共查询到20条相似文献，搜索用时 31 毫秒
1.
We conducted powder neutron diffraction for δ-AlOOH samples with and without Mg and Si ions under ambient conditions in order
to investigate the long-standing problem of the symmetry of this phase. The observed reflection conditions clearly show that
the space group of pure δ-AlOOH is P21
nm with ordered hydrogen bonds, whereas that of δ-(Al0.86Mg0.07Si0.07)OOH is Pnnm or Pnn2 with disordered hydrogen bonds. It is more likely that the space group of δ-(Al0.86Mg0.07Si0.07)OOH is Pnnm, because cation or hydrogen ordering that breaks the mirror plane perpendicular to c axis in the Pnnm structure would not occur. The previously reported inconsistency for the space group of this phase was caused by the substitution
of Mg and Si ions to Al site, i.e., the disordered cations with different valences may fluctuate hydrogen positions, and the
disordered hydrogen causes the symmetry change. 相似文献
2.
A. Råheim 《Australian Journal of Earth Sciences》2013,60(5-6):329-338
Important mineral assemblages of metapelite and quartzite of the Strathgordon area are phengite + chlorite + tourmaline + quartz and phengite + garnet + chlorite + tourmaline + quartz. Over a limited area the Si4+‐content of phengite does not vary significantly and is considered to depend only on the PT regime. The Si4+‐content of phengite coexisting with almandine‐grossular‐spessartine garnet and tourmaline indicate that the maximum metamorphism of the area occurred at 400 ± 50°C and 3 ± 1 kb. 相似文献
3.
4.
Recent experimental studies have shown that the rates of Al–Si order-disorder and interdiffusion in alkali feldspars at high pressures under dry conditions increase dramatically in the approximate pressure range 7–14 kb, depending on temperature and feldspar composition (Goldsmith 1987, 1988). Enhancement of Al–Si interdiffusion rates is ascribed to the involvement of hydrogen, but the species of hydrogen involved is undetermined.A simple kinetic analysis of the data of Goldsmith (1987) on disordering of dry albite at 800°–950° C and 6–24 kb in the solid media press is consistent with the NaCl pressure cell acting as a proton donor by enhancing dissociation of water in the pressure medium, generating a high
in the experimental environment. The rate constant for disordering of albite is found to increase linearly with the estimated experimental
and with the density of aqueous salt solution, implicating H+ as the rate-enhancing species.Further experimental studies confirm the importance of
. At 16 kb and 850° C, dry albite in sealed Pt capsules in a NaCl cell containing tantalum powder (which reduces H2O to H2) remains highly ordered over the same time that complete disordering would occur in the absence of Ta. H2 cannot therefore be the rate-enhancing species. At 1 kb and 850° C, the extent of Al–Si disorder in albite in direct contact with various NaCl–H2O solutions increases from partially disordered for pure H2O to completely disordered for saturated aqueous NaCl solution, giving strong support to the proton model. SIMS scanning ion imaging of albite run products demonstrates conclusively that solution-reprecipitation is not responsible for enhanced disordering rates.Results of disordering experiments in the solid media apparatus cannot be duplicated in Ar gas media internally-heated pressure vessels, even with the same experimental configuration around the albite-bearing capsules, due to the different proton-buffering capacities of the solid and gas media apparatus. 相似文献
5.
The effect of the Si/Al distribution in the tetrahedral sheets of the vermiculite mineral has been investigated employing density functional theory. The structures of six models for vermiculite with the structural formula (Mg4)(Mg12)(Si8Al8)O40(OH)8·24(H2O) per unit cell were fully optimized. The models differ by the T···Mg2+···T coordination of the interlayer Mg2+ cations by two central cations from the adjacent tetrahedral sheets of the 2:1 vermiculite layers (T,T=Si,Al). We observed the formation of very strong hydrogen bonds between water molecules solvating the interlayer Mg2+ cations and the surface basal oxygen atoms of the 2:1 layers. The directionality of hydrogen bonds is the major factor determining the layer stacking in the vermiculite structure. Results showed that the most stable model is that where only silicon atoms in the tetrahedral sheets coordinate all interlayer Mg2+ cations. 相似文献
6.
We present a model of the global biogeochemical cycle of silicon (Si) that emphasizes its linkages to the carbon cycle and temperature. The Si cycle is a crucial part of global nutrient biogeochemistry regulating long-term atmospheric CO2 concentrations due to silicate mineral weathering reactions involving the uptake of atmospheric CO2 and production of riverine dissolved silica, cations and bicarbonate. In addition and importantly, the Si cycle is strongly coupled to the other nutrient cycles of N, P, and Fe; hence siliceous organisms represent a significant fraction of global primary productivity and biomass. Human perturbations involving land-use changes, burning of fossil fuel, and inorganic N and P fertilization have greatly altered the terrestrial Si cycle, changing the river discharge of Si and consequently impacting marine primary productivity primarily in coastal ocean waters. 相似文献
7.
8.
《Russian Geology and Geophysics》2015,56(11):1622-1633
The 1370 km long 4-AR reference profile crosses the North Barents Basin, the northern end of the Novaya Zemlya Rise, and the North Kara Basin. Integrated geophysical studies including common deep point (CDP) survey and deep seismic sounding (DSS) were carried out along the profiles. The DSS was performed using autonomous bottom seismic stations (ABSS) spaced 10–20 km apart and a powerful air gun producing seismic signals with a step size of 250 m. As a result, detailed P- and S-wave velocity structures of the crust and upper mantle were studied. The basic method was ray-tracing modeling. The Earth’s crust along the entire profile is typically continental with compressional wave velocities of 5.8–7.2 km/s in the consolidated part. Crustal thickness increases from 30 km near the islands of Franz Josef Land to 35 km beneath the North Barents Basin, 50 km beneath the Novaya Zemlya Rise, and 40 km beneath the North Kara Basin. The North Barents Basin 15 km deep is characterized by unusually low velocities in the consolidated crust: The upper crust layer with velocities of 5.8–6.4 km/s has a thickness of about 15 km beneath the basin (usually, this layer wedges beneath deep sedimentary basins). Another special property of the crust in the North Barents Basin is the destroyed structure of the Moho. 相似文献
9.
Zubkova N. V. Pekov I. V. Pushcharovskii D. Yu. Kazantsev S. S. 《Doklady Earth Sciences》2009,427(1):814-818
Doklady Earth Sciences - Using X-ray analysis, the crystal structure of yegorovite Na4[Si4O8(OH)4] · 7H2O, a newly-discovered mineral from the Lovozero alkaline complex (Kola Peninsula,... 相似文献
10.
The nature of the solubility of water as [4H]Si defects in quartz, and their role in providing a source of molecular water on heating, is investigated. Existing ab inito energy calculations on the incorporation of water in quartz are used to show that energetically 4H for Si substitution is likely to constitute the most prevalent mode of water uptake on the atomic scale in quartz under equilibrium conditions, and that the planar defects previously observed by a number of different authors by electron microscopy in wet quartz are likely to be planar rafts of aggregated [4H]Si defects which are formed on supersaturation. These new conclusions call into question the previous identification of the planar defects as high pressure water clusters and require that their role in the production of molecular water in the context of recent theories of hydrolytic weakening be re-assessed. Accordingly the existing ab initio results have been used to establish the characteristics of the phase diagram for the system quartz-water in the temperature and pressure range of interest in hydrolytic weakening. Additional electron-optical experiments on wet quartz show that, on annealing at temperature in the electron microscope, similar planar defects develop in wet quartz by a diffusion process. In the context of existing theories of hydrolytic weakening it is now proposed that the conversion of [4H]Si defects to molecular water, where this is dictated by the equilibrium phase diagram, leads to a relatively large increase in volume and to the appearance of the bubbles of free water and the nucleation of associated prismatic dislocation loops of Burgers vector b=1/3 a $\langle 11\bar 20\rangle $ as previously observed. Ultimately the development of these loops leads to dislocation-induced plasticity. 相似文献
11.
Mochalov A. G. Yakubovich O. V. Stuart F. M. Bortnikov N. S. 《Doklady Earth Sciences》2021,498(1):372-378
Doklady Earth Sciences - This article presents the 190Pt–4He dating results of native platinum group minerals from a unique platinum-metals placer deposit in the basin of the Kondyor and... 相似文献
12.
Koroteev V. A. Chervyakovskiy V. S. Zaitseva M. V. Volchek E. N. Necheukhin V. M. 《Doklady Earth Sciences》2019,487(1):756-760
Doklady Earth Sciences - This paper reports on the first U–Pb dating of zircons from dacites of the volcanic paleo-edifice of the andesite–dacite complex of the Eastern Zone of the... 相似文献
13.
《Geochimica et cosmochimica acta》1993,57(16):3847-3853
Ab initio, molecular orbital calculations at the 6-31G1 level including second-order Møller-Plesset electron correlation predict that the species [Si(OH)5]1− is dynamically stable in a distorted trigonal bipyramid configuration. Reaction pathways for Si(OH)4 + (OH)− → [Si(OH)5]1− → [(OH)3SiO]1−—H2O are also calculated. The first reaction represents the formation of pentacoordinate Si from orthosilicic acid and hydroxide. The activation energy for adding a fifth Si-(OH)− bond to the Si(OH)4 molecule is ≈0.1 eV /molec (≈10kJ/mol). The second reaction is the deprotonation of the Si(OH)4 which forms as a hydroxyl group leaves the [Si(OH)5]1− molecule. Removal of a bond from this complex requires 0.9 eV/molecule (≈85 kJ/mol). Lengthening the Si—OH2 distance results in the isolated molecules [(OH)3SiO]1− + H2O. This represents dehydration of the deprotonated orthosilicic acid.[Si(OH)5]1− and [(OH)3SiO]1−- H2O have the same energetic stability within the accuracy of these calculations. The potential energies of the isolated molecular systems [(OH)3SiO]1−+ H2O and Si(OH)4 + (OH)− are considerably higher. These results suggest that [Si(OH)5]1− may be a stable species or reaction intermediate in dissolution of silicate minerals in basic aqueous solutions. 相似文献
14.
Hagen-Thorn V. A. Troitskaya Yu. V. Hagen-Thorn E. I. Troitsky I. S. Savchenko S. S. Arharov A. A. Efimova N. V. Klimanov S. K. Volkov E. V. 《Astronomy Reports》2019,63(5):378-390
The results of multicolor photometric and polarization observations of the blazar 4C 38.41 (Q 1633+382) performed at St. Petersburg State University, the Pulkovo Astronomical Observatory of the Russian Academy of Sciences, Boston University, and Steward Observatory in 2006–2017 are analyzed. Separate variable sources responsible for the observed activity are distinguished, whose power-lawspectra and high degree of polarization confirm their synchrotron nature. The observed color variability of the object (redder when brighter) can be explained by an increase in the contribution to the total emission of a red component with variable flux and a constant relative spectral energy distribution. A close correlation between the optical and gamma-ray light curves is identified, suggesting the same location of the variable sources responsible for the radiation in these bands.
相似文献15.
T. Shinmei T. Sanehira D. Yamazaki T. Inoue T. Irifune K. Funakoshi A. Nozawa 《Physics and Chemistry of Minerals》2005,32(8-9):594-602
Thermal equation of state of an Al-rich phase with Na1.13Mg1.51Al4.47Si1.62O12 composition has been derived from in situ X-ray diffraction experiments using synchrotron radiation and a multianvil apparatus at pressures up to 24 GPa and temperatures up to 1,900 K. The Al-rich phase exhibited a hexagonal symmetry throughout the present pressure–temperature conditions and the refined unit-cell parameters at ambient condition were: a=8.729(1) Å, c=2.7695(5) Å, V 0=182.77(6) Å3 (Z=1; formula weight=420.78 g/mol), yielding the zero-pressure density ρ0=3.823(1) g/cm3 . A least-square fitting of the pressure-volume-temperature data based on Anderson’s pressure scale of gold (Anderson et al. in J Appl Phys 65:1534–543, 1989) to high-temperature Birch-Murnaghan equation of state yielded the isothermal bulk modulus K 0=176(2) GPa, its pressure derivative K 0 ′ =4.9(3), temperature derivative (?K T /?T) P =?0.030(3) GPa K?1 and thermal expansivity α(T)=3.36(6)×10?5+7.2(1.9)×10?9 T, while those values of K 0=181.7(4) GPa, (?K T /?T) P =?0.020(2) GPa K?1 and α(T)=3.28(7)×10?5+3.0(9)×10?9 T were obtained when K 0 ′ was assumed to be 4.0. The estimated bulk density of subducting MORB becomes denser with increasing depth as compared with earlier estimates (Ono et al. in Phys Chem Miner 29:527–531 2002; Vanpeteghem et al. in Phys Earth Planet Inter 138:223–230 2003; Guignot and Andrault in Phys Earth Planet Inter 143–44:107–128 2004), although the difference is insignificant (<0.6%) when the proportions of the hexagonal phase in the MORB compositions (～20%) are taken into account. 相似文献
16.
The first results on current movements are presented for the western part of the Dzhugdzhur–Stanovoi Terrane based on GPS geodesy of a geodynamic survey area of the Upper Amur region. Processing of the GPS data resulted in a vector field of the displacement rates of points of the geodynamic survey area with zones of intense deformations. It was concluded from a comprehensive analysis of geological–geophysical data and estimates of the displacement rates that the terrane is characterized by kinematic integrity and was subjected to a complex of tectonic factors related to the evolution of the eastern segment of Baikal Rift Zone in the area of transpression interaction of the Eurasian and Amur plates. 相似文献
17.
Analysis of the degree of contamination and evolution in the last 100 years of the composition of the bed sediments of the Anllóns Basin 总被引：3，自引：2，他引：1
Rosa Devesa-Rey M. T. Barral J.-M. Jouanneau F. Díaz-Fierros 《Environmental Earth Sciences》2010,61(7):1401-1417
In this study, five cores of the Anllóns River bed sediments were analyzed in order to evaluate the downcore and downstream
variations in their chemical composition. The first step was the evaluation of the metal distribution in the bulk (<2 mm)
and fine fractions (<63 μm). The analysis revealed that most of the metals followed the same trend in both fractions, although
the fine fraction presented usually higher concentrations. However, the concentration of both fractions tended to equalize
with increasing contamination. No general increase was observed in the metal concentrations toward the surface which could
be attributed to recent anthropogenic contributions. Instead, the distributions were homogeneous or peaked at various depths
downcore. The most important historical feature was observed at the mouth of the river, at 96-cm depth, corresponding to the
end of the eighteenth century. Upcore increased metal concentrations in parallel with increased fine fraction occurred from
this depth, which were attributed to a bridge construction and consequent changes in sediment dynamics. As the metal concentrations
can be influenced by variations in texture or other sediment characteristics, the second step was to evaluate the efficiency
of several normalized indexes in the assessment of the degree of contamination, by calculating the enrichment factor (EF),
the geoaccumulation index (I
GEO) and the pollution load index (PLI). The EFs obtained were <10, thus revealing little anthropogenic inputs to the basin.
The I
GEO produced higher values when compared with the EFs. Instead of absolute EF or I
GEO absolute values, the use of cumulative probability plots allowed identifying more accurately potential outliers indicating
contamination. Only one population was identified for Zn and Pb, with a reduced number of outliers at the highest concentrations
for Pb. As shown, a more complex plot with the outliers identified at C4 and C5. Finally, the PLI allowed determining the
absence of a significant contamination in the bed sediments. The bioavailable and non-geogenic fractions contribute up to
a 90% of the total concentrations in the case of As and Cu, and showed similar (dissimilar) profiles in comparison with total
metals. Also, the quality guidelines were surpassed, so the high solubility of As, Zn, Pb and Ni in the sediments revealed
the need to monitor the bed sediment quality of the Anllóns River. 相似文献
18.
Data on the mechanisms of mantle phase transformations have come primarily from studies of analogue systems reacted experimentally at low pressures. In order to study transformation mechanisms in Mg2SiO4 at mantle pressures, forsterite () has been reacted in the stability field of -phase, at 15 GPa and temperatures up to 900° C, using a multianvil split-sphere apparatus. Transmission electron microscope studies of samples reacted for times ranging from 0.25–5.0 h show that forsterite transforms to -phase by an incoherent nucleation and growth mechanism involving nucleation on olivine grain boundaries. This mechanism and the resultant microstructures are very similar to those observed at much lower pressures in analogue systems (Mg2GeO4 and Ni2SiO4) as the result of the olivine to spinel () transformation. Metastable spinel () also forms from Mg2SiO4 olivine at 15 GPa, in addition to -phase, by the incoherent nucleation and growth mechanism. With time, the spinel progressively transforms to the stable -phase. After 1 h, spinels exhibit a highly striated microstructure along {110} and electron diffraction patterns show streaking parallel to [110] which indicates a high degree of structural disorder. High resolution imaging shows that the streaking results from thin lamellae of -phase intergrown with the spinel. The two phases have the orientation relationship [001]//[001] and [010]//[110] so that the quasi cubic-close-packed oxygen sublattices are continuous between both phases. These microstructures are similar to those observed in shocked meteorites and show that spinel transforms to -phase by a martensitic (shear) mechanism. There is also evidence that the mechanism changes to one involving diffusion-controlled growth at conditions close to equilibrium. 相似文献
19.
Ilya V. Veksler Yana M. Fedorchuk Troels F. D. Nielsen 《Contributions to Mineralogy and Petrology》1998,131(4):347-363
The evolution of nephelinitic melts in equilibrium with mica-bearing liquidus assemblages and melting relations have been
studied on two silica-undersaturated joins of the KAlSiO4– Mg2SiO4– Ca2SiO4– SiO2– F system at atmospheric pressure by quench runs in sealed platinum capsules. Fluorine has been added to the batch compositions
by the direct exchange of fluorine for oxygen (2F− = O2−). The first join is the pseudo-ternary Forsterite – Diopside – KAlSiO3F2 system. Forsterite, diopside, F-phlogopite and leucite crystallisation fields and a fluoride-silicate liquid immiscibility
solvus are present on the liquidus surface of the join. Sub-liquidus and sub-solidus phases include akermanite, cuspidine,
spinel, fluorite and some other minor fluorine phases. The second system is the pseudo-binary Akermanite – F-phlogopite join
that intersects the Forsterite – Diopside – KAlSiO3F2 join. Akermanite, forsterite, diopside, F-phlogopite, leucite and cuspidine are found to crystallise on the join. Forsterite
(fo) and leucite (lc) are related to F-phlogopite (phl) by a reaction with the fluorine-bearing liquid: fo + lc + l = phl,
and the reaction proceeds until forsterite or leucite are completely consumed. The reaction temperature and resulting phase
association depend on batch composition. Thus, leucite is not stable in the sub-solidus of the Akermanite – F-phlogopite join,
but is preserved in a part of the Forsterite – Diopside – KAlSiO3F2 system where forsterite reacts out, or does not crystallise at all. The phlogopite-in reaction has an important effect on
the composition of the coexisting liquid. The liquids initially saturated in forsterite evolve to extremely Ca rich, larnite-normative
residuals. The experimental data show that larnite-normative melilitolites can crystallise from evolved melilititic melts
generated from “normal” melanephelinitic parental magmas with no normative larnite. The evolution towards melilitites requires fractionation of phlogopite-bearing assemblages under volatile pressure.
Received: 3 June 1997 / Accepted: 5 January 1998 相似文献
20.
Doklady Earth Sciences - The influence of the temperature and moisture content of the near-surface soil layer on variations of the barodeformation interaction of the boundary layer of the... 相似文献