Changes in the Dead Sea Level and their Impacts on the Surrounding Groundwater Bodies     

E. Salameh  H. El‐Naser 《洁净——土壤、空气、水》2000,28(1):24-33

In this paper the reaction of the salt‐/freshwater interface due to the changes in the Dead Sea level are elaborated at in details by using the inflows into the Dead Sea, the outflows due to evaporation losses and artificial discharges, and the hydrographic registrations of the Dead Sea level. The analyses show that the interface seaward migration resulted in a groundwater discharge of around 423 Mio m³ per meter drop in the level of the Dead Sea in the period 1994–1998 and of around 525 Mio m³/m in the period 1930–1937. The additional amount of groundwater joining the Dead Sea due to the interface seaward migration was 51 Mio m³ per one square kilometer of shrinkage in the area of the Dead Sea in the period 1930–1937 and 91 Mio m³/km² in the period 1994–1998. The riparian states of the Dead Sea are nowadays loosing 370 Mio m³/a of freshwater to the Dead Sea through the interface readjustment mechanisms as a result of their over exploitation of waters which formerly fed the Dead Sea.  相似文献   

Tritium in the Dead Sea     

I. Carmi  J.R. Gat  M. Stiller 《Earth and Planetary Science Letters》1984,71(2):377-389

Tritium data in the Dead Sea for the period 1960–1979 are given. Tritium levels have increased until 1965 in the upper layers of the Dead Sea reaching a level of 170 TU, in response to the atmospheric buildup of tritium from thermonuclear testing. The levels have been decreasing ever since, both because of rapidly declining atmospheric concentrations of tritium and because of mixing of the surface layers with tritium deficient, deeper water masses. The depth of penetration of the tracer delineated the depth of meromictic stratification and successfully monitored the deepening of the pycnocline, until the overturn in 1979 homogenised the entire tritium profile. Modelling the changing tritium inventory over this period showed the predominance of the direct exchange across the air/sea interface, both in the buildup of tritium in the lake and also in its subsequent removal from it. The good fit between calculated and measured tritium inventories confirmed the evaporation estimate of 1.46 m/yr (the mean value for the period) with a precision unattained by other methods.  相似文献   

Measurements of the18O/16O ratio of dissolved oxygen in the North Sea during FLEX 76     

H. Förstel  H. Zielke 《Pure and Applied Geophysics》1978,116(2-3):486-496

In spring 1976 a special part of the North Sea was the subject of research by a group of international scientists in the so-called Fladenground Experiment 1976 (FLEX 76). Our team participated aboard the research shipPlanet in an attempt to study the oxygen exchange between sea and atmosphere and the mixing within the water column. The water samples were taken in a small area during a period of two weeks. The water depth did not exceed 140 m. The dissolved oxygen was extracted using a vacuum system, and stored after adsorption on a molecular sieve. In the laboratory the oxygen was burned to carbon dioxide and the¹⁸O/¹⁶O ratio was determined with a mass spectrometer. At the surface the sea water was saturated with air and showed the¹⁸O/¹⁶O ratio of atmospheric oxygen. Towards the deeper layers the oxygen was consumed, and as a result the heavier isotope¹⁸O was enriched. This enrichment can be seen in a very marked manner even in the upper 100 m of the sea. In our case the¹⁸O enrichment indicates that the mixing processes did not exchange the oxygen of the layers beneath the surface rapidly.  相似文献   

The Apure River: geochemistry of major and selected trace elements in an Orinoco River tributary coming from the Andes,Venezuela     

Abrahan Mora  Juan Carlos Baquero  Juan A. Alfonso  Daniel Pisapia  Laura Balza 《水文研究》2010,24(26):3798-3810

The analysis of physicochemical variables and selected dissolved elements was performed on the Apure River waters for 15 months. The variables pH, alkalinity, dissolved O₂, conductivity and Na, Ca, Mg and Cd concentrations showed maximum values during low water, whereas K, Si, Fe, Al, Mn, Zn, Cu, Cr and dissolved organic carbon (DOC) showed maximum concentrations during rising and high water. Five important factors were found to control the amount and temporal variability of the dissolved elements: lithology, hydrology, vegetation–floodplain processes, redox conditions and organic complexation. Weathering of silicates, carbonates and evaporites in the Andes provides most of the proportion of Na, Ca, Mg and HCO₃^? to waters. The temporal variability of these ions is controlled by a dilution process. Although Si can be taken up by the biomass, Si and K can be leached from the floodplain by weathering of clays. Microbial decay of the submerged plants in the floodplain during the inundation periods provides DOC and K to river waters and changes the redox conditions in water. The changing redox conditions control the solubility of Mn, Zn and Fe. Dissolved Mn is a function of pH‐dependent redox process, whereas Zn solubility is controlled by scavenging of Zn during the oxidation of Mn²⁺ to MnO₂. Positive relationships between Al, Fe, Cu, Cr and DOC suggest that these elements are complexed by organic colloids generated in the floodplain. Moreover, the binding capacity of Fe with DOC increases under reducing conditions. Although Cd seems to be provided by weathering in the Andes, several processes can affect the mobility of Cd during transport. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Chemistry of the crater lake during the 1971–1972 Soufrière eruption     

Haraldur Sigurdsson 《Journal of Volcanology and Geothermal Research》1977,2(2):165-186

During the 1971–1972 eruption of Soufrière volcano on St. Vincent Island, a lava mass was extruded subaqueously in the crater lake. An investigation of the chemistry of the lake indicates that over 50,000 tons of dissolved solids were taken into solution during the eruption, in addition to 9000 tons of iron precipitated as ferric oxide in syngenetic metalliferous sediments on the crater floor. Leaching of hot disintegrating lava and volcanic glass is the principal source of cations dissolved in the lake (Na, Ca, Mg, Si and K), whereas chlorine and sulfur were introduced during injection of acid volcanic gases from the submerged lava mass. Concentrations of the common cations in the lake are not affected by mineral solubility, except in the case of Fe³⁺, but rather by the rate of leaching, evaporation, and water-rock reactions. Variations in Cl/Na, total Cl and acidity have aided in identification of distinct fumarolic phases during the eruption, which may correlate with observed increase in frequency of minor volcanic tremors in the crater. Accumulation of ferric oxide in sediments on the crater floor is thought to be due to leaching of ferrous iron at high temperature from the lava mass, followed by oxidation and precipitation of hematite in the cooler lake.  相似文献   

Water balance estimation under the challenge of data scarcity in a hyperarid to Mediterranean region          下载免费PDF全文

Agnes Sachse  Christian Fischer  Jonathan B. Laronne  Hanna Hennig  Amer Marei  Olaf Kolditz  Tino Rödiger 《水文研究》2017,31(13):2395-2411

Water budget analyses are important for the evaluation of the water resources in semiarid and arid regions. The lack of observed data is the major obstacle for hydrological modelling in arid regions. The aim of this study is the analysis and calculation of the natural water resources of the Western Dead Sea subsurface catchment, one which is highly sensitive to rainfall resulting in highly variable temporal and spatial groundwater recharge. We focus on the subsurface catchment and subsequently apply the findings to a large‐scale groundwater flow model to estimate the groundwater discharge to the Dead Sea. We apply a semidistributed hydrological model (J2000g), originally developed for the Mediterranean, to the hyperarid region of the Western Dead Sea catchment, where runoff data and meteorological records are sparsely available. The challenge is to simulate the water budget, where the localized nature of extreme rainstorms together with sparse runoff data results in few observed runoff and recharge events. To overcome the scarcity of climate input data, we enhance the database with mean monthly rainfall data. The rainfall data of 2 satellites are shown to be unsuitable to fill the missing rainfall data due to underrepresentation of the steep hydrological gradient and temporal resolution. Hydrological models need to be calibrated against measured values; hence, the absence of adequate data can be problematic. Therefore, our calibration approach is based on a nested strategy of diverse observations. We calculate a direct surface runoff of the Western Dead Sea surface area (1,801 km²) of 3.4 mm/a and an average recharge (36.7 mm/a) for the 3,816 km² subsurface drainage basin of the Cretaceous aquifer system.  相似文献   

Manganese oxidation in pH and O2 microenvironments produced by phytoplankton     

Richardson LL  Aguilar C  Nealson KH 《Limnology and oceanography》1988,33(3):352-363

Pure cultures of Chlorella sp. catalyzed the oxidation of soluble Mn(II) to particulate, extracellular, manganic oxides. Manganese oxidation was dependent on photosynthetic activity: no oxidation was observed in the dark when cells were grown heterotrophically on glucose, or in the light when photosystem II was inhibited by the addition of DCMU. Manganates were not formed when media were buffered below pH 8.0, suggesting that an important driving force for manganese oxidation was the high pH resulting from photosynthesis. Field studies with minielectrodes in Oneida Lake, New York, demonstrated steep gradients of O2 and pH and the presence of particulate manganic oxides associated with pelagic aggregates of the cyanobacterium Microcystis sp. The manganese oxidation reaction apparently occurs only when photosynthesizing algae are present as dense populations that can generate microenvironments of high (>9.0) pH, either as aggregates in the pelagic zone or concentrated cell cultures in the laboratory. A large-scale transition from soluble to particulate manganese was measured in the surface waters of Oneida Lake throughout summer 1986. Removal of Mn(II) was correlated with the presence of aggregate-forming cyanobacteria that oxidize Mn(II) by the mechanism described above.  相似文献   

Hydrogeochemistry,contaminant transport and tectonic effects in the Okposi-Uburu salt lake area of Imo State,Nigeria     

BONIFACE C. E. EGBOKA  KALU O. UMA 《水文科学杂志》2013,58(2):205-221

ABSTRACT

Hydrogeochemical data of groundwater samples from 35 boreholes drilled in the Okposi-Uburu salt lake area are analysed. The data reveal that concentrations of dissolved geochemical constituents such as calcium (Ca²⁺), manganese (Mn²⁺), magnesium (Mg²⁺), chloride (C1^?), and sulphate (SO²⁺ ₄) ions show significant areal variations. Dissolved solids, chloride and manganese ions have concentrations up to and above the objectionable limits for drinking water in the salt lake area. Concentrations of dissolved solids in this zone are about 1200 mg 1^?1. Concentrations of chloride and manganese ions are 350 mg 1^?1 and 1.0 mg 1^?1 respectively. These geochemical constituents and groundwater flow patterns show that transport of contaminants away from the source zone has been greatly influenced by advection, while in areas of high velocity dispersion is the controlling factor. Temperatures for the Okposi and Uburu salt springs are 34.4 and 37.5°C respectively. Bomb tritium indicated water of pre-1953 age. Deuterium and oxygen-18 showed high isotopic enrichment. The high concentrations of dissolved salts resulted from the combined effects of migration of dissolved salts through fractures at the lake floor and evaporation from the lake surface. These findings are related to the tectonic history of the Okposi-Uburu area.  相似文献   

The estuarine chemistry and isotope systematics of U in the Amazon and Fly Rivers     

Peter Swarzenski  Pamela Campbell  Don Porcelli  Brent McKee 《Continental Shelf Research》2004,24(19):2357

Natural concentrations of ²³⁸U and δ²³⁴U values were determined in estuarine surface waters and pore waters of the Amazon and Fly (Papua New Guinea) Rivers to investigate U transport phenomena across river-dominated land–sea margins. Discharge from large, tropical rivers is a major source of dissolved and solid materials transported to the oceans, and are important in defining not only oceanic mass budgets, but also terrestrial weathering rates.On the Amazon shelf, salinity-property plots of dissolved organic carbon, pH and total suspended matter revealed two vastly contrasting water masses that were energetically mixed. In this mixing zone, the distribution of uranium was highly non-conservative and exhibited extensive removal from the water column. Uranium removal was most pronounced within a salinity range of 0–16.6, and likely the result of scavenging and flocculation reactions with inorganic (i.e., Fe/Mn oxides) and organic colloids/particles. Removal of uranium may also be closely coupled to exchange and resuspension processes at the sediment/water interface. An inner-shelf pore water profile indicated the following diagenetic processes: extensive (1 m) zones of Fe(III)—and, to a lesser degree, Mn(IV)—reduction in the absence of significant S(II) concentrations appeared to facilitate the formation of various authigenic minerals (e.g., siderite, rhodocrosite and uraninite). The pore water dissolved ²³⁸U profile co-varied closely with Mn(II). Isotopic variations as evidenced in δ²³⁴U pore waters values from this site revealed information on the origin and history of particulate uranium. Only after a depth of about 1 m did the δ²³⁴U value approach unity (secular equilibrium), denoting a residual lattice bound uranium complex that is likely an upper-drainage basin weathering product. This suggests that the enriched δ²³⁴U values represent a riverine surface complexation product that is actively involved in Mn–Fe diagenetic cycles and surface complexation reactions.In the Fly River estuary, ²³⁸U appears to exhibit a reasonably conservative distribution as a function of salinity. The absence of observed U removal does not necessarily imply non-reactivity, but instead may record an integration of concurrent U removal and release processes. There is not a linear correlation between δ²³⁴U vs. 1/²³⁸U that would imply simple two component mixing. It is likely that resuspension of bottom sediments, prolonged residence times in the lower reaches of the Fly River, and energetic particle–colloid interactions contribute to the observed estuarine U distribution. The supply of uranium discharged from humid, tropical river systems to the sea appears to be foremost influenced by particle/water interactions that are ultimately governed by the particular physiographic and hydrologic characteristics of an estuary.  相似文献   

²¹⁰Pb and²¹⁰Po during the destruction of stratification in the Dead Sea     

M. Stiller  A. Kaufman 《Earth and Planetary Science Letters》1984,71(2):390-404

The progressive weakening and final disappearance (in 1979) of the long-term meromictic structure of the Dead Sea are clearly reflected in the depth profiles of²¹⁰Pb and²¹⁰Po. In 1977/78, prior to overturn, dissolved²¹⁰Pb (35–50 dpm kg^?1) predominated over particulate²¹⁰Pb (1–2 dpm kg^?1) in the oxic upper waters, whereas the reverse was true in the anoxic deep waters (16–20 dpm kg^?1 particulate vs. 2–5 dpm kg^?1 dissolved). The exact extent of the disequilibrium between²¹⁰Pb and²²⁶Ra is hard to evaluate in the upper oxic layers, because the progressive deepenings resulted in mixing with deep waters. By contrast, one can estimate the residence time of dissolved²¹⁰Pb in the unperturbed anoxic deepest layers, because these remained isolated, at about 3 years. Following the overturn of 1979, dissolved²¹⁰Pb exceeded particulate²¹⁰Pb at all depths. The²¹⁰Po profiles of the stratified lake resembled in shape those of its grandparent²¹⁰Pb, but with distinct characteristics of their own in the oxic upper waters where particulate²¹⁰Po (8–12 dpm kg^?1) was greatly in excess over particulate²¹⁰Pb, while dissolved²¹⁰Po (25–40 dpm kg^?1) was slightly deficient. Immediately following the overturn, dissolved and particulate²¹⁰Po were similar (about 15 dpm kg^?1), at all depths. The destruction of the lake's meromictic structure was accompanied by a reduction of its²¹⁰Pb inventory, while that of²¹⁰Po was almost unaffected. Thus, at overturn a transient state was created with the inventory of²¹⁰Po exceeding that of²¹⁰Pb.  相似文献   

Helium-3 and manganese at the 21°N East Pacific Rise hydrothermal site     

J.E. Lupton  G.P. Klinkhammer  W.R. Normark  R. Haymon  K.C. MacDonald  R.F. Weiss  H. Craig 《Earth and Planetary Science Letters》1980,50(1):115-127

Water samples collected at the 21°N hydrothermal site on the East Pacific Rise crest, including Deep-Tow and hydrocast samples collected in 1977 and three hot vent water samples collected recently with the submersible “Alvin”, contain significant additions of³He,⁴He, and Mn. Although the vent water collections were at least 50-fold diluted with ambient seawater, they are up to 53 times enriched in³He and 7.4 times enriched in⁴He relative to saturated seawater, with concentrations of total dissolvable manganese (TDM) up to 310 μg/kg.³He and⁴He covary in the vent samples, with³He/⁴He about 8 times the atmospheric ratio, reflecting a mantle helium source. In contrast to the helium isotopes the Mn/³He ratio in the vent samples is variable, ranging from 4.3 × 10⁴ up to 1.0 × 10⁵ g/cm³. Profiles of³He/⁴He and TDM in the water column at 21°N show a sharp maximum ofδ(³He) = 47%and TDM= 0.69 μg/kg, much higher than the average values of 34% and 0.2 μg/kg for the deep water in this region. This spike in³He and Mn occurs at 2400 m depth, 200 m above the level of the 21°N vents, and 100 m higher than any local bathymetry, evidence for upward transport of the hydrothermal discharge via rising plumes of hot vent water. Two of the 21°N Deep-Tow samples associated with small (?0.010°C) temperature anomalies hadδ(³He) = 38%and TDM= 0.28 and 0.58 μg/kg, also slightly elevated relative to background. The Deep-Tow and hydrocast samples have lower Mn/³He ratios than average vent samples due to Mn removal by scavenging. Comparison of vent samples and water column measurements at 21°N indicate that the pure vent water could be detected using³He and Mn even when diluted ～10⁵ times with seawater, confirming that these two tracers are extremely sensitive indicators of submarine hydrothermal activity.  相似文献