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1.
Tungsten mineralisation in the NE Hindu Kush terrain occurs 8 km NW of the Tirich Boundary Zone suture between Karakoram and Eastern Hindu Kush. Scheelite occurs mainly in calc-silicate rocks and subordinately in tourmalinites associated with metasediments at Miniki Gol, Chitral. The investigated area underwent two phases of deformation and was metamorphosed up to sillimanite grade, followed by the emplacement of leucogranite and hydrothermal activity. The mineral assemblages of the calc-silicate rocks, comprising clinozoisite, quartz, calcic-amphibole, plagioclase, chlorite, biotite, calcite, sphene, garnet and scheelite, clearly express a skarn type environment. The coexistence of the scheelite grains with clinozoisite and the occurrence of anomalous values of ZrO2 and Ta2O5 in the scheelite grains imply a genetic link between the scheelite mineralisation and post-magmatic hydrothermal fluids. The enrichment of Zr, Hf, Be, Sn, W, Th, U, Ga, Nb, F and Y along with total REE in the scheelite-bearing calc-silicate rocks compared with the associated metasediments assigns that the rocks at Miniki Gol have undergone a pronounced hydrothermal activity. Strong positive correlations between Zr, Hf, Nb, Y, Ta, F and REE, and the mobility of REE are consistent with this consideration. Aqueous fluid inclusions in the scheelite-bearing calc-silicate rocks display very low salinity, suggesting a mixing of magmatic fluids with meteoric water. The formation of intergrown scheelite and clinozoisite indicates a high pH and CO2-deficient fluid. The tungsten mineralization may be related to the Miniki Gol leucogranite which occurs at a distance of only 400 m.  相似文献   

2.
Abstract Mafic phyllosilicates in metabasites affected by low-grade regional metamorphism from Wales and eastern North Greenland show variations in their structure and chemistry. These variations are related to four mineral zones in these metabasites, which are recognized on the presence/absence of various key calc-silicate minerals and also actinolite. Zones 1 and 2 equate with the zeolite facies, zone 3 with the prehnite–pumpellyite facies (or prehnite–actinolite facies in rocks with appropriate bulk rock composition) and zone 4 with the greenschist facies. Whilst variations in Fe/(Fe + Mg) in chlorite correlate closely with Fe/(Fe + Mg) ratios in the whole-rock, other chemical variations are clearly unrelated to whole-rock compositions. Contents of Aliv are seen to increase systematically in samples from zone 1 through to zone 4, which relate to an increase in temperature. Calibration of alteration temperatures, calculated using the chlorite geothermometer (based on Aliv contents) developed for meta-andesites in the Los Azufres geothermal system (Mexico), against x values (an estimate of the proportion of chlorite to swelling component in the mafic phyllosilicates) shows a decrease in the swelling component in passing from zone 1 to zone 4, i.e. with an increase in temperature. Calculated temperatures compare favourably with published stability estimates for the various key calc-silicates and actinolite. These data indicate that the chlorite geothermometer, although developed for meta-andesites from a hydrothermal system, does show a correlation with temperatures estimated from calc-silicate assemblages in metabasites affected by low-grade metamorphism developed on a regional scale.  相似文献   

3.
Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ13Ccalcite values of –2 to –7% and δ18Ocalcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ18Owhole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ13Ccalcite of –1.6 to –0.6%, and δ18Ocalcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ18O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ18O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ13C vs. δ18O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.  相似文献   

4.
In the eastern Sierras Pampeanas, Central Argentina, tourmalinites and coticules are found in close association with stratabound scheelite deposits in metamorphic terranes. In Sierra Grande (Agua de Ramón and Ambul districts) and Sierra de Altautina, tourmalinites are associated with stratabound scheelite deposits related to orthoamphibolites. In the Pampa del Tamboreo area, tourmalinites are located in biotite schists stratigraphically related to acid to intermediate metavolcanic rocks and scheelite-bearing quartzites.The mineral chemistry and boron isotopic compositions of tourmalinite-hosted and vein-hosted tourmalines are investigated. Overall, the tourmalines belong to the dravite-schorl series and are generally aluminous; Fe/(Fe+Mg) ranges from 0.33 to 0.85, Al/(Al+Fe+Mg) from 0.66 to 0.76 and the amount of X-site vacancy (0.12–0.48) indicates significant foitite components. Their boron isotopic compositions (δ11B) are from −24.0‰ to−15.0‰.Similar mineral chemistries and boron isotopic values for tourmaline in tourmalinites related to stratabound scheelite mineralisation and in tungsten-bearing quartz veins suggest a common source for the boron and probably the tungsten. The field, chemical and isotopic relationships are consistent with tungsten and boron in quartz-vein deposits being remobilised from stratabound scheelite and tourmalinite, dominantly by liquid-state transfer associated with regional shear zones. Tungsten and boron in the original sedimentary sequence (now meta-exhalites) are ascribed to volcanogenic exhalations.  相似文献   

5.
U-Pb isotope analyses of zircon and titanite extracted from different rocks of the Felbertal scheelite deposit yield the following information: (1) An age of 593±22 Ma (2) is obtained for zircon crystallization in the scheelite-bearing matrix of an eruption breccia in the western ore field. (2) Discordant zircons from an elongated, up to 8 m thick scheelite-rich quartzite body in the eastern ore field give an upper intercept age of 544±5 Ma. This quartzite contains a laminated, fine-grained scheelite mineralization. (3) Zircons from a small granitoid intrusion of the western ore field reveal an age of 336±16 Ma, and concordant titanites document an age of 282±2 Ma for Variscan amphibolite facies metamorphism. Both events, granitoid intrusion and later metamorphism caused ore re-mobilization, including the formation of yellowish fluorescent (molybdo-) scheelite porphyroblasts. (4) For a narrow lamprop-1hyric dike in the western ore field, a concordant titanite age of 283±7 Ma is obtained. This age is identical with the titanites from the amphibolite facies metamorphic intrusion. Tiny scheelite grains were tapped by the dike from pre-existing scheelite mineralizations in the truncated host rocks. (5) Alpine metamorphism at 31±4 Ma did not exceed lowermost amphibolite facies conditions, and it caused scheelite re-mobilization on a minor scale only, producing bluish fluorescent porphyroblasts in quartz veinlets and veins, as well as bluish fluorescent scheelite rims around older scheelite grains. Moreover, crosscutting Alpine fissure fillings show bluish fluorescent, inclusion-free scheelite. (6) The preservation of Variscan titanites, the absence of Alpine titanite growth, and the large degree of Variscan scheelite re-mobilization demonstrate that amphibolite facies metamorphism in the Felbertal area has a Variscan age. This result clearly documents Variscan tectono-metamorphism to be the dominant event, instead of the hitherto surmised Alpine metamorphism. This multi-stage evolution of the Felbertal ore bodies corroborates the view that tungsten deposits are conditioned by several succeeding thermal events, leading to a series of stages that ultimately produce high-grade scheelite concentrations. These high-grade ores predominately occur along shear zones of different age, accompanied by the formation of large volumes of low-grade scheelite mineralizations along host rock foliations and quartz veinlets and veins.  相似文献   

6.
Primary multiphase brine fluid inclusions in omphacite and garnet from low‐ to medium‐temperature eclogites have been analysed for Cl, Br, I, F, Li and SO4. Halogen contents and ratios provide information about trapped lower crustal fluids, even though the major element (Na, K, Ca) contents of inclusion fluids have been modified by fluid–mineral interactions and (step‐) daughter‐crystal formation after trapping. Halogens in the inclusion fluids were analysed with crush–leach techniques. Cl/Br and Cl/I mass ratios of eclogite fluids are in the range 31–395 and 5000–33 000, respectively. Most fluids have a Cl/Br ratio lower than modern seawater and a Cl/I ratio one order of magnitude lower than modern seawater. Fluids with the lowest Cl/Br and highest Cl/I ratios come from an eclogite that formed by hydration of granulite facies rocks, and may indicate that Br and I are fractionated into hydrous minerals. Reconstructions indicate that the inclusion fluids originally contained 500–4000 ppm Br, 1–14 ppm I and 33–438 ppm Li. Electron microprobe analyses of eclogite facies amphibole, biotite, phengite and apatite indicate that F and Cl fractionate most strongly between phengite (F/Cl mass ratio of 1469 ± 1048) and fluid (F/Cl mass ratio of 0.008), and the least between amphibole and fluid. The chemical evolution of Cl and Br in pore fluids during hydration reactions is in many ways analogous to Cl and Br in seawater during evaporation: the Cl/Br ratio remains constant until the aH2O value is sufficiently lowered for Cl to be removed from solution by incorporation into hydrous minerals.  相似文献   

7.
The Navachab gold deposit in the Damara belt of central Namibia is hosted by a near-vertical sequence of amphibolite facies shelf-type metasediments, including marble, calc-silicate rock, and biotite schist. Petrologic and geochemical data were collected in the ore, alteration halos, and the wall rock to evaluate transport of elements and interaction between the wall rock and the mineralizing fluid. The semi-massive sulfide lenses and quartz–sulfide veins are characterized by a complex polymetallic ore assemblage, comprising pyrrhotite, chalcopyrite, sphalerite, and arsenopyrite, native bismuth, gold, bismuthinite, and bismuth tellurides. Mass balance calculations indicate the addition of up to several orders of magnitude of Au, Bi, As, Ag, and Cu. The mineralized zones also record up to eightfold higher Mn and Fe concentrations. The semi-massive sulfide lenses are situated in the banded calc-silicate rock. Petrologic and textural data indicate that they represent hydraulic breccias that contain up to 50 vol.% ore minerals, and that are dominated by a high-temperature (T) alteration assemblage of garnet–clinopyroxene–K-feldspar–quartz. The quartz–sulfide veins crosscut all lithological units. Their thickness and mineralogy is strongly controlled by the composition and rheological behavior of the wall rocks. In the biotite schist and calc-silicate rock, they are up to several decimeters thick and quartz-rich, whereas in the marble, the same veins are only a few millimeters thick and dominated by sulfides. The associated alteration halos comprise (1) an actinolite–quartz alteration in the biotite schist, (2) a garnet–clinopyroxene–K-feldspar–quartz alteration in the marble and calc-silicate rock, and (3) a garnet–biotite alteration that is recorded in all rock types except the marble. The hydrothermal overprint was associated with large-scale carbonate dissolution and a dramatic increase in CO2 in the ore fluid. Decarbonation of wall rocks, as well as a low REE content of the ore fluid resulted in the mobilization of the REE, and the decoupling of the LREE from the HREE. The alteration halos not only parallel the mineralized zones, but may also follow up single layers away from the mineralization. Alteration is far more pronounced facing upward, indicating that the rocks were steep when veining occurred. The petrologic and geochemical data indicate that the actinolite–quartz– and garnet–clinopyroxene–K-feldspar–quartz alterations formed in equilibrium with a fluid (super-) saturated in Si, and were mainly controlled by the composition of the wall rocks. In contrast, the garnet–biotite alteration formed by interaction with a fluid undersaturated in Si, and was mainly controlled by the fluid composition. This points to major differences in fluid–rock ratios and changes in fluid composition during alteration. The alteration systematics and geometry of the hydrothermal vein system are consistent with cyclic fluctuations in fluid pressure during fault valve action. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

8.
The highly deformed c. 3800 Ma Isua supracrustal belt is a fragment of a more extensive Early Archaean sedimentary and volcanic succession intruded by and tectonically intercalated with tonalitic and granitic Amftsoq gneisses in the period 3800-3600 Ma. The supracrustal rocks recrystallised under amphibolite facies conditions between 3800 and 3600 Ma, in the Late Archaean and locally at c. 1800 Ma. Layered sequences of rock of sedimentary and probable volcanic origin form over 50% of the belt. Bodies of high MgAl basic rocks and ultramafic rocks were intruded into the layered sequences prior to isoclinal folding and intrusion of Amitsoq gneisses. The layered rocks which are < 1 km thick are divided into two sequences, that are in faulted contact with each other. The way-up of these sequences has been determined from facing-directions of locally-preserved graded layering in felsic metasediments at several localities. The overall upwards change in sedimentary succession is interpreted as showing change from dominantly basic to dominantly felsic volcanism which provided the major clastic component of the sediments. Clastic sedimentation took place against a background of chemical sedimentation, shown by interlayers of banded iron formation, metachert and calc-silicate rocks throughout the sequences. The felsic rocks locally preserve graded bedding and possible conglomerate structures, indicating deposition from turbidite flows and possibly as debris flows. Nodules in the felsic rocks contain structures interpreted as fiammé. There is an irregular enrichment in K2O/Na2O in many of the felsic rocks at constant SiO2 and Al2O3 content, interpreted as owing to alteration of original andesitic to dacitic volcanic rocks. Banded iron formations locally contain conglomeratic structures suggesting sedimentary reworking, possibly under shallow water conditions. Lithological and geochemical characters of the clastic components of the supracrustal sequences are consistent with derivation from felsic and basic volcanic rocks and do not require a continental source.  相似文献   

9.
A new type of tungsten deposit was discovered in the Eastern Alps at the Mallnock, Nock mountains, Austria. The mineralization is restricted to concordant layers of carbonate rocks within phyllites belonging to the metamorphic Palaeozoic of the Upper Austroalpine Gurktal nappe system. Wolframite (ferberite 95) and scheelite occur as network fissure fillings in coarse-grained Fe-magnesite (siderite 15) rocks (average W content ca. 0.9 wt%); fine-grained dolomite marbles contain scheelite as the only tungsten mineral (average W content ca. 0.5 wt%). Assuming the dolomite marbles as a primary metal source, mobilization processes are responsible for the formation of the wolframite- and scheelite-bearing Fe-magnesite rocks.  相似文献   

10.
万山汞矿卤素元素地球化学特征及其地质意义   总被引：5，自引：1，他引：4  
本文对万山汞放卤素元素地球化学特征进行了较系统的研究。研究表明,Ｂｒ与１在矿区赋矿城、蚀变岩及矿石中都不同程度富集,从赋矿围岩→蚀变岩→矿石,含量明显升高,而Ｆ与Ｃｌ主要富集于蚀变岩石中,在隐伏矿体上部围岩中,Ｆ、Ｃｌ、Ｂｒ、１都有异常显示,这种卤素元素异常对寻找隐伏矿体具有指示意义。  相似文献   

11.
The Ansil Cu–Au volcanogenic massive sulfide deposit is located within an Archean-age cauldron infill sequence that contains the well-known Noranda base metal mining district. The deposit is unusual in that 17% of the massive pyrrhotite–chalcopyrite orebody is replaced by semi-massive to massive magnetite. Temporally associated with the magnetite formation are several calc-silicate mineral assemblages within the massive sulfide lens and the underlying sulfide stockwork vein system. Coarse-grained andradite–hedenbergite and ferroactinolite–ilvaite alteration facies formed in the immediate footwall to the massive magnetite–sulfide lens, whereas an epidote–albite–pyrite-rich mineral assemblage overprints the margins of the chlorite-rich stockwork zone. The epidote-rich facies is in turn overprinted by a retrograde chlorite–magnetite–calcite mineral assemblage, and the andradite–hedenbergite is overprinted first by ferroactinolite–ilvaite, followed by semi-massive to massive magnetite. The footwall sulfide- and magnetite-rich alteration facies are truncated by a late phase of the Flavrian synvolcanic tonalite–trondhjemite complex. Early phases of this intrusive complex are affected to varying degrees by calc-silicate-rich mineral assemblages that are commonly confined to miarolitic cavities, pipe vesicles and veins. The vein trends parallel the orientation of synvolcanic faults that controlled volcanism and hydrothermal fluid migration in the overlying cauldron succession. The magnetite-rich calc-silicate alteration facies are compositionally similar to those of volcanic-hosted Ca–Fe-rich skarn systems typical of oceanic arc terranes. Tonalite–trondhjemite phases of the Flavrian complex intruded to within 400 m of the base of the earlier-formed Ansil deposit. The low-Al trondhjemites generated relatively oxidized, acidic, Ca–Fe-rich magmatic–hydrothermal fluids either through interaction with convecting seawater, or by assimilation of previously altered rocks. These fluids migrated upsection along synvolcanic faults that controlled the formation of the original volcanogenic massive sulfide deposit. This is one of the few documented examples of intense metasomatism of a VMS orebody by magmatic–hydrothermal fluids exsolved from a relatively primitive composite sub-seafloor intrusion. Received: 15 April 1999 / Accepted: 20 January 2000  相似文献   

12.
Iodine, bromine, and chlorine concentrations were determined in different Antarctic meteorite specimens (eucrites, high-iron and low-iron chondrites) with isotope dilution mass spectrometry. In all Antarctic meteorites I-overabundances have been analysed compared with the concentrations for non-Antarctic meteorites of the same class. Half of the Antarctic specimens show especially high concentrations of more than 1 μ/g. A similarly high enrichment effect in Antarctic meteorites was not found for Br and Cl, but smaller Cl excesses could be observed in some eucrites and high-iron chondrites.By analysing different types of Antarctic rocks, a significant decrease of the I concentration—but not of the Br and Cl concentration-was determined from the surfaces to the centers of the rocks. This shows that atmospheric I compounds interact with the surfaces of Antarctic rocks and, therefore, with those of Antarctic meteorites as well. Analyses of atmospheric halogens show that the gaseous compound CH3I is probably responsible for the I-overabundance in Antarctic meteorites and rocks. Chloride and bromide are found in particles derived from sea-spray in Antarctic aerosols. Deposition of halogens in Antarctic snow near the coast shows I/Cl ratios 10–190 higher than the average value for seawater. The corresponding Br/Cl ratios are in the same range as seawater. On the basis of our results and of other reported data we construct a preliminary hypothesis for a geochemical I cycle in Antarctica, taking into consideration long-distance and short-distance transportation of different I compounds from the coast to inland Antarctica.  相似文献   

13.
据记载,分布于上扬子区寒武系的石膏岩仅有零星资料。如今,大量蒸发岩如溶蚀角砾岩、硬石膏、石盐岩及富钾卤水等已被发现。沉积相经历了从盆地相、台地相到蒸发岩相的演化过程。在中、下寒武统中找到海退沉积序列。古构造-古地理背景是蒸发岩沉积的重要控矿条件之一。周边板块运动及塑性基底的褶皱,导致台缘隆起及台内坳陷的形成。岩相古地理图展示从碳酸盐、硫酸盐到氯化物盐类的“泪滴式”沉积相带。蒸发岩沉积于台缘隆起及礁生长进入堰塞潟湖至盐湖阶段。在稳定坳陷区沉积盆地中蒸发岩系发育;石盐岩较厚,其溴氯比值为0.2—0.4;古气候炎热、干燥;在蒸发岩体周围有沉积(封层)水及溶滤水,其含钾(K~+)量为0.10—4.76g/L;水文地球化学比值(如钾氯比值、钾盐比值及钾溴比值等)指示含钾异常;盐湖浓缩卤水达到氯化物盐类沉积阶段及相应的构造封闭程度;含盐地质标志广泛分布等等。鉴于上述,估计该区可能具备钾盐成矿条件。然而目的层埋藏太深,因此笔者建议,应在浅埋部位进行有效的成矿预测,为普查指出远景区。  相似文献   

14.
Agpaitic rocks comprise most of the exposed part of the 1.16 Ga old, 8 × 17 km large and about 1700 m thick Ilímaussaq intrusion in South Greenland. Within these, more than 600 m thick sequence of sodalite-rich “naujaites” (mainly sodalite + arfvedsonite + alkali feldspar + nepheline + eudialyte + aenigmatite) are interpreted as a sodalite flotation cumulate. Sodalites show two to three different zones in cathodoluminescence (CL) and at least two zones in thin sections. The CL zones can be related to chemical differences detectable by electron microprobe, whereas relations with optical zonations are less obvious. Compositional trends in sodalite reflect trends in the evolution of volatile contents in the melt. The sodalite at Ilímaussaq is almost free of Ca and closely corresponds to the pure Na–Cl sodalite endmember with about 7 wt.% of Cl; S contents reach up to 0.9 wt.%. Cl/Br ratios range from 500 to 1700. Raman spectroscopy shows that S is present as [SO4]2− in sodalite, although sphalerite (ZnS) is a stable phase in naujaites. Peralkalinity and fO2 conditions allow S2− and [SO4]2− to be present contemporaneously.

The whole naujaite sequence is divided into two parts, an upper part with low, homogeneous S contents and Cl/Br ratios in the sodalite cores, and a lower part with strongly variable and higher S contents and with Cl/Br ratios, which are decreasing downwards. The details of the S content and the Cl/Br ratio evolution show that sodalite strongly influences the halogen contents of the melt by scavenging Cl and Br.

The naujaites were formed from a highly reduced, halogen-rich magma in equilibrium with magmatic methane at about 800 °C, which, upon ascent, cooling and fractionation, exsolved an aqueous fluid phase. Both fluids were trapped in separate inclusions indicating their immiscibility.

Micrometer-sized aegirine crystals and primary hydrocarbon-bearing inclusions are abundant in the crystal cores. The inclusions were trapped at pressures up to 4 kbar, although the emplacement pressure of the intrusion is about 1 kbar. This indicates growth of the sodalite during melt ascent and a very effective mechanism of trace element scavenging during sodalite growth. Sodalite rims are devoid of aegirine or primary hydrocarbon inclusions and probably reflect the emplacement stage.  相似文献   


15.
Geochemical investigations in the Utralanama Block, an intermediate pressure granulite facies terrain in the Arunta Block, central Australia, has revealed several anomalous features, not consistent with the depletion of granitophile components generally considered to accompany granulite facies metamorphism. However, other geochemical features are indicative of depletion. The mean K2O for the Utralanama Block is exceptionally low relative to most other granulite facies terrains, but Rb contents are comparatively high. Consequently, the mean K/Rb ratio is relatively low for granulite facies terrains as is the mean Ba/Rb ratio, whilst mean K/Sr and Rb/Sr ratios are much higher than usual for such terrains. Only the K/Ba ratio shows equivalent values to depleted terrains elsewhere.Comparison of these ratios for the three main compositional groups of rocks in the Utralanama Block reveals that for mafic rocks all the above ratios are characteristic of extreme depletion, whereas, for all but the K/Ba ratio, mean ratios for the pelitic rocks, and to a lesser extent for the quartzofeldspathic rocks approach normal crustal values or values for metasomatic rocks. The abnormally high Rb/Sr ratios of these rocks compared to average crustal rocks suggest, however, that metasomatism is the cause of the anomalous geochemical features of the Utralanama Block, and this is supported by field and microstructural evidence. Thus, Rb/Sr ratios appear to be useful indicators of metasomatism where no gross mineralogical or microstructural evidence for metasomatism is obvious, and under such conditions the K/Ba ratio may be more reliable than the K/Rb ratio for indicating prior depletion of the terrain.  相似文献   

16.
Proterozoic rocks of the Cloncurry district in NW Queensland, Australia, are host to giant (tens to hundreds of square kilometers) hydrothermal systems that include (1) barren regional sodic–calcic alteration, (2) granite-hosted hydrothermal complexes with magmatic–hydrothermal transition features, and (3) iron oxide–copper–gold (IOCG) deposits. Fluid inclusion microthermometry and proton-induced X-ray emission (PIXE) show that IOCG deposits and the granite-hosted hydrothermal complexes contain abundant high temperature, ultrasaline, complex multisolid (type 1) inclusions that are less common in the regional sodic–calcic alteration. The latter is characterized by lower salinity three-phase halite-bearing (type 2) and two-phase (type 3) aqueous inclusions. Copper contents of the type 1 inclusions (>300 ppm) is higher than in type 2 and 3 inclusions (<300 ppm), and the highest copper concentrations (>1,000 ppm) are found both in the granite-hosted systems and in inclusions with Br/Cl ratios that are consistent with a magmatic source. The Br/Cl ratios of the inclusions with lower Cu contents are consistent with an evaporite-related origin. Wide ranges in salinity and homogenization temperatures for fluid inclusions in IOCG deposits and evidence for multiple fluid sources, as suggested by halogen ratios, indicate fluid mixing as an important process in IOCG genesis. The data support both leaching of Cu by voluminous nonmagmatic fluids from crustal rocks, as well as the direct exsolution of Cu-rich fluids from magmas. However, larger IOCG deposits may form from magmatic-derived fluids based on their higher Cu content.  相似文献   

17.
云南文山官房钨矿床团山矿段围岩蚀变与矿化规律研究   总被引：1，自引：0，他引：1  
云南省文山县官房白钨矿床属于中—大型矽卡岩型白钨矿床。矿区内围岩蚀变强烈,蚀变分带明显,依据蚀变岩岩相学及岩石化学测试结果,并结合钻孔编录资料,将团山矿段围岩蚀变划分为3个蚀变带,自花岗岩体向外依次为金云母-绿帘石化带→透辉石-透闪石化带→镁橄榄石化带。通过对各蚀变带中岩石组分迁移量分析认为:在团山矿段热液蚀变及白钨矿化过程中,来自花岗质岩浆热液的A l2O3、S iO2、TFe、K2O、Na2O迁入,灰岩(白云质灰岩)中MgO、CaO迁出,团山矿段白钨矿化主要发生在透辉石-透闪石化带中,矿体产状与透辉石-透闪石带产状基本一致,橄榄石化带中钨矿化相对较弱,金云母-绿帘石化带中仅可见零星钨矿化。这一研究成果将对文山官房钨矿床成矿规律研究以及矿区进一步找矿提供重要的理论依据。  相似文献   

18.
Abstract The Llano Uplift in central Texas is a Grenville aged (c. 1.1 Ga) metamorphic terrane consisting predominantly of amphibolite facies mineral assemblages. The formation of these assemblages has been attributed to the emplacement of relatively late granite plutons throughout the area. Two types of granitic intrusion have previously been recognized: (1) Town Mountain Granites, which occur as relatively large, circular-shaped bodies of coarse-grained granite, and (2) Younger Granites which are present as smaller and more irregular bodies of finer-grained granite. In the central part of the uplift, wollastonite-bearing calc-silicate rocks occur within the Valley Spring Gneiss. The development of these calc-silicate rocks has been linked to infiltrating fluids presumably derived from spatially associated Younger Granites. The stability of coexisting quartz, calcite, wollastonite, grossular and anorthite and coexisting quartz, calcite, wollastonite, andradite and hedenbergite shows that the calc-silicate rocks equilibrated under H2O-rich conditions with χCO2 <0.10. Fluid inclusions present within the calc-silicate minerals are H2O-rich with salinities of <17 wt% equivalent NaCl. The absence of any detectable CO2 in the fluid inclusions may indicate entrapment of the inclusions at lower pressures and more H2O-rich conditions compared to the stability of the peak metamorphic mineral assemblage. Homogenization temperatures, measured for texturally primary inclusions, range from 360 to 368° C corresponding to a density range from 0.53 to 0.82 g/cm3. Isochores for these fluid inclusions, when combined with the stability of the solid-solid equilibria Grs + Qtz = Wo + An, yield formation conditions of 500–550° C at 1–2 kbar. This indicates that the granitic intrusions involved in the formation of the Blount Mountain calc-silicates were emplaced at a pressure of at least 1–2 kbar.  相似文献   

19.
Rudaceous felsic to ultramafic clastic rocks of the Jones Creek Conglomerate are in tectonic contact with supracrustal mafic and ultramafic igneous rocks and associated fine‐grained sediments. All these rocks have a lower amphibolite facies mineralogy. Heterogeneously developed penetrative deformation has allowed sedimentary structures, including an unconformable contact between the Conglomerate and an adamellite, to be preserved in places. However, narrow, strike‐oriented zones containing blastomylonites and very flattened rudites normally characterize both contacts of the Conglomerate. Structural complexities within and at the contacts of the Conglomerate cast doubt on previous postulates that the Conglomerate separates an older from a younger supracrustal cycle.  相似文献   

20.
崔峤 《矿床地质》1984,3(1):77-82
块状硫化物矿床(黄铁矿型矿床、黑矿型矿床)与玄武岩-流纹岩建造的相互关系是由矿石与围岩形成的近似性所决定的,更确切地说,是矿石有规律地产在火山岩一定的岩相中。近年来,火山岩系的岩相分析已成为火山岩地区区域地质调查、块状硫化物矿床普查勘探工作中最重要的方法之一。这是因为,一方面岩相分析和古火山恢复方法,可以对火山体、火山岩系的喷发沉积旋回,以及火山岩的层序进行详细的研究,从而较为客观地总结出  相似文献   

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