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1.
The principal minor element (including Ti) characteristics of mare basalts which must be explained by an acceptable theory of petrogenesis are reviewed. Thes include: (i) Theabsolute abundances of incompatible elements vary over a twentyfold range yet therelative abundances within this group rarely deviate by more than a factor of two from the chondritic relative abundances. (ii) The sizes of the europium and strontium anomalies show a general trend to decrease as the absolute abundances of incompatible elements decrease. This trend is also one of increasing degree of partial melting and implies that the source region did not possess intrinsic Eu or Sr anomalies. (iii) Titanium seems to behave largely as an incompatible element. (iv) Many mare basalts have Rb/Sr model ages of about 4.5 b.y. whereas their crystallization ages are 3.2–3.8 b.y.Recent hypotheses have proposed that mare basalts formed by equilibrium partial melting of pyroxene-rich cumulates which underlay and were complementary to the anorthositic crust. According to a variant of this category, the residual liquid resulting from fractional crystallization of the highlands and their complementary cumulates segregated to form an intermediate layer between the highlands and the underlying primary cumulates. This highly fractionated residual liquid crystallized to form a pyroxene-olivine-ilmenite assemblage. High-Ti mare basalts subsequently formed by partial melting of this layer, whereas low-Ti basalts formed by partial melting of the underlying cumulates. These hypotheses are examined in detail and are rejected on several grounds.A new hypothesis based upon partial melting under conditions of surface or local equilibrium is proposed. It is assumed that the moon accreted from material which had ultimately formed by fractional condensation from a gas phase of appropriate composition. The essential members of the condensation sequence with falling temperature were perovskite, melilite, spinel, fassaite, forsterite, enstatite, alkali felspar. As the gas cooled over an extended period (>100 yr) large megacrysts (> 1 m) were formed. Trace elements were partitioned into these phases according to equilibrium condensation and crystal chemical relationships. Trivalent rare earths and other incompatible elements mainly entered perovskite, most of the Eu and Sr entered melilite whilst Rb entered alkali felspar. Radiogenic87Sr thus produced remained within the alkali felspar. The moon accreted from a mixture of these condensates to form a disequilibrium mineral assemblagewith a bulk composition similar to that of the pyroxenite source region of mare basalts as derived from experimental petrological considerations. After heating deep in the lunar interior, solid state reaction occurred around megacryst boundaries to form an equilibrium pyroxenite containing large unreacted cores of refractory melilite and perovskite. The latter mineral readily forms low melting point liquids when in contact with pyroxenes whereas melilite remains relatively inert. As partial melting commenced, all the perovskite and other low-melting accessory minerals (eg. alk. felspar) entered the first batch of liquid which thereby received most of the incompatible elements and87Sr (but not Eu and common Sr) present in the source region. Further melting of the pyroxenite matrix occurred under conditions of surface equilibrium. As the degree of partial melting increased, the first batch of incompatible-element-rich liquid was diluted by major elements from the pyroxenite matrix whilst refractory melilite cores were gradually consumed, thereby supplying relatively constant amounts of Eu and Sr to liquids so produced. It is considered that this model is capable of explaining the principal minor element characteristics of mare basalts and is consistent with interpretations of the major element chemistry of their source region based upon experimental petrology.  相似文献   

2.
Crystallization from the molten state has been an important process for the formation of rocks on the Moon; the phenomenon of fractional crystallization is therefore discussed. The principal chemical and mineralogical features of the Apollo 11, 12 and 14 basaltic crystalline rocks are described, and an account is given of other rock types and minerals which are represented among the coarser particles in the lunar soils. A comparison is made between the chemical compositions (major, minor and trace element concentrations) of rocks and soils.Based upon the above data, one possible model for the outer shell of the Moon is presented, which consists of an outer layer of Al-rich rocks underlain by a layer which is more ferromagnesian in character. Partial melting of the latter was probably responsible for the extrusion of lavas at the surface which spread to form the basalts (Apollo 11 and 12) of the non-circular maria. The Apollo 14 (Fra Mauro) basalts are relatively enriched in potassium, rare earth elements, zirconium, phosphorus and certain other elements and may derive from partial melting of the more aluminous upper layer.The separation of the outer Moon into two layers could have occurred through gravity-aided fractional crystallization at an early stage (first few hundred m yr) in lunar history.Paper presented to the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 1971.  相似文献   

3.
Recent studies geared toward understanding the volatile abundances of the lunar interior have focused on the volatile‐bearing accessory mineral apatite. Translating measurements of volatile abundances in lunar apatite into the volatile inventory of the silicate melts from which they crystallized, and ultimately of the mantle source regions of lunar magmas, however, has proved more difficult than initially thought. In this contribution, we report a detailed characterization of mesostasis regions in four Apollo mare basalts (10044, 12064, 15058, and 70035) in order to ascertain the compositions of the melts from which apatite crystallized. The texture, modal mineralogy, and reconstructed bulk composition of these mesostasis regions vary greatly within and between samples. There is no clear relationship between bulk‐rock basaltic composition and that of bulk‐mesostasis regions, indicating that bulk‐rock composition may have little influence on mesostasis compositions. The development of individual melt pockets, combined with the occurrence of silicate liquid immiscibility, exerts greater control on the composition and texture of mesostasis regions. In general, the reconstructed late‐stage lunar melts have roughly andesitic to dacitic compositions with low alkali contents, displaying much higher SiO2 abundances than the bulk compositions of their host magmatic rocks. Relevant partition coefficients for apatite‐melt volatile partitioning under lunar conditions should, therefore, be derived from experiments conducted using intermediate compositions instead of compositions representing mare basalts.  相似文献   

4.
Lunar meteorite Northwest Africa (NWA) 5744 is a granulitic breccia with an anorthositic troctolite composition that may represent a distinct crustal lithology not previously described. This meteorite is the namesake and first‐discovered stone of its pairing group. Bulk rock major element abundances show the greatest affinity to Mg‐suite rocks, yet trace element abundances are more consistent with those of ferroan anorthosites. The relatively low abundances of incompatible trace elements (including K, P, Th, U, and rare earth elements) in NWA 5744 could indicate derivation from a highlands crustal lithology or mixture of lithologies that are distinct from the Procellarum KREEP terrane on the lunar nearside. Impact‐related thermal and shock metamorphism of NWA 5744 was intense enough to recrystallize mafic minerals in the matrix, but not intense enough to chemically equilibrate the constituent minerals. Thus, we infer that NWA 5744 was likely metamorphosed near the lunar surface, either as a lithic component within an impact melt sheet or from impact‐induced shock.  相似文献   

5.
The chemical compositions of shergottite meteorites, basaltic rocks from Mars, provide a broad view of the origins and differentiation of these Martian magmas. The shergottite basalts are subdivided based on their Al contents: high‐Al basalts (Al > 5% wt) are distinct from low‐Al basalts and olivine‐phyric basalts (both with Al < 4.5% wt). Abundance ratios of highly incompatible elements (e.g., Th, La) are comparable in all the shergottites. Abundances of less incompatible elements (e.g., Ti, Lu, Hf) in olivine‐phyric and low‐Al basalts correlate well with each other, but the element abundance ratios are not constant; this suggests mixing between components, both depleted and enriched. High‐Al shergottites deviate from these trends consistent with silicate mineral fractionation. The “depleted” component is similar to the Yamato‐980459 magma; approximately, 67% crystal fractionation of this magma would yield a melt with trace element abundances like QUE 94201. The “enriched” component is like the parent magma for NWA 1068; approximately, 30% crystal fractionation from it would yield a melt with trace element abundances like the Los Angeles shergottite. This component mixing is consistent with radiogenic isotope and oxygen fugacity data. These mixing relations are consistent with the compositions of many of the Gusev crater basalts analyzed on Mars by the Spirit rover (although with only a few elements to compare). Other Mars basalts fall off the mixing relations (e.g., Wishstone at Gusev, Gale crater rocks). Their compositions imply that basalt source areas in Mars include significant complexities that are not present in the source areas for the shergottite basalts.  相似文献   

6.
New petrography, mineral chemistry, and whole rock major, minor, and trace element abundance data are reported for 29 dominantly unbrecciated basaltic (noncumulate) eucrites and one cumulate eucrite. Among unbrecciated samples, several exhibit shock darkening and impact melt veins, with incomplete preservation of primary textures. There is extensive thermal metamorphism of some eucrites, consistent with prior work. A “pristinity filter” of textural information, siderophile element abundances, and Ni/Co ratios of bulk rocks is used to address whether eucrite samples preserve endogenous refractory geochemical signatures of their asteroid parent body (i.e., Vesta), or could have experienced exogenous impact contamination. Based on these criteria, Cumulus Hills 04049, Elephant Moraine 90020, Grosvenor Range 95533, Pecora Escarpment 91245, and possibly Queen Alexander Range 97053 and Northwest Africa 1923 are pristine eucrites. Eucrite major element compositions and refractory incompatible trace element abundances are minimally affected by metamorphism or impact contamination. Eucrite petrogenesis examined through the lens of these elements is consistent with partial melting of a silicate mantle that experienced prior metal–silicate equilibrium, rather than as melts associated with cumulate diogenites. In the absence of the requirement of a large-scale magma ocean to explain eucrite petrogenesis, the interior structure of Vesta could be more heterogeneous than for larger planetary bodies.  相似文献   

7.
Abstract— Siderophile elements have been used to constrain projectile compositions in terrestrial and lunar impact melt rocks. To obtain a better knowledge of compositional differences between potential chondritic projectile types, meteorite analyses of the elements Ru, Rh, Pd, Os, Ir, Pt, Cr, Co, Ni, and Au were gathered into a database. The presented compilation comprises 806 analyses of 278 chondrites including new ICP‐MS analyses of Allende and two ordinary chondrites. Each data set was evaluated by comparing element ratios of meteorites from the same chondrite group. Characteristic element abundances and ratios were determined for each group. Features observed in the element abundance patterns can be linked directly to the presence of certain components, such as the abundance of refractory elements Os, Ir, and Ru correlating with the occurrence of refractory inclusions in CV, CO, CK, and CM chondrites. The refined characteristic element ratios appear to be representative not only for meteorites, but also for related asteroidal bodies. Chondrite element ratios were compared to previously published values from impact melt rocks of the Popigai and Morokweng impact structures confirming that an identification of the specific type of projectile (L and LL chondrite, respectively) is possible. The assessment for Morokweng is supported by the recent discovery of an LL chondrite fragment in the impact melt rocks. Ultimately, the database provides valuable information for understanding processes in the solar nebula as they are recorded in chondrites. A new type of complementarity between element patterns of CK and EH chondrites is suggested to be the result of condensation, redox, and transportation processes in the solar nebula.  相似文献   

8.
A summary is given of the literature data on the content of volatiles in the lunar regolith, the characterization of the likely sources of the volatiles, and the possible processes of their migration and burial. The main sources of volatiles in the regolith are the solar wind, small Solar System bodies (comets and meteorites), and the lunar interior. Different sources are the leading ones for different volatiles. Water and other volatiles can accumulate on the surface and in the near-surface layers of the Moon only in the so-called cold traps in polar basins, where other volatiles, as well as water ice, including highly toxic elements such as mercury and cadmium must be accumulated. The content of volatiles in the lunar interior is comparable to that in terrestrial rocks. Water could have played an important role in the early stages of the Moon’s history, e.g., in the formation of mare basalts. The isotopic composition of the lunar juvenile water is similar to that on the Earth, which suggests a common origin of the terrestrial and lunar water.  相似文献   

9.
Abstract— We report here the petrography, mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300 (SaU 300). SaU 300 is dominated by a fine‐grained crystalline matrix surrounding mineral fragments (plagioclase, pyroxene, olivine, and ilmenite) and lithic clasts (mainly feldspathic to noritic). Mare basalt and KREEPy rocks are absent. Glass melt veins and impact melts are present, indicating that the rock has been subjected to a second impact event. FeNi metal and troilite grains were observed in the matrix. Major element concentrations of SaU 300 (Al2O3 21.6 wt% and FeO 8.16 wt%) are very similar to those of two basalt‐bearing feldspathic regolith breccias: Calcalong Creek and Yamato (Y‐) 983885. However, the rare earth element (REE) abundances and pattern of SaU 300 resemble the patterns of feldspathic highlands meteorites (e.g., Queen Alexandra Range (QUE) 93069 and Dar al Gani (DaG) 400), and the average lunar highlands crust. It has a relatively LREE‐enriched (7 to 10 x CI) pattern with a positive Eu anomaly (?11 x CI). Values of Fe/Mn ratios of olivine, pyroxene, and the bulk sample are essentially consistent with a lunar origin. SaU 300 also contains high siderophile abundances with a chondritic Ni/Ir ratio. SaU 300 has experienced moderate terrestrial weathering as its bulk Sr concentration is elevated compared to other lunar meteorites and Apollo and Luna samples. Mineral chemistry and trace element abundances of SaU 300 fall within the ranges of lunar feldspathic meteorites and FAN rocks. SaU 300 is a feldspathic impact‐melt breccia predominantly composed of feldspathic highlands rocks with a small amount of mafic component. With a bulk Mg# of 0.67, it is the most mafic of the feldspathic meteorites and represents a lunar surface composition distinct from any other known lunar meteorites. On the basis of its low Th concentration (0.46 ppm) and its lack of KREEPy and mare basaltic components, the source region of SaU 300 could have been within a highland terrain, a great distance from the Imbrium impact basin, probably on the far side of the Moon.  相似文献   

10.
The notion of a dry Moon has recently been challenged by the discovery of high water contents in lunar apatites and in melt inclusions within olivine crystals from two pyroclastic glasses. The highest and most compelling water contents were found in pyroclastic glasses that are not very common on the lunar surface. To obtain more representative constraints on the volatile content of the lunar interior, we measured the Zn content, a moderately volatile element, of mineral and rock fragments in lunar soils collected during Apollo missions. We here confirm that the Moon is significantly more depleted in Zn than the Earth. Combining Zn with existing K and Rb data on similar rocks allows us to anchor a new volatility scale based on the bond energy of nonsiderophile elements in their condensed phases. Extrapolating the volatility curve to H shows that the bulk of the lunar interior must be dry (≤1 ppm). This contrasts with the water content of the mantle sources of pyroclastic glasses, inferred to contain up to approximately 40 ppm water based on H2O/Ce ratios. These observations are best reconciled if the pyroclastic glasses derive from localized water‐rich heterogeneities in a dominantly dry lunar interior. We argue that, although late addition of 0.015% of a chondritic veneer to the Moon seems required to explain the abundance of platinum group elements (Day et al. 2007), the volatile content of the added material was clearly heterogeneous.  相似文献   

11.
The principal rock types in the highlands are highland basalt (gabbroic anorthosite) with 28% Al2O3 and low K Fra Mauro basalt with 18% Al2O3. The chemistry of the highland soils and breccias can be represented by simple mixing models involving these rock types as major constituents. The mixing occurred during the intense highland cratering. Layering observed at the Apennine Front is interpreted as produced the Serenitatis basin collision. The plains-forming Cayley Formation and the Descartes Formation are not volcanic, but are derived from pre-existing highland crust.Although the overall chemical composition of the Moon has been affected by pre-accretion processes (e.g. loss of volatile elements), the composition of the highlands is mainly the result of postaccretion melting and element fractionation. Thus the individual rock types show involatile element distribution patterns, relative to primitive abundances, indicative of solid-liquid equilibria, evidence of post-accretion lunar igneous activity.The chemistry of the primitive green glass component (15426) indicates that the abundance of the involatile elements (REE, Ba, Zr, Hf, Th and U) in the source regions is at most only 2–3 times the abundances in chondrites.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.  相似文献   

12.
Several investigators have attempted, from studies of lithic fragments and/or glasses, to determine the types of rocks that constitute the parent materials of lunar highland soils. Comparing only major element data, and thus avoiding the problems induced by individual classifications, these data appear to converge on a relatively limited number of rock types. The highland soils are derived from a suite of highly feldspathic rocks comprising anorthositic gabbros (or norites), high alumina basalts, troctolites, and less abundant gabbroic (or noritic) anorthosites, anorthosites and KREEP basalts.  相似文献   

13.
Abstract– The feldspathic lunar meteorites contain rare fragments of crystalline basalts. We analyzed 16 basalt fragments from four feldspathic lunar meteorites (Allan Hills [ALHA] 81005, MacAlpine Hills [MAC] 88104/88105, Queen Alexandra Range [QUE] 93069, Miller Range [MIL] 07006) and utilized literature data for another (Dhofar [Dho] 1180). We compositionally classify basalt fragments according to their magma’s estimated TiO2 contents, which we derive for crystalline basalts from pyroxene TiO2 and the mineral‐melt Ti distribution coefficient. Overall, most of the basalt fragments are low‐Ti basalts (1–6% TiO2), with a significant proportion of very‐low‐Ti basalts (<1% TiO2). Only a few basalt clasts were high‐Ti or intermediate Ti types (>10% TiO2 and 6–10% TiO2, respectively). This distribution of basalt TiO2 abundances is nearly identical to that obtained from orbital remote sensing of the moon (both UV‐Vis from Clementine, and gamma ray from Lunar Prospector). However, the distribution of TiO2 abundances is unlike those of the Apollo and Luna returned samples: we observe a paucity of high‐Ti basalts. The compositional types of basalt differs from meteorite to meteorite, which implies that all basalt subtypes are not randomly distributed on the Moon, i.e., the basalt fragments in each meteorite probably represent basalts in the neighborhood of the meteorite launch site. These differences in basalt chemistry and classifications may be useful in identifying the source regions of some feldspathic meteorites. Some of the basalt fragments probably originate from ancient cryptomaria, and so may hold clues to the petrogenesis of the Moon’s oldest volcanism.  相似文献   

14.
Substantial indigenous abundances of siderophile elements have been found to be present in the lunar highlands. The abundances of 13 siderophile elements in the parental magma of the highlands crust were estimated by using a simple model whereby the Apollo 16 highlands were regarded as being a mixture of three components (i.e. cumulus plagioclase + intercumulus magma that was parentel to the highlands crust + meteoritic contamination by ordinary chondrites). The parental magma of the highlands was found to possess abundances of siderophile elements that were generally similar to the abundances of the unequivocally indigenous siderophile elements in primitive, low-Ti mare basalts. This striking similarity implies that these estimated abundances in the parental highlands magma are truly indigenous, and also supports the basic validity of our simple model.It is shown that metal/silicate fractionation within the Moon cannot have been the cause of the siderophile element abundances in the parental highlands magma and primitive, low-Ti mare basalts. The relative abundances of the indigenous siderophile elements in highland and mare samples seem, instead, to be the result of complex processes which operatedprior to the Moon's accretion.The abundances of the relatively involatile, siderophile elements in the parental highlands magma are strikingly similar to the abundances observed in terrestrial oceanic tholeiites. Furthermore, the abundances of the relatively volatile, siderophile elements in the parental highlands magma are also systematically related to the corresponding abundances in terrestrial oceanic tholeiites. In fact, the parental magma of the lunar highlands can be essentially regarded as having been a volatile-depleted, terrestrial oceanic tholeiite.The complex, siderophile element fractionations in the Earth's upper mantle are thought to be the result of core segregation. However, it is well-known that the siderophile element abundances do not correspond to expectations based solely upon equilibration of metal/silicate at low-pressures, as evidenced by the over-abundances of Au, Re, Ni, Co and Cu. Ringwood (1977a) has suggested that the siderophile element abundances in the Earth's upper mantle are the product of equilibration at very high-pressures between the mantle and a segregating core that contained substantial quantities of an element with a low atomic weight, such as oxygen. Comparable processes cannot have operated within the Moon due to its small internal pressures and the very small size of its possible core. Therefore, the fact that the Moon exhibits a systematic resemblance to the Earth's upper mantle is highly significant.The origin of the Moon is discussed in the context of these results. The possibility that depletion of siderophile elements occurred in an earlier generation of differentiated planetesimals similar to those which formed the basaltic achondrites, stony-irons, and irons is examined but can be dismissed on several grounds. It seems that the uniquely terrestrial siderophile signature within the Moon can be explained only if the Moon was derived from the Earth's mantle subsequent to core-formation.Paper dedicated to Professor Hannes Alfvén on the occasion of his 70th birthday, 30 May, 1978.  相似文献   

15.
Lunar seismic data from three Apollo seismometers are interpreted to determine the structure of the Moon's interior to a depth of about 100 km. The travel times and amplitudes ofP arrivals from Saturn IV B and LM impacts are interpreted in terms of a compressional velocity profile. The most outstanding feature of the model is that, in the Fra Mauro region of Oceanus Procellarum, the Moon has a 65 km thick layered crust. Other features of the model are: (i) rapid increase of velocity near the surface due to pressure effects on dry rocks, (ii) a discontinuity at a depth of about 25 km, (iii) near constant velocity (6.8 km/s) between 25 and 65 km deep, (iv) a major discontinuity at 65 km marking the base of the lunar crust, and (v) very high velocity (about 9 km/s) in the lunar mantle below the crust. Velocities in the upper layer of the crust match those of lunar basalts while those in the lower layer fall in the range of terrestrial gabbroic and anorthositic rocks.Lamant-Doherty Geological Observatory Contribution No. 1768.  相似文献   

16.
Abstract— Fifty-eight lunar rocks have been analysed by prompt gamma neutron activation for B, Gd and Sm. The data were interpreted together with published analyses for Li and other elements. The behaviour of B in lunar rocks is virtually identical to that of Sm, Gd, Li and the other incompatible LIL (Large Ion Lithophile) and HFS (High Field Strength) elements, collectively known as the KREEP component. To a first approximation, the distribution of B concentrations in all lunar rocks can be described as a two-component mixture of KREEP, with ～32 ppm, and B-free mare basalts and anorthositic rocks. The lunar B abundance, estimated from correlations with other KREEP elements, is ～0.14 ppm. Alpha-track images of the analysed lunar rocks were made from thin sections specially prepared to avoid contamination from terrestrial B. They provided surprising evidence that the distributions of B and Li within individual rocks fall into four categories: (1) substitution in mineral structures; (2) in irregular minute particles, disseminated through the rock with no apparent connection with mineralogy; (3) as aggregate properties of rock fragments, acquired prior to assembly in a breccia; and, (4) as aggregate properties of a breccia matrix, distinct from unaffected clasts. Only category (1) is encountered in terrestrial rocks. Categories (2), (3) and (4) become progressively more important as the abundance of KREEP components increases, and it is concluded that the alpha-track images probably show the localisation of not only B and Li but all the KREEP elements. In terrestrial rocks, such textures could be understood in terms of successive episodes of permeation by solutions followed by brecciation, then cementation. It is difficult to adapt such a mechanism to a dry Moon, with brecciation imposed by impact melting. The linear correlation of lunar B and Gd contrasts strongly with the relationship seen in terrestrial rocks, where the presence of water creates a terrestrial B cycle quite different from that of Gd and other lunar incompatible elements.  相似文献   

17.
Lunar mare basalts provide insights into the compositional diversity of the Moon's interior. Basalt fragments from the lunar regolith can potentially sample lava flows from regions of the Moon not previously visited, thus, increasing our understanding of lunar geological evolution. As part of a study of basaltic diversity at the Apollo 12 landing site, detailed petrological and geochemical data are provided here for 13 basaltic chips. In addition to bulk chemistry, we have analyzed the major, minor, and trace element chemistry of mineral phases which highlight differences between basalt groups. Where samples contain olivine, the equilibrium parent melt magnesium number (Mg#; atomic Mg/[Mg + Fe]) can be calculated to estimate parent melt composition. Ilmenite and plagioclase chemistry can also determine differences between basalt groups. We conclude that samples of approximately 1–2 mm in size can be categorized provided that appropriate mineral phases (olivine, plagioclase, and ilmenite) are present. Where samples are fine‐grained (grain size <0.3 mm), a “paired samples t‐test” can provide a statistical comparison between a particular sample and known lunar basalts. Of the fragments analyzed here, three are found to belong to each of the previously identified olivine and ilmenite basalt suites, four to the pigeonite basalt suite, one is an olivine cumulate, and two could not be categorized because of their coarse grain sizes and lack of appropriate mineral phases. Our approach introduces methods that can be used to investigate small sample sizes (i.e., fines) from future sample return missions to investigate lava flow diversity and petrological significance.  相似文献   

18.
Returned lunar KREEP basalts originated through impact processes or endogenous melting of the lunar interior. Various methods have been used to distinguish between these two origins, with varying degrees of success. Apollo 15 KREEP basalts are generally considered to be endogenous melts of the lunar interior. For example, sample 15434,181 is reported to have formed by a two‐stage cooling process, with large orthopyroxene (Opx) phenocrysts forming first and eventually cocrystalizing with smaller plagioclase crystals. However, major and trace element analyses of Opx and plagioclase coupled with calculated equilibrium liquids are inconsistent with the large orthopyroxenes being a phenocryst phase. Equilibrium liquid rare earth element (REE) profiles are enriched relative to the whole rock (WR) composition, inconsistent with Opx being an early crystallizing phase, and these are distinct from the plagioclase REE equilibrium liquids. Fractional crystallization modeling using the Opx equilibrium liquids as a parental composition cannot reproduce the WR values even with crystallization of late‐stage phosphates and zircon. This work concludes that instead of being a phenocryst phase, the large Opx crystals are actually xenocrysts that were subsequently affected by pyroxene overgrowths that formed intergrowths with cocrystallizing plagioclase.  相似文献   

19.
The thermal history and current state of the lunar interior are investigated using constraints imposed by recent geological and physical data. Theoretical temperature models are computed taking into account different initial conditions, heat sources, differentiation and simulated convection. To account for the early formation of the lunar highlands, the time duration of magmatism and presentday temperatures estimated from lunar electrical conductivity profiles, it is necessary to restrict initial temperatures and abundances of radioactivie elements. Successful models require that the outer half of the Moon initially heated to melting temperatures, probably due to rapid accretion. Differentiation of radioactive heat sources toward the lunar surface occurred during the first 1.6 billion years. Temperatures in the outer 500 km are currently low, while the deep interior (radius less than 700 to 1000 km) is warmer than 1000°C, and is of primordial material. In some models there is a partially melted core. The calculated surface heat flux is between 25 and 30 erg/cm2 s.Presently at the Research Triangle Institute, Research Triangle, North Carolina 27709, U.S.A.  相似文献   

20.
Lunar heat-flow calculations are carried out for a model Moon in which (a) near-surface initial temperatures are very high (as the occurence of a surface anorthositic layer seems to require), and (b) heat-generating radionuclides are transported upward when melting occurs. Near-surface regions are found to cool and then experience a resurgence of high temperature, as radionuclide-rich magmas from the lunar interior accumulate near the surface. This peaking of near-surface temperature can be brought into correspondence with the episode of vulcanism (∼ 3.5 × 109 years ago) that gave rise to the basalts represented in the Apollo samples, if we assume relatively high lunar temperatures in early times (due to high initial temperatures, or high content of radioactive elements, or both).  相似文献   

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