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1.
New 40Ar/39Ar ages, based on incremental heating techniques for groundmass separates of 25 samples, are presented for the Harrat Al-Madinah volcanic field, part of Harrat Rahat in the north western part of the Arabian plate. This area is an active volcanic field characterized by the occurrence of two historical eruptions approximately in 641 and 1256 AD. Field investigations of the main volcanic landforms indicate dominantly monogenetic strombolian eruptions, in addition to local more explosive eruptions. The lavas consist mainly of olivine basalt and hawaiite flows with minor evolved rocks of mugearite, benmoreite, and trachyte that occur mainly as domes, tuff cones and occasionally as lava flows. Previous K/Ar dating shows that the Harrat Al-Madinah lava flows and associated domes comprise seven units spanning an age range of ca. 1.7 Ma–Recent. The new 40Ar/39Ar age determinations confirm, to a great extent, the previously obtained K/Ar ages in the sense that no major systematic biases were found in the general stratigraphy of the different flow units. However, the 40Ar/39Ar plateau ages show that volcanism in this area began in the Neogene (∼10 Ma) and continued to Recent, with the most voluminous eruptions occurring in the Quaternary. Neogene volcanism occurred in at least three pulses around 10, 5 and 2 Ma, whereas Quaternary volcanism produced at least seven units reflecting lava flow emplacement in the time period of 1.90 Ma–Recent. Thus, the whole duration of volcanic activity in the Harrat Al-Madinah (10 Ma–Recent) appears much longer than that previously identified. The longevity of volcanism in the same part of the moving Arabian plate and absence of evidence for uni-directional migration of volcanic activity indicate that there is no fixed plume beneath this region. The NNW-trending distribution of the volcanic vents is parallel to the Red Sea, and suggests their origin is related to periodic extensional episodes along the reactivated Red Sea fault system.  相似文献   

2.
The Plio-Quaternary Balhaf–Bir Ali volcanic field (BBAVF) constitutes one of the largest volcanic fields in SE Yemen, covering some 500 km2. It comprises cinder cones complexes associated with vesicular lava flows and scoria–spatter cones. In many places, ultramafic xenoliths are encountered within these volcanics. The explosive volcanism is mainly of alkaline character including alkali olivine basalt, hawaiite and mugearite together with subordinate tuffaceous trachytes. Major, trace and REEs data from the basaltic rocks of the BBAVF are interpreted in terms of a mantle-lithospheric origin in which crustal contribution during the initial stage of rift magmatism has occurred. Magma genesis may have resulted from plume-derived melt introducing into the base of the lithosphere. A mantle plume source is proposed for the Balhaf–Bir Ali basaltic lavas that are here interpreted as having been generated by partial melting of garnet lherzolite in the uppermost part of asthenosphere. The magmatic evolution of Balhaf–Bir Ali volcanic field may be accounted for by the recent models developed for plume structure.  相似文献   

3.
The paper discusses the results of mineralogical and petrographic studies of spinel lherzolite xenoliths and clinopyroxene megacrysts in basalt from the Jixia region related to the central zone of Cenozoic basaltic magmatism of southeastern China. Spinel lherzolite is predominantly composed of olivine (Fo89.6–90.4), orthopyroxene (Mg# = 90.6–92.7), clinopyroxene (Mg# = 90.3–91.9), and chrome spinel (Cr# = 6.59–14.0). According to the geochemical characteristics, basalt of the Jixia region is similar to OIB with asthenospheric material as a source. The following equilibrium temperatures and pressures were obtained for spinel peridotite: 890–1269°C and 10.4–14.8 kbar. Mg# of olivine and Cr# of chrome spinel are close to the values in rocks of the enriched mantle. It is evident from analysis of the textural peculiarities of spinel lherzolite that basaltic melt interacted with mantle rocks at the xenolith capture stage. Based on an analysis of the P–T conditions of the formation of spinel peridotite and clinopyroxene megacrysts, we show that mantle xenoliths were captured in the course of basaltic magma intrusion at a significantly lower depth than the area of partial melting. However, capture of mantle xenoliths was preceded by low-degree partial melting at an earlier stage.  相似文献   

4.
A variety of alkaline lavas from the Dunedin Volcano have been analyzed for the rare earth elements (REE) La-Yb. The compositions analyzed were: basalt-hawaiite-mugearite-benmoreite; basanite, nepheline hawaiite, nepheline trachyandesite and nepheline benmoreite; trachyte; phonolite. The series from basalt to mugearite shows continuous enrichment in the REE, consistent with a crystal fractionation model involving removal of olivine and clinopyroxene. From mugearite to benmoreite there is a depletion in the REE which is explained by the appearance of apatite as a liquidus phase. The chondrite normalized REE patterns for the phonolites are characterized by strong enrichment and fractionation coupled with a sharp depletion in Eu. Removal of plagioclase from benmoreite magma is suggested for the derivation of the phonolites. The series basanite-nepheline hawaiite, and basanite-nepheline hawaiite-nepheline benmoreite appear to be high pH2O analogues of the series basalt-ben-moreite, with enrichment of the REE being achieved by removal of clinopyroxene, kaersutite and olivine. Compared with other lavas the trachyte has low REE abundances and is characterized by a striking positive Eu anomaly.  相似文献   

5.
Chemical analyses of over seventy lavas or dykes containing spinel lherzolite inclusions of high pressure mineralogy, show that most host magmas are of alkali olivine basalt or basanite composition with relatively rare olivine nephelinites, and olivine melilitites. The 100 Mg/Mg+Fe++ ratios of host magmas display a strong maximum at about Mg70 consistent with partial melting of source peridotite with olivine of Fo88–90. In contrast to these primary magmas, there occur some host magmas with 100 Mg/Mg+Fe++<60 and with chemical compositions resembling those of classical hawaiite, mugearite, and nepheline benmoreite magmas. It is inferred that these magmas have been produced by crystal fractionation, within the upper mantle, of parental basanites or alkali olivine basalts. The presence of kaersutitic hornblende xenocrysts accompanying the lherzolite inclusions, and the nature of the chemical variation between associated basanites and nepheline benmoreites suggests that crystal fractionation has been dominated by kaersutitic hornblende, together with olivine and, in some cases, probably clinopyroxene. The mantle-derived nepheline benmoreite magmas also show similarities to some plutonic nepheline syenites.  相似文献   

6.
Neyriz ophiolite in Abadeh Tashk area appears as four major separated massifs in an area with 125 km2, south of Iran. Peridotites including harzburgite, dunite, and lesser low-Cpx lherzolite are the major constituents of the ophiolite with very minor mafic rocks. Usual gabbros of ophiolite complexes are virtually absent from the study area. Mineral modality associated with bulk rock and mineral chemistry of the peridotites show a progression from fertile to ultra-refractory character, reflected by a progressive decrease in modal pyroxenes and in Al2O3, CaO, SiO2, Sc, Ta, V, and Ga values of the studied rocks by approaching chromite deposits. The Neyriz peridotites vary from low-Cpx lherzolite (MgO, 41.97–43.1 wt.%; Al2O3, 0.8–1.3 wt.%) with low content of Cr# spinel (36.7–37.6) and Fo olivine (90.79–91.5) to harzburgite (MgO, 44.31–45.25 wt.%;Al2O3, 0.29–0.45 wt.%; Cr# spinel, 58.2–73.45; Fo olivine, 91.23–91.56), and then to dunite (MgO, 45.9–49.2 wt.%; Al2O3, 0.18–0.48 wt.%) with higher content of Cr# spinel (74.34–79.36) and Fo olivine (91.75–94.68). Compared to modern oceanic settings, mineral and rock composition of low-Cpx lherzolite plot within the field of mid-ocean-ridge environment, whereas those of harzburgite and dunite fall in the field of fore-arc peridotites. As a result of the studies on minerals and whole rock chemistry along with rock interrelationships, we contend that the peridotites were subsequently affected by percolating hydrous boninitic melt from which the high-Cr–Mg, low-Ti chromitites were formed within mantle wedge above the supra-subduction zone in a fore-arc setting.  相似文献   

7.
The Dramala massif, located in the Dinarides–Hellenides orogenic belt, forms the mantle section of the Neotethyan Pindos ophiolite complex in NW continental Greece. Its southern domain is comprised mainly of voluminous harzburgite masses with variable clinopyroxene and olivine modal abundances, ranging from clinopyroxene‐bearing to typical and olivine‐rich harzburgites. The harzburgite varieties are characterized by elevated Cr# [Cr/(Cr + Al)] in Cr‐spinel (0.43–0.79), high forsterite (Fo) content in olivine (0.90–0.93), low Al2O3 content in clinopyroxene (≤1.77 wt.%) and poor whole‐rock abundances of Al2O3 (≤0.68 wt.%), CaO (≤0.68 wt.%), Sc (≤11 ppm) and REE, which are indicative of their refractory nature. In terms of fO2 values, the southern Pindos harzburgites plot between the FMQ‐2 (Fayalite–Magnetite–Quartz) and FMQ + 2 buffers. Simple batch and fractional melting models are not sufficient to explain their depleted composition. Their Ni/Yb ratios vs. Yb bulk‐rock abundances can be reproduced by up to 22–31% closed‐system non‐modal dynamic melting of an assumed spinel‐bearing lherzolite source. Cr‐spinel chemistry data suggest that the southern Dramala harzburgites were formed in an oceanic centre and then were reworked in the mantle wedge above a subducted slab. Combined petrographic and compositional data indicate that the studied harzburgites interacted with arc‐derived tholeiitic melts. This interaction resulted in substantial olivine and minor Cr‐spinel addition to the studied harzburgites, thus enhancing their refractoriness. Cryptic metasomatism was plausibly responsible for the demolition of any strong geochemical signatures suggestive of a previous melting event in a spreading centre. Comparable observations from the neighbouring Vourinos suite imply that the southern Dramala harzburgites probably represent an arc/fore‐arc mantle region within the mutual Pindos–Vourinos, Mesohellenic lithospheric mantle. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

8.
Iron isotope and major- and minor-element compositions of coexisting olivine, clinopyroxene, and orthopyroxene from eight spinel peridotite mantle xenoliths; olivine, magnetite, amphibole, and biotite from four andesitic volcanic rocks; and garnet and clinopyroxene from seven garnet peridotite and eclogites have been measured to evaluate if inter-mineral Fe isotope fractionation occurs in high-temperature igneous and metamorphic minerals and if isotopic fractionation is related to equilibrium Fe isotope partitioning or a result of open-system behavior. There is no measurable fractionation between silicate minerals and magnetite in andesitic volcanic rocks, nor between olivine and orthopyroxene in spinel peridotite mantle xenoliths. There are some inter-mineral differences (up to 0.2 in 56Fe/54Fe) in the Fe isotope composition of coexisting olivine and clinopyroxene in spinel peridotites. The Fe isotope fractionation observed between clinopyroxene and olivine appears to be a result of open-system behavior based on a positive correlation between the Δ56Feclinopyroxene-olivine fractionation and the δ56Fe value of clinopyroxene and olivine. There is also a significant difference in the isotopic compositions of garnet and clinopyroxene in garnet peridotites and eclogites, where the average Δ56Feclinopyroxene-garnet fractionation is +0.32 ± 0.07 for six of the seven samples. The one sample that has a lower Δ56Feclinopyroxene-garnet fractionation of 0.08 has a low Ca content in garnet, which may reflect some crystal chemical control on Fe isotope fractionation. The Fe isotope variability in mantle-derived minerals is interpreted to reflect subduction of isotopically variable oceanic crust, followed by transport through metasomatic fluids. Isotopic variability in the mantle might also occur during crystal fractionation of basaltic magmas within the mantle if garnet is a liquidus phase. The isotopic variations in the mantle are apparently homogenized during melting processes, producing homogenous Fe isotope compositions during crust formation.  相似文献   

9.
Dunitic xenoliths from late Palaeogene, alkaline basalt flows on Ubekendt Ejland, West Greenland contain olivine with 100 × Mg/(Mg + Fe), or Mg#, between 92.0 and 93.7. Orthopyroxene has very low Al2O3 and CaO contents (0.024–1.639 and 0.062–0.275 wt%, respectively). Spinel has 100 × Cr/(Cr + Al), or Cr#, between 46.98 and 95.67. Clinopyroxene is absent. The osmium isotopic composition of olivine and spinel mineral separates shows a considerable span of 187Os/188Os values. The most unradiogenic 187Os/188Os value of 0.1046 corresponds to a Re-depletion age of ca. 3.3 Gy, while the most radiogenic value of 0.1336 is higher than present-day chondrite. The Os isotopic composition of the xenoliths is consistent with their origin as restites from a melt extraction event in the Archaean, followed by one or more subsequent metasomatic event(s). The high Cr# in spinel and low modal pyroxene of the Ubekendt Ejland xenoliths are similar to values of some highly depleted mantle peridotites from arc settings. However, highly depleted, arc-related peridotites have higher Cr# in spinel for a given proportion of modal olivine, compared to cratonic xenolith suites from Greenland, which instead form coherent trends with abyssal peridotites, dredged from modern mid-ocean ridges. This suggests that depleted cratonic harzburgites and dunites from shallow lithospheric mantle represent the residue from dry melting in the Archaean.  相似文献   

10.
《Gondwana Research》2001,4(3):427-436
The ‘Three Phenocryst Basalts’ (TPB) from Pavagadh hill constitute one of the most primitive basalts in Deccan traps. Electron microprobe analyses of phenocryst minerals from the TPB reveal that the Fo % of olivine varies from 89 to 68, the clinopyroxene grains are diopside/salite or augite and the Cr# [Cr/(Cr+Al)] in spinel is about 0.65. The An content of feldspar varies from 63 to 67. The mineral chemical data allow us to infer that olivine and spinel crystallized early, and when olivine attained Fo76–73%, the crystallization of clinopyroxene was initiated. Plagioclase crystallization occurred at the late stage. It is indicated that the source region of the TPB may possibly be undepleted mantle (lherzolite zone) at about 85 km depth and 27 kbar pressure, where Cr# of spinel is about 0.47.  相似文献   

11.
Sanshui basin is one of the typical Mesozoic–Cenozoic intra-continental rift basins with voluminous Cenozoic volcanic rocks in southeastern China. Thirteen cycles of volcanic eruptions and two dominant types of volcanic rocks, basalt and trachyte–rhyolite, have been identified within the basin. Both basalt and trachyte–rhyolite members of this bimodal suit have high values of εNd (+2.3 to +6.2) and different Sr isotopic compositions (initial 87Sr/86Sr ratios are 0.70461–0.70625 and 0.70688–0.71266 for basalts and trachyte–rhyolite, respectively), reflecting distinct magma evolution processes or different magma sources. The results presented in this study indicate that both of the trachyte–rhyolite and basaltic magmas were derived from similar independent primitive mantle, but experienced different evolution processes. The trachyte-rhyolitic magma experienced significant clinopyroxene and plagioclase fractionational crystallization from deeper magma chamber with significant crustal contamination, while the basaltic magmas experienced significant olivine and clinopyroxene fractionational crystallization in shallower magma chamber with minor crustal contamination. New zircon U–Pb dating confirms an initial volcanic eruption at 60 Ma and the last activity at 43 Ma. Geologic, geochemical, and geochronological data suggest that the inception of the Sanshui basin was resulted from upwelling of a mantle plume. The Sanshui basin widened due to subsequent east–west extension and the subsequent volcanism constantly occurred in the center of the basin. Evidence also supports a temporal and spatial association with other rift basins in southeastern China. The upwelling mantle plume became more active during late Cenozoic time and most likely triggered opening of other basins, including the young South China Sea basin.  相似文献   

12.
Previous studies on iron isotope compositions of subduction zone magmas have revealed significant and complex variations that have great bearings on petrogenetic processes in the mantle wedge, e.g., partial melting, fluid metasomatism and redox state. However, interpretations for the fractionations are highly debatable and lack direct constraints from mantle wedge peridotites. This study presents iron isotope compositions for whole rocks and mineral separates in fresh forearc peridotites from the Yushigou ophiolite, North Qilian orogen in northern Tibet. Major and trace element compositions of whole rock and mineral indicate that the peridotites are highly depleted forearc peridotites overprinted by melt metasomatism, in contrast to the long‐holding opinion that the peridotites are derived from mid‐oceanic ridges. The minerals fall on a line with a slope of ~1 on the plot of δ56Fe vs. δ56Fe, indicating isotope equilibrium between minerals. δ56Fe fractionation between olivine and orthopyroxene is within the range of 0~0.05, while fractionation between olivine and spinel is about 0.05~0.10. The fractionation trend between olivine and spinel is opposite to previous theoretical and experimental constraints, which may be due to substantial Cr substitution into the spinel. This indicates that negative correlations between spinel Cr#, fO2 and spinel δ56Fe in previous studies are probably a reflection of gradual Cr enrichment in spinel during melt extraction, and spinel δ56Fe values are not a proxy for oxygen fugacity. Whole rock δ56Fe values are well correlated with mineral δ56Fe values, varying from overlapping with depleted mantle to slightly lower than depleted mantle. Therefore, variations in iron isotope compositions of subduction zone magmas are probably due to combined effect of source heterogeneity and partial melting fractionation.  相似文献   

13.
Scottish Dinantian transitional to mildly alkaline volcanism is represented by abundant outcrops in the Midland Valley, Southern Uplands and Highlands provinces. Dinantian volcanic rocks from Kintyre in the Scottish Highlands range in composition from basalt through basaltic hawaiite, hawaiite, mugearite and benmoreite to trachyte, the compositions of the evolved types being largely due to differentiation from the basaltic parents.Recent geochemical investigations of Scottish Caledonian granitoids, Siluro-Devonian Old Red Sandstone (ORS) lavas and xenolith suites from numerous vents and dykes of Permo-Carboniferous to Tertiary age have revealed that the Scottish crust and upper mantle both increase in age and are increasingly enriched in incompatible elements towards the north and northwest. The upper mantle and lower crust below the Highlands province are therefore largely considered to be more enriched and in parts older than those below the Midland Valley and Southern Uplands. Dinantian alkali basalts from these latter two provinces have Nd values predominantly in the range +3 to +6, initial 87Sr/86Sr values of 0.7029–0.7041 and 207Pb/ 204Pb values of 15.48–15.60. However, similar basalts from Kintyre and Arran in the Highlands have lower Nd (+0.1 to +3.4) and 207Pb/204Pb (for given 206Pb/204Pb ratios; 15.49–15.51) and slightly higher 87Sr/86Sr (0.7033–0.7046). This regional variation correlates well with the differences seen between Midland Valley and Highland magmas in the ORS calc-alkaline suite (Thirlwall 1986) and it is suggested that both the ORS and Dinantian basic rocks are derived from similar types of mantle, although no lithospheric slab component is present in the later Dinantian suites. Isotopically-distinct portions of mantle therefore appear to have been present below the Highland and Midland Valley-Southern Upland provinces from at least Caledonian to Carboniferous times. The combined incompatible element and Sr-Nd-Pd isotopic evidence from Kintyre and Arran basaltic rocks does not allow unequivocal distinction between a lithospheric mantle and a sublithospheric mantle source. The observed correlation between isotopic composition of Dinantian basalts and the chemical composition of the lithosphere, together with the apparent involvement of long-term separated source reservoirs suggests that Kintyre and Arran lavas were derived largely from a lithospheric mantle source. On the other hand, the isotopic enrichment of Kintyre basaltic rocks is not extreme; trace element and isotopic compositions are still comparable to modem OIB. Sublithospheric mantle could therefore also be a viable source for Kintyre and Arran Dinantian volcanism.  相似文献   

14.
The Tengchong volcanic field north of the Burma arc comprises numerous Quaternary volcanoes in the southeastern margin of the Tibetan Plateau. The volcanic rocks are grouped into four units (1–4) from the oldest to youngest. Units 1, 3 and 4 are composed of olivine trachybasalt, basaltic trachyandesite and trachyandesite, and Unit 2 consists of hornblende dacite. The rocks of Units 1, 3, and 4 form a generally alkaline suite in which the rocks plot along generally linear trends on Harker diagrams with only slight offset from unit to unit. They contain olivine phenocrysts with Fo values ranging from 65 to 85 mol% and have Cr-spinel with Cr# ranging from 23 to 35. All the rocks have chondrite-normalized REE patterns enriched in LREE and primitive mantle-normalized trace element patterns depleted in Ti, Nb and Ta, but they are rich in Th, Ti and P relative to typical arc volcanics. Despite minor crustal contamination, 87Sr/86Sr ratios (0.706–0.709), εNd values (−3.2 to −8.7), and εHf values (+4.8 to −6.4) indicate a highly heterogeneous mantle source. The Pb isotopic ratios of the lavas (206Pb/204Pb = 18.02–18.30) clearly show an EMI-type mantle source. The underlying mantle source was previously modified by subduction of the Neo-Tethyan oceanic and Indian continental lithosphere. The present heterogeneous mantle source is interpreted to have formed by variable additions of fluids and sediments derived from the subducted Indian Oceanic lithosphere, probably the Ninety East Ridge. Magma generation and emplacement was facilitated by transtensional NS-trending strike-slip faulting.  相似文献   

15.
Tombel graben and Mounts Bambouto are two volcanic fields of the typical system of alternating graben and horst structure of the Cameroon Volcanic Line. Tombel graben is a young volcanic field, whereas Mounts Bambouto horst is an old stratovolcano with calderas. Volcanic products in both settings have a signature close to that of Ocean Island Basalt implying a major role of FOZO (focal zone) component and varied contribution of depleted mantle (DMM) and enriched mantle (EM) components. The Cameroon Volcanic Line is a hot line essentially resulting from passive rifting. Eocene to Recent intraplate basaltic volcanism in the study area was probably a result of mantle upwelling coupled with lithospheric extension. The olivine basaltic magma of horst volcanoes evolved in a large-scale, steady-state magmatic reservoir via crystal fractionation and limited contamination to highly differentiated alkaline lavas (trachyte and phonolite). Conversely, rapid ascent of lavas along multiple fault lines of graben structures produced less evolved lavas (hawaiite) within small reservoirs. This model, evaluated for the study area, involves mantle upwelling inside zones of weakness in the lithosphere after intra-continental extension. It can be applied to other parts of the Cameroon Volcanic Line as well, and is similar to that described in other intra-continental rift-related areas in Africa.  相似文献   

16.
The microstructures, major‐ and trace‐element compositions of minerals and electron backscattered diffraction (EBSD) maps of high‐ and low‐Cr# [spinel Cr# = Cr3+/(Cr3++Al3+)] chromitites and dunites from the Zedang ophiolite in the Yarlung Zangbo Suture (South Tibet) have been used to reveal their genesis and the related geodynamic processes in the Neo‐Tethyan Ocean. The high‐Cr# (0.77‐0.80) chromitites (with or without diopside exsolution) have chromite compositions consistent with initial crystallization by interaction between boninitic magmas, harzburgite and reaction‐produced magmas in a shallow, mature mantle wedge. Some high‐Cr# chromitites show crystal‐plastic deformation and grain growth on previous chromite relics that have exsolved needles of diopside. These features are similar to those of the Luobusa high‐Cr# chromitites, possibly recycled from the deep upper mantle in a mature subduction system. In contrast, mineralogical, chemical and EBSD features of the Zedang low‐Cr# (0.49‐0.67) chromitites and dunites and the silicate inclusions in chromite indicate that they formed by rapid interaction between forearc basaltic magmas (MORB‐like but with rare subduction input) and the Zedang harzburgites in a dynamically extended, incipient forearc lithosphere. The evidence implies that the high‐Cr# chromitites were produced or emplaced in an earlier mature arc (possibly Jurassic), while the low‐Cr# associations formed in an incipient forearc during the initiation of a new episode of Neo‐Tethyan subduction at ~130‐120 Ma. This two‐episode subduction model can provide a new explanation for the coexistence of high‐ and low‐Cr# chromitites in the same volume of ophiolitic mantle.  相似文献   

17.
Whole-rock geochemical and Sr, Nd and Pb isotope data are presented for the Harrat Al-Madinah volcanic field, in the north western part of the Arabian plate, aiming to understand their origin and the composition of their mantle source. This area is an active volcanic field characterized by the occurrence of two historic eruptions approximately in 641 and 1256 A.D. Field investigation of the main volcanic landforms indicates dominantly monogenetic strombolian eruptions, in addition to local phreatomagmatic eruption style. The lavas consist mainly of alkali olivine basalt, olivine transitional basalt, and hawaiite with ocean island basalt (OIB)-like characteristics. Evolved rocks, represented by mugearites, benmoreites, and trachytes, occur mainly as domes, tuff cones and occasionally as lava flows. Chemical variations in the evolved rocks indicated their evolution by low pressure crystal fractionation of olivine, plagioclase, clinopyroxene, and Fe–Ti oxides from the relatively primitive basalts. The isotopic compositions of 143Nd/144Nd (0.512954–0.512995), 87Sr/86Sr (0.702899 to–0.702977) and Pb (206Pb/204Pb = 18.5515–18.7446, 207Pb/204Pb = 15.5120–15.5222, 208Pb/204Pb = 38.1347–38.4468), show restricted variations suggesting only minor crustal contamination. They defined an array consistent with mixing of two geochemically distinct components of depleted MORB-mantle (DMM) and high 238U/204Pb ratio (HIMU). The variations in Tb/Yb, La/Yb and Sm/Yb ratios in the relatively primitive basalts (MgO > 6 wt.%) indicated garnet peridotite source. However, the positive Nb, Sr, Ba and Ti anomalies in the primitive mantle-normalized incompatible element patterns and the significant variation between Zr/Nb vs. Ce/Y and La/Yb vs. Yb suggest contribution of an amphibole-bearing spinel lherzolite source. Moreover, the negative correlations between SiO2 vs. 87Sr/86Sr and Th vs. 143Nd/144Nd are interpreted as an indication of mixing melts derived from two end-members; one is garnet bearing asthenospheric source with OIB characteristic and the other is amphibole-bearing spinel lherzolite. The Harrat Al-Madinah volcanic field occurs near the Red Sea Rift System and its origin reflects a strong lithospheric control on the loci of partial melting. The dominantly NNW alignment patterns of the volcanoes, which is similar to the regional Red Sea trend, may suggest that the magmas were produced by decompression partial melting triggered by lithospheric extension related to the Red Rift.  相似文献   

18.
The mantle xenoliths in the Quaternary ChangbaishanVolcano in southern Jilin Province contain spinel-facies lherzolites. The equilibration temperatures for these samples range from 902oC to 1064oC based on the two-pyroxene thermometer of Brey and K?hler (1990), and using the oxybarometry of Nell and Wood (1991), the oxidation state was estimated from FMQ-1.32 to -0.38 with an average value of FMQ-0.81 (n?=?8), which is comparable to that of abyssal peridotites and the asthenospheric mantle. The fO2 values of peridotites, together with their bulk rock compositions (e.g., Mg#, Al2O3, CaO, Ni, Co, Cr) and mineral compositions (e.g., Mg# of olivine and pyroxene, Cr# [=Cr/[Cr+Al]] and Mg# [=Mg/[Mg+Fe2+] of spinel), suggest that the present-day subcontinental lithospheric mantle (SCLM) beneath the Changbaishan Volcano most likely formed from an upwelling asthenosphere at some time after the late Mesozoic and has undergone a low degree of partial melting. The studied lherzolite xenoliths show low concentrations of S, Cu, and platinum group elements (PGE), which plot a flat pattern on primitive-mantle normalized diagram. Very low concentrations in our samples suggest that PGEs occur as alloys or hosted by silicate and oxide minerals. The compositions of the studied samples are similar to those of peridotite xenoliths in the Longgang volcanic field (LVF) in their mineralogy and bulk rock compositions including the abundance of chalcophile and siderophile elements. However, they are distinctly different from those of peridotite xenoliths in other areas of the North China Craton (NCC) in terms of Cu, S and PGE. Our data suggest that the SCLM underlying the northeastern part of the NCC may represent a distinct unit of the newly formed lithospheric mantle.  相似文献   

19.
Within the volcanic sequence of the twin volcanoes of Lyttelton and Akaroa, Banks Peninsula, New Zealand a number of different magma series have been distinguished.An early series of hawaiites (McQueens Valley Formation) was erupted about 32 m.y. ago and is of transitional or mildly tholeiitic chemistry. Stratigraphically above the McQueens Valley Formation, but unconformably overlain by the main volcanic dome sequence, is a unit of rhyolite (Gebbies Pass Rhyolites) which is not directly related to the earlier or later basaltic volcanism. The rhyolite was probably formed during intracrustal melting which was related to the rise of basaltic magma into the crust.Between 12 and 9.7 m.y. a large volcanic dome, composed mainly of hawaiite, was built at Lyttelton. Dykes, which intrude the Lyttelton volcanic sequence, range in composition from basalt to trachyte. Late, mildly alkalic, basaltic flank flows (7.5–5.8 m.y.) occur in several areas and they, and the differentiated rocks of the dyke swarm can be related by a crystal fractionation model which has been quantitatively tested.Following construction of the Lyttelton dome a second larger dome was built at Akaroa between 9 and 7.5 m.y. The rocks of the Akaroa Volcano are principally hawaiites but rocks ranging in composition through to trachyte also occur. The differentiated rocks of the Akaroa volcano have derived from the basaltic rocks by a crystal fractionation controlled process, operating during ascent through the crust.None of the Banks Peninsula basalts appear to have derived from primitive (pyrolitic) mantle material, but progressive changes in the chemistry of the basalts with time implies that the mantle source regions were evolving geochemically as partial melting proceeded. Later lavas tend to be more alkalic and to have lower MgO/FeO ratios than earlier lavas. The volcanic rocks of the Banks Peninsula volcanoes were derived by fractional removal of olivine, plagioclase, clinopyroxene, magnetite and apatite from ascending basaltic magma batches. Variations between the suites reflect differences between the parental magma batches.  相似文献   

20.
The Sidingheishan mafic-ultramafic intrusion is located in the eastern part of the Northern Tianshan Mountain, along the southern margin of the Central Asian Orogenic Belt in northern Xinjiang autonomous region of China. The Sidingheishan intrusion is mainly composed of wehrlite, olivine websterite, olivine gabbro, gabbro and hornblende gabbro. At least two pulses of magma were involved in the formation of the intrusion. The first pulse of magma produced an olivine-free unit and the second pulse produced an olivine-bearing unit. The magmas intruded the Devonian granites and granodiorites.An age of 351.4±5.8 Ma(Early Carboniferous) for the Sidingheishan intrusion has been determined by U-Pb SHRIMP analysis of zircon grains separated from the olivine gabbro unit. A U-Pb age of 359.2±6.4 Ma from the gabbro unit has been obtained by LA-ICP-MS. Olivine of the Sidingheishan intrusion reaches 82.52 mole% Fo and 1414 ppm Ni. On the basis of olivine-liquid equilibria, it has been calculated that the MgO and FeO included in the parental magma of a wehrlite sample were approximately10.43 wt% and 13.14 wt%, respectively. The Sidingheishan intrusive rocks are characterized by moderate enrichments in Th and Sm, slight enrichments in light REE, and depletions in Nb, Ta, Zr and Hf. The ε_(Nd)(t) values in the rock units vary from +6.70 to +9.64, and initial ~(87)Sr/~(86)Sr ratios range between 0.7035 and0.7042. Initial ~(206)Pb/~(204)Pb, ~(207)Pb/~(204)Pb and ~(208)Pb/~(204)Pb values fall in the ranges of 17.23-17.91,15.45-15.54 and 37.54-38.09 respectively. These characteristics are collectively similar to the Heishan intrusion and the Early Carboniferous subduction related volcanic rocks in the Santanghu Basin, North Tianshan and Beishan area. The low(La/Gd)_(PM) values between 0.26 and 1.77 indicate that the magma of the Sidingheishan intrusion was most likely derived from a depleted spinel-peridotite mantle.(Th/Nb)_(PM)ratios from 0.59 to 20.25 indicate contamination of the parental magma in the upper crust.Crystallization modeling methods suggest that the parental magma of the Sidingheishan intrusion was generated by flush melting of the asthenosphere and subsequently there was about 10 vol%contamination from a granitic melt. This was followed by about 5 vol% assimilation of upper crustal rocks. Thus, the high-Mg basaltic parental magma of Sidingheishan intrusion is interpreted to have formed from partial melting of the asthenosphere during the break-off of a subducted slab.  相似文献   

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