共查询到20条相似文献，搜索用时 46 毫秒
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在ＰＨ４．５的ＨＡｃ－ＮａＡｃ介质中,Ｉｎ－１－苯基－３－甲基－４－苯甲酰基吡唑啉酮－５（ＰＭＢＰ）－安替比林体系于－０．５７Ｖ处产生一良好的极谱波。Ｉｎ在０．０１－０．５ｍｇ／Ｌ与波高呈线性关系。 相似文献
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钇—5—Br—PADAP—CPC—OP显色反应的研究 总被引：6，自引：0，他引：6
研究了钇(Ⅲ)-5-Br-PADAP-CPC-乳化剂OP混合体系的光度特性,在pH7.5～9.8范围内,显色体系在580nm处有最大吸收峰,空白值低,对比度(Δλ)较高,摩尔吸光系数ε为1.0×10~5。配合物组成Y:5-Br-PADAP:CPC为1:4:3,形成稳定常数(logβ)为9.84。在0—45μg Y/50ml范围内服从比尔定律。该法已成功地应用于测定Fe-Cr-Al合金和矿物中痕量钇。 相似文献
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用抽空石英管法研究以Fe_(0·96) Sb_(2·04) S_(4·12)为投影顶点,8×(PbS-SnS-SnS_2)为投影平面的Pb-Sn-Fe-Sb-S体系的相图表明,由于Pb(?)Sn~(2+)之间互相取代,500℃时辉锑锡铅矿固溶体中Sn~(2+)变化范围(以单位分子式11个金属原子总数为计量)是0—4.8个原子,400℃时则为0—4.0个原子。同时,Sn~(4+)变化范围是1.3—2.3个原子和1.5—2.1个原子。圆柱锡矿固溶体变化范围较小。500℃时Sn~(2+)变化范围是0.4—1.8个原子,400℃时为0.5—1.7。Sn~(+4)变化范围则分别为3.2—4.2个原子和3.3—4.2个原子。变更Fe含量(0.81—1.09)及Sb含量(1.83—2.29)进行的几组合成实验表明,上述两个矿物中Fe、Sb含量变化范围很小,不超过±0.15个原子。辉锑锡铅矿固溶体可与方铅矿、块硫锑铅矿、针硫锑铅矿、硫锡铅矿、硫锡矿、圆柱锡矿等形成平衡结线。而圆柱锡矿不与方铅矿、硫锡矿、硫锡铅矿形成平衡结线,但可与辉锑矿、SnS_2及上述其他矿物形成平衡结线。结合锡的硫化物及氧化物(锡石)热力学稳定场计算表明,在本体系内辉锑锡铅矿在300℃时稳定区的硫活度在lga_(s2)=-20(atm)附近,氧活度小于lga_(o2)=-40(atm),而圆柱锡矿稳定区硫活度大于lga_(s2)=-10(atm)。 相似文献
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4—（2—羟基—4—硝基苯偶氮）—1—苯基—3—甲基吡唑啉酮与钍的显色反应 总被引：4，自引：0，他引：4
在pH为 2～ 3的HAc介质中 ,4 - ( 2 -羟基 - 4 -硝基苯偶氮 ) - 1 -苯基 - 3-甲基吡唑啉酮 (HNAPMP)与钍反应生成 2∶1的稳定络合物 ,λmax=540nm ,ε=4 .96× 1 0 4L·moL- 1·cm- 1,Th质量浓度在 0～ 2 .8mg/L内符合比尔定律。方法用于钍钨合金中钍的测定 ,相对标准偏差 (n =5)小于 1 % ,加标回收率为 97%～ 1 0 2 %。 相似文献
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鉴于大陆岩浆弧上盘广泛分布有碳酸盐岩,岩体上升侵位过程使其碳通量明显的高于洋内岛弧,从而有可能影响着地质历史长时间尺度(百万年)的气候变化。陆弧碳的排放可分为两部分,一部分是与喷出岩相关的火山作用,另一部分是与侵入岩相关的脱碳过程。侵入岩的体量一般是喷出岩体量的10倍以上,由此与侵入岩有关的脱碳作用释放的碳通量不可忽视,可能类似与喷出岩有关的火山作用释放的碳通量甚至更大。火山作用能够将气体直接排入大气中,因此在以往的工作中研究较为充分。但与侵入岩相关的脱碳过程如:矽卡岩化,发生在地下,关于地下脱碳过程如何将碳释放到大气中还缺少详细的工作。本文,通过对比研究火山地区和非火山地区与侵入岩相关的深部脱碳过程,发现深部碳可以通过区域断层系统、地下水系统和热泉、火山通道、隐爆角砾岩筒、高频率的岩浆热液事件等途径瞬时地释放进入大气。通过初步估算,发现单个矽卡岩矿化事件所产生的二氧化碳通量(0.02~0.2Mt/yr)能够与目前地球绝大部分的普通单个火山的碳通量(<0.5Mt/yr)类比。因此岩浆深部脱碳过程对大气的影响至少与火山相当,其对气候的影响不可忽视。 相似文献
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Mathematical Geosciences - 相似文献
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本文从人生信念、道德境界以及我国传统美德等方面阐述了敬业精神对当今激烈的市场竞争中的重要作用,并推出大力倡导敬业精神,纠正行业不正之风的基本途径和方法。 相似文献
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An extension to the DRASTIC model is proposed in order to assess aquifer vulnerability to pollution. In contrast to the DRASTIC
model, which considers the unsaturated and saturated zones together and computes a global intrinsic vulnerability index, the
suggested approach discriminates between the aquifer vertical vulnerability (a concept related to the pollutant percolation)
and the groundwater susceptibility (a concept that depends on the behaviour and uses of the groundwater). This approach is
applied to the Haouz aquifer (Morocco) that supplies water to the Marrakech area. This aquifer is widely overexploited and
there is evidence that the groundwater quality is threatened by various sources of pollution. Evaluation of the vertical vulnerability
indicates that the aquifer mainly presents a moderate-to-weak vertical vulnerability. The zones potentially most favourable
to pollutant percolation are mainly located in Central Haouz, along or near the surface wadis. The aquifer susceptibility
is high in places located near the N’Fis, Baaja and Issil wadis. Everywhere else, low-to-moderate susceptibility is observed.
This new approach therefore enables areas of vertical vulnerability and areas of susceptibility to be delineated separately.
As a result, it constitutes a valuable decision-making tool for optimising the management of aquifer water resources and land-use
planning. 相似文献
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Nutrient loading to estuaries with heavily populated watersheds can have profound ecological consequences. In evaluating policy
options for managing nitrogen (N), it is helpful to understand current and historic spatial loading patterns to the system.
We modeled N inputs to Narragansett Bay from 1850 to 2000, using data on population, human waste disposal, livestock, fertilizer,
and atmospheric deposition. We found that total N loading to the bay increased 250% from 1850 to 2000, and 80% from 1900 to
2000. Loading to the upper bay increased far more than that to the lower bay, and the most important source shifted from non-point
animal waste to human waste concentrated at sewage treatment facilities. We also modeled future N loads in 2015 under four
management scenarios. Planned improvements in sewage treatment would reduce N loads 9% below business-as-usual, to the 1990
loading rate. Greater reductions, to circa 1900 rates of loading, may be possible. 相似文献
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Nowadays, environmental problems related to soil pollution with heavy metals are numerous, therefore, it is important to understand metals behaviour in aquatic sediments and soils and to estimate their transfer. The fate of metals in the environment is closely related to their interactions with the major reactive compartments (organic matter, iron and manganese oxides, clays). The objective of this work is to develop an approach based on the combination of several models to study metal ion speciation in different environmental systems. Models used to describe the interactions of metals with the main reactive phases in the soil are CD-MUSIC (amorphous and crystallized iron oxides), NICA-Donnan (organic matter and manganese oxides) and cationic ion exchange model (clays). First, this work implies the definition of generic parameters to describe the interactions of the studied metals with iron and manganese oxides and part of this information is missing in the literature. Then, after a validation of the approach by comparison with analytical results, this multi-surface model is applied to test sites corresponding to one soil and two riverine environments.These new models give good predictions of the behaviour of major and trace metal ions even in heterogeneous systems characteristic of natural environment. The measured free metal concentrations in the solution are in agreement with those obtained from model calculations. In the case of the soil test site, the soil solution composition and speciation are predicted using the soil major constituents characteristics. 相似文献
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Der Sarkissian Rita Abdallah Chadi Zaninetti Jean-Marc Najem Sara 《Natural Hazards》2020,103(1):121-137
Natural Hazards - Estimating the resilience of a road network (one of the essential critical infrastructures in times of crisis) to natural hazards is crucial in achieving the goals of disaster... 相似文献
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水平定向钻进地层适应性的评价方法 总被引：1，自引：0，他引：1
水平定向钻进的地层适应性对施工技术方案、钻具选择、参数选取和施工效益都有着重要影响。应采用钻进地层的岩土硬度、完整性和研磨性三方面指标,对比钻进技术工艺和技术器具特点,对钻进效率、钻孔的成孔和孔壁稳定性、以及钻具寿命等进行定性及定量的评价,从而有利于大大提高水平定向钻进铺管施工的技术和经济效益。 相似文献