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1.
Rate coefficient of the cyanide anion (CN−) with cyanoacetylene (HC3N) reaction, has been studied in gas phase at room temperature using a Flowing Afterglow Langmuir Probe - Mass Spectrometer (FALP-MS) apparatus. The rate constant for the CN− + HC3N reaction is k = 4.8 × 10−9 cm3/s with an uncertainty of 30%. 相似文献
2.
We report the Balmer broad absorption lines (BALs) in the quasar SDSS J2220 + 0109 discovered from the SDSS data, and present a detailed analysis of the peculiar absorption line spectrum, including the He I* multiplet at λλ3189, 3889 arising from the metastable 23s-state helium and the Balmer Hα and Hβ lines from the excited hydrogen H I of n = 2 level, which are rarely seen in quasar spectra, as well as many absorption lines arising from the excited Fe II* of the levels 7 955 cm−1, 13 474 cm−1 and 13 673 cm−1 in the wavelength range 3100∼3300 Å. Ca II H, K absorption line doublets also clearly appear in the SDSS spectrum. All absorption lines show a similar blueshifted velocity structure of Δv ≈ − 1500 ∼ 0 km·s−1 relative to the quasar's systematic redshift determined from the emission lines. Detailed analysis suggests that the Balmer absorption lines should arise from the partially ionized region with a column density of NHI ≈ 1021 cm−2 for an electron density of ne ∼ 106 cm−3; and that the hydrogen n = 2 level may be populated via collisional excitation with Lyα pumping. 相似文献
3.
The propagation of ionizing radiation through model atmospheres of terrestrial-like exoplanets is studied for a large range of column densities and incident photon energies using a Monte Carlo code we have developed to treat Compton scattering and photoabsorption. Incident spectra from parent star flares, supernovae, and gamma-ray bursts are modeled and compared to energetic particles in importance. Large irradiation events with fluences of 106-109 erg cm−2 at the conventional habitable zone can occur at a rate from many per day (flares from young low-mass parent stars) to ∼100 per Gyr (supernovae and gamma-ray bursts). We find that terrestrial-like exoplanets with atmospheres thinner than about 100 g cm−2 block nearly all X-rays, but transmit and reprocess a significant fraction of incident γ-rays, producing a characteristic, flat surficial spectrum. Thick atmospheres (?100 g cm−2) efficiently block even γ-rays, but nearly all the incident energy is redistributed into diffuse UV and visible aurora-like emission, increasing the effective atmospheric transmission by many orders of magnitude. Depending on the presence of molecular UV absorbers and atmospheric thickness, up to 10% of the incident energy can reach the surface as UV reemission. For the Earth, between 2×10−3 and 4×10−2 of the incident flux reaches the ground in the biologically effective 200-320 nm range, depending on O2/O3 shielding. For atmospheres thicker than ∼50 g cm−2 in the case of pure Rayleigh scattering and ∼100 g cm−2 in the case of O2/O3 absorption, the UV reemission exceeds the surficial transmitted ionizing radiation. We also discuss the effects of angle of incidence and derive a modified two-stream approximation solution for the UV transfer. Finally, we suggest that transient atmospheric ionization layers can be frequently created at altitudes lower than the equilibrium layers that result from steady irradiation and winds from the parent star. We suggest that these events can produce frequent fluctuations in atmospheric ionization levels and surficial UV fluxes on terrestrial-like planets. 相似文献
4.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed. 相似文献
5.
We performed a complete wavelet analysis of Saturn’s C ring on 62 stellar occultation profiles. These profiles were obtained by Cassini’s Ultraviolet Imaging Spectrograph High Speed Photometer. We used a WWZ wavelet power transform to analyze them. With a co-adding process, we found evidence of 40 wavelike structures, 18 of which are reported here for the first time. Seventeen of these appear to be propagating waves (wavelength changing systematically with distance from Saturn). The longest new wavetrain in the C ring is a 52-km-long wave in a plateau at 86,397 km. We produced a complete map of resonances with external satellites and possible structures rotating with Saturn’s rotation period up to the eighth order, allowing us to associate a previously observed wave with the Atlas 2:1 inner Lindblad resonance (ILR) and newly detected waves with the Mimas 6:2 ILR and the Pandora 4:2 ILR. We derived surface mass densities and mass extinction coefficients, finding σ = 0.22(±0.03) g cm−2 for the Atlas 2:1 ILR, σ = 1.31(±0.20) g cm−2 for the Mimas 6:2 ILR, and σ = 1.42(±0.21) g cm−2 for the Pandora 4:2 ILR. We determined a range of mass extinction coefficients (κ = τ/σ) for the waves associated with resonances with κ = 0.13 (±0.03) to 0.28(±0.06) cm2 g−1, where τ is the optical depth. These values are higher than the reported values for the A ring (0.01-0.02 cm2 g−1) and the Cassini Division (0.07-0.12 cm2 g−1 from Colwell et al. (Colwell, J.E., Cooney, J.H., Esposito, L.W., Srem?evi?, M. [2009]. Icarus 200, 574-580)). We also note that the mass extinction coefficient is probably not constant across the C ring (in contrast to the A ring and the Cassini Division): it is systematically higher in the plateaus than elsewhere, suggesting smaller particles in the plateaus. We present the results of our analysis of these waves in the C ring and estimate the mass of the C ring to be between3.7(±0.9) × 1016 kg and 7.9(±2.0) × 1016 kg (equivalent to an icy satellite of radius between 28.0(±2.3) km and 36.2(±3.0) km with a density of 400 kg m−3, close to that of Pan or Atlas). Using the ring viscosity derived from the wave damping length, we also estimate the vertical thickness of the C ring between 1.9(±0.4) m and 5.6(±1.4) m, comparable to the vertical thickness of the Cassini Division. 相似文献
6.
This paper reports 13CO, C18O, HCO+ (J = 1−0) spectral observations toward IRAS 23133+6050 with the 13.7 m millimeter-wave telescope at Qinghai Station of PMO. Corresponding to the 13CO, C18O, HCO+ line emissions, the size of the observed molecular cloud core is 4.0 pc, 2.1 pc and 2.3 pc, the virial mass is 2.7 × 103 M⊙, 0.9 × 103 M⊙ and 2.3 × 103 M⊙, and the volume density of H2 is 2.7 × 103 cm−3, 5.1 × 103 cm−3 and 4.6 × 103 cm−3, respectively. Using the power-law function n(r) ∼r−p, the spatial density distribution of the cloud core was analyzed, the obtained exponent p is respectively 1.75, 1.56 and 1.48 for the 13CO, C18O and HCO+ cores, and it is found that the density distribution becomes gradually flatter from the outer region to the inner region of the core. The HCO+ abundance is 4.6 × 10−10, one order of magnitude less than the value for dark clouds, and slightly less than that for giant molecular clouds. The 13CO/C18O relative abundance ratio is 12.2, comparable with the value 11.8 for dark clouds, and the value 9.0 ∼ 15.6 for giant molecular clouds. A 13CO bipolar outflow is found in this region. The IRAS far-infrared luminosity and the virial masses give the luminosity-mass ratios 18.1, 51.1 and 21.2 from the three lines. 相似文献
7.
The published sunspot spectrum obtained with National Solar Observatory/Kitt Peak laboratory’s high signal to noise ratio telescope and high resolution Fourier Transform Spectrometer were used for the study. A search was made for the prominent lines of the (0, 0) and (1, 1) A2Δ − X2Π for Silicon hydride isotopomers which lie between 23500 cm−1 and 24500 cm−1. The presence of lines from the (0, 0) and (1, 1) A2Δ − X2Π transition of SiH molecule coincided with the sunspot umbral lines suggest that Silicon hydride appears to be a non-negligible component of sunspot umbrae. However, the presence of A2Δ − X2Π (0, 0) and (1, 1) bands of SiD was found to be doubtful because of the lack of number of well identified lines in sunspot umbral spectra. Equivalent widths have been measured for well-resolved lines and, thereby, the rotational temperatures have been estimated for the band systems for which the presence is confirmed. 相似文献
8.
Fifteen organic and three inorganic compounds were tested for methane (CH4) evolution under simulated martian conditions of 6.9 mbar; UVC (200-280 nm) flux of 4 W m−2; 20 °C; simulated optical depth of 0.1; and a Mars gas composition of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.13%), and water vapor (0.03%). All three inorganic compounds (i.e., NaCl, CaCO3, graphite) failed to evolve methane at the minimum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved methane when exposed to UV irradiation under simulated martian conditions. The polycyclic aromatic hydrocarbon, pyrene, released the most methane per unit of time at 0.175 nmol CH4 g−1 h−1, and a spectral reflectance target material used for the MER rovers and Phoenix lander released the least methane at 0.00065 nmol CH4 cm−2 h−1. Methane was also released from UV-killed bacterial endospores of Bacillus subtilis. Although all organic compounds evolved methane when irradiated with UV photons under martian conditions, the concentrations of residual organics, biogenic signature molecules, and dead microbial cells should be relatively low on the exterior surfaces of the MSL rover, and, thus, not significant sources of methane contamination. In contrast, kapton tape was found to evolve methane at the rate of 0.00165 nmol CH4 cm−2 h−1 (16.5 nmol m−2 h−1) under the UV and martian conditions tested. Although the evolution of methane from kapton tape was found to decline over time, the large amount of kapton tape used on the MSL rover (lower bound estimated at 3 m2) is likely to create a significant source of terrestrial methane contamination during the early part of the mission. 相似文献
9.
New laboratory spectra of crystalline and amorphous diacetylene ice have been recorded in the range of 7000-500 cm−1 (1.4-20 μm) to aid in the identification of solid diacetylene on Saturn's moon Titan. We have established that amorphous diacetylene ice is stable only at temperatures less than 70±1 K. With respect to observations on Titan, the best approach would be to utilize future space-based telescopes to search for the ν4 (3277/3271 cm−1) in absorption against the reflected light from the sun and the slightly weaker ν8 absorption bands (676/661 cm−1) in absorption against the continuum emission. 相似文献
10.
Our model [Dimitrov, V., Bar-Nun, A., 1999. A model of energy dependent agglomeration of hydrocarbon aerosol particles and implication to Titan's aerosol. J. Aerosol. Sci. 30(1), 35-49] describes the experimentally found polymerization of C2H2 and HCN to form aerosol embryos, their growth and adherence to form various aerosols objects [Bar-Nun, A., Kleinfeld, I., Ganor, E., 1988. Shape and optical properties of aerosols formed by photolysis of C2H2, C2H4 and HCN. J. Geophys. Res. 93, 8383-8387]. These loose fractal objects describe well the findings of DISR on the Huygens probe [Tomasko, M.G., Bézard, B., Doose, L., Engel, S., Karkoschka, E., 2008. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this issue, doi:10.1016/j.pss.2007]. These include (1) various regular objects of R=(0.035-0.064)×10−6 m, as compared with DISR's 0.05×10−6 m; (2) diverse low and high fractal structures composed of random combinations of various regular and irregular objects; (3) the number density of fractal particles is 6.9×106 m−3 at Z=100 km, as compared with DISR's finding of 5.0×106 m−3 at Z=80 km; (4) the number of structural units per higher fractals in the atmosphere at Z∼100 km is (2400-2700), as compared with DISR's 3000, and their size being of R=(5.4-6.4)×10−6 m will satisfy this value and (5) condensation of CH4 on the highly fractal structures could begin at the altitude where thin methane clouds were observed, filling somewhat the new open fractal structures. 相似文献
11.
Vladimir A. Krasnopolsky 《Icarus》2011,215(1):197-203
The vertical profile of H2SO4 vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H2O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H2O and H2SO4 and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H2SO4 vapor mixing ratio is ∼10−12 at 70 and 110 km with a deep minimum of 3 × 10−18 at 88 km. The H2O-H2SO4 system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H2SO4 is 1.6 × 105 cm−2 s−1 at 70 km and 23 cm−2 s−1 at 90 km. The calculated abundance of H2SO4 vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 106 and 109, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H2SO4 (impossible for a source of SOX), and cross sections for H2SO4·H2O (impossible above the pure H2SO4) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SOX at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SOX on Venus remains unclear and probably does not exist. 相似文献
12.
Based on measurements performed by the Hydrogen Deuterium Absorption Cell (HDAC) aboard the Cassini orbiter, Titan’s atomic hydrogen exosphere is investigated. Data obtained during the T9 encounter are used to infer the distribution of atomic hydrogen throughout Titan’s exosphere, as well as the exospheric temperature.The measurements performed during the flyby are modeled by performing Monte Carlo radiative transfer calculations of solar Lyman-α radiation, which is resonantly scattered on atomic hydrogen in Titan’s exosphere. Two different atomic hydrogen distribution models are applied to determine the best fitting density profile. One model is a static model that uses the Chamberlain formalism to calculate the distribution of atomic hydrogen throughout the exosphere, whereas the second model is a Particle model, which can also be applied to non-Maxwellian velocity distributions.The density distributions provided by both models are able to fit the measurements although both models differ at the exobase: best fitting exobase atomic hydrogen densities of nH = (1.5 ± 0.5) × 104 cm−3 and nH = (7 ± 1) × 104 cm−3 were found using the density distribution provided by both models, respectively. This is based on the fact that during the encounter, HDAC was sensitive to altitudes above about 3000 km, hence well above the exobase at about 1500 km. Above 3000 km, both models produce densities which are comparable, when taking into account the measurement uncertainty.The inferred exobase density using the Chamberlain profile is a factor of about 2.6 lower than the density obtained from Voyager 1 measurements and much lower than the values inferred from current photochemical models. However, when taking into account the higher solar activity during the Voyager flyby, this is consistent with the Voyager measurements. When using the density profile provided by the particle model, the best fitting exobase density is in perfect agreement with the densities inferred by current photochemical models.Furthermore, a best fitting exospheric temperature of atomic hydrogen in the range of TH = (150-175) ± 25 K was obtained when assuming an isothermal exosphere for the calculations. The required exospheric temperature depends on the density distribution chosen. This result is within the temperature range determined by different instruments aboard Cassini. The inferred temperature is close to the critical temperature for atomic hydrogen, above which it can escape hydrodynamically after it diffused through the heavier background gas. 相似文献
13.
D. Jacquemart E. Lellouch C. de Bergh N. Lacome M. Tomasko 《Planetary and Space Science》2008,56(5):613-623
Laboratory spectra of methane-nitrogen mixtures have been recorded in the near-infrared range (1.0-1.65 μm) in conditions similar to Titan's near surface, to facilitate the interpretation of the DISR/DLIS (DISR—Descent Imager/Spectral Radiometer) spectra taken during the last phase of the descent of the Huygens Probe, when the surface was illuminated by a surface-science lamp. We used a 0.03 cm−1 spectral resolution, adequate to resolve the lines at high pressure (pN2∼1.5 bar). By comparing the laboratory spectra with synthetic calculations in the well-studied ν2+2ν3 band (7515-7620 cm−1), we determine a methane absorption column density of 178±20 cm atm and a temperature of 118±10 K in our experiment. From this, we derive the methane absorption coefficients over 1.0-1.65 μm with a 0.03 cm−1 sampling, allowing for the extrapolation of the results to any other methane column density under the relevant pressure and temperature conditions. We then revisit the calibration and analysis of the Titan “lamp-on” DLIS spectra. We infer a 5.1±0.8% methane-mixing ratio in the first 25 m of Titan's atmosphere. The CH4 mixing ratio measured 90 s after landing from a distance of 45 cm is found to be 0.92±0.25 times this value, thus showing no post-landing outgassing of methane in excess of ∼20%. Finally, we determine the surface reflectivity as seen between 25 m and 45 cm and find that the 1500 nm absorption band is deeper in the post-landing spectrum as compared to pre-landing. 相似文献
14.
We present RPWS Langmuir probe data from the third Enceladus flyby (E3) showing the presence of dusty plasma near Enceladus’ South Pole. There is a sharp rise in both the electron and ion number densities when the spacecraft traverses through Enceladus plume. The ion density near Enceladus is found to increase abruptly from about 102 cm−3 before the closest approach to 105 cm−3 just 30 s after the closest approach, an amount two orders of magnitude higher than the electron density. Assuming that the inconsistency between the electron and ion number densities is due to the presence of dust particles that are collecting the missing electron charges, we present dusty plasma characteristics down to sub-micron particle sizes. By assuming a differential dust number density for a range in dust sizes and by making use of Langmuir probe data, the dust densities for certain lower limits in dust size distribution were estimated. In order to achieve the dust densities of micrometer and larger sized grains comparable to the ones reported in the literature, we show that the power law size distribution must hold down to at least 0.03 μm such that the total differential number density is dominated by the smallest sub-micron sized grains. The total dust number density in Enceladus’ plume is of the order of 102 cm−3 reducing to 1 cm−3 in the E-ring. The dust density for micrometer and larger sized grains is estimated to be about 10−4 cm−3 in the plume while it is about 10−6-10−7 cm−3 in the E-ring. Dust charge for micron sized grains is estimated to be about eight thousand electron charges reducing to below one hundred electron charges for 0.03 μm sized grains. The effective dusty plasma Debye length is estimated and compared with inter-grain distance as well as the electron Debye length. The maximum dust charging time of 1.4 h is found for 0.03 μm sized grains just 1 min before the closest approach. The charging time decreases substantially in the plume where it is only a fraction of a second for 1 μm sized grains, 1 s for 0.1 μm sized grains and about 10 s for 0.03 μm sized grains. 相似文献
15.
J. P. Vallée 《Astrophysics and Space Science》1995,234(1):1-10
A search is made here for possible variations in the behavior of magnetic field valuesB at various gas density valuesn, when comparing low density gas versus high density gas, and when comparing compressed gas versus quiescent gas.
- For thequiescent microturbulent interstellar gas (e.g., clouds, interclumps — see TableI), the statistical relationB ~n k yieldsk = 0.46 ± 0.07 forhigh gas densityn > 100 cm?3, andk = 0.17 ± 0.03 forlow gas densityn < 100 cm?3 (see Figure 1).
- For thecompressed macroturbulent interstellar gas (e.g., masers, expanding shells — see Table II), the statistical relationB ~n K yieldsK = 0.61 ± 0.09 forhigh gas densityn > 100 cm?3, andK = 0.37 ± 0.2 forlow gas densityn < 100 cm?3 (see Figure 2).
- The separation betweenlow density gas andhigh density gas is statistically significant. The 2 different physical behaviors (below and above the break at 100 cm?3) are confirmed statistically (about 2 to 4 sigma away for the quiescent gas alone; about 3 to 6 sigma away for the combined quiescent plus compressed gas).
- The separation betweencompressed gas andquiescent gas is not statistically significant now (see Figure 3). Atn > 100 cm?3, a comparison of quiescent gas versus compressed gas shows no statistically significant differences in behavior (they are only about 1 sigma away). Atn < 100 cm?3, a comparison of quiescent versus compressed gas also shows no statistically significant differences in behavior (less than 1 sigma away).
- A relation between the densityn and the galactic-wide Star Formation Rate (SFR) can be made for galactic magnetic fields, i.e.: (SFR) ~n n . For galactic-wide parameters using quiescent, low densityn < 100 cm?3, and the known relationshipsB ~n k/j withk = 0.17,B ~ (SFR) j withj = 0.13, then one gets here a lawSFR ~n k/j with an exponentk/j = 1.3. This is in rough accord with known data for the Milky Way and for NGC6946.
16.
In July 1994, the Shoemaker-Levy 9 (SL9) impacts introduced hydrogen cyanide (HCN) to Jupiter at a well confined latitude band around −44°, over a range of specific longitudes corresponding to each of the 21 fragments (Bézard et al. 1997, Icarus 125, 94-120). This newcomer to Jupiter's stratosphere traces jovian dynamics. HCN rapidly mixed with longitude, so that observations recorded later than several months after impact witnessed primarily the meridional transport of HCN north and south of the impact latitude band. We report spatially resolved spectroscopy of HCN emission 10 months and 6 years following the impacts. We detect a total mass of HCN in Jupiter's stratosphere of 1.5±0.7×1013 g in 1995 and 1.7±0.4×1013 g in 2000, comparable to that observed several days following the impacts (Bézard et al. 1997, Icarus 125, 94-120). In 1995, 10 months after impact, HCN spread to −30° and −65° latitude (half column masses), consistent with a horizontal eddy diffusion coefficient of Kyy=2-3×1010 cm2 s−1. Six years following impact HCN is observed in the northern hemisphere, while still being concentrated at 44° south latitude. Our meridional distribution of HCN suggests that mixing occurred rapidly north of the equator, with Kyy=2-5×1011 cm2 s−1, consistent with the findings of Moreno et al. (2003, Planet. Space Sci. 51, 591-611) and Lellouch et al. (2002, Icarus 159, 112-131). These inferred eddy diffusion coefficients for Jupiter's stratosphere at 0.1-0.5 mbar generally exceed those that characterize transport on Earth. The low abundance of HCN detected at high latitudes suggests that, like on Earth, polar regions are dynamically isolated from lower latitudes. 相似文献
17.
A large number of cometary dust particles were captured with low-density silica aerogels by NASA’s Stardust Mission. Knowledge of the details of the capture mechanism of hypervelocity particles in silica aerogel is needed in order to correctly derive the original particle features from impact tracks. However, the mechanism has not been fully understood yet. We shot hard spherical projectiles of several different materials into silica aerogel of density 60 mg cm−3 and observed their penetration processes using an image converter or a high-speed video camera. In order to observe the deceleration of projectiles clearly, we carried out impact experiments at two velocity ranges; ∼4 km s−1 and ∼200 m s−1. From the movies we took, it was indicated that the projectiles were decelerated by hydrodynamic force which was proportional to v2 (v: projectile velocity) during the faster penetration process (∼4 km s−1) and they were merely overcoming the aerogel crushing strength during the slower penetration process (∼200 m s−1). We applied these deceleration mechanisms for whole capture process to calculate the track length. Our model well explains the track length in the experimental data set by Burchell et al. (Burchell, M.J., Creighton, J.A., Cole, M.J., Mann, J., Kearsley, A.T. [2001]. Meteorit. Planet. Sci. 36, 209-221). 相似文献
18.
Mercury's close orbit around the Sun, its weak intrinsic magnetic field and the absence of an atmosphere (Psurface<1×10−8 Pa) results in a strong direct exposure of the surface to energetic ions, electrons and UV radiation. Thermal processes and particle-surface-collisions dominate the surface interaction processes leading to surface chemistry and physics, including the formation of an exosphere (N?1014 cm−2) in which gravity is the dominant force affecting the trajectories of exospheric atoms. NASA's Mariner 10 spacecraft observed the existence of H, He, and O in Mercury's exosphere. In addition, the volatile components Na, K, and Ca have been observed by ground based instrumentation in the exosphere. We study the efficiency of several particle surface release processes by calculating stopping cross-sections, sputter yields and exospheric source rates. Our study indicates surface sputter yields for Na between values of about 0.27 and 0.35 in an energy range from 500 eV up to 2 keV if Na+ ions are the sputter agents, and about 0.037 and 0.082 at an energy range between 500 eV up to 2 keV when H+ are the sputter agents and a surface binding energy of about 2 eV to 2.65 eV. The sputter yields for Ca are about 0.032 to 0.06 and for K atoms between 0.054 to 0.1 in the same energy range. We found a sputter yield for O atoms between 0.025 and 0.04 for a particle energy range between 500 eV up to 2 keV protons. By taking the average solar wind proton surface flux at the open magnetic field line area of about 4×108 cm−2 s−1 calculated by Massetti et al. (2003, Icarus, in press) the resulting average sputtering flux for O is about 0.8-1.0×107 cm−2 s−1 and for Na approximately 1.3-1.6×105 cm−2 s−1 depending on the assumed Na binding energies, regolith content, sputtering agents and solar activity. By using lunar regolith values for K we obtain a sputtering flux of about 1.0-1.4×104 cm−2 s−1. By taking an average open magnetic field line area of about 2.8×1016 cm2 modelled by Massetti et al. (2003, Icarus, in press) we derive an average surface sputter rate for Na of about 4.2×1021 s−1 and for O of about 2.5×1023 s−1. The particle sputter rate for K atoms is about 3.0×1020 s−1 assuming lunar regolith composition for K. The sputter rates depend on the particle content in the regolith and the open magnetic field line area on Mercury's surface. Further, the surface layer could be depleted in alkali. A UV model has been developed to yield the surface UV irradiance at any time and latitude over a Mercury year. Seasonal and diurnal variations are calculated, and Photon Stimulated Desorption (PSD) fluxes along Mercury's orbit are evaluated. A solar UV hotspot is created towards perihelion, with significant average PSD particle release rates and Na fluxes of about 3.0×106 cm−2 s−1. The average source rates for Na particles released by PSD are about 1×1024 s−1. By using the laboratory obtained data of Madey et al. (1998, J. Geophys. Res. 103, 5873-5887) for the calculation of the PSD flux of K atoms we get fluxes in the order of about 104 cm−2 s−1 along Mercury's orbit. However, these values may be to high since they are based on idealized smooth surface conditions in the laboratory and do not include the roughness and porosity of Mercury's regolith. Further, the lack of an ionosphere and Mercury's small, temporally and spatially highly variable magnetosphere can result in a large and rapid increase of exospheric particles, especially Na in Mercury's exosphere. Our study suggests that the average total source rates for the exosphere from solar particle and radiation induced surface processes during quiet solar conditions may be of the same order as particles produced by micrometeoroid vaporization. We also discuss the capability of in situ measurements of Mercury's highly variable particle environment by the proposed NPA-SERENA instrument package on board ESA's BepiColombo Mercury Planetary Orbiter (MPO). 相似文献
19.
The main gas-phase constituents of Titan's upper atmosphere, N2 and CH4, are photolyzed and radiolyzed by solar photons and magnetospheric electrons, respectively. The primary products of these chemical interactions evolve to heavier organic compounds that are likely to associate into the particles of haze layers that hide Titan's surface. The different theories and models that have been put forward to explain the characteristics and properties of the haze composites require a knowledge of their optical properties, which are determined by the complex refractive index. We present a new set of values for refractive index n and extinction coefficient k calculated directly from the transmittance and reflectance curves exhibited by a laboratory analogue of Titan's aerosols in the 200-900 nm range. Improvements in the aerosol analogue quality have been made. The effects of variables such as the uncertainty in sample thickness, aerosol porosity, and amount of scattered light on the final n and k values are assessed and discussed. Within the studied wavelength domain, n varies from 1.53 to 1.68 and k varies from 2.62×10−4 to 2.87×10−2. These final n and k values should be considered as a new reference to modelers who compute the properties of Titan's aerosols in trying to explain the atmospheric dynamics and surface characteristics. 相似文献
20.
We present absorption cross sections of propane (C3H8) at temperatures from 145 K to 297 K in the 690–1550 cm−1 region. Pure and N2-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm−1, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm−1 region was determined to be 52.93 (±3%) × 10−19 cm−1/(molecule cm−2) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C3H8 pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo). 相似文献