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1.
The Dry Valleys of Antarctica are an excellent analog of the environment at the surface of Mars. Soil formation histories involving slow processes of sublimation and migration of water-soluble ions in polar desert environments are characteristic of both Mars and the Dry Valleys. At the present time, the environment in the Dry Valleys is probably the most similar to that in the mid-latitudes on Mars although similar conditions may be found in areas of the polar regions during their respective Mars summers. It is thought that Mars is currently in an interglacial period, and that subsurface water ice is sublimating poleward. Because the Mars sublimation zones seem to be the most similar to the Antarctic Dry Valleys, the Dry Valleys-type Mars climate is migrating towards the poles. Mars has likely undergone drastic obliquity changes, which means that the Dry Valleys analog to Mars may be valid for large parts of Mars, including the polar regions, at different times in geologic history. Dry Valleys soils contain traces of silicate alteration products and secondary salts much like those found in Mars meteorites. A martian origin for some of the meteorite secondary phases has been verified previously; it can be based on the presence of shock effects and other features which could not have formed after the rocks were ejected from Mars, or demonstrable modification of a feature by the passage of the meteorite through Earth's atmosphere (proving the feature to be pre-terrestrial). The martian weathering products provide critical information for deciphering the near-surface history of Mars. Definite martian secondary phases include Ca-carbonate, Ca-sulfate, and Mg-sulfate. These salts are also found in soils from the Dry Valleys of Antarctica. Results of earlier Wright Valley work are consistent with what is now known about Mars based on meteorite and orbital data. Results from recent and current Mars missions support this inference. Aqueous processes are active even in permanently frozen Antarctic Dry Valleys soils, and similar processes are probably also occurring on Mars today, especially at the mid-latitudes. Both weathering products and life in Dry Valleys soils are distributed heterogeneously. Such variations should be taken into account in future studies of martian soils and also in the search for possible life on Mars.  相似文献   

2.
Lakes on Mars were formed under periglacial to glacial climates. Extreme conditions prevailed including freezing temperatures, low atmospheric pressure, high evaporation/sublimation rates, and liquid water reservoirs locked in aquifers below a thick cryosphere. Although many of the Martian paleolakes display evidence of a short period of activity consistent with these conditions, others display clear evidence of lifetimes ranging from 104 to 105 years. The discovery of young seeping processes in impact craters and pole-facing valley slopes along with young volcanic activity raise questions about the conditions and limitations of liquid water flow and potential lacustrine activity today on Mars. Current climate models show that in today's conditions there exist regions on Mars of sols above the triple point and below boiling point of water that could provide hydrogeological conditions comparable to these of the Antarctic Dry Valley lakes (with the exception of the atmosphere pressure). The locations of the most recent Martian paleolakes are correlated with these regions. Throughout the history of Mars, lakes generated diversified environments, which could have provided potential habitats for life. The recent discovery of young energy sources from volcanism and the potential for liquid water reinforces the possibility of extant life on Mars, and suggests recent ponds and ancient paleolakes as primary targets for rover and sample return missions.  相似文献   

3.
Processing of organic molecules by liquid water was probably an essential requirement towards the emergence of terrestrial primitive life. According to Oparin's hypothesis, organic building blocks required for early life were produced from simple organic molecules formed in a primitive reducing atmosphere. Geochemists favour now a less reducing atmosphere dominated by carbon dioxide. In such an atmosphere, very few building blocks are formed. Import of extraterrestrial organic molecules may represent an alternative supply. Experimental support for such an alternative scenario is examined in comets, meteorites and micrometeorites. The early histories of Mars and Earth clearly show similarities. Liquid water was once stable on the surface of Mars attesting the presence of an atmosphere capable of decelerating C-rich micro-meteorites. Therefore, primitive life may have developed on Mars, as well. Liquid water disappeared from the surface of Mars very early, about 3.8 Ga ago. The Viking missions did not find, at the surface of the Martian soil, any organic molecules or clear-cut evidence for microbial activities such as photosynthesis, respiration or nutrition. The results can be explained referring to an active photochemistry of Martian soil driven by the high influx of solar UV. These experiments do not exclude the existence of organic molecules and fossils of micro-organisms which developed on early Mars until liquid water disappeared. Mars may store below its surface some well preserved clues of a still hypothetical primitive life.  相似文献   

4.
Recent studies have demonstrated that terrestrial subaqueous basalts and hyaloclastites are suitable microbial habitats. During subaqueous basaltic volcanism, glass is produced by the quenching of basaltic magma upon contact with water. On Earth, microbes rapidly begin colonizing the glassy surfaces along fractures and cracks that have been exposed to water. Microbial colonization of basaltic glass leads to the alteration and modification of the rocks and produces characteristic granular and/or tubular bioalteration textures. Infilling of the alteration textures by minerals such as phyllosilicates, zeolites and titanite may enable their preservation through geologic time. Basaltic rocks are a major component of the Martian crust and are widespread on other solar system bodies. A variety of lines of evidence strongly suggests the long-term existence of abundant liquid water on ancient Mars. Recent orbiter, lander and rover missions have found evidence for the presence of transient liquid water on Mars, perhaps persisting to the present day. Many other solar system bodies, notably Europa, Enceladus and other icy satellites, may contain (or have once hosted) subaqueous basaltic glasses. The record of terrestrial glass bioalteration has been interpreted to extend as far back as ∼3.5 billion years ago and is widespread in oceanic crust and its metamorphic equivalents. The terrestrial record of glass bioalteration strongly suggests that glassy or formerly glassy basaltic rocks on extraterrestrial bodies that have interacted with liquid water are high-value targets for astrobiological exploration.  相似文献   

5.
Dynamical transport of gases within the martian regolith controls many climatic processes, and is particularly important in the deposition and/or mobilization of shallow ground ice, as well as exchange of other volatiles between the martian regolith and atmosphere. A variety of theoretical studies have addressed issues related to ground ice dynamics on Mars and in the terrestrial analog environment of the Antarctic Dry Valleys. These theoretical studies have drawn on a limited set of empirical measurements to constrain the structural parameters controlling gas diffusion and flow in soils. Here, we investigate five groups of Mars-analog soils: glass spheres, JSC Mars-1, aeolian dune sand, Antarctic Dry Valley soils, and arctic loess. We present laboratory measurements of the structural properties most relevant to gas transport in these soils: porosity, tortuosity, permeability, bulk and intrinsic densities, grain-size distribution, pore-size distribution and BET surface area. Our results bear directly both on the appropriateness of assumptions made in theoretical studies and on current outstanding issues in the study of shallow ground ice on Mars and in the Dry Valleys. Specifically, we find that (1) measured values of tortuosity are lower than values commonly assumed for Mars by a factor of two to three; (2) diffusive loss of ground ice on Mars can likely proceed up to four times faster than predicted by theoretical studies; (3) soil permeabilities are sufficiently high that flushing of the soil column by bulk flow of atmospheric gases may further speed loss or deposition of shallow ground ice; (4) the pore volume in some Mars-analog soils is sufficiently high to explain high volumetric ice abundances inferred from Mars Odyssey Gamma Ray Spectrometer data as simple pore ice; and (5) measured properties of soils collected in Beacon Valley, Antarctica agree well with assumptions made in theoretical studies and are consistent with rapid loss of ground ice in the current climate.  相似文献   

6.
Abstract— A model for emplacement of deposits of impact craters is presented that explains the size range of Martian layered ejecta craters between 5 km and 60 km in diameter in the low and middle latitudes. The impact model provides estimates of the water content of crater deposits relative to volatile content in the aquifer of Mars. These estimates together with the amount of water required to initiate fluid flow in terrestrial debris flows provide an estimate of 21% by volume (7.6 × 107km3) of water/ice that was stored between 0.27 and 2.5 km depth in the crust of Mars during Hesperian and Amazonian time. This would have been sufficient to supply the water for an ocean in the northern lowlands of Mars. The existence of fluidized craters smaller than 5 km diameter in some places on Mars suggests that volatiles were present locally at depths less than 0.27 km. Deposits of Martian craters may be ideal sites for searches for fossils of early organisms that may have existed in the water table if life originated on Mars.  相似文献   

7.
Mars appears to have experienced little compositional differentiation of primitive lithosphere, and thus much of the surface of Mars is covered by mafic lavas. On Earth, mafic and ultramafic rocks present in ophiolites, oceanic crust and upper mantle that have been obducted onto land, are therefore good analogs for Mars. The characteristic mineralogy, aqueous geochemistry, and microbial communities of cold-water alkaline springs associated with these mafic and ultramafic rocks represent a particularly compelling analog for potential life-bearing systems. Serpentinization, the reaction of water with mafic minerals such as olivine and pyroxene, yields fluids with unusual chemistry (Mg–OH and Ca–OH waters with pH values up to ~12), as well as heat and hydrogen gas that can sustain subsurface, chemosynthetic ecosystems. The recent observation of seeps from pole-facing crater and canyon walls in the higher Martian latitudes supports the hypothesis that even present conditions might allow for a rock-hosted chemosynthetic biosphere in near-surface regions of the Martian crust. The generation of methane within a zone of active serpentinization, through either abiogenic or biogenic processes, could account for the presence of methane detected in the Martian atmosphere. For all of these reasons, studies of terrestrial alkaline springs associated with mafic and ultramafic rocks are particularly timely. This study focuses on the alkaline Adobe Springs, emanating from mafic and ultramafic rocks of the California Coast Range, where a community of novel bacteria is associated with the precipitation of Mg–Ca carbonate cements. The carbonates may serve as a biosignature that could be used in the search for evidence of life on Mars.  相似文献   

8.
The composition of the silicate portion of Martian regolith fines indicates derivation of the fines from mafic to ultramafic igneous rocks, probably rich in pyroxene. Rock types similar in chemical and mineralogical composition include terrestrial Archean basalts and certain achondrite meteorites. If these igneous rocks weathered nearly isochemically, the nontronitic clays proposed earlier as an analog to Martian fines could be formed. Flood basalts of pyroxenitic lavas may be widespread and characteristic of early volcanism on Mars, analogous to maria flood basalts on the Moon and early Precambrian basaltic komatiites on Earth. Compositional differences between lunar, terrestrial, and Martian flood basalts may be related to differences in planetary sizes and mantle compositions of the respective planetary objects.  相似文献   

9.
火星是人类重要的地外天体探测目标之一,对火星表面进行的探测和研究表明,火星表面曾经存在液态水,水是生命存在的基础,因此,在次表层寻找不同形式的水是目前火星探测的重要科学目标之一.近17年来,欧洲火星快车(Mars Express)上搭载的火星次表层和电离层探测先进雷达(Mars Advanced Radar for S...  相似文献   

10.
There is increasing evidence that the nature of extended dark features on slopes of Martian craters and uplands is related to existing sources of liquid water located on these slopes and to confined water flows rather than to the movement of large masses of dry sand (dust) or rock falls. Images acquired by the Mars Global Surveyor Mars Orbiter Camera at spatial resolutions of a few meters per pixel make it possible to distinguish such objects. The availability of big reserves of ground ice on Mars and conditions for the local conversion of ice to the liquid phase is now universally accepted. Although the presence of liquid water on the Martian surface is usually thought to be impossible because of low pressures and low mean temperatures, there is a sufficient number of lowlands on Mars where pressure exceeds the critical value required for the existence of liquid water. The extended narrow gullies on slopes with tributaries were formed, as it is supposed, by water streams. The structure of gullies has an unusual appearance, reverse of that of mountain rivers on Earth: gullies are broad in the upper part of a slope, narrow downslope, end with a thin stream, and disappear at the valley or crater floor. Both tributaries and the major channel seem to be directed uphill. This paper provides a simple explanation of this apparent paradox. Under low-temperature conditions, the conversion of liquid water to the ice phase should be considered in dynamics: the water released by the source comes in contact with a cold ground, partly soaks in ground, and freezes, forming an ice bed along which the stream moves further and continues to interact with ground. The distance from the source at which water completely disappears depends on the initial temperature of the source, its abundance, and the ground temperature. The apparent paradox is explained by the interaction of a cooling stream with a very cold ground. As regards the side structures, they are not tributaries but branches, which rapidly freeze. This paper also shows that a high source debit and/or sufficiently high ambient temperature promote the formation on the valley floor of a small pond that accumulates water flows. The walls of this pond consist of frozen ground and ice. Objects that might be small water reservoirs are detected in some new images of Mars. High concentration of sources of groundwater in two equatorial regions of Mars may serve as a useful indication to the location of places promising for searching traces of life on this planet.  相似文献   

11.
Analyses of Martian surface soil by Viking and Earth-based telescopes have been interpreted as indicating a regolith dominated by the weathering products of mafic or ultramafic rocks. Basaltic glass has previously been proposed as a more likely precursor than crystalline rock, given the low efficiency of surface weathering under present Martian conditions. On Earth large volumes of basaltic glass formed by quenching of magma by water. A similar interaction, between magma and ground ice, may have been a common occurrence on Mars. On the basis of this scenario palagonite, the alteration product of basaltic sideromelane glass, was studied as a possible analog to Martian soil. Samples from Iceland, Alaska, Antarctica, Hawaii, and the desert of New Mexico and Mexico were examined by optical and scanning electron microscopy, electron microprobe analysis, X-ray diffraction, spectrophotometry, and magnetic and thermogravimetric analysis. We suggest that palagonite is a good analog to the surface soil of Mars in chemical composition, particle size, spectral signature, and magnetic properties. Our model for the formation of fine-grained Martian surface soil begins with eruptions of basaltic magma through ground ice, forming deposits of glassy tuff. Individual glass shards are then altered by low-temperature hydrothermal systems to palagonitic material. Dehydration and aeolian abrasion strip the alteration rinds from the glass, and wind storms distribute the silt-sized palagonitic fragments in a planet-wide deposit.  相似文献   

12.
Evidence of recent gully activity on Mars has been reported based on the formation of new light toned deposits within the past decade, the origin of which remains controversial. Analogous recent light toned gully features have formed by liquid water activity in the Atacama Desert on Earth. These terrestrial deposits leave no mineralogical trace of water activity but rather show an albedo difference due to particle size sorting within a fine-grained mudflow. Therefore, spectral differences indicating varying mineralogy between a recent gully deposit and the surrounding terrain may not be the most relevant criteria for detecting water flow in arid environments. Instead, variation in particle size between the deposit and surrounding terrain is a possible discriminator to identify a water-based flow. We show that the Atacama deposit is similar to the observed Mars gully deposits, and both are consistent with liquid water activity. The light-toned Mars gully deposits could have formed from dry debris flows, but a liquid water origin cannot be ruled out because not all liquid water flows leave hydrated minerals behind on the surface. Therefore, the Mars deposits could be remnant mudflows that formed on Mars within the last decade.  相似文献   

13.
A.O. Fuller  R.B. Hargraves 《Icarus》1978,34(3):614-621
Flooding of low-lying areas of the Martian regolith may have occurred early in the planet's history when a comparatively dense primitive atmosphere existed. If this model is valid, the following are some pedogenic and mineralogical consequences to be expected. Fluctuation of the water table in response to any seasonal or longer term causes would have resulted in precipitation of ferric oxyhydroxides with the development of a vesicular duricrust (or hardpan). Disruption of such a crust by scarp undercutting or frost heaving accompanied by wind deflation of fines could account for the boulders visible on Utopia Planitia in the vicinity of the second Viking lander site. Laboratory and field evidence on Earth suggests that under weakly oxidizing conditions lepidocrocite (rather than goethite) would have preferentially formed in the Martian regolith from the weathering of ferrous silicates, accompanied by montmorillonite, nontronite, and cronstedtite. Maghemite may have formed as a low-temperature dehydrate of lepidocrocite or directly from ferrous precursors.  相似文献   

14.
Clay minerals, although ubiquitous on the ancient terrains of Mars, have not been observed in Martian meteorite Allan Hills (ALH) 84001, which is an orthopyroxenite sample of the early Martian crust with a secondary carbonate assemblage. We used a low‐temperature (20 °C) one‐dimensional (1‐D) transport thermochemical model to investigate the possible aqueous alteration processes that produced the carbonate assemblage of ALH 84001 while avoiding the coprecipitation of clay minerals. We found that the carbonate in ALH 84001 could have been produced in a process, whereby a low‐temperature (~20 °C) fluid, initially equilibrated with the early Martian atmosphere, moved through surficial clay mineral and silica‐rich layers, percolated through the parent rock of the meteorite, and precipitated carbonates (thereby decreasing the partial pressure of CO2) as it evaporated. This finding requires that before encountering the unweathered orthopyroxenite host of ALH 84001, the fluid permeated rock that became weathered during the process. We were able to predict the composition of the clay minerals formed during weathering, which included the dioctahedral smectite nontronite, kaolinite, and chlorite, all of which have been previously detected on Mars. We also calculated host rock replacement in local equilibrium conditions by the hydrated silicate talc, which is typically considered to be a higher temperature hydrothermal phase on Earth, but may have been a common constituent in the formation of Martian soils through pervasive aqueous alteration. Finally, goethite and magnetite were also found to precipitate in the secondary alteration assemblage, the latter associated with the generation of H2. Apparently, despite the limited water–rock interaction that must have led to the formation of the carbonates ~ 3.9 Ga ago, in the vicinity of the ALH 84001 source rocks, clay formation would have been widespread.  相似文献   

15.
Middle-Miocene age paleosols in the Antarctic Dry Valleys were studied for their compositional variation and concentrations of secondary oxides/coatings in <2 mm matrix material in tills. The paleosols date to between 10-18 Ma by 10Be, forming prior to and just following the transition from warm-based to cold-based ice, when the climate is thought to have entered a prolonged cold/dry period in which soil moisture would have been frozen most of the year. The progression of release of secondary oxides of Fe and Al shows variable percentages of individual oxihydrites relative to chemical element totals, and thus, to consume total Fe and Al would require tens of millions of additional years. The slow progression of Fed/Fet, used as a measure of relative age in other warmer alpine and Arctic climates, is shown here to amount to <15 percent of the total Fe available for weathering. Ferrihydrite variability in paleosols, often used to indicate the presence of fluctuating/perched ground water tables, suggests that liquid water may have accumulated in mid-profile in some instances, perhaps during periods when the climate was somewhat warmer for several weeks during the summer. Variable Fe and Al ratios and arithmetic functions argue for extremely slow but sustainable release of oxides in a cold, polar desert climate, in which temperatures prohibit the formation of clay minerals. The secondary mineral species present likely amount to residue from past climates that were more conducive to clay mineral genesis and aerosolic input over time. The presence of microbial life in Antarctic paleosols, with minor amounts of Fe available for physiological processes to function, argues for the potential existence of microorganisms in ice-enriched paleosols of Mars, particularly given its watery and dynamic geologic past and relatively high concentration of total Fe in subaerial paleosols. The distribution of Fe over a large part of the northern plains of Mars as determined by the GRS instrument is invoked as a comparison with the Antarctic.  相似文献   

16.
Abstract— Radiometric age dating of Martian rocks and surfaces at known locations for which crater densities can be determined is highly desirable in order to fully understand Martian history. Performing K‐Ar age dating of igneous rocks on Mars by robots, however, presents technical challenges. Some of these challenges can be defined by examining Ar‐Ar data acquired on Martian meteorites, and others can be evaluated through numerical modeling of simulated K‐Ar isochrons like those that would be acquired robotically on Martian rocks. Excess 40Ar is present in all shergottites. Thus for Martian rocks, the slopes of K‐Ar isochrons must be determined to reasonable precision in order to calculate reliable ages. Model simulations of possible isochrons give an indication of some requirements in order to define a precise rock age: Issues addressed here are: how many K‐Ar analyses should be made of rocks thought to have the same age; what range of K concentrations should these analyzed samples have; and what analytical uncertainty in K‐Ar measurements is desirable. Meteorite data also are used to determine the D/a2 diffusion parameters for Ar in plagioclase and pyroxene separates of several shergottites and nakhlites. These data indicate the required temperatures and times for heating similar Martian rocks in order to extract Ar. Quantitatively extracting radiogenic 40Ar could be difficult, and degassing cosmogenic Ar from mafic phases even more so. Considering all these factors, robotic K‐Ar dating of Martian rocks may be achievable, but will be challenging.  相似文献   

17.
Abstract— Martian meteorites (MMs) have been launched from an estimated 5–9 sites on Mars within the last 20 Myr. Some 80–89% of these launch sites sampled igneous rock formations from only the last 29% of Martian time. We hypothesize that this imbalance arises not merely from poor statistics, but because the launch processes are dominated by two main phenomena: first, much of the older Martian surface is inefficient in launching rocks during impacts, and second, the volumetrically enormous reservoir of original cumulate crust enhances launch probability for 4.5 Gyr old rocks. There are four lines of evidence for the first point, not all of equal strength. First, impact theory implies that MM launch is favored by surface exposures of near‐surface coherent rock (≤102 m deep), whereas Noachian surfaces generally should have ≥102 m of loose or weakly cemented regolith with high ice content, reducing efficiency of rock launch. Second, similarly, both Mars Exploration Rovers found sedimentary strata, 1–2 orders of magnitude weaker than Martian igneous rocks, favoring low launch efficiency among some fluvial‐derived Hesperian and Noachian rocks. Even if launched, such rocks may be unrecognized as meteorites on Earth. Third, statistics of MM formation age versus cosmic‐ray exposure (CRE) age weakly suggest that older surfaces may need larger, deeper craters to launch rocks. Fourth, in direct confirmation, one of us (N. G. B.) has found that older surfaces need larger craters to produce secondary impact crater fields (cf. Barlow and Block 2004). In a survey of 200 craters, the smallest Noachian, Hesperian, and Amazonian craters with prominent fields of secondaries have diameters of ?45 km, ?19 km, and ?10 km, respectively. Because 40% of Mars is Noachian, and 74% is either Noachian or Hesperian, the subsurface geologic characteristics of the older areas probably affect statistics of recognized MMs and production rates of secondary crater populations, and the MM and secondary crater statistics may give us clues to those properties.  相似文献   

18.
Abstract– Analyses by the Mars Exploration Rover (MER), Spirit, of Martian basalts from Gusev crater show that they are chemically very different from terrestrial basalts, being characterized in particular by high Mg‐ and Fe‐contents. To provide suitable analog basalts for the International Space Analogue Rockstore (ISAR), a collection of analog rocks and minerals for preparing in situ space missions, especially, the upcoming Mars mission MSL‐2011 and the future international Mars‐2018 mission, it is necessary to synthesize Martian basalts. The aim of this study was therefore to synthesize Martian basalt analogs to the Gusev crater basalts, based on the geochemical data from the MER rover Spirit. We present the results of two experiments, one producing a quench‐cooled basalt (<1 h) and one producing a more slowly cooled basalt (1 day). Pyroxene and olivine textures produced in the more slowly cooled basalt were surprisingly similar to spinifex textures in komatiites, a volcanic rock type very common on the early Earth. These kinds of ultramafic rocks and their associated alteration products may have important astrobiological implications when associated with aqueous environments. Such rocks could provide habitats for chemolithotrophic microorganisms, while the glass and phyllosilicate derivatives can fix organic compounds.  相似文献   

19.
Paul D. Komar 《Icarus》1979,37(1):156-181
Comparisons are undertaken between the hydraulics of channelized water flows on Mars, large terrestrial rivers, deep-sea turbidity currents, and the catastrophic flow of Lake Missoula floods. Expected bottom shear stresses, velocities and discharges, flow powers, and other parameters are computed for each. Sand transport rates and the times required for channel erosion are estimated for Mangala Channel. These calculations indicate that the turbidity currents and Lake Missoula floods were similar to channelized water flow on Mars in their flow characteristics and in their abilities to erode and transport sediments. Like the Lake Missoula floods, deep-sea turbidity currents are catastrophic in character, being formed by the slumping of large masses of sediment trapped in submarine canyons or deposited on the continental slope. The repeated flows originating from submarine canyons have formed deep-sea channels similar in scale and overall morphology to the Martian outflow channels. The submarine canyon can be viewed as the counterpart of the chaotic terrain or crater which serves as sources for many Martian channels. Like most Martian outflow channels, the deep-sea channels generally lack tributaries or have only minor tributaries, instead consisting of a single pronounced channel extending for several hundred kilometers from its origin at the submarine canyon to deep abyssal depths. The channels vary considerably in dimensions, but most commonly have widths in the range 2 to 15 km with reliefs of 50 to 450 meters, again similar in scale to the Martian channels. Other similarities include sections of anastomosing channels, a general lack of pronounced meandering, and a lack of an apparent “delta” where the transported sediments are deposited. The similarities of channel morphology and flow hydraulics indicate the deep-sea channels and turbidity currents can be useful in furthering our understanding of the Martian outflow channels. Physical processes in the deep-sea occur under a reduced effective gravity because of the overlying water with its buoyancy. The deep-sea channels provide another set of Earth-based channels which can be studied to determine the effects of gravity on such factors as channel meandering and anastomosing characteristics.  相似文献   

20.
Abstract— We present here ion microprobe analyses of rare earth and other selected trace and minor elements in pyroxenes of shergottite Queen Alexandra Range 94201 and lunar basalt 15555. Pyroxene zonation patterns record the crystallization histories of these two basaltic samples from Mars and the Moon, respectively, and allow a comparison of mafic melt evolution on these two planetary bodies. Elemental abundances and trends in pyroxenes of these two rocks indicate that their minerals formed by continuous, closed system fractional crystallization of their respective parent melts. This further supports the idea that QUE 94201 closely represents the composition of a true Martian basaltic melt (McSween et al., 1996). The main differences in pyroxene elemental zonation patterns in these two objects are attributed to earlier crystallization of whitlockite in QUE 94201 (i.e., before the Fe-rich pyroxenes) than in 15555 (after the Fe-rich pyroxenes). The size of Eu anomalies in pyroxenes of QUE 94201 is intermediate between that in pyroxenes of 15555 and the other shergottites and may imply that fO2 conditions during crystallization of this Martian basalt were significantly more reducing than for other shergottites, although not quite as reducing as for lunar basalts. Cerium anomalies appear to be less prevalent in pyroxenes of QUE 94201 than other Antarctic shergottites and could be indicative of lesser degree of weathering in the Antarctic.  相似文献   

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