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1.
Chondrules are the major high temperature components of chondritic meteorites which accreted a few millions years after the oldest solids of the solar system, the calcium–aluminum-rich inclusions, were condensed from the nebula gas. Chondrules formed during brief heating events by incomplete melting of solid dust precursors in the protoplanetary disk. Petrographic, compositional and isotopic arguments allowed the identification of metal-bearing Mg-rich olivine aggregates among the precursors of magnesian type I chondrules. Two very different settings can be considered for the formation of these Mg-rich olivines: either a nebular setting corresponding mostly to condensation–evaporation processes in the nebular gas or a planetary setting corresponding mostly to differentiation processes in a planetesimal. An ion microprobe survey of Mg-rich olivines of a set of type I chondrules and isolated olivines from unequilibrated ordinary chondrites and carbonaceous chondrites revealed the existence of several modes in the distribution of the ?17O values and the presence of a large range of mass fractionation (several ‰) within each mode. The chemistry and the oxygen isotopic compositions indicate that Mg-rich olivines are unlikely to be of nebular origin (i.e., solar nebula condensates) but are more likely debris of broken differentiated planetesimals (each of them being characterized by a given ?17O). Mg-rich olivines could have crystallized from magma ocean-like environments on partially molten planetesimals undergoing metal–silicate differentiation processes. Considering the very old age of chondrules, Mg-rich olivine grains or aggregates might be considered as millimeter-sized fragments from disrupted first-generation differentiated planetesimals. Finally, the finding of only a small number of discrete ?17O modes for Mg-rich olivines grains or aggregates in a given chondrite suggests that these shattered fragments have not been efficiently mixed in the disk and/or that chondrite formation occurred in the first vicinity of the breakup of these planetary bodies.  相似文献   

2.
Chondritic meteorites and their components formed in the protoplanetary disk surrounding the nascent sun. We show here that the two volumetrically dominating components of carbonaceous chondrites, chondrules and matrix did not form independently. They must have been derived from a single, common source. We analyzed Ca and Al in chondrules and matrix of the CV type carbonaceous chondrites Allende and Y-86751. The Ca/Al-ratios of chondrules and matrix of both chondrites are complementary, but in case of Allende chondrules have sub-chondritic and matrix super-chondritic Ca/Al-ratios and in case of Y-86751 chondrules have super-chondritic and matrix sub-chondritic Ca/Al-ratios. This rules out the redistribution of Ca between chondrules and matrix during parent body alteration. Tiny spinel grains in the matrix produce the high Al in the matrix of Y-86751. In Allende these spinels were most probably included in chondrules. The most plausible explanation for this Ca- and Al-distribution in the same type of chondrite is that both chondrules and matrix formed from the same chemical reservoir. Tiny differences in nebular conditions during formation of these two meteorites must have led to the observed differences. These are severe constraints for all models of chondrule formation. Any model involving separate formation of chondrules and matrix, such as the X-wind model can be excluded.  相似文献   

3.
Recent models of Ca, Al-rich inclusion (CAI) petrogenesis suggest that refractory inclusions may be residues of interstellar dust aggregates that were incompletely evaporated and partially melted in the solar nebula. These models, and the recent availability of new thermodynamic data, have led us to re-examine the traditional interpretation that lithophile refractory trace elements (LRTE) condensed as oxides in solid solution in refractory major condensates, while refractory noble metals (RNM) condensed as micron-sized nuggets of Pt-metal alloys. Calculations of LRTE-RNM alloy stability fields under nebular oxygen fugacities and partitioning experiments lead us to conclude that: (1) Ti, Zr, Nb, Hf, U, and Ta form stable alloys with RNM under nebular conditions; (2) the observation that metallic Zr, Nb, and Ta occur in some Pt-metal nuggets and grains is explained by the stability of these LRTE-RNM alloys under normal nebular oxygen fugacities; (3) metallic Ti, Hf, and U may also occur in some nuggets; (4) the lanthanides, the other actinides (Th, Pu), and Y do not form stable alloys, and thus probably do not occur alloyed with RNM; and (5) the partitioning of U (but not Th, Pu, or the REE) into RNM is a novel actinide and REE/actinide fractionation mechanism that is based on metal/silicate fractionation (rather than on the relative volatility of their oxides).We propose that micron-sized Pt-metal nuggets formed from smaller grains of RNM alloys and compounds during the evaporation and melting of primitive dust aggregates. This process would have been enhanced by: (1) the possibility that the RNM were present as compounds (especially with As and S) as well as metallic alloys in interstellar dust and in some primitive meteoritical material, since they often exhibit non-siderophile behavior; and (2) the fluxing of volatiles through CAI's during distillation. Microscopic nuggets are common in melilite chondrules, indicating that residence in a slowly-cooled silicate melt may have favored their formation. Cation diffusivity and variations in localfO2 can explain why metallic LRTE-bearing nuggets are not common in CAI's (despite the relative stability of LRTE-RNM alloys). We propose that the lithophile component of Fremdlinge is enriched in super-refractory elements, and that Group II CAI's formed from Fremdlinge-poor dust. We interpret the Group II REE fractionation as a pre-solar event, and predict that Nd/Sm dating will yield an age greater than the canonical age of the solar system. If metal/silicate fractionation in a cold solar nebula can explain Group II REE patterns, the possibility that Group II CAI's are also distillation residues cannot be excluded.  相似文献   

4.
The association between agglutinates and chondrule-like spherules, which characterizes the assemblage of impact-derived melt products in lunar regolith samples and some gas-rich achondrites, is not found in primitive chondrites. This observation suggests that impacts into a parent-body regolith are unlikely to have produced the chondrules. We believe that if chondrules were formed from impact melt, it was probably generated by jetting during particle-to-particle collisions, presumably in the nebula.  相似文献   

5.
Allan Hills 85085 is a chemically and mineralogically unique chondrite whose components have suffered little metamorphism or alteration. This chondrite is unique because it has fewer and smaller chondrules (4 wt. %; mean diameter 16 μm) than any other chondrite, more metallic Fe,Ni (36%) and lithic and mineral silicate fragments (56%), and a lower abundance of troilite (2%) and volatiles. Most chondrules are cryptocrystalline or glassy and are depleted in volatiles, some small chondrules are also very depleted in refractory lithophiles. Matrix lumps (4%) partly resemble CI and CM matrices and may be foreign to the parental asteroid. Despite these differences, the components of ALH 85085 have some features common to most type 2 and the least metamorphosed type 3 chondrites: metallic Fe,Ni grains that contain 0.1–1 wt.% Cr, Si and P; Fe/(Fe + Mg) values of olivines, pyroxenes and chondrules are concentrated in the range 1–6 at.% with a few percent in the range 7–30%; porphyritic chondrules are chondritic in composition (except for their low volatile abundances). Thus the components of ALH 85085 probably have similar origins to those of components in other chondrites, and their properties largely reflect nebular, not asteroidal, processes.The bulk composition of ALH 85085 fits none of the nine groups of chondrites: it is richer in Fe (1.4 × CI levels when normalized to Si) and poorer in Na and S (0.1–0.2 × CI) than other chondrites. Low volatile concentrations are due to a low matrix abundance and loss of volatiles during or prior to chondrule formation, not to volatile loss during metamorphism. Chondrule textures imply extensive heating of chondrule melts above the liquidus, consistent with loss of volatiles from small volumes of melt during chondrule formation. The small size of chondrules is partly due to extensive fragmentation by impacts, which may have occurred on the parent asteroid or in the solar nebula. Collisions between chondrule precursor aggregates in the nebula could also be responsible for the small sizes of chondrules.Assuming that ALH 85085 is a representative sample of an asteroid, its properties lend support to models for the origins of the Earth, eucrite parent body and volatile-poor iron meteorites that invoke chondritic planetesimals depleted in volatiles. The existence of ALH 85085 and Kakangari suggests that the nine chondrite groups may provide a remarkably poor sample of the primitive chondritic material from which the asteroids formed. Certain similarities between ALH 85085 and Bencubbin and Weatherford suggest that the latter two primitive meteorites may actually be chondrites with even higher metal abundances (50–60 wt.%) and very large, partly fragmented chondrules.  相似文献   

6.
The origin of olivine grains isolated in the matrix of C2 carbonaceous chondrites is an important problem. If these grains are condensates from a solar nebular gas, they contain compositional, isotopic and physical features that further elucidate that process. If, however, they are grains released by the breakup of chondrules, then many important condensation features have been lost during the melting that took place to form chondrules.In evaluating these two possibilities, care must be taken to determine which inclusions in C2 meteorites are actual chondrules and which are aggregates of grains that have never undergone melting. The two main types of aggregates, pyroxene-rich and pyroxene-poor, are forty to fifty times more abundant than chondrules. Four scenarios are presented to account for the kinds of aggregates and isolated grains seen in the Murchison C2 meteorite. An analysis of these scenarios is made in light of olivine crystal morphology, comparison of composition of glass inclusions inside olivine grains with interstitial glass in true chondrules and size distributions of olivines, isolated, in aggregates and in chondrules.It is concluded that no scenario that includes a chondrule-making step can account for the observed population of isolated olivine grains. An origin by direct condensation, partial comminution, aggregation and accretion best accounts for the sizes and morphological features observed.  相似文献   

7.
Petrographic and chemical studies of the Qingzhen chondrite strongly suggest that it is the most highly unequilibrated (type 3) enstatite chondrite recognized so far. Qingzhen contains abundant, well-defined chondrules, some of which were incompletely molten during the chondrule formation process. The relict olivine grains within these chondrules contain dusty inclusions of almost pure metallic Fe, which appear to be the in-situ reduction product of the fayalitic component of the olivine. The reduction process presumably took place at the time of chondrule formation and the chondrule precursor material must have been more oxidized than average enstatite chondrite material. We believe that this oxidized material may have formed at the enstatite chondrite formation location in the solar nebula, provided fluctuations in the degree of oxidation of the nebular gas existed at such locations. Reheating of this material under more reducing conditions would lead to the observed reduction of the olivine. Igneous olivines within chondrules always contain detectable amounts of CaO, while relict olivines are essentially CaO-free. This seems to suggest that the relict olivines did not originate during a previous igneous process of chondrule formation and might represent condensation products from the early solar nebula.  相似文献   

8.
Solar abundances based on recent laboratory oscillator strengths confirm the relationship between solar matter and carbonaceous chondrites. Within spectroscopic uncertainties (typically±40%) these meteorites contain refractory and volatile elements in solar proportions. Significant improvement of accuracy at present seems restricted to a few abundant elements having reliable quantum-mechanical oscillator strengths, and necessitates strictly differential spectrum analysis. Taking this into account, the solar abundance ratios Na/Ca and S/Ca have been determined to an accuracy of±15%. The results are:Na/Ca= 0.91and S/Ca= 6.8. These volatile/refractory ratios just match type 1 carbonaceous chondrites, but contrast with other types.These and related interstellar abundance features place constraints on the condensation process and a potential heterogeneity of the solar nebula. There is evidence that no drastic pre-solar separation of interstellar gas and grains has occurred, but minor imbalance may be a common mechanism co-determining stellar metal content.  相似文献   

9.
This paper presents the results of a disaggregation and thin section analysis of the size distribution of chondrules in two friable meteorites, Bjurböle and Chainpur. Dodd [Earth Planet. Sci. Lett. 30 (1976) 281] found in chondrites that the size distribution of metal and silicate particles (be they chondrules, chondrule fragments or independent grains in the matrix) obey Rosin's law. He used thin sections of meteorites. Martin and Mills [Earth Planet. Sci. Lett. 33 (1976) 239] imply that thin section studies are not valid and that meteoritic disaggregation and the subsequent measurement of the individual particles is required. They found that the “near-spherical” chondrules picked out from the disaggregated meteorite do not obey Rosin's law and suggest that these chondrules result from the melting of dust, rather than from impact as suggested by Dodd. The Rosin's law criterion could be crucial to the acceptabilities of these theories.In thin sections both droplet and lithic fragment chondrules can be easily identified. The Bjurböle section had 33 ± 4% of its area occupied by droplet chondrules and 30 ± 3% occupied by lithic fragment chondrules. The matrix occupied 37 ± 2%. Disaggregation of 4 g of Bjurböle produced 27% (by mass) near-spherical chondrules. The lithic fragment chondrules had a degree of friability similar to that of the matrix. Due to this they unfortunately broke up during the disaggregation process. The size distribution of droplet and lithic fragment chondrules was found to be similar. All chondrules were found to obey Rosin's law.The size distribution of the disaggregated chondrules has been used to calculate the expected thin section size distribution by assuming that chondrules are sectioned randomly. Empirical correction factors have thus been obtained which enable observed thin-section parameters to be converted into true parameters. The observed and expected thin section distributions agreed well. On disaggregation 4 g of Bjurböle yielded 955 near-spherical chondrules. A 0.78-cm2 thin section of Bjurböle revealed 61 droplet and 57 lithic fragment chondrules so to obtain comparable precision large (~10 cm2) thin sections or slices must be used.The near-spherical chondrules disaggregated from Bjurböle had a median diameter of 0.688 ± 0.003 mm, a mean density of 3.258 ± 0.008 g cm?3 and a median mass of 5.6 × 10?4 g. Their diameters ranged between 0.25 ± 0.01 mm and 3.67 mm. The lower limit is considerably below the value of 0.4 mm obtained by Martin and Mills.  相似文献   

10.
Chondrules were extracted from a disaggregated sample of the Allegan meteorite. Individual chondrules were examined with apparatus incorporating two orthogonal binocular microscopes, and their three major axes measured. Maximum chondrule diameters ranged from 0.15 to 2.75 mm with a peak in distribution between 0.35 and 0.75 mm. The chondrule size distribution was found not to conform to Rosin's law. The chondrules were found to depart from sphericity by only small amounts. The authors still believe that the melting of nebula dust-ball agglomerates by some high-energy event was the most probable mechanism for the formation of chondrules.  相似文献   

11.
Magnetite in the oxidized CV chondrite Allende mainly occurs as spherical nodules in porphyritic-olivine (PO) chondrules, where it is associated with Ni-rich metal and/or sulfides. To help constrain the origin of the magnetite, we measured oxygen isotopic compositions of magnetite and coexisting olivine grains in PO chondrules of Allende by an in situ ion microprobe technique. Five magnetite nodules form a relatively tight cluster in oxygen isotopic composition with delta 18O values from -4.8 to -7.1% and delta 17O values from -2.9 to -6.3%. Seven coexisting olivine grains have oxygen isotopic compositions from -0.9 to -6.3% in delta 18O and from -4.6 to -7.9% in delta 17O. The delta 17O values of the magnetite and coexisting olivine do not overlap; they range from -0.4 to -2.6%, and from -4.0 to -5.7%, respectively. Thus, the magnetite is not in isotopic equilibrium with the olivine in PO chondrules, implying that it formed after the chondrule formation. The delta 17O of the magnetite is somewhat more negative than estimates for the ambient solar nebula gas. We infer that the magnetite formed on the parent asteroid by oxidation of metal by H2O which had previously experienced minor O isotope exchange with fine-grained silicates.  相似文献   

12.
(1) The observed anomalies in meteoritic oxygen isotope compositions are not due to an incomplete mixing of several dust or gas-plus-dust components in the solar nebula. If they were, other elements would display similar anomalies. (The FUN inclusions in Allende appear to be exceptions to this premise.) (2) The anomalies must therefore stem from differing degrees of incomplete exchange of oxygen isotopes between the primordial gas and dust components of the nebula. The dust is more likely to have been the16O-enriched component. (3) Since the isotopic difference between dust and gas probably could not have been preserved if the dust was ever completely vaporized in the nebula, the Ca,Al-rich inclusions (CAI's) in carbonaceous chondrites are unlikely to be condensates, but instead are distillation residues. (4) If so, the observed depletion of super-refractory elements in the Group II CAI's cannot have been accomplished by fractional condensation in the solar nebula. (5) Then this depletion, and a number of other properties of the components of primitive meteoritic material, must be relics of pre-solar system fractionations among different populations of interstellar dust grains.  相似文献   

13.
Microprobe analyses of 33 melt pocket glasses in five L6d and L6e chondrites show them to be chemically varied but typically enriched in the constituents of plagioclase relative to the host meteorites. This enrichment appears to increase with the degree of melting (0–6.5 vol.%), but other chemical variations among the glasses (sodium depletion, reduction of ferrous iron) appear to be unrelated to shock intensity and melt abundance.Chemical trends for melt pocket glasses differ sharply from those reported for chondrules in ordinary chondrites. Thus partial shock melting of chondritic material is an inadequate explanation for the chemical properties of chondrules.  相似文献   

14.
New, high-precision W isotope data on iron meteorites are presented that provide important constraints on the timing of silicate–metal segregation in planetesimals. Magmatic iron meteorites all have ε182W within error or less radiogenic than initial ε182W estimated by studies of chondritic meteorites. At face value this implies that iron meteorites are as old and older than refractory calcium–aluminium rich inclusions (CAI), which are widely thought to be the oldest solar system objects. Moreover, different meteorites from the same magmatic groups, believed to be derived from the same planetissimal core, display a range of ε182W. We suggest that the paradoxical ε182W values more negative than initial Solar System Initial (SSI) are most readily explained as a result of secondary, spallation reactions with cosmic rays during transit between parent body and the earth. This is supported by the most negative ε182W being found in meteorites with the oldest exposure ages and the magnitude of the effect is shown to be consistent with known nuclear reactions. On the other hand, it is also striking that none of the magmatic iron group meteorites have ε182W analyses, outside error, more radiogenic than the estimated solar system initial ratio. This suggests that core formation in parent bodies of magmatic iron meteorites occurred ≤ 1.5 Myr after the formation age of CAI [Y. Amelin, A.N. Krot, I.D. Hutcheon, and A.A. Ulyanov, Lead isotopic ages of chondrules and calcium-aluminum inclusions, Science 297, 1678–1683, 2002]. This extremely early metal–silicate differentiation is coeval with the first chondrules [M. Bizzarro, J.A. Baker, and H. Haack, Mg isotope evidence for contemporaneous formation of chondrules and refractory inclusions, Nature 431, 275–278, 2004, A.N. Krot, Y. Amelin, P. Cassen, and A. Meibom, Young chondrules in CB chondrites from a giant impact in the early Solar System, Nature 436, 989–992, 2005]. Formation of later chondrules, and hence the parent bodies of some chondritic meteorites, must therefore have occurred in the presence of planetesimals large enough to possess iron cores. We conclude that early planetary accretion and differentiation was sufficiently fast for 26Al-decay to be an important heat source. Non-magmatic iron meteorites, however, display more radiogenic and varied W isotope signatures. This is in keeping with them being generated later, by impact melting during which the metal (partially) re-equilibrated with the then more radiogenic silicate fraction.  相似文献   

15.
Granoblastic olivine aggregates (GOA) have been discovered in some Type I magnesian chondrules within carbonaceous chondrites by Libourel and Krot [Libourel, G., Krot, A.N., 2007. Evidence for the presence of planetesimal material among the precursors of magnesian chondrules of nebular origin. Earth Planet. Sci. Lett. 254, 1–8], who proposed an origin from pre-existing planetesimals. Amoeboid olivine aggregates (AOA), generally considered as aggregates of solar nebula condensates and found within similar carbonaceous chondrites, display similar equilibrium texture, though on a finer scale. For these reasons, we conducted experiments to determine if annealing of olivine required time scales appropriate to planetesimal or nebular heating. Pressed < 43 µm and < 63 µm San Carlos olivine powder (Fo88.4) was isothermally heated at temperatures ranging from 1350–1550 °C for 1–100 h. The 100 h runs yield olivine aggregates with well-developed granoblastic texture at all temperatures, manifest as a network of randomly-oriented and sutured olivine grains with 120° triple junctions. Individual olivine grains are 4–6 sided and polygonal by 1450 °C and equigranular texture is developed at high temperature (1500–1550 °C). Melting of olivine commences at 1450–1500 °C and aids in ‘ripening’ and suturing (grain coarsening and grain boundary migration). Textural equilibrium is clearly met at 1550 °C. A planetesimal origin cannot be ruled out; however, the experimental evidence reveals that granoblastic texture can be reproduced in an interval not inconsistent with heating times for nebular objects. GOA may have experienced higher degrees of thermal processing than the finer-grained AOA. If the precursors were the same, grain coarsening would have to be accompanied by modification to bulk and isotopic compositions. However, the precursors could have been olivine condensates formed later than AOA. Annealing may have been a widespread process operating in the primordial solar nebula responsible for thermal processing and formation of GOA prior to their incorporation into chondrules.  相似文献   

16.
Thermomagnetic and microprobe studies of native iron in the terrestrial upper-mantle hyperbasites (xenoliths in basalts), Siberian traps, and oceanic basalts are carried out. The results are compared to the previous data on native iron in sediments and meteorites. It is established that in terms of the composition and grain size and shape, the particles of native iron in the terrestrial rocks are close to each other and to the extraterrestrial iron particles from sediments and meteorites. This suggests that the sources of the origin of these particles were similar; i.e., the formation conditions in the Earth were close to the conditions in the meteorites’ parent bodies. This similarity is likely to be due to the homogeneity of the gas and dust cloud at the early stage of the solar system. The predominance of pure native iron in the sediments can probably be accounted for by the fact that interstellar dust is mostly contributed by the upper-mantle material of the planets, whereas the lower-mantle and core material falls on the Earth mainly in the form of meteorites. A model describing the structure of the planets in the solar system from the standpoint of the distribution of native iron and FeNi alloys is proposed.  相似文献   

17.
The origin of olivine grains in C2 carbonaceous chondrites is a controversial topic: directly condensed material or detrital remnants of preexisting chondrules? This study shows that the Niger C2 meteorite is similar to Murchison but reveals several interesting features in relation to the origin of the olivine. Microprobe analysis of olivine (Si, Fe, Mg, Ca, Mn, Cr), glass and nickel-iron inclusions within the grains, and Fe-S-O phase as well as the relationships between the olivine grains in the aggregates, between the grains and the interstitial phyllosilicate matrix, between the inclusions and their host olivine grains, and the morphology of some aggregates all show that two populations of olivine coexist, probably crystallized from chondrule melts rather than by direct condensation from a solar nebula gas. The characteristics of the nickel-iron inclusions within the olivine suggest a magmatic chondrule-making stage from previously condensed materials.  相似文献   

18.
SmNd isotopic data for mineral separates from the ferroan anorthosite 60025 define a precise isochron of 4.44 ± 0.02Ga age. This age is roughly 110 m.y. younger than the formation of the first large solid objects in the solar nebula, as recorded by the radiometric ages of the differentiated meteorites. In the magma ocean model for early lunar differentiation, ferroan anorthosites are the first crustal rocks to form on the Moon. If the Moon is as old as the oldest meteorites, the relatively young age determined for 60025 implies either that the magma ocean did not form synchronously with lunar formation, or that the magma ocean required over 100 m.y. before reaching the stage of ferroan anorthosite crystallization. Alternatively, we propose that the accumulated body of radiogenic isotope data for lunar rocks permit the Moon to be as young as 4.44–4.51 Ga. If so, isotopic evidence for chemical differentiation on the Earth at about this same time suggests that the formation of the Moon is reflected in the chemical evolution of the Earth. This, in turn, is consistent with the idea that the materials that now make up the Moon were derived from the Earth, perhaps ejected by collision between the Earth and another very large planetesimal during the final stages of accumulation of the terrestrial planets. Terrestrial origin models for the Moon lessen the requirement that the Earth and Moon each have near chondritic relative abundances of the refractory elements and could require that certain chemical and isotopic characteristics of both bodies be considered in the framework of the chemical mass-balance of the combined Earth-Moon system.  相似文献   

19.
Cosmic dust grains, whatever their origin may be, have probably suffered a complex sequence of events including exposure to high doses of low-energy nuclear particles and cycles of turbulent motions. High-voltage electron microscope observations of micron-sized grains either naturally exposed to space environmental parameters on the lunar surface or artificially subjected to space simulated conditions strongly suggest that such events could drastically modify the mineralogical composition of the grains and considerably ease their aggregation during collisions at low speeds. Furthermore, combined mass spectrometer and ionic analyzer studies show that small carbon compounds can be both synthesized during the implantation of a mixture of low-energy D, C, N ions in various solids and released in space by ion sputtering. The present results have implications concerning the origin of small molecules in interstellar or circumstellar clouds, the “aging” of cosmic dust grains in space, and the “sticking” process in the solar nebula.  相似文献   

20.
Rims or rim sequences surrouding chondrules have been identified in carbonaceous and unequilibrated ordinary chondrites. These chondrule rims include three chemical subtypes: Fe,Ca-rich and Fe,Ni-metal-rich rims, which occur predominantly in Kainsaz (CO3), and ferromagnesian rims which occur in Kainsaz (CO3), Allende (CV3), Renazzo (CR2), Chainpur (LL3), Semarkona (LL3), Krymaka (L3), and Tieschitz (H3). The compositions of minerals in these rims are often drastically different from those in the underlying chondrule cores, indicating that the solar nebula was chemically heterogeneous. In many cases the compositions of the rims require an environment that was much more oxidizing than a solar composition gas. Particularly interesting is that some of the Fe,Ca-rich chondrule rims are remarkably similar to some of the rims around refractory inclusions, suggesting that chondrules and refractory inclusions experienced late, coeval processing. The textures of the chondrule rims suggest they formed at high temperatures and that they accreted onto chondrules that had already solidified. The lengthscale of the thermal heterogeneities necessary to make available hot material that could accrete to cold chondrules has been calculated to be less than 10 km, implying there were localized heat sources in the solar nebula.  相似文献   

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