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1.
A novel experimental cell was developed for in situ measurements of transport phenomena in porous media using Fourier-Transform Infrared (FTIR) Spectroscopy. The technique was employed at ambient pressure in the temperatures range of 11–44 °C to study the H2O → D2O exchange between water-saturated weathered feldspars (bulk porosity of 5–19 vol% for feldspar) from granitic saprolites and a surrounding aqueous liquid. Such measurements are an important step for understanding internal weathering reactions of feldspars in soils and aquifers. Effective diffusion coefficients Deff for water in water-saturated porous feldspars were determined assuming one-dimensional diffusion in a quasi-homogeneous medium. The values of Deff vary from 7.2 × 10−10 to 1.9 × 10−11 m2/s and are 1–2 orders of magnitude lower than the diffusion coefficients (D) of protons and molecular H2O in liquid water. The activation energy for the H2O → D2O exchange process in porous feldspars ranges from 7.8 to 18.8 kJ/mol.The results imply that the effective diffusivity of water is mainly controlled by physical properties of the feldspars like porosity, pore connectivity, pore geometry and distribution. Perthitic feldspars with homogeneous pore distribution in the albitic lamellas have diffusional tortuosity factors X = D/Deff between 3 and 10 while alkali feldspars with inhomogeneously distributed and disconnected pores have much higher X values up to 129. Diffusion anisotropy has been verified for a vein perthite with diffusion perpendicular to the lamellas being faster by 0.3–0.5 log units than within the lamellas. It has to be emphasized that the study is based only on few selected feldspars, including perthitic feldspar, and additional work on samples with different weathering stages is needed to test the importance of the different parameters controlling diffusive transport in the pore system.  相似文献   

2.
The Nernst partition coefficient of nickel (DNi) between Cr-spinel and silicate melt in natural systems has been investigated using mid-ocean ridge basalts (MORB) and other volcanic rocks. The Cr-spinel/olivine DNi values in volcanic rocks are between 1.2 and 0.3, indicating that the Cr-spinel/liquid DNi values vary from slightly higher to significantly lower than the olivine/liquid DNi values in natural systems. The Cr-spinel/liquid DNi values from the MORB samples vary between 6 and 11, slightly higher than those from the S-bearing experiments of Satari et al. [Satari P., Brenan J. M., Horn I. and McDonough W. F. (2002) Experimental constraints on the sulfide- and chromite-silicate melt partitioning behavior of rhenium and platinum-group elements. Economic Geology97, 385-398]. The results of the MORB samples and the experiments of Satari et al. (2002) indicate a negative correlation between the Cr-spinel/liquid DNi and the XCr values in Cr-spinels (Cr cation number on the basis of 3 total cations in the spinel structure). Variations of Cr-spinel/liquid DNi values with Cr-spinel compositions can be estimated from an empirical equation based on the results of the MORB samples and the experiments by Satari et al. (2002). The choice of Cr-spinel/liquid DNi = 10 for numerical modeling by Righter et al. [Righter K., Leeman W. P. and Hervig R. L. (2006) Partitioning of Ni, Co, and V between spinel-structured oxides and silicate melts: importance of spinel composition. Chemical Geology227, 1-25] is reasonable for basaltic systems. For picritic and komatiitic systems a lower value of ∼5 is more appropriate.  相似文献   

3.
Sediment macropores (with effective diameters larger than 100 μm) comprise 11% of the bulk sediment volume in a tidal freshwater wetland vegetated withPeltandra virginica. In order to determine effects of macroporous sediment structure on solute transport, we conducted a solute tracer experiment in the sediment. The effective transport volume (θeff, the volume of sediment through which solute was transported normalized to sediment bulk volume) was 0.15 cm3 cm?3, which is considerably smaller than the total pore space that is potentially available for transport (porosity of sediment is 0.63 cm3 cm?3). A mean transport time of 13 d was required to flush preferential flow paths inPeltandra hummocks; hydrologic turnover of the volumetrically dominant matrix pores (0.53 cm3 cm?3) was apparently much slower. Based on porewater sampler design and hydrological principles, we suggest that N2-purged tension solution samplers and diffusion equilibrators preferentially sample porewater from macropore and matrix domains, respectively. Dissolved ammonium and orthophosphate concentrations were three-fold higher in matrix pores compared to macropores, which is consistent with our finding that more rapid hydrological flushing occurred in macropores compared to matrix pores. Further evaluation of porewater sampler designs in macroporous sediment is needed to improve studies of hydrologic transport and biogeochemical cycling in wetlands.  相似文献   

4.
This work investigated the pore structure characteristics and reservoir features of the finegrained tight reservoirs in the lower member of the Xinhe Formation(J_2 x_1) in the Xiaohu subsag,Yabulai Basin based on core samples through various techniques. Interbedded silt/fine sandstones and mudstones are developed in the study area. Scanning electron microscopy(SEM) images were used to delineate different types of pores, including primary intergranular pores, secondary intergranular and intragranular pores, organic pores and fractures. The pore types were distinguished by pore size, pore area, location and formation process. The pore radii of the fine-grained rocks range from 1 nm to 1.55μm, mainly concentrated between 5 and 300 nm by low pressure N_2 adsorption and MICP analyses. The pore structure parameters of pore throat size and pore throat sorting coefficient are both positively correlated with porosity, while pore throat sorting coefficient has a negative correlation with permeability. The pore structures of the studied samples are much related to the mineral type and content and grain size, followed by TOC content. In these rocks with relatively low TOC and low maturity, the rigid minerals protect pores with pressure shadow from collapse, and dissolution-related pores contribute a lot to inorganic porosity. In contrast, these rocks with abundant TOC contain a large number of organic pores. The permeability of the fine-grained tight reservoir is mainly dominated by larger pore throats, while a large number of small pores(mostly 0.1 μm) contribute considerably to porosity. These results have deepened our understanding of the interbedded fine-grained tight reservoirs and can be applicable to fine-grained reservoirs in a similar setting.  相似文献   

5.
Olivine dissolution in basaltic melt   总被引：1，自引：0，他引：1  
The main purpose of this work is to understand and quantify diffusive and convective olivine dissolution in basaltic melt. Crystal dissolution and growth in a magma chamber is often accompanied by the descent or ascent of the crystal in the chamber due to gravity. The motion induces convection that enhances mass transport. Such convective dissolution and growth rates have not been quantified before. MgO diffusivity in the melt (DMgO), MgO concentration of the interface melt (C0) and the effective thickness of the compositional boundary layer (δ) are necessary parameters to model the convective dissolution. Experiments of non-convective olivine dissolution in a basaltic melt were conducted at 1271-1480 °C and 0.47-1.42 GPa in a piston-cylinder apparatus. At specific temperature and pressure conditions, multiple experiments of different durations show that the interface melt reaches near-saturation within 2 min. Therefore, diffusion, not interface reaction, is the rate-controlling step for non-convective olivine dissolution in basaltic melt. The compositional profile length and olivine dissolution distance are proportional to the square root of experimental duration, consistent with diffusive dissolution. DMgO and C0 are obtained from the experimental results. DMgO displays Arrhenian dependence on temperature, but the pressure dependence is small and not resolved. C0 increases with increasing temperature and decreases with increasing pressure. Comparison with literature data shows that DMgO depends strongly on the initial melt composition, while C0 does not. δ is estimated from fluid dynamics. DMgO/δ, which characterizes the kinetic and dynamic aspects of convective crystal dissolution, is parameterized as a function of temperature, pressure, and olivine composition. Convective olivine dissolution rate in basaltic melt can be conveniently calculated from the model results. Application to convective crystal growth and xenolith digestion is discussed.  相似文献   

6.
The surface layer of aquatic sediments is a zone characterized by both porosity gradients and intensive mixing. In the standard approach, porosity gradients are ignored when estimating mixing intensity. Here, model formulations with both constant and varying porosity are contrasted to estimate mixing coefficients Db from tracer depth profiles. Complementing the well-known exponential solution of the constant-porosity model, we present a general solution to the variable-porosity model in terms of hypergeometric functions. When using these models in a forward way, the tracer activities predicted by the variable-porosity model are higher than those generated by the constant-porosity model. Similarly, when inverse modelling, Db values estimated by the variable-porosity model are systematically higher than those derived from the constant-porosity model. Still, differences in Db values remain relatively small. When applying both mixing models to excess 210Pb data profiles from slope sediments, a maximal difference of 30% is obtained between Db values, the average deviation being 16%. A systematic exploration of parameter space predicts a maximal underestimation of 60% when deriving Db values from the constant-porosity mixing model. Given the uncertainty imposed by other model assumptions underlying the diffusive mixing model, the influence of porosity gradients on Db values must be classified as rather modest. Hence, the current mixing coefficient database is not biased by the constant porosity approximation.  相似文献   

7.
A simple rock model is presented which reproduces the measured hydraulic and electric transport properties of sedimentary rocks and connects these properties with each other, as well as with the acoustic propagation velocities and elastic moduli. The model has four geometric parameters (average coordination number Z of the pores, average pore radius r, average distance between nearest pores d, and average throat radius δ) which can be directly determined from the measured porosity Φ, hydraulic permeability k, and cementation exponent m of the rock via simple analytic expressions. Inversion examples are presented for published sandstone data, and for cores taken from Saudi Arabian, Upper Jurassic and Permian carbonate reservoirs. For sandstone, the inversion works perfectly; for carbonates, the derived rock model shows order-of-magnitude agreement with the structure seen in thin sections. Inverting the equations, we express the transfer properties Φ, k, and m as functions of r, d, δ, and Z. Formulae are derived for the bulk density D b, formation factor F, and P-wave velocity in terms of the proposed geometrical parameters.  相似文献   

8.
In the present study, 12 theoretical models have been introduced for studying the effect of the grain size and shape on the intergranular porosity, ?. From the first eight models, it is stated that the grain size has no effect on the intergranular porosity, but it is declared that the smaller the grain size means the smaller the interstitial pore spaces and therefore, the less the ability of the pore spaces to receive finer sediments, then the higher the porosity. On the other hand, studying the present models revealed that the total intergranular porosity decreases when increasing the grain elongation ‘E’ (the length of the grain/the diameter of the grain) as a shape anisotropy parameter. A new equation has been introduced relating the total pore volume to the grain shape/elongation. $$ \emptyset = 26.188\ {E^{-1 }} + 21.431 $$ The grain sorting of the present models has been studied by adding another group of grains of the critical grain size of occupation inside the pore spaces; the pore volume decreases by about 41.0 % of the total porosity. To check the applicability of the proposed equation, 46 samples of highly porous sandstone have been selected from different places in Egypt and studied petrographically, and their total pore volume have been measured using Digital Image Analysis (DIA) ‘? Im’ and helium injection technique ‘? He.’ Petrographically, the studied samples are quartz arenite and ferruginous quartz arenite. The pore types are mostly characterized mostly as (1) intergranular porosity and rarely as (2) intragranular porosity, (3) vuggy porosity, and (4) fracture porosity. The grain elongation ‘E’ for the present samples has been measured using the DIA technique; it varies from 1.34 to 1.73. Porosity ‘? He’ varies between 25.8 and 34.7 %, gas permeability ‘k’ varies from 0.14 to 6.92 μm2 (very good to excellent rank), and the mean pore diameter ‘D’ varies between 3.9 and 25.7 μm (macro to mega pores). The study stated the applicability of the present equation and introduced a number of equations that could be used to calculate porosity, permeability, and pore radius in terms of grain elongation. The applicability of the present study has some limitations due to (1) cementation, (2) microporosity, and (3) fracturing. The effect of cementation can be minimized by processing the grains and the surrounding cement statistically as a bulk ellipsoid unit, whereas the micropores/fractures can be measured by helium injection.  相似文献   

9.
The ophiolitic metabasalts (pillowed and sheeted dikes) of Wadi Ghadir area, Eastern Desert, Egypt, were analyzed for their major, trace and rare earth elements, Nd and Sr isotopes and the chemistry of their plagioclase, amphibole and chlorite was also reported. Geochemically these rocks range from tholeiitic basalt to basaltic andesite. The generally low MgO, Cr and Ni and high Zr contents are consistent with derivation of these rocks from an evolved magma. The high TiO2 contents (mostly between 1.76% and 2.23%) classify Wadi Ghadir ophiolitic metabasalts as MORB ophiolite. The chondrite-normalized REE patterns of most samples display small LREE-enrichment with (La/Yb)n ranging from 1.44 to 2.56. The MORB-normalized spider diagram shows variable LILE abundances, which are either similar to or enriched relative to MORB, and most samples display small Nb depletion. The abundances of some LILE (Ba, Rb and K) as well as Na and Si were modified by post-magmatic seafloor hydrothermal alteration. Enrichment of the least mobile LILE (Th & U) indicates that Wadi Ghadir ophiolitic metabasalts are akin to C (contaminated)-MORB. These geochemical characteristics are similar to BABB modified by contamination.Wadi Ghadir metabasalts have low initial Sr ratios (0.7010–0.7034) which are similar to those of MORB, while their εNd(t) values (+7.7–+4.5) are either more or less positive than the value of depleted mantle (DM). The more positive εNd(t) values indicate DM source for these basalts, while the less positive εNd(t) values reflect the involvement of slightly older component in Wadi Ghadir ophiolite. We suggest that the parent magma of metabasalts was contaminated by slightly older material, most probably oceanic-arc crustal rocks, which caused enrichment in LREE, and by analogy LILE, but did not significantly affect Nd isotopic systematics or modify Sr isotopes.Such contaminated MORB character also revealed by other ophiolitic metavolcanics in the Central Eastern Desert, contrasting the N-MORB character of the Gerf ophiolite in the South Eastern Desert. Moreover, the present work suggests the increase of the degree of contamination of the ophiolitic metabasalts from south to north in the Central Eastern Desert.  相似文献   

10.
Diffusion and sorption behaviors of cationic Cs+, anionic I− and neutral HTO in samples of the Wakkanai Formation from the Horonobe underground research laboratory (URL), Japan, were investigated as a function of ionic strength (I) of synthetic groundwater by through-diffusion and batch sorption experiments and mechanistic modeling. The effective diffusivities (De) measured by through-diffusion experiments showed cation excess and anion exclusion effects, which were strongly dependent on I; De for Cs+ decreased as I increased, De for I− showed the opposite dependency and De for HTO showed no dependence. The sorption of Cs+ measured by through-diffusion and batch sorption experiments were described by Freundlich isotherms with consistent parameters and decreased with I as a result of competitive ion exchange.Diffusion and sorption behaviors were interpreted by assuming the clay components of illite and smectite control diffusion and sorption mechanisms. The component additive (CA) sorption model, which includes illite and smectite contents and their ion exchange constants, provided a reasonable account of the Cs+ sorption trends measured as functions of I and Cs concentration. The diffusion model was developed by coupling the electrical double layer (EDL) model, describing the change of ionic concentrations (cation excess and anion deficit) and viscoelectric effects caused by electrostatic interaction at negatively charged clay surfaces, and a simplified pore model assuming one type of pore shape and includes their size distribution. When averaging the electrostatic effects by using the pore surface area distribution, the model could predict the cation excess and anion exclusion effects, and its dependence on I reasonably well. This result implies the nanoscale pores dominating the pore surface area can strongly impact on ionic diffusion in argillaceous rocks. The clay-based modeling approach described here provides a useful tool to predict ionic diffusion and sorption in argillaceous rocks.  相似文献   

11.
《China Geology》2020,3(4):545-557
The composition of gas released under vacuum by crushing from the gas shale of Longmaxi Formation in Upper Yangtze Plate, Southern China was systematically investigated in this study. The effect of residual gas release on pore structures was checked using low-pressure nitrogen adsorption techniques. The influence of particle size on the determination of pore structure characteristics was considered. Using the Frenkel-Halsey-Hill method from low-pressure nitrogen adsorption data, the fractal dimensions were identified at relative pressures of 0−0.5 and 0.5−1 as D1 and D2, respectively, and the evolution of fractal features related to gas release was also discussed. The results showed that a variety component of residual gas was released from all shale samples, containing hydrocarbon gas of CH4 (29.58% −92.53%), C2H6 (0.97% −2.89%), C3H8 (0.01% −0.65%), and also some non-hydrocarbon gas such as CO2 (3.54% − 67.09%) and N2 (1.88%−8.07%). The total yield of residual gas was in a range from 6.1 μL/g to 17.0 μL/g related to rock weight. The geochemical and mineralogical analysis suggested that the residual gas yield was positively correlated with quartz (R2=0.5480) content. The residual gas released shale sample has a higher surface area of 17.20−25.03 m2/g and the nitrogen adsorption capacity in a range of 27.32−40.86 ml/g that is relatively higher than the original samples (with 9.22−16.30 m2/g and 10.84−17.55 ml/g). Clearer hysteresis loop was observed for the original shale sample in nitrogen adsorption-desorption isotherms than residual gas released sample. Pore structure analysis showed that the proportions of micro-, meso- and macropores were changed as micropores decreased while meso- and macropores increased. The fractal dimensions D1 were in range from 2.5466 to 2.6117 and D2 from 2.6998 to 2.7119 for the residual gas released shale, which is smaller than the original shale. This factor may indicate that the pore in residual gas released shale was more homogeneous than the original shale. The results indicated that both residual gas and their pore space have few contributions to shale gas production and effective reservoir evaluation. The larger fragments samples of granular rather than powdery smaller than 60 mesh fraction of shale seem to be better for performing effective pore structure analysis to the Longmaxi shale.  相似文献   

12.
Residual and movable porosity are significant parameters for characterising petrophysical properties, especially in tight reservoirs. Eight tight sandstone samples from the upper Paleozoic gas-bearing strata in the Kangning area, from the eastern margin of the Ordos Basin, were analysed using nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), petrography, and porosity and permeability tests. The lithology and pore types were identified and classified using petrography and SEM. The residual and movable porosity were obtained with NMR. In addition, NMR was used to visualise pore structure and pore size distribution. The results suggest that the upper Paleozoic sandstones in the study area mainly comprise feldspathic litharenite and litharenite. The sandstone porosity and permeability are low, with means of 5.9% and 0.549 mD, respectively. Four pore types exist in the tight sandstones: residual primary pores, grain dissolution pores, micropores (clay-dominated) and microfractures. The T2 spectra under water-saturated conditions correlate with pore size and can be used to distinguish small and large pores based on the transverse relaxation time cutoff value of 10 ms, which corresponds to a pore diameter of 0.232 μm. Small pores account for 72% of the pores in the tight sandstones. The continuous bimodal T2 spectra suggest good connectivity between small and large pores, despite the low porosity and permeability. In this study, the movable porosity of the major tight sandstone gas reservoirs is higher than the residual porosity, which confirms the effective evaluation of movable porosity to tight sandstone reservoirs, based on NMR experiments.  相似文献   

13.
Partial melting in the middle to lower crustal level produces melts of granitic composition during orogeny. Thrusts play a vital role in their exhumation after consolidation of these granitic melts. In this paper we focus on one such granite along the eastern margin of the Delhi Fold Belt (DFB) rocks near Srinagar, Rajasthan, India. This is the first report of granite within the area and holds a key stratigraphic position in the entire rock package. The said granite is found to be intrusive to the DFB metasediments as well as their basement popularly known as the Banded Gneissic Complex (BGC). We disentangle the deformation fabrics seen within the granite and associated DFB metasediments, suggesting that subsequent to emplacement and consolidation, the granite has co-folded along with the country rocks. Three deformational events could be identified within the DFB metasediments namely, D1D, D2D and D3D. The peak metamorphism was achieved in the D1D event. The granite magma is generated and emplaced late syn-kinematic to D1D and thereafter is deformed by D2D and D3D producing D1G and D2G structural fabrics. These compressive deformations resulted in the collapse of the basin; the combined package of DFB rocks and the granite was thrusted eastwards over the basement rocks. The tectonic transport direction during thrusting is suggested eastwards from our structural analysis. Transverse faults developed perpendicular to the length of the granite have led to partitioning of the strain thereby showing a heterogeneity in the development of fabric within it.  相似文献   

14.
To assess further the role of pore fluids in enhancing mass transport in deep-seated rocks, bulk diffusion coefficients (D-values) for chlorine have been measured at 1.0 GPa and 1000°C in texturally-equilibrated quartzites containing varying amounts (0.3–2.8 vol%) of H2O or a CO2–H2O mixture (X CO2=0.4). Experiments were used to monitor transport predominantly through the fluid phase by employing a chemical tracer dissolved in the fluid (chlorine) that is virtually insoluble in the rock matrix (quartzite) but is somewhat soluble in a small fraction of dispersed indicator minerals (fluorapatite). For diffusion in H2O-bearing quartzite, experiments with 1 vol.% fluid exhibit a continuous decrease in D-values with decreasing porosity whereas an abrupt drop in the diffusion coefficient is indicated by the experiments with 0.3 vol.% fluid. At a given total porosity, diffusion coefficients obtained from quartzites containing the CO2–H2O fluid range from 80x to > 3000x lower than those from H2O-bearing experiments. Bulk transport measurements were correlated with textural observations and the observed reduction in bulk D-values for quartzites containing the CO2–H2O fluid reflects the overall isolated nature of porosity in such samples. The drop in the bulk D-value for quartzites with 0.3 vol.% H2O probably arises from the elimination of interconnected porosity owing to the presence of a sufficient number of dry grain edges. Textural observations, combined with transport measurements, are consistent with the pore structure predicted by dihedral angle measurements. However, due to anisotropy in the interfacial energy of quartz, long-range fluid connectivity is dramatically reduced in quartzites with low H2O contents, despite a median dihedral angle of less than (but near) 60°. Observed variations in chlorine D-values in samples with connected and non-connected porosity are found to be consistent with previous bulk property measurements on texturally-equilibrated, fluid-bearing rocks. Results of this study, combined with prior bulk diffusion measurements for oxygen, provides a general assessment of the effect of small amounts of fluid on the enhancement of mass transport in quartzose lithologies over a range of crustal P and T. At conditions of textural equilibrium, it is expected that the fluid phase provides little or no contribution to the long-range diffusive flux of solutes in quartz-rich rocks containing small amounts of H2O or CO2–H2O mixtures.  相似文献   

15.
We investigated the effects of diagenetic alteration (dissolution, secondary aragonite precipitation and pore filling) on the distribution of U in live and Holocene coral skeletons. For this, we drilled into large Porites lutea coral-heads growing in the Nature Reserve Reef (NRR), northern Gulf of Aqaba, a site close to the Marine Biology Laboratory, Elat, Israel, and sampled the core material and porewater from the drill-hole. In addition, we sampled Holocene corals and beachrock aragonite cements from a pit opened in a reef buried under the laboratory grounds. We measured the concentration and isotopic composition of U in the coral skeletal aragonite, aragonite cements, coral porewater and open NRR and Gulf of Aqaba waters.Uranium concentration in secondary aragonite filling the skeletal pores is significantly higher than in primary biogenic aragonite (17.3 ± 0.6 compared to 11.9 ± 0.3 nmol · g−1, respectively). This concentration difference reflects the closed system incorporation of uranyl tri-carbonate into biogenic aragonite with a U/Ca bulk distribution coefficient (KD) of unity, versus the open system incorporation into secondary aragonite with KD of 2.4. The implication of this result is that continuous precipitation of secondary aragonite over ∼1000 yr of reef submergence would reduce the coral porosity by 5% and can produce an apparent lowering of the calculated U/Ca - SST by ∼1°C and apparent age rejuvenation effect of 7%, with no measurable effect on the calculated initial U isotopic composition.All modern and some Holocene corals (with and without aragonite cement) from Elat yielded uniform δ234U = 144 ± 5, similar to the Gulf of Aqaba and modern ocean values. Elevated δ234U values of ∼180 were measured only in mid-Holocene corals (∼5000 yr) from the buried reef. The values can reflect the interaction of the coral skeleton with 234U-enriched ground-seawater that washes the adjacent granitic basement rocks.We conclude that pore filling by secondary aragonite during reef submergence can produce small but measurable effects on the U/Ca thermometry and the U-Th ages. This emphasizes the critical importance of using pristine corals where the original mineralogy and porosity are preserved in paleooceanographic tracing and dating.  相似文献   

16.
The microstructure characteristics of the reservoir are closely related to the seepage capacity of the reservoir. Compared with conventional reservoirs and low permeability reservoirs, the tight oil is stored in a smaller nanoporous space. The microscopic pore structure of reservoir is the geometrical shape, size, distribution, and interconnected relationship of porosity and throat. The experiment was conducted on several tight rock samples taken from the Chang 7 formation in Xunyi county of Ordos Basin, China. Based on nano-CT scanning and advanced image processing technology Avizo, we build a three-dimensional comprehensive pore and throat network model. In the result of our study, reservoir space types are dissolution pores with mineral particles inside in the pore network model. Then, the pore throat morphology in the forms of small globular and tubular with SEM was explained. There is a big difference in quantity distribution at different locations, which is limited to the permeability of samples. Pore types are mostly round tubular and long tubular, while isolated pores account for a significant proportion. Through making and analyzing the three-dimensional structure of interconnected pores, obtained their specific forms and the division of connectivity types.  相似文献   

17.
The Ilesha granite gneiss comprises a varied series ranging from porphyroblastic alkali gneiss and granitic gneiss to banded and strongly foliated melanocratic rocks. Deformation is intense and the dominant structural trend is approximately N-S.Chemical data show essentially a systematic variation reflecting the differences in the petrographic character of the outcrops. SiO2, Na2O, K2O and related trace elements, particularly Rb, are higher in the alkali and granitic varieties, whereas the melanocratic types have lower contents of these elements. The basic rocks are likewise significantly enhanced in TiO2, Fe, MgO, CaO, Cr and Ni concentrations, with some values being comparable to those of basaltic rocks.  相似文献   

18.
有机质孔隙是页岩储集空间的重要组成部分,具有强烈的非均质性,阻碍对页岩储层质量的正确认识和评价,其本质是受有机显微组分类型及其在生烃过程中孔隙演化的影响。本文采用场发射扫描电镜和荧光显微镜定位观察手段实现特定显微组分孔隙发育特征的表征,结合Image J图像处理技术,对不同演化阶段的显微组分进行定量化统计,总结不同有机显微组分的孔隙演化规律。研究结果表明:固体沥青孔隙度随着成熟度的升高呈现先增加后减小的趋势,在固体沥青反射率SBR_O介于1.6%～2.0%时,固体沥青孔隙最为发育,而以SBR_O=2.0%为界,固体沥青孔隙度开始减小。镜质体和惰质体的孔隙发育规律相似,随着成熟度增加,总体表现出先减小而后微弱增加的趋势。在生油窗阶段,镜质体和惰质体孔隙度最小,无机矿物和固体沥青的充填使胞腔孔隙损失达90%以上,而进入高成熟阶段,固体沥青孔隙的发育使原始胞腔孔隙得到一定程度的恢复,成为镜质体和惰质体残余孔隙的主要贡献者,贡献率达56.73%和100%,可见固体沥青孔隙对页岩储层储集空间的重要性。综合沉积成岩作用和生烃作用,页岩储层在未成熟阶段和高成熟阶段晚期孔隙最为发育,前者有机质以原始胞腔孔隙为主,后者以固体量孔隙为主。明确有机显微组分孔隙演化规律为页岩有利储层预测和页岩气生产开发储层改造提供参考。  相似文献   

19.
鄂尔多斯盆地中奥陶统马家沟组最上部的马五5-马五1亚段为盆地内中部气田区主要的天然气储产层之一,厚度70~80米,面积约4.8×104平方千米。储集岩主要的原始岩性为不同程度地存在晶间孔隙的含硬石膏柱状晶和结核的粉晶白云岩和粗粉晶白云岩。中奥陶世末至中石炭世,经历了140余Ma的表生裸露期成岩作用,古风化壳岩溶十分强烈,特别是在含硬石膏柱状晶和结核的粉晶白云岩中形成广布于气田区的形式多样的储集空间类型。埋藏成岩作用次生溶蚀孔隙主要叠加于古风化壳岩溶所形成的孔、缝及洞中,使其再次扩溶,或使孔、缝及洞中半充填的沉积物再次溶解或部分溶解。印支期产生的80°方向和燕山期30°和60°方向的共轭裂隙,亦以在古岩溶作用较强烈、并存在孔隙的岩性中较明显。从岩芯和铸体薄片中识别出21种孔、洞、缝和裂隙,包括沉积(准同生)期的原生孔隙3种; 表生裸露成岩期次生孔隙9种; 埋藏成岩期次生孔隙5种; 构造裂隙和断层4种。在同一块岩芯,甚至同一块铸体薄片中,常可见到不同成岩期次的多种孔隙类型叠加和同时出现。在中部气田区,各种孔隙空间的发育程度,分布范围和对储层的贡献值是不一样的,是导致储层的非均质性的主要原因之一。  相似文献   

20.
利用数字图像分析法对南堡地区碳酸盐岩储层的孔隙结构参数进行定量求取,明确了不同类型孔隙的孔隙结构参数特征,分析了孔隙结构特征对储层物性的影响,并应用优选出的孔隙结构参数建立碳酸盐岩储层物性预测模型。结果表明:研究区内碳酸盐岩储层的储集空间以次生孔隙为主,为一套典型的孔隙型储层。应用孔隙结构参数可以较好的区分铸模孔、粒间孔、粒内孔和晶间孔等孔隙类型,其中铸模孔呈较低的平均等效直径与高的宽纵比,粒间孔以高等效直径25%为特征,粒内孔对应最低的比表面、最高的等效直径标准差,晶间孔比表面较高且宽纵比分布范围局限。等效直径、形状因子、球度和宽纵比等参数对储层物性的影响显著。分别针对孔隙度和渗透率,在提取的28项孔隙结构参数中优选出6种相关性高的参数,并应用多元线性回归方法分别进行拟合。验证结果显示拟合公式具有较高的可信度,且渗透率(R^2=0.916)优于孔隙度(R^2=0.778)。该方法可为研究区及其他地区的孔隙型碳酸盐岩储层评价研究提供参考。  相似文献   

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