate with a chemical oxygen demand (COD) of 30 g L?1 is used, starting with molasses solution for 30 days and followed by a 10% v/v increment of POME/molasses ratio. At 100% POME, a hydrogen content of 80%, hydrogen production rate of 36 L H2 per day, and maximum COD removal of 48.7% are achieved. Bio‐kinetic coefficients of Monod, first‐order, Grau second‐order, and Stover‐Kincannon kinetic models are calculated to describe the performance of the system. The steady‐state data with 100% POME shows that Monod and Stover‐Kincannon models with bio‐kinetic coefficients of half‐velocity constant (Ks) of 6000 mg COD L?1, microbial decay rate (Kd) of 0.0015 per day, growth yield constant (Y) of 0.786 mg volatile suspended solids (VSS)/mg COD, specific biomass growth rate (μmax) of 0.568 per day, and substrate consumption rate of (Umax) 3.98 g/L day could be considered as superior models with correlation coefficients (R2) of 0.918 and 0.989, respectively, compared to first‐order and Grau's second‐order models with coefficients of K1 1.08 per day, R2 0.739, and K2s 1.69 per day, a = 7.0 per day, b = 0.847.  相似文献   

2.
In the present research, laundry wastewater treatment is studied using the electrocoagulation/electroflotation process. For the optimization of treatment conditions such as electrode type (Al–Al, Al–Fe, Fe–Fe, and Fe–Al), initial pH (5–9), current (0.54–2.16 A), and application time (15–60 min), response surface methodology is used. Removal efficiencies of chemical oxygen demand (COD), color, anionic surfactant, microplastic, and phosphate are studied. It is determined that the most effective removal is obtained with 2.16 A current, pH 9, and 60 min reaction time using Fe–Al electrode. Here, 91%, 94%, 100%, and 98% removal efficiencies are achieved for COD, surfactant, color, and microplastic, respectively. The operating cost of the combined process is calculated as $1.32 m?3 for the optimum removal parameters. The adsorption kinetics study shows that the removal follows second‐order kinetics. The laboratory‐scale test results indicate that the electrocoagulation/electroflotation process is feasible for the treatment of laundry wastewater.  相似文献   

3.
This study reports the performance of a combined anaerobic–aerobic packed‐bed reactor that can be used to treat domestic sewage. Initially, a bench‐scale reactor was operated in three experimental phases. In the first phase, the anaerobic reactor was operated with an average organic matter removal efficiency of 77% for a hydraulic retention time (HRT) of 10 h. In the second phase, the reactor was operated with an anaerobic stage followed by an aerobic zone, resulting in a mean value of 91% efficiency. In the third and final phase, the anaerobic–aerobic reactor was operated with recirculation of the effluent of the reactor through the anaerobic zone. The system yielded mean total nitrogen removal percentages of 65 and 75% for recycle ratios (r) of 0.5 and 1.5, respectively, and the chemical oxygen demand (COD) removal efficiencies were higher than 90%. When the pilot‐scale reactor was operated with an HRT of 12 h and r values of 1.5 and 3.0, its performance was similar to that observed in the bench‐scale unit (92% COD removal for r = 3.0). However, the nitrogen removal was lower (55% N removal for r = 3.0) due to problems with the hydrodynamics in the aerobic zone. The anaerobic–aerobic fixed‐bed reactor with recirculation of the liquid phase allows for concomitant carbon and nitrogen removal without adding an exogenous source of electron donors and without requiring any additional alkalinity supplementation.  相似文献   

4.
A three-layer Artificial Neural Network (ANN) model (9:12:1) for the prediction of Chemical Oxygen Demand Removal Efficiency (CODRE) of Upflow Anaerobic Sludge Blanket (UASB) reactors treating real cotton textile wastewater diluted with domestic wastewater was presented. To validate the proposed method, an experimental study was carried out in three lab-scale UASB reactors to investigate the treatment efficiency on total COD reduction. The reactors were operated for 80 days at mesophilic conditions (36–37.5°C) in a temperature-controlled water bath with two hydraulic retention times (HRT) of 4.5 and 9.0 days and with organic loading rates (OLR) between 0.072 and 0.602 kg COD/m3/day. Five different dilution ratios of 15, 30, 40, 45 and 60% with domestic wastewater were employed to represent seasonal fluctuations, respectively. The study was undertaken in a pH range of 6.20–8.06 and an alkalinity range of 1,350–1,855 mg/l CaCO3. The concentrations of volatile fatty acids (VFA) and total suspended solids (TSS) were observed between 420 and 720 mg/l CH3COOH and 68–338 mg/l, respectively. In the study, a wide range of influent COD concentrations (CODi) between 651 and 4,044 mg/l in feeding was carried out. CODRE of UASB reactors being output parameter of the conducted anaerobic treatment was estimated by nine input parameters such as HRT, pH, CODi concentration, operating temperature, alkalinity, VFA concentration, dilution ratio (DR), OLR, and TSS concentration. After backpropagation (BP) training combined with principal component analysis (PCA), the ANN model predicted CODRE values based on experimental data and all the predictions were proven to be satisfactory with a correlation coefficient of about 0.8245. In the ANN study, the Levenberg-Marquardt Algorithm (LMA) was found as the best of 11 BP algorithms. In addition to determination of the optimal ANN structure, a linear-nonlinear study was also employed to investigate the effects of input variables on CODRE values in this study. Both ANN outputs and linear-nonlinear study results were compared and advantages and further developments were evaluated.  相似文献   

5.
In the following study, two methods were employed in which olive mill wastewaters were treated by using reverse osmosis membranes (BW30 and XLE). In the first, wastewater was centrifuged and then passed through the reverse osmosis whereas in the second, an ultrafiltration was placed between the centrifuge and the reverse osmosis. The reverse osmosis experiments were conducted under 10, 15, 20, and 25 bar. The chemical oxygen demand (COD) removal efficiencies under 25 bar were found to be 97.5% for both BW30 and XLE membranes. The highest conductivity removal rates obtained under 25 bar for BW30 and XLE membranes were found to be 95.6 and 96.2%, respectively. As for the highest permeation flux values obtained under 25 bar, they were separately determined for BW30 and XLE as 15.3 and 21.2 L m?2 h?1, respectively. The performances of the membranes were also evaluated in terms of their mass transfer coefficients. According to this, all mass transfer coefficients were found to be <1 and also in proximate to one another; this clearly reflects the results as COD and conductivity removals were approximate and there was a lack of any significant difference, whether ultrafiltration was applied or not.  相似文献   

6.
In this study, the oxidative decolorization of C.I. reactive yellow 145 (RY 145) from synthetic textile wastewater including RY 145 and polyvinyl alcohol by Fenton and sono‐Fenton processes which are the combination of Fenton process with ultrasound has been carried out. The effects of some operating parameters which are the initial pH of the solution, the initial concentration of Fe2+, H2O2, and the dye, temperature, and agitation speed on the color and chemical oxygen demand (COD) removals have been investigated. The optimum conditions have been found as [Fe2+] = 20 mg/L, [H2O2] = 20 mg/L, pH 3 for Fenton process and [Fe2+] = 20 mg/L, [H2O2] = 15 mg/L, pH 3 for sono‐Fenton process by indirectly sonication at 35 kHz ultrasonic frequency and 80 W ultrasonic power. The color and COD removal efficiencies have been obtained as 91 and 47% by Fenton process, and 95 and 51% by sono‐Fenton processes, respectively. Kinetic studies have been performed for the decolorization of RY 145 under optimum conditions at room temperature. It has been determined that the decolorization has occurred rapidly by sono‐Fenton process, compared to Fenton process.  相似文献   

7.
《Marine pollution bulletin》2012,64(5-12):98-101
The treatment capacity of an integrated constructed treatment system (CTS) was explored which was designed to reduce phosphorus (P) from secondary effluents. The integrated CTS was combined with vertical-flow constructed wetland, floating bed and sand filter. The vertical wetland was filled from the bottom to the top with gravels, steel slag and peat. Vetiver zizanioides (L.) Nash was selected to grow in the vertical constructed wetland while Coix lacrymajobi L. was grown in floating bed. The results suggested that integrated CTS displayed excellent removal efficiency for chemical oxygen demand (COD), dissolved phosphorus (DP), and total phosphorus (TP). The average COD removal efficiency of the integrated CTS was 90.45% after 40 days of operation, the average DP and TP removal efficiencies of the integrated CTS were 97.43% and 96.40%, respectively. The integrated CTS has good potential in removing COD as well as P from secondary effluents.  相似文献   

8.
Olive oil mill wastewater (OMW) is environmentally hazardous not only because it contains high recalcitrant and toxic compounds, but also due to its high organic load and turbidity. In this study, oxidation of OMW by microwave (MW)‐activated persulfate is investigated. Box–Behnken design is applied to investigate the effects of operating conditions on operating cost, organic matter, and color removal. Multi response optimization is performed according to minimum operating cost, maximum organic matter and color removal efficiencies. At optimum conditions (persulfate anion dose of 266 g L?1, oxidation duration of 23.58 min, MW power of 567 W, and initial pH 2), chemical oxygen demand (COD) removal of 63.38%, color removal of 94.85%, and operating cost of 0.0633 Euro/g total organic carbon (TOC) removal are found. The biochemical oxygen demand (BOD5)/COD ratio is increased from 0.144 to 0.285. Results of Pareto analysis show individual effect of MW power is 92.81% for TOC removal, 15.52% for color removal, 68.99% for operating cost, respectively. According to the results, it is not recommended to use this process as an ultimate treatment unit due to the high amount of oxidizing agent consumed. Instead, it is recommended to be used as a pre‐ or post‐treatment step.  相似文献   

9.
In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H2O2 process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO2 L–1, which cannot be further eliminated with physicochemical processes. The UV/H2O2 treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H2O2 concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H2O2 process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H2O2 g–1 COD L–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H2O2 by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal.  相似文献   

10.
A single bioaugmentation reactor and a side-stream gaslift membrane bioreactor combined with bioaugmentation are conducted to treat real wastewater from a centralized piggery slaughterhouse in Vietnam. The bioaugmented reactor is inoculated with heterotrophic microorganisms (Bacillus sp.) isolated from piggery slaughterhouse wastewater. The results of a single bioaugmentation experiment show high removal efficiency of chemical oxygen demand (COD) (84.8%–97.5%) and total nitrogen (TN) (69.9%–87.2%) at loading rates of 1.28–3.89 and 0.14–0.37 kg m−3 d−1, respectively. The combined system demonstrates a significantly higher TN removal efficiency (89.0%–96.1%) (p < 0.001), more stable flux (36.0–38.4 L m−2 h−1), and transmembrane pressure (0.95–1.05 bar), and better capacity of separation of solid–liquid phases compared to the single bioaugmentation. High COD and TN removal efficiency is possibly due to assimilation and simultaneous nitrification and denitrification processes. The results of this study also indicate the feasibility and propitious efficiency of the bioaugmented gaslift membrane bioreactor for piggery slaughterhouse wastewater treatment.  相似文献   

11.
Studies on the direct application of the photo-Fenton process (PFOP) to disinfect and decontaminate textile wastewater are rare. The output of the artificial neural network (ANN) models applied to the wastewater of a textile factory producing woven fabrics, which is used to assess the efficiency of the PFOP process, are investigated and compared with each other in this study. The highest PFOP efficiency is obtained at a pH of 3. Chemical oxygen demand (COD), suspended solids (SS) and color removal rates are 94%, 90%, and 96%, respectively. The data are modeled with ANNs and nonlinear external input autoregressive ANNs (NARX-ANN) using the MATLAB R2020a software program. Both Levenberg–Marquardt (trainlm) and scaled conjugate gradient (trainscg) algorithms are employed in the ANN and NARX-ANN models, whereas hyperbolic tangent sigmoid (Tansig) and logistic sigmoid (Logsig) functions are superimposed on the hidden layer in the ANN model, and Tansig functions are superimposed on the NARX-ANN model. It is determined that the developed ANN models are more effective in estimating the PFOP efficiency. The mean squared error is 0.000 953, and the coefficient of determination (R2) is 0.96 661.  相似文献   

12.
This study established wetland microcosms that were either unplanted or planted in monoculture with native mangrove species in Taiwan (Avicennia marina, Rhizophora stylosa, and Lumnitzera racemosa) for the purpose of receiving high-salinity mariculture effluents; additionally, the microcosms operated at different hydraulic retention times (HRTs). Plant growth and the performance of the microcosms with respect to pollutant removal were investigated. The results showed that seedlings of all three mangrove species survived and grew sufficiently well under continuous flooding. The presence of mangroves consistently improved SS, BOD5, and TP removal, particularly under short HRT conditions. The mangrove microcosms removed pollutants from the mariculture effluents with efficiencies of 5.7-27.1% (SS), 4.9-36.3% (BOD5), 18.7-29.9% (TP), 21.2-49.8% (NH4-N), and 5.4-37.7% (NOx-N). A. marina and L. racemosa were more tolerant of continuous flooding than R. stylosa. However, no species displayed consistently superior performance in decreasing all pollutant-related parameters investigated. For all pollutants, microcosms operating at a 2-d HRT exhibited a higher removal efficiency than those operating at a 0.5-d HRT.  相似文献   

13.
This study characterized sludge from an anoxic baffled reactor (ABR) used to treat textile dyeing wastewater. The process was run over 150 days. On day 152, five sludge samples were collected from compartments 1–5 of the ABR and a set of captive tests was conducted to investigate their particle size distributions (PSDs), dye biosorption and biodegradation properties, and dehydrogenase activity (DHA). The results indicated that the PSD of the five sludge samples from the ABR were similar. Methylene blue biosorption to the sludge samples followed the pseudo‐second‐order kinetic model and the actual biosorption process was controlled by external and intraparticle diffusion, simultaneously. After the sludge samples were cultivated for 24 h, the acid red GR dye removal efficiencies were 59.5, 68.3, 76.4, 61.5, and 65.4%, respectively. Eliminating dye biosorption, the dye biodegradation efficiencies were only 38.8, 46.3, 52.6, 48.3, and 46.0%, respectively. Furthermore, the DHA values were 28.2, 45.3, 56.5, 41.0, and 35.0 µg TF mL?1 h?1, respectively, and the DHA variation was in accordance with the dye biodegradation efficiency variation.  相似文献   

14.
The treatment capacity of an integrated constructed treatment system (CTS) was explored which was designed to reduce phosphorus (P) from secondary effluents. The integrated CTS was combined with vertical-flow constructed wetland, floating bed and sand filter. The vertical wetland was filled from the bottom to the top with gravels, steel slag and peat. Vetiverzizanioides (L.) Nash was selected to grow in the vertical constructed wetland while Coixlacrymajobi L. was grown in floating bed. The results suggested that integrated CTS displayed excellent removal efficiency for chemical oxygen demand (COD), dissolved phosphorus (DP), and total phosphorus (TP). The average COD removal efficiency of the integrated CTS was 90.45% after 40 days of operation, the average DP and TP removal efficiencies of the integrated CTS were 97.43% and 96.40%, respectively. The integrated CTS has good potential in removing COD as well as P from secondary effluents.  相似文献   

15.
In this research, the efficiency of electrocoagulation treatment process using aluminum electrodes to treat synthetic wastewater containing Reactive Red198 (RR198) was studied. The effects of parameters such as voltage, time of reaction, electrode connection mode, initial dye concentration, electrolyte concentration, and inter electrode distance on dye removal efficiency were investigated. In addition, electrical energy consumption, electrode consumption, and operating cost at optimum condition have been investigated. The results showed that dye and chemical oxygen demand removals were 98.6 and 84%, respectively. Electrode consumption, energy consumption and operating cost were 0.052 kg/m3, 1.303 kWh/m3 and 0.256 US$/m3, respectively. Dye removal kinetic followed first order kinetics. It can be concluded that electrocoagulation process by aluminum electrode is very efficient and clean process for reactive dye removal from colored wastewater.  相似文献   

16.
In this study, untreated and treated wood fly ash (WA) was used as a low‐cost sorbent in batch sorption tests to investigate the removal of organic pollutants from a real wastewater generated by cleaning/washing of machinery in a wood‐laminate floor industry in Sweden. The experiments focused on the effect of the WA dosage and particle size on the removal efficiency for organic compounds. With a WA dosage of 160 g L?1 and a particle size less than 1 mm, the reductions of chemical oxygen demand (COD), biologic oxygen demand, and total organic carbon were 37 ± 0.4, 24 ± 0.4, and 30 ± 0.3%, respectively. Pre‐treatment of WA with hot water improved the COD removal efficiency by absorption from 37 ± 0.4 to 42 ± 1.6% when the same dosage (160 g L?1) was applied. Sorption isotherm and sorption kinetics for COD using untreated WA can be explained by Freundlich isotherm and pseudo‐second‐order kinetic models. Intra‐particle diffusion model indicates that pore diffusion is not the rate‐limiting step for COD removal. Based on the experimental data, WA could be used as an alternative low‐cost sorption media/filter for removal of organic compounds from real industrial wastewater.  相似文献   

17.
Olive mill wastewaters (OMWs), which are known to have deep impacts on the receiving water bodies due to their high‐strength contents of organic materials and color, must be treated before discharge. For this reason; a number of research studies have been available in current literature related to the treatment of OMWs. However, no widely accepted treatment alternatives have been proposed yet. The common results of these studies suggest that OMWs must be pretreated prior to final purification processes. This study focuses on the comparison of alternative pre‐treatment processes in the aspect of chemical oxygen demand (COD) removal and costs of operation. Centrifuging, lime precipitation, acid cracking, and electrocoagulation processes were performed to compare removal efficiencies and operational costs. The COD removal efficiencies for centrifuging, lime precipitation, acid cracking, and electrocoagulation processes were determined to be 30.1, 24.1, 20.0, 53.7%, respectively, with operational costs being $0.30, $0.37, $1.42, and $11.60 per cubic meter of wastewater treated, respectively. The centrifuging process was concluded to be the most appropriate one according to the COD removal efficiency and cost of operation.  相似文献   

18.
In the present work the kinetics and the feasibility of batch anaerobic filter operations for the treatment of beet molasses distillery slops have been investigated. Up to 50% of the influent COD up to 25 g/l are removed after 5… 10 h and up to 80% after 24… 40 h treating time. Highest removal rates were obtained for 50% removal and influent COD concentration ≧13 kg. m?3. The highest methane productivity was observed in the same range of COD influent concentration during the first 10 hours (initial velocity) of the treatment. The benefits of the anaerobic treatment of waste water applying systems with biomass retention are discussed.  相似文献   

19.
A number of studies have showed that the mass removal rates of phosphorus (P) in different constructed wetlands (CWs) varied significantly, and it is essential to quantify the contributions of major P removal processes in order to improve system design. The objective of this study was to investigate the effects of vegetation, hydraulic retention time (HRT), and water temperature on P removal from polluted river water and to quantify the contributions of different P removal pathways in surface CWs. Results showed that the average total P removal rates ranged between 2.69 and 20.84 mg/(m2 day) in different seasons and were influenced significantly by vegetation, HRT, and water temperature. According to the mass balance approach, plant uptake removed 4.81–22.33% of P input, while media storage contributed 36.16–49.66%. Other P removal processes such as microbiota uptake removed around 0.26–4.13%. Media storage and plant uptake were identified as the main P removal processes in surface CWs treating polluted river water. This illustrated the importance of selecting media and plants in CWs for future practical application.  相似文献   

20.
In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe2+/H2O2 molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe2+/H2O2 molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.  相似文献   

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