共查询到20条相似文献，搜索用时 570 毫秒
1.
Zn-粘土催化剂对染料废水的O3氧化降解性能的影响 总被引：16，自引：0，他引：16
对于生物难降解性有机染料废水,用矿物催化剂进行复合催化氧化获 得了比较理想 的实验处理效果。以粘土为载体加载金属锌氧化物制成的可重复使用的固体催化剂,对人工模拟的染料废水进行复合催化臭氧氧化实验,获得了满意的效果。该法进一步提高了臭氧的降解效果,降低了处理成本。 相似文献
2.
铁(氢)氧化物矿物对有机污染物的光催化氧化作用 总被引：22，自引：3，他引：19
对水溶液中(氢)氧化铁的光催化氧化反应的发展与机理研究进行了总结,着重对近十年来应用针铁矿／过氧化氢进行光催化氧化环境中有机物的研究进展及其环境矿物学意义作了概述和探讨。采用天然生物矿化的纳米针铁矿／过氧化氢以偶氮染料甲基橙为光解模型物进行了光催化氧化的初步研究,结果表明铁细菌形成的针铁矿具有降解生物难降解的有机污染物的能力。在甲基橙溶液初始浓度为30mg／L,铁细菌矿化的针铁矿用量2．5g／L,反应体系H2O2的初始浓度97mmol／L,pH值为6．92,15W紫外灯照射2h后,甲基橙浓度可降低33％。 相似文献
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超临界水氧化(SCWO)技术是一项极具发展潜力的工业有机废水处理技术,特别针对传统处理工艺难以处理的高浓度、有毒、难降解有机废水优势明显.运用超临界水独特的物理性质与氧化机理,分析超临界水氧化过程在不同温度、停留时间、氧化剂当量及有无催化剂等条件下去污效果,找出不同废液适宜的处理条件.结合国内超临界水氧化技术在焦化、印染、造纸等有机废水处理研究现状,总结该法存在的主要问题和未来研究的主要方向. 相似文献
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对含氯类有机物的降解进行研究,提出,氯代烷烃的降解主要采用双金属体系法;氯代芳香烃的降解多采用光催化氧化法;对于氯代酚类则采用催化臭氧氧化法、超声波降解法等. 相似文献
6.
膜生物反应器处理难降解废水的特性研究 总被引：3，自引：3，他引：0
膜生物反应器与生物接触氧化法处理难降解废水的对比研究表明,在相同的运行条件下,膜生物反应器比生物接触氧化法具有更稳定的出水水质,其平均出水CODcr去除率达到88.41%,比接触氧化法提高了近30%;其平均色度去除率达到85.27%,相比接触氧化法,提高了近30%。通过出水分子量组成分析发现,膜出水以分子量介于3 000和10 000之间的物质为主,占总数的88.36%,接触氧化以分子量大于10 000的物质为主,占总物质的72.04%,介于3 000和10 000之间的仅占9.76%。 相似文献
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KN系列污水处理剂对不同污水采用多孔、层状非金属矿经活化复配而成，不仅对难降解有机废水具有良好的处理效果，也可用于易生物降解废水，并且价格低，相关工艺具有占地少、投资省、运转费用低的特点。所产生的污泥脱水性能好，并可无害化最终处理，不产生二次污染。 相似文献
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Fenton氧化膜-生物反应器出水中丙烯腈的实验研究 总被引：4，自引：0，他引：4
采用膜-生物反应器和Fenton氧化组合工艺对丙烯腈废水进行处理。从GC/MS测量结果来看,膜-生物反应器出水中主要物质为2,6双（二甲基-乙基）-4-酚、苯二甲酸和硝基苯二甲酸,均为生物难降解有机物,使出水不能达标。后续Fenton氧化工艺处理膜生物反应器出水,可以使COD含量等指标达到所要求的排放标准。经过膜-生物处理与Fenton法结合的优化工艺,COD去除率达到80%~88%,去除率达到98%,出水水质可达排放标准。Fenton氧化工艺的最佳工艺条件为：pH值为3.4,硫酸亚铁的投加量为700mg/L,双氧水的投加量为600mg/L。 相似文献
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《矿物学报》2016,(2)
通过共沉淀法将水溶性四羧基镍酞菁(Ni Pc)负载到镍-铝碳酸根水滑石(Ni Al-LDHs)上,制备负载型催化剂(Ni Pc/Ni Al-LDHs)。采用XRD、FT-IR、UV-Vis、TG-DTA和SEM等技术对酞菁衍生物和Ni Pc/Ni Al-LDHs的结构进行表征。结果表明Ni Pc没有改变Ni Al-LDHs的晶型结构和热稳定性能。在10 mg/L、25 m L的甲基橙溶液、p H值为3、H2O2用量50μL的条件下,Ni Pc/Ni Al-LDHs协同H2O2光催化氧化降解甲基橙3 h后,甲基橙剩余率为16.33%。溶液p H值在3~7范围内,Ni Pc/Ni Al-LDHs/H2O2都能有效光催化氧化降解甲基橙,且光催化氧化降解过程涉及到羟基自由基反应。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
14.
Emmanuel Skourtsos Daniel Vachard Alexandra Zambetakis-Lekkas Rossana Martini Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931. 相似文献
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正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.) 相似文献
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正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.) 相似文献
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正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.) 相似文献
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正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus., 相似文献
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正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an 相似文献
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正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of 相似文献