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1.
Horizontal diffusion in the surface layer is dependent on the standard deviation of wind direction fluctuations . Diurnal variation of this parameter in complex terrain was studied for the July 1979 Geysers, Cal., experiment using data from a network of 11 short meteorological towers in the 25 km2 Anderson Creek watershed Valley side slopes are roughly 20 ° and maximum terrain difference is about 1 km.Values of for wind directions sampled for one hour at a height of 10 m are about 35 ° during the daytime. They slowly decrease to about 20 ° by 8 to 10 p.m. as stability increases but wind speeds are still relatively high. After 10 p.m. the drainage flow sets in at most stations, with speeds of 1 to 2 m s-1, and average increases to about 30° during the period 11 p.m. to 6 a.m. In general, highest values of at night are associated with lowest values of wind speed and greatest static stability. This enhancement of by the terrain suggests that horizontal diffusion at night always conforms to that expected during nearly neutral stabilities. That is, Pasquill class D diffusion applies to the horizontal component all night in complex terrain.  相似文献   

2.
Many applied dispersion models require the knowledge of boundary-layer parameters such as sensible heat flux,Q H , friction velocity,u *, and turbulent energy components, w and v . Formulas are suggested for calculating these parameters over a wide variety of types of ground surfaces, based on simple observations of wind speed near the ground and fractional cloud cover, and specification of constants such as roughness length, albedo, and soil moisture availability. Observations ofu *,Q H , w , and v during field experiments in St. Louis and Indianapolis are used to test the formulas for urban sites. Relative errors of about ±20% in the predictions are seen to occur whenu *,Q H , w , and v are large. However, when these quantities are small (e.g.,u * < 0.2 m/s), the errors in the predictions are as large as the mean value of the quantity itself.In addition, it is concluded from studies of available field data and theories that the magnitude of w is not well-known at elevations above about 100m during the late afternoon and night. Some simple parameterizations for w . are suggested that are consistent with the observed steady decrease in ground-level concentration in the afternoon and the sudden increase in concentration that can occur a few hours after sunset due to wind shears associated with a low-level jet, for continuous plumes emitted from moderate to tall stacks.  相似文献   

3.
The applicability of the tungsten oxide denuder tube technique for the measurement of nitric acid in the rural troposphere was investigated. The technique is based on selective chemisorption of HNO3 from the gas stream, thermal desorption, conversion to NO, and analysis by NO–O3 chemiluminescence. Ammonia, which is also collected and desorbed as NH3 and NO, was separated from the HNO3-derived NO by linear temperature-programed thermal desorption. Possible interferences by NO2, HCN, PAN, and n-propyl nitrate (NPN) were tested and found to be significant under conditions found in the lower troposphere. Simultaneous ambient measurements of HNO3 were made with the tungsten oxide denuder tube and nylon filter methods at a rural site in the Colorado mountains (Niwot Ridge, CO). Nitric acid levels measured by the tungsten oxide denuder tube averaged a factor of 3 higher than levels measured by the nylon filter technique. Tests involving the placement of nylon materials in front of the tungsten oxide denuder tube show that there are species, as yet unidentified, present in the atmosphere that interfere with the measurement of HNO3 by the tungsten oxide technique.  相似文献   

4.
The standard deviation of vertical two-point longitudinal velocity fluctuation differences is analyzed experimentally with eleven sets of turbulence measurements obtained at the NASA 150-m ground-winds tower site at Cape Kennedy, Florida. It is concluded that /u *0 is proportional to (fz/u *0)0.22, where the coefficient of proportionality is a function of fz/u *0 and u *0/fL 0. The quantities f and L0 denote the Coriolis parameter and the surface Monin-Obukhov stability length, respectively; u *0 is the surface friction velocity; z is the vertical distance between the two points over which the velocity difference is calculated; and zz is the mean height of the mid-point of the interval z above natural grade. The results of the analysis are valid for 20<-u *0/fL 0<2000.  相似文献   

5.
A one-month experiment was performed at Amsterdam Island in January 1998, to investigate the factors controlling the short-term variations of atmospheric dimethylsulfide (DMS) and its oxidation products in the mid-latitudes remote marine atmosphere. High mixing ratios of DMS, sulfur dioxide (SO2) and dimethylsulfoxide (DMSO) have been observed during this experiment, with mean concentrations of 395 parts per trillion by volume (pptv) (standard deviation, = 285, n = 500), 114 pptv ( = 125, n = 12) and 3 pptv ( = 1.2, n = 167), respectively. Wind speed and direction were identified as the major factors controlling atmospheric DMS levels. Changes in air temperature/air masses origin were found to strongly influence the dimethylsulfoxide (DMSO)/DMS and SO2/DMS molar ratios, in line with recent laboratory data. Methanesulfonic acid (MSA) and non-sea-salt sulfate (nss-SO4 2–) mean concentrations in aerosols during this experiment were 12.2± 6.5 pptv (1, n=47) and 59 ± 33 pptv (1, n=47), respectively. Evidence of vertical entrainment was reported following frontal passages, with injection of moisture-poor, ozone-rich air. High MSA/ nss-SO4 2– molar ratios (mean 0.44) were calculated during these events. Finally following frontal passages, few spots in condensation nuclei (CN) concentration were also observed.  相似文献   

6.
Refuge has patchy vegetation in sandy soil. During midday and at night, the surface sources and sinks for heat and moisture may thus be different. Although the Sevilleta is broad and level, its metre-scale heterogeneity could therefore violate an assumption on which Monin-Obukhov similarity theory (MOST) relies. To test the applicability of MOST in such a setting, we measured the standard deviations of vertical (w) and longitudinal velocity (u), temperature (t), and humidity (q), the temperature-humidity covariance (¯tq), and the temperature skewness (St). Dividing the former five quantities by the appropriate flux scales (u*, *, and q*) yielded the nondimensional statistics w/u*, u/u*, t/|t*|, q/|q*|, and ¯tq/t*q*. w/u*, t/|t*|, and St have magnitudes and variations with stability similar to those reported in the literature and, thus, seem to obey MOST. Though u/u* is often presumed not to obey MOST, our u/u* data also agree with MOST scaling arguments. While q/|q*| has the same dependence on stability as t/|t*|, its magnitude is 28% larger. When we ignore ¯tq/t*q* values measured during sunrise and sunset transitions – when MOST is not expected to apply – this statistic has essentially the same magnitude and stability dependence as (t/t*)2. In a flow that truly obeys MOST, (t/t*)2, (q/q*)2, and ¯tq/t*q* should all have the same functional form. That (q/q*)2 differs from the other two suggests that the Sevilleta has an interesting surface not compatible with MOST. The sources of humidity reflect the patchiness while, despite the patchiness, the sources of heat seem uniformly distributed.  相似文献   

7.
To investigate tubulence characteristics and organized motion within and above an urban canopy, field observations were conducted in July 1991 and November 1992 in Sapporo, Japan. The measurement heights were 5.4, 10.3, 18, 35 and 45 m above ground; the canopy height was 7 m. The profiles of u peaked slightly above the canopy, while v and w had nearly uniform profiles. Vertical profiles of Reynolds stress - peaked slightly at 1.5 times the canopy height and decreased slowly with height thereafter. A four-quadrant analysis showed that sweep and ejection motions caused high-velocity fluid from above moves downward toward the surface and low-velocity fluid from below moves upward. An ensemble-averaging technique was used to isolate typical features of the flow and temperature fields. A time-height cross-section of velocity vectors and temperature contours showed details of the flow structures associated with temperature ramps. It has been noted that the organized motions play important roles in the transport of heat near the urban canopy, where the sweep motion causes negative temperature fluctuations and the ejection motion causes positive temperature fluctuations.  相似文献   

8.
The design and performance of a smog chamber for the study of photochemical reactions under simulated environmental conditions is described. The chamber is thermostated for aerosol experiments, and it comprises a gas chromatographic sample enrichment system suitable for monitoring hydrocarbons at the ppbv level. By irradiating NO x /alkane-mixtures rate constants for the reaction of OH radicals with n-alkanes are determined from n-pentane to n-hexadecane to be (k±2)/10–12 cm3 s–1=4.29±0.16, 6.2±0.6, 7.52 (reference value), 8.8±0.3, 10.2±0.3, 11.7±0.4, 13.7±0.3, 15.1±0.5, 17.5±0.6, 19.3±0.7, 22.3±1.0, and 25.0±1.3, respectively at 312 K. Rate constants, (k±2)/10–17 cm3 s–1, for the reaction of ozone with trans-2-butene (21.2±1.0), cis-3-methylpentene-(2) (47.2±1.7), cyclopentene (62.4±3.5), cyclohexene (7.8±0.5), cycloheptene (28.3±1.5), -pinene (8.6±1.3), and -pinene (1.4±0.2) are determined in the dark at 297 K using cis-2-butene (13.0) as reference standard.  相似文献   

9.
E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c 2 /e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c 2 = 1.92, = 1.3, e = 1). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and e to 1.1 and 1.6, respectively, giving, with c 2 = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.  相似文献   

10.
Ammonia (NH3) is the most abundant alkaline gas in the atmosphere and plays a key role in atmospheric chemistry. Reliable and high-time-resolution data for gaseous ammonia are necessary to understand the sources and sinks of ammonia gas in ambient air. In the present study, a sensitive and continuous instrument for measuring gaseous ammonia was developed. Ammonia gas in ambient air was collected in an aqueous solution using a counter-current flow tube (CCFT) sampler. Then, ammonium formed in the aqueous solution was detected by the indophenol method. Based on a CCFT length of 50 cm and air flow rate of 1 L/min, the collection efficiency exceeded 98.5 % at an ammonia mixing ratio of up to 120 ppbv. The detection limit of this method was 0.062 ppbv. Interferences from several gases were investigated, and the results showed that the present method was not affected by NOx, O3, SO2, HONO, methylamine, formaldehyde, hydrogen sulfide or a mixture of these gases. The most important result was that only gaseous ammonia was detected in the present method without any interference from the particulate ammonium in ambient air. Comparisons with data based on the dry denuder method indicated that the present method showed good agreement with the denuder method.  相似文献   

11.
The refractive index of air (n) mainly depends on temperature andwater vapour content. For near-infrared radiation, temperature isthe main determining factor. To determinethe structure parameter of temperature ( ) fromthe structure parameter of the refractive index( ), the influence ofwater vapour content on n needs to be taken into account as acorrection. Three levels of approximation are presented. The firstinvolves the standard deviations of T and q (T andq) as well as the correlation coefficient betweenT and q (RTq). The second approximation involvesRTq and the Bowen ratio (), and the last uses only the Bowen ratio.The latter is the classical Bowen ratio correction.Evaluation of the validity of the assumptions used in the derivationreveals that a large error may be introduced (for situations withRTq < 0.8) by replacing T/qwith the Bowen ratio.Consequently, estimating from using the Bowen ratiocan contain errors of 5–40% for || < 1. Adding RTqas extra information reduces the errors only marginally. For || > 1,the correction is small, and all three approximations give errors of lessthan 1% in . When is used to compute the sensible heat flux,the influence of the quality of the correction forwater vapour fluctuations on the measured energy balance is small: forsmall ||, the correction is large, but the absolute value ofthe heat flux is small, whereas for large ||, the correctionis insignificant.  相似文献   

12.
An atmospheric monitoring station is operated at Cape Matatula, American Samoa, by the Geophysical Monitoring for Climatic Change program under the National Oceanic and Atmospheric Administration. A nearly continuous record of condensation nucleus (CN) concentration and multiwavelength aerosol scattering extinction coefficient (sp) is available from mid-1977 to the present. This report presents the 1977–1983 data. The long-term mean of CN concentration is 274 cm-3 the long-term mean of sp (550 nm) is 1.54×10-5, and no significant long-term, annual, or diurnal trend is apparent in either data record.  相似文献   

13.
Surface-layer features with different prevailing wind directions for two distinct seasons (Southwest Monsoon and Northeast Monsoon) on the west coast of India are studied using data obtained from tower-based sensors at a site located about 500 m from the coast. Only daytime runs have been used for the present analysis. The surface boundary-layer fluxes have been estimated using the eddy correlation method. The surface roughnessz 0 obtained using the stability-corrected wind profiles (Paulson, 1970) has been found to be low for the Southwest monsson season. For the other season,z 0 is relatively high. The drag coefficientC D varies with height in the NE monsoon season but not in the season with lowz 0. This aspect is reflected in the wind profiles for the two seasons and is discussed in detail. The scaling behaviour of friction velocityu * and the turbulence intensity of longitudinal, lateral and vertical winds u, v and w, respectively) are further examined to study their dependence on fetch. Our study shows that for the non-dimensional case, u/u* and v/u* do not show any surface roughness dependence in either season. On the other hand, for w/u* for the season with lowz 0, the values are seen to agree well with that of Panofskyet al. (1977) for homogeneous terrain whereas for the other season with highz 0, the results seem to conform more to the values observed by Smedman and Högström (1983) for coastal terrain. The results are discussed in the light of observations by other investigators.  相似文献   

14.
Quantitative infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere are reported. The results have been obtained from the analysis of absorption features of the 9 band at 12.2 m, which have been identified in high-resolution ballon-borne and aircraft solar absorption spectra. The ballon-borne spectral data were recorded at sunset with the 0.02 cm-1 resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The aircraft spectra were recorded at sunset in July 1978 with a 0.06 cm-1 resolution interferometer aboard a jet aircraft at 12 km altitude, near 35°N, 96°W. The balloon analysis indicates the C2H6 mixing ratio decreased from 3.5 ppbv near 8.8 km to 0.91 ppbv near 12.1 km. The results are consistent with the colum value obtained from the aircraft data.  相似文献   

15.
It is shown that for the purpose of trajectory simulation, the vertical velocityw L (t) of a fluid element, which is moving in a system (such as a forest canopy, or the unstably stratified atmospheric surface layer) whose turbulent velocity scale w is height-dependent, must be chosen from a frequency-distribution which is asymmetric aboutw L = 0. If the gradient w /z varies only slowly with height, correct trajectories may be obtained by adding a bias (where L is the length scale) to a fluctuating velocity chosen from a symmetric distribution with variance w 2(z).  相似文献   

16.
Summary The atmospheric aerosol scattering coefficient s , measured for more than a year more or less continuously in Vienna, Austria, exhibits unexpected patterns of variation. Apart from the usual ones following changes in relative humidity or traffic characteristics,a distinctive pattern is found before a change in air mass. s rises by a factor of 1.5 to 2 some hours (usually two or three) before the passage of the front without a corresponding change in emission characteristics or relative humidity and then falls either below or to its previous level. This behaviour of s occurred at all frontal passages during the sampling period at all times of day and of year except when the wind speeds were very high.An explanation is attempted by examining the mixing heights before a change in airmass since a reduced vertical dispersion due to pre-frontal changes of stability could account for the increase in s (and thus the aerosol concentration). It has been found that calculated mixing heights are reduced by nearly the same factor as the value of s is increased before the front. After the front the factors are similar, but then the aerosol concentration depends also on the origin of the air mass.
Zusammenfassung Der Streukoeffizient des atmosphärischen Aerosols ( s ) wurde in Wien mehr als ein Jahr lang mehr oder weniger kontinuierlich gemessen. Dabei zeigten sich unerwartete Änderungen. Abgesehen vom üblichen Tagesgang im Zusammenhang mit Verkehr und relativer Feuchte fand sich vor einem Luftmassenwechsel ein charakteristischer zeitlicher Verlauf. s steigt einige Stunden (meist zwei oder drei) vor dem Frontdurchgang an, ohne daß sich die relative Feuchte oder die Quellencharakteristik entsprechend ändert, und fällt dann entweder auf oder unter seinen ursprünglichen Wert. Dieses Verhalten trat bei allen Frontdurchgängen zu jeder Tages- und Jahreszeit auf. Die einzigen Ausnahmen waren Fronten mit sehr hohen Windgeschwindigkeiten.In dieser Arbeit wird versucht, das Verhalten des Streukoeffizienten (und damit der Aerosolkonzentration) durch eine Betrachtung der Mischungshöhen zu erklären, da eine Reduktion der vertikalen Ausbreitung durch Stabilitätsänderungen vor der Front den Anstieg von s bewirken könnte. Eine Berechnung der Mischungshöhen ergab, daß sie vor der Front um fast denselben Faktor abnahmen um den s anstieg. Nach der Front waren die Änderungsfaktoren einander ähnlich, obwohl die Aerosolkonzentration auch vom Ursprung der Luftmasse abhing.

With 5 Figures  相似文献   

17.
Ambient gas phase nitrous acid (HONO) has been measured by Tunable Diode Laser Absorption Spectroscopy with sub-ppbv detection limits. An R-branch line in the 1263.4 cm–1 3 band was found tobe free of interference and suitable for ambient HONO measurements. Nitrous acid was measured during the night and early morning at an urban site in Toronto, Canada, during the summer of 1998. Average mixing ratios, integrated over 30 minutes, ranged from below the minimum detection limit of 300 pptv to 1.9 ppbv, with the highest concentrations observed during the early morning hours. During the night of 19 June 1998, the concentration of HONO increased by as much as 0.5 ppbv/hr. The usual decrease in HONO after sunrise was delayed by a few hours, possibly due to a combination of an increase in the production rate of HONO with rush hour, and attenuation of the early morning light by high NO2 within the aerosol fog/haze.  相似文献   

18.
An experimental study has been carried out in the Mainz vertical wind tunnel to determine the rate at which NH3 in the presence of CO2 is absorbed by freely suspended water drops. The experimental uptake rates were found to be in good agreement with the rates predicted by the Kronig-Brink convective diffusion model and, for gas concentrations in the ppbv range also by the model in which it is assumed that the absorbed gas is well mixed inside the drop (henceforth called well mixed model). The same conclusion was shown to apply also to the desorption of NH3 from a drop previously exposed to NH3. The latter result is in contrast to the desorption of SO2 which must be described by a model which accounts for the diffusion of the species inside the drop. Comparison of our experimental results with theory show further that the uptake of NH3 in presence of CO2 is significantly overestimated if the slow reaction CO2(aq)+H2OHCO 3 – +H+ is neglected in the theoretical computation.  相似文献   

19.
Mesoscale measurements of the vertical dispersion coefficient 2 by using a composite turbulence water tank were validated through a comparison with CONDORS (Convective Diffusion Observed with Remote Sensors) field data, and were analysed with respect to the intensity of the thermal flux, mechanical turbulence, and plume release height.It seems possible to correct the plume z values for different release heights below 0.5zi (zi is the mixing height) by applying an equation expressing the height dependency of turbulence intensity. The downwind distance where the plume's mass centre height approaches its final level was also analysed with respect to the above three parameters, and an empirical equation to estimate the downwinddistance derived.  相似文献   

20.
TheConvectiveDiffusionObserved byRemoteSensors (CONDORS) field experiment conducted at the Boulder Atmospheric Observatory used innovative techniques to obtain three-dimensional mappings of plume concentration fields, /Q, of oil fog detected by lidar and chaff detected by Doppler radar. It included extensive meteorological measurements and, in 1983, tracer gases measured at a single sampling arc. Final results from ten hours of elevated and surface release data are summarized here. Many intercomparisons were made. Oil fog /Q measured 40m above the arc are mostly in good agreement withSF 6 values, except in a few instances with large spacial inhomogeneities over short distances. After a correction scheme was applied to compensate for the effect of its settling speed, chaff dy/Q agreed well with those of oil except in two cases of oil fog hot spots. Mass or frequency distribution vs. azimuth or elevation angle comparisons were made for chaff, oil, and wind, with mostly good agreements. Spacial standard deviations, y and z, of chaff and oil agree overall and are consistent at short range with velocity standard deviations vand w 0.6w* (the convective scale velocity), as measured atz>100m. Surface release y is enhanced up to 60% at smallx, consistent with the Prairie Grass measurements and with larger v and reduced wind speed measured near the surface. Decreased y at small dimensionless average times is also noted. Finally, convectively scaled dy, C y, were plotted versus dimensionlessx andz for oil, chaff, and corrected chaff for each 30–60 min period. Aggregated CONDORSC y fields compare well with laboratory tank and LES numerical simulations; surface-released oil fog compares expecially well with the tank experiments. However, large deviations from the norm occurred in individual averaging periods; these deviations correlated strongly with anomalies in measured distributions.On assignment to the US Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory, RTP, NC.  相似文献   

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