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1.
Arsenic (As) and fluoride (F?) in groundwater are increasing global water quality and public health concerns. The present study provides a deeper understanding of the impact of seasonal change on the co-occurrence of As and F?, as both contaminants vary with climatic patterns. Groundwater samples were collected in pre- and post-monsoon seasons (n = 40 in each season) from the Brahmaputra flood plains (BFP) in northeast India to study the effect of season on As and F? levels. Weathering is a key hydrogeochemical process in the BFP and both silicate and carbonate weathering are enhanced in the post-monsoon season. The increase in carbonate weathering is linked to an elevation in pH during the post-monsoon season. A Piper diagram revealed that bicarbonate-type water, with Na+, K+, Ca2+, and Mg2+ cations, is common in both seasons. Correlation between Cl? and NO3 ? (r = 0.74, p = 0.01) in the post-monsoon indicates mobilization of anthropogenic deposits during the rainy season. As was within the 10 µg L?1 WHO limit for drinking water and F? was under the 1.5 mg L?1 limit. A negative correlation between oxidation reduction potential and groundwater As in both seasons (r = ?0.26 and ?0.49, respectively, for pre-monsoon and post-monsoon, p = 0.05) indicates enhanced As levels due to prevailing reducing conditions. Reductive hydrolysis of Fe (hydr)oxides appears to be the predominant process of As release, consistent with a positive correlation between As and Fe in both seasons (r = 0.75 and 0.73 for pre- and post-monsoon seasons, respectively, at p = 0.01). Principal component analysis and hierarchical cluster analysis revealed grouping of Fe and As in both seasons. F? and sulfate were also clustered during the pre-monsoon season, which could be due to their similar interactions with Fe (hydr)oxides. Higher As levels in the post-monsoon appears driven by the influx of water into the aquifer, which drives out oxygen and creates a more reducing condition suitable for reductive dissolution of Fe (hydr)oxides. An increase in pH promotes desorption of As oxyanions AsO4 3? (arsenate) and AsO3 3? (arsenite) from Fe (hydr)oxide surfaces. Fluoride appears mainly released from F?-bearing minerals, but Fe (hydr)oxides can be a secondary source of F?, as suggested by the positive correlation between As and F? in the pre-monsoon season.  相似文献   

2.
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3.
This study investigates the characteristics of geothermal water in 10 geothermal fields in Beijing. The relationships between the deuterium excess parameter (d) and temperature, depth, age of geothermal groundwater, groundwater flow field, and Eh were investigated using geothermal groundwater samples. Results showed that (1) the average d value of geothermal water is 5.4, whereas that of the groundwater in normal temperature is 6.04. The differences are induced by the oxygen isotope exchange during the water–rock interaction, which may be more easily completed in geothermal water than in cold groundwater. (2) The d value increases remarkably with the age of the geothermal groundwater. The d value increases from 11.2 to 14.6 when the age of the geothermal water is 12,760 ± 130 a and 38,960 ± 630 a, respectively. Moreover, the isotope heat exchange for composition of the hydrogen and oxygen isotopes in the geothermal groundwater proceeds sufficiently with time. (3) The d value decreases from 5.72 to 3.03 when the depth increases from 125.13 to 3221 m. Generally, in the same area, the d value decreases with depth because the temperature is increasing. (4) The d value of the groundwater gradually reduces from the northern recharge area to the southern discharge area. The average d value is 7.31 in the northern recharge area and 5.68 in the middle Beijing Depression, whereas the d value in the southern area of Fengheying is ?9.20. The larger difference in d values between the recharge and discharge areas is due to the slower velocity of underwater flow, which induces longer time for oxygen exchange. (5) The relationship between the d and Eh is complex. When Eh is <200 mV, the d value of the geothermal water decreases with the decrease in Eh. When Eh is higher than 200 mV, the d value increases slightly with the decrease in Eh. The study of the characteristics of deuterium excess parameters for geothermal water could provide a scientific isotopic evidence for assessment and exploitation measures in geothermal groundwater systems.  相似文献   

4.
Located in the southeast of Tunisia, on the Mediterranean Sea, Jerba Island has a semiarid climate condition. The surface water scarcity has made groundwater the main source to supply the domestic, touristic, and agricultural water demand. Unconfined aquifer is a vulnerable costal aquifer system that undergoes several phenomena. This work aims at assessing the geochemical and bacteriological groundwater quality, defining groundwater pollution sources and promoting sustainable development and effective management of groundwater resources in Jerba Island. Data were collected after the wet season in 2014 from 79 wells. Electric conductivity, pH, TDS, and major and fecal tracers (total coliforms, thermotolerant coliforms, Escherichia coli, and Salmonella) were analyzed. Geochemical modeling including the relationships between geochemical tracers Na+ vs. Cl?, Ca2+ vs. Cl?, K+ vs. Cl?, representative ionic ratios (Br?/Cl?, Na+/Cl?, Mg2+/Ca2+), and statistical analysis were used to specify major process contributing to groundwater pollution and main factors controlling groundwater mineralization in the island. Groundwater varieties were hydrochemically classified into three types in terms of salinity values: group 1 (8.86%) to fresh water, group 2 (27.84%) to brackish water, and group 3 (63.29%) belongs to saline water. In addition, groundwater quality revealed high concentrations in chemical pollution tracers (Na+, Cl?, SO4 2?, and NO3 ?) and fecal tracers. Besides, most of the sampled wells were contaminated with nitrate (50.63%). Also, thermotolerant coliforms and E. coli were detected in all groundwater samples (96.2% of wells). Results indicated that the Jerba shallow aquifer was under serious threat from both natural and anthropogenic contamination. However, the wild discharge of domestic effluents, septic tanks, and sewage were the main origins of underground water contamination in Jerba Island. The reduction of fecal sources, through constructing normalized latrines is thus recommended.  相似文献   

5.
The recent development of the coalbed methane (CBM) industry has a significant role in advancing hydraulic fracturing theory and technology. However, further development requires a better understanding of how fractures influence reservoir permeability. In situ stress data from 54 CBM wells in the southern Qinshui Basin, China, were obtained by the injection/falloff test method to analyse the effect of in situ stress on the permeability of the CBM reservoir. The types of in situ stress states were classified, and the coal reservoir permeability under different in situ stress states was analysed. The results indicate that the maximum horizontal principal stress (σH), minimum horizontal principal stress (σh) and vertical principal stress (σv) all have positive linear relationships with the coal seam burial depth. Three in situ stress states were observed from the shallow to deep regions of the CBM reservoir in the study area: σH?>?σh?>?σv, σH?>?σv?>?σh and σv?>?σH?>?σh, which account for 9, 76 and 15% of the test wells, respectively. Coal reservoir permeability decreases with increasing horizontal principal stress, whereas it first decreases with increasing σv, then increases and finally decreases. The variation in permeability with σv is due to the conversion of the in situ stress states. Coal reservoir permeability has obvious differences under different in situ stress states. The permeability is the largest when σv?>?σH?>?σh, followed by σH?>?σh?>?σv and smallest when σH?>?σv?>?σh. The permeability differences are caused by the fracture propagation shape of the rock strata under different in situ stress states.  相似文献   

6.
Groundwater levels in hard-rock areas in India have shown very large declines in the recent past. The situation is becoming more critical due to a paucity of rainfall, limited surface water resources and an increasing pattern of groundwater extraction in these areas. Consequently, the Ground Water Department with the aid of World Bank has implemented the water structuring programme to mitigate groundwater scarcity and to develop a viable solution for sustainable development in the region. The present study has been undertaken to assess the impact of artificial groundwater recharge structures in the hard-rock area of Rajasthan, India. In this study groundwater level data (pre-monsoon and post-monsoon) of 85 dug-wells are used, spread over an area of 413.59 km2. The weathered and fractured gneissic basement rocks act as major aquifer in the area. Spatial maps for pre- and post-monsoon groundwater levels were prepared using the kriging interpolation technique with best fitted semi-variogram models (Spherical, Exponential and Gaussian). The groundwater recharge is calculated spatially using the water level fluctuation method. The entire study period (2004–2011) is divided into pre- (2004–2008) and post-intervention (2009–2011) periods. Based on the identical nature of total monsoon rainfall, two combinations of average (2007 and 2009) and more than average (2006 and 2010) rainfall years are selected from the pre- and post-intervention periods for further comparisons. All of the water harvesting structures are grouped into the following categories: as anicuts (masonry overflow structure); percolation tanks; subsurface barriers; and renovation of earthen ponds/nadis. A buffer of 100 m around the intervention site is taken for assessing the influence of these structures on groundwater recharge. The relationship between the monsoon rainfall and groundwater recharge is fitted by power and exponential functions for the periods of 2004–2008 and 2008–2011 with R 2 values of 0.95 and 0.98, respectively. The average groundwater recharge is found to be 18% of total monsoon rainfall prior to intervention and it became 28% during the post-intervention period. About 70.9% (293.43 km2) of the area during average rainfall and more than 95% (396.26 km2) of the area during above-average rainfalls show an increase in groundwater recharge after construction of water harvesting structures. The groundwater recharge pattern indicates a positive impact within the vicinity of intervention sites during both average and above-average rainfall. The anicuts are found to be the most effective recharge structures during periods of above-average rainfall, while subsurface barriers are responded well during average rainfall periods. In the hard-rock terrain, water harvesting structures produce significant increases in groundwater recharge. The geo-spatial techniques that are used are effective for evaluating the response of different artificial groundwater recharge techniques.  相似文献   

7.
Evaporation and recharge are important hydrological processes in the water cycle. However, accurately quantifying these two processes of river remains to be difficult due to their spatial heterogeneity and the limitations of traditional methods. In this study, a more reliable method of stable isotopes of δ 18O and δ 2H based on the Rayleigh distillation equation and mass conservation was used to estimate the evaporation and recharge of the rivers in the lower reaches of the Yellow River, North China Plain. Comprehensive sampling campaigns including 30 surface water samples from 10 rivers, 33 groundwater samples from domestic and observation wells, and two Yellow River water samples were conducted. The results showed that the evaporation proportion of the rivers based on δ 18O and δ 2H both averaged 14.4%. The evaporation proportions in each river did not completely follow a linear increasing trend along the flow path. This phenomenon could be mainly explained by the different proportions of recharge from groundwater and Yellow River water. With closer to the Yellow river, evaporation of the rivers decreased while the recharge by the Yellow River increased. Regression equations based on δ 18O, δ 2H, and their average revealed that the evaporation proportion respectively increased by 1.02, 0.79, and 0.90% with the increase in the distance to the Yellow River per 10 km. On the contrary, the recharge proportion decreased by 7.68, 5.51, and 6.59%, respectively. In addition, using δ 18O rather than δ 2H was more reliable in studying the spatial influence of the Yellow River on evaporation and recharge. Sensitivity analysis showed that the evaporation model was most sensitive to isotopic composition, rather than to air temperature or relative humidity. The results of this study provide insights into the determination of river hydrological processes and the management of water resources.  相似文献   

8.
The present study attempts to model the spatial variability of three groundwater qualitative parameters in Guilan Province, northern Iran, using artificial neural networks (ANNs) and support vector machines (SVMs). Data collected from 140 observation wells for the years 2002–2014 were used. Five variables, X and Y coordinates of the observation well, distance of the observation well from the shoreline, areal average 6-month rainfall depth, and groundwater level at the day of water quality sampling, were considered as primary input variables. In addition, nine qualitative variables were also considered as auxiliary input variables. Electrical conductivity (EC), sodium concentration (Na+), and sulfate concentration (SO4 2?) of the groundwater in the region were estimated using ANNs and SVMs with different input combinations. The results showed that both ANNs and SVMs work well when the only primary input variable is the well location. The ANN yielded an RMSE of 1.03 mEq/l for SO4 2?, 1.05 mEq/l for Na+, and 203.17 μS/cm for EC, using the X and Y coordinates of the observation wells in the study area. In the case of SVM, these values were, respectively, 0.87, 0.87, and 176.68. Considering the auxiliary input variables (pH, EC, and the concentrations of Na+, K+, Ca2+, Mg2+, Cl?, SO4 2?, and HCO3 ?) resulted in a significant decrease in the RMSE of both ANNs (0.22, 0.30, and 33.04) and SVMs (0.26, 0.34, and 36.23). Comparing these RMSE values with those of cokriging interpolation technique (0.59, 0.98, and 177.59) indicated that ANNs and SVMs produced more accurate estimates of the three qualitative parameters. The relative importance of auxiliary input variables was also determined using Gamma test. The output uncertainty of ANNs and SVMs were determined using p-factor and d-factor. The results showed that SVMs have less uncertainty than ANNs.  相似文献   

9.
We analyze three-phase flow of immiscible fluids taking place within an elementary capillary tube with circular cross-section under water- and oil-wet conditions. We account explicitly for momentum transfer between the moving phases, which leads to the phenomenon of viscous coupling, by imposing continuity of velocity and shear stress at fluid-fluid interfaces. The macroscopic flow model which describes the system at the Darcy scale includes three-phase effective relative permeabilities, K i j,r , accounting for the flux of the ith phase due to the presence of the jth phase. These effective parameters strongly depend on phase saturations, fluid viscosities, and wettability of the solid matrix. In the considered flow setting, K i j,r reduce to a set of nine scalar quantities, K i j,r . Our results show that K i j,r of the wetting phase is a function only of the fluid phase own saturation. Otherwise, K i j,r of the non-wetting phase depends on the saturation of all fluids in the system and on oil and water viscosities. Viscous coupling effects (encapsulated in K i j,r with i ≠ j) can be significantly relevant in both water- and oil-wet systems. Wettability conditions influence oil flow at a rate that increases linearly with viscosity ratio between oil and water phases.  相似文献   

10.
The space distribution of quasars from the 2dF and SDSS DR5 catalogs in the redshift interval 0.3 < z < 1.9 is analyzed. The distributions of quasars in both catalogs are found to have the following common features: (1) when the distance between the nearest objects exceeds 35h ?1 Mpc (where h = H 0/100 km/s Mpc is the dimensionless Hubble constant), the distribution of quasars virtually coincides with a uniform three-dimensional distribution; (2) on scale lengths of (5–35)h ?1 Mpc, the fractal dimension of the quasar distribution is 2.3; (3) the amplitude of quasar clustering and the average distance between neighboring quasars increase slowly with z (at a significance level of about 1.5σ). Twenty large groups of quasars with sizes of (50–150)h ?1 Mpc can be identified in the 2dF catalog at the 4σ significance level. These groups are incipient superclusters (two earlier known groups are confirmed). The space density of these groups is of the order of 7h 3 Gpc?3.  相似文献   

11.
This paper presents revision of the Neogene chronostratigraphic framework of the Huanghekou area in the Bohai Bay Basin, northern China, on the basis of integration of palaeomagnetic data and Neogene seismic stratigraphy. The modern Lake Dongting was selected for analyses of bottom sediments, water depth and elemental composition. Four elements, namely Al, V, Ni and Ga with R 2 value larger than 0.7, were chosen to establish a quantitative relationship (F P) between elemental composition and water depth of bottom sediments. A water depth of ~2.4 m was identified as an accumulation depth of Candoniella albicans, which is used to derive environmental variable (Φ) of formula F P. Candoniella albicans is also found within the Neogene well W10 in the Huanghekou area. Considering 2.4 m as D value in formula F p and measured element values at different depths of W10, Φ values were obtained at different depths. The quantitative palaeowater depths of each drilling well were estimated for the first time in this area by considering elemental composition of chip samples of four drilling wells in the Huanghekou area, which are directly iterated to the F F. Palaeowater depth reconstruction of the Neogene in the Huanghekou area indicates an initial deepening trend and a later shallowing trend during the evolution, with average and deepest bathymetry at ~2.3 and ~4.8 m, respectively. Frequent fluctuations of palaeowater depth control the sand dispersal pattern in a shallow delta during the lower part of the Lower Member of Minghuazhen Formation.  相似文献   

12.
Naegleria fowleri is a thermophilic free-living amoeba found worldwide in soils and warm freshwater. It is the causative agent of primary amebic meningoencephalitis, a nearly always fatal disease afflicting mainly children and young adults. Humans are exposed to the organism via swimming, bathing, or other recreational activity during which water is forcefully inhaled into the upper nasal passages. Although many studies have looked at the occurrence of N. fowleri in surface waters, limited information is available regarding its occurrence in groundwater and geothermally heated natural waters such as hot springs. This paper reviews the current literature related to the occurrence of N. fowleri in these waters and the methods employed for its detection. Case reports of potential groundwater exposures are also included. Despite increased interest in N. fowleri in recent years due to well-publicized cases linked to drinking water, many questions still remain unanswered. For instance, why the organism persists in some water sources and not in others is not well understood. The role of biofilms in groundwater wells and plumbing in individual buildings, and the potential for warming due to climate change to expand the occurrence of the organism into new regions, are still unclear. Additional research is needed to address these questions in order to better understand the ecology of N. fowleri and the conditions that result in greater risks to bathers.  相似文献   

13.
The study was done to assess the effect of the river Sutlej on arsenic (As) contamination. Sampling was done from the alluvial plain with increasing distance from the river Sutlej in district Vehari and compared with the study done in the proximity of River Sutlej. Sixty (60) groundwater samples mostly from shallow depths were collected and analyzed for As concentrations. Multivariate statistical tools (PCA and CA), saturation index, piper plots and Gibbs diagrams were used to detect evidence about the interrelationship and sources of As and other water quality variables responsible for groundwater contamination. Results revealed that As concentration ranged from below detection limit to 156 µg/L indicating that 50% samples exceeding the WHO guidelines (10 µg/L) and 17% exceeding the Pakistan National Environmental Quality Standards (NEQS) limits (50 µg/L) Sutlej. The piper plot revealed that water chemistry of the study area was Ca–HCO3?, Ca–Mg–Cl, type. Correlations between As and HCO3? (r2?=?0.433) was positive, while negative correlations were observed between As–Mn2+ and As–Fe2+ (r2?=???0.102), (r2?=?0.107) respectively. Geochemical signatures of the groundwater in the study area showed that the As could be released by oxidative dissolution to some extent and elevated evaporation in the arid environment of the study area under the stimulus of alkaline water and high pH (range 7.1–8.4). Although the concentrations are exceeding the WHO limit in 50% of the water samples but, are less than the previous study done in Mailsi near River Sutlej. Further, the concentrations decreased as the distance from the River increased which shows the probable role of sediments deposited by the River Sutlej.  相似文献   

14.
A detailed survey showed that groundwater fluoride was 6.1ppm in the Talupula area of the Anantapur district in southern India which is higher than is normally observed in groundwater elsewhere in India but not so extreme as that reported in Andhra Pradesh (up to 21 mg L-1). Groundwater is used for irrigating agricultural crops as well as for drinking which may expose its population to higher concentrations of fluoride through their diet. A preliminary study examined the concentrations of fluoride in five agricultural crops in the Talupula area and the soil beneath agricultural crops. The stem and leaves of Heliathusannuas, Arachishypogaea, Morusalba, Lychopersiconesculantum, and Phaseolus vulgaris were examined for fluoride and heavy metal accumulation. Heavy metal (Zn, Cu and Pb) accumulation in the stem and leaves were examined to determine if there was any correlation between their uptake and that of fluoride. In the soil beneath the crops, fluoride concentrations ranged from 6.53±0.44 to 8.23±1.22 ppm and a significant accumulation of fluoride was observed in the stems (13.2±2.0 to 23.9±3.6 ppm; p < 0.001) and leaves (16.4±1.9 to 61.5±4.5 ppm) of the agricultural plants. A significant accumulation of fluoride was observed from the stem to the leaves for all plants (p < 0.03) except Helianthus annuas. Copper also displayed significant accumulation from the soil to the stems in some of the plants tested but there was no significant accumulation of zinc or lead. A significant translocation from the stem and accumulation in the leaves was not observed for Cu or Pb but there was significantly higher zinc in the leaves of Arachishypogaea and Morusalba when compared to their stems. This study demonstrated that agricultural plants grown under field conditions and irrigated with groundwater high in fluoride will accumulate fluoride, but that fluoride is unlikely to have a significant effect on Cu, Zn or Pb accumulation in the stems and leaves of agricultural plants of the area. While drinking water is still the major cause of fluorosis in southern India, consumption of foods with high fluoride concentrations may also increase the risk of fluorosis.  相似文献   

15.
Unlike the studies in small parcels by systematic measurements, the spatial variability of soil properties is expected to increase in those over relatively large areas or scales. Spatial variability of soil hydraulic conductivity (K h) is of significance for the environmental processes, such as soil erosion, plant growth, transport of the plant nutrients in a soil profile and ground water levels. However, its variability is not much and sufficiently known at basin scale. A study of testing the performance of cokriging of K h compared with that of kriging was conducted in the catchment area of Sarayköy II Irrigation Dam in Cank?r?, Turkey. A total of 300 soil surface samples (0–10 cm) were collected from the catchment with irregular intervals. Of the selected soil properties, because the water-stable aggregates (WSA) indicated the highest relationship with the hydraulic conductivity by the Pearson correlation analysis, it is used as an auxiliary variable to predict K h by the cokriging procedure. In addition, the sampling density was reduced randomly to n = 175, n = 150, n = 75 and n = 50 for K h to determine if the superiority of cokriging over kriging would exist. Statistically, the results showed that all reduced K h was as good as the complete K h when its auxiliary relations with WSA were used in cokriging. Particularly, the results of the “Relative Reduction in MSE” (RMSE) revealed that the reduced data set of n = 75 produced the most accurate map than the others. In this basin-scaled study, there was a clear superiority of the cokriging procedure by the reduction in data although a very undulating topography and topographically different aspects, two different land uses with non-uniform vegetation density, different parent materials and soil textures were present in the area. Hence, using the statistically significant auxiliary relationship between K h and WSA might bring about a very useful data set for watershed hydrological researches.  相似文献   

16.
In this paper, analytical methods, artificial neural network (ANN) and multivariate adaptive regression splines (MARS) techniques were utilised to estimate the discharge capacity of compound open channels (COC). To this end, related datasets were collected from literature. The results showed that the divided channel method with a coefficient of determination (R 2) value of 0.76 and root mean square error (RMSE) value of 0.162 has the best performance, among the various analytical methods tested. The performance of applied soft computing models with R 2=0.97 and RMSE = 0.03 was found to be more accurate than analytical approaches. Comparison of MARS with the ANN model, in terms of developed discrepancy ratio (DDR) index, showed that the accuracy of MARS model was better than that of MLP model. Reviewing the structure of the derived MARS model showed that the longitudinal slope of the channel (S), relative flow depth (H r ) and relative area (A r ) have a high impact on modelling and forecasting the discharge capacity of COCs.  相似文献   

17.
To investigate the groundwater levels changes effects on the transpiration of Salix psammophila (S. psammophila) bush, systemic measurements of meteorological conditions, sap flow of S. psammophila, soil water contents and groundwater levels were conducted in the Hailiutu River catchment, NW of China. Based on the collected field data, Hydrus-1D software package was used to calibrate water movement for root uptake in the saturated–unsaturated zone. The soil hydraulic parameters and root uptake function parameters were calibrated. The simulated results of soil water contents and sap flow fitted well with the observed ones. Based on the calibrated hydraulic parameters, different groundwater levels were imposed at the low boundary to simulate the groundwater levels changes effects on the transpiration. The relationship between ratio of actual transpiration and potential (T/T p) and groundwater water table depth was established. The results shows that the ratio of actual transpiration and potential transpiration decreases with groundwater table depth increase as inverse ‘S’ shape. And the turn point is corresponding to the extinct depth, i.e., no groundwater contribution to S. psammophila transpiration. To further verify this phenomenon is universal, the soil hydraulic parameters were replaced with the other five groups in the calibrated forward model. The results confirmed the similar changes of T a/T p with the groundwater levels changed, i.e. inverse ‘S’ shape. However, the extinction depth is different corresponding to different soil hydraulic parameters. So, the research results indicated the relationship between transpiration and groundwater levels is non-linear function.  相似文献   

18.
The present study investigated the prevalence of pathogenic organisms (Salmonella spp, Vibrio cholerae, and Shigella spp) and their correlation to the abundance of faecal indicator organisms in water and riverbed sediments in the Apies River, South Africa. In all, 558 water and sediment samples were collected from 10 sites in the river (May 2013–February 2014) and analysed through culture and molecular (real-time PCR) techniques. Concentrations of faecal indicator organisms in sediments reached 1.39 × 105 (±standard deviation) CFU/100 mL. All three pathogens were detected in water and sediments. Pathogens were mostly detected in sediments at sites influenced either by wastewater treatment works or by informal settlements. During the wet and dry seasons (water column), a strong positive correlation was observed between E. coli and all pathogens; C. perfringens only correlated with V. cholerae. Within sediments, strong positive correlations were only observed between E. coli and Salmonella spp, E. coli and V. cholerae (dry season); E. coli and V. cholerae and E. coli and Shigella spp (wet season). No correlation was observed between sediments C. perfringens counts and all the pathogens. Thus, sediments of the Apies River harbour pathogenic organisms. Correlation between E. coli and pathogenic organisms in the sediments suggests that E. coli could also be an indicator of pathogens’ presence. However, the lack of a correlation between E. coli and some pathogens in sediments and between C. perfringens and all the pathogens highlights the need to investigate for more indicators of pathogens’ presence in this complex matrix.  相似文献   

19.
There is a need for research that advances understanding of flow alterations in contemporary watersheds where natural and anthropogenic interactions can confound mitigation efforts. Event-based flow frequency, timing, magnitude, and rate of change were quantified at five-site nested gauging sites in a representative mixed-land-use watershed of the central USA. Statistically independent storms were paired by site (n = 111 × 5 sites) to test for significant differences in event-based rainfall and flow response variables (n = 17) between gauging sites. Increased frequency of small peak flow events (i.e., 64 more events less than 4.0 m3 s?1) was observed at the rural–urban interface of the watershed. Differences in flow response were apparent during drier periods when small rainfall events resulted in increased flow response at urban sites in the lower reaches. Relationships between rainfall and peak flow were stronger with decreased pasture/crop land use and increased urban land use by approximately 20%. Event-based total rainfall explained 40–68% of the variance in peak flow (p < 0.001). Coefficients of determination (r2) were negatively correlated with pasture/crop land use (r2 = 0.92; p = 0.007; n = 5) and positively correlated with urban land use (r2 = 0.90; p = 0.008; n = 5). Significant differences in flow metrics were observed between rural and urban sites (p < 0.05; n = 111) that were not explained by differences in rainfall variables and drainage area. An urban influence on flow timing was observed using median time lag to peak centroid and time of maximum precipitation to peak flow. Results highlight the need to establish manageable flow targets in rapidly urbanizing mixed-land-use watersheds.  相似文献   

20.
Copper Adsorption by Chernozem Soils and Parent Rocks in Southern Russia   总被引：1，自引：0，他引：1  
Laboratory data in Cu2+ adsorption by chernozems and parent rocks in Rostov region show that adsorption isotherms can be approximated by the Langmuir equation, whose parameters (Kl and C∞) were calculated for all of the samples. The values of C∞ show a strong negative correlation with the values of cationexchange capacity (CEC) (r =–0.88 at Р = 0.95), and Kl is correlated with the content of physical clay (particles <0.01 mm) (r = 0.78) and with clay (particles <0.001 mm) content in ordinary chernozem and southern chernozems of various particle size distribution (r = 0.80). Even stronger correlations were detected between these parameters in southern chernozems (r = 0.89 for the physical clay (PC) and r = 0.91 for the silt). However, none of the samples displays a significant correlation of C∞ and Kl with the contents of physical clay and silt. This led us to conclude that the composition of the samples, for example, their organic matter, can affect Cu2+ adsorption by the soils and parent rocks. Acidification mechanisms of the equilibrium solutions during the Cu2+ adsorption by soils are discussed, as also are the reasons for the absence of balance between Cu2+ adsorbed by soils and exchangeable cations transferred into solution. Analysis of the fine structures of the XANES and EXAFS spectra suggests that Cu2+ can form coordinated chelate complex compounds with humic acids (HA) of soils and can substitute Al3+ at octahedral sites when interacting with clay minerals in soils.  相似文献   

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