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1.
The isotopic (U-Pb, 238U-235U, 234U-238U) and chemical study of whole-rock samples and finegrained fractions of rocks in a vertical section of the terrigenous sequence at the Dybryn uranium deposit in the Khiagda ore field shows that a wide U-Pb isotopic age range (26.9-6.5 Ma) is caused by oxidation and disturbance of the U-Pb isotopic system in combination with protracted uranium ore deposition. The oxidation of rocks resulted in the loss of uranium relative to lead and eventually to an overestimated 206Pb/238U age at sites with a low U content. The 238U/235U ratios in the studied samples are within the range of 137.74–137.88. Samples with a high uranium content are characterized by a decreasing 238U/235U ratio with a decrease in 207Pb/235U and 206Pb/238U ages. A nonequilibrium 234U/238U ratio in most studied samples furnishes evidence for young (<1.5 Ma) transformation of the Miocene uranium ore, which is responsible for uranium migration and its redeposition.  相似文献   

2.
本文报道在庐山筲箕洼组中获得细碧岩SHIRMP锆石U-Pb年龄(840±6) Ma,MSWD=1.3,流纹岩锆石U-Pb年龄(833±4) Ma,MSWD=1.4,和流纹岩锆石U-Pb年龄(831±3) Ma,对应的MSWD=1.47.而在星子群流纹岩中获得206pb/238U年龄为(825±5)Ma,对应的MSWD=0.46.笔者依据上述精确锆石年龄,首次提出将筲箕洼组明确定位于星子岩群之下.本文结合“江南造山带”锆石U-Pb年龄:东部变质基底的双桥山群,西部变质基底梵净山群和似盖层下江群以及中部变质基底冷家溪群和似盖层板溪群的锆石SHRIMP U-Pb年龄,将筲箕洼组定位于“武陵运动”之下的新元古代地层.依据星子岩群年龄数据,首次将星子岩群明确定位于筲箕洼组之上与双桥山群为同期的深变质岩.该年龄对限定区域地层对比和构造演化都有着重要意义.上述锆石U-Pb年龄标示了赣西北地区同样存在820 Ma界面上下的新元古代地层,为江南古陆变质地层的对比提供了新的年代学数据.  相似文献   

3.
LA-ICP-MS U-Pb zircon dating of the Bozhushan granite in Southeast Yunnan   总被引：1，自引：0，他引：1  
The LA-ICP-MS U-Pb zircon dating of eight typical samples from four units of the Bozhushan granite intrusion in southeastern Yunnan Province, constrains the age of acidic magmatic intrusion in this area. Both the oscillatory zoning and chondrite-normalized REE patterns characterized by LREE-depletion and HREE-enrichment with positive Ce anomaly and negative Eu anomaly indicate the magmatic genesis of these zircons. Eight zircon samples from the Bozhushan granite yielded a mean 206 Pb/ 238 U age of (85.58±1.0) Ma (MSWD=4.1) to (88.10±0.66) Ma (MSWD=1.8). These chronology data suggest an accurate isotopic age for the intrusion of the Bozhushan granite, and are different from the published age data of 48 to 111.5 Ma. The geochronology data of the Gejiu, Dulong and Dachang super-large deposits and related Yanshanian granites indicated that there occurred large-scale granitic magmatism and mineralization events in western Nanling region during the Late Cretaceous.  相似文献   

4.
Whole-rock geochemical, zircon U-Pb geochronological and Sr-Nd-Hf isotopic data are presented for the Early Cretaceous volcanic rocks from the northern Da Hinggan Mountains. The volcanic rocks generally display high SiO2(73.19–77.68 wt%) and Na2O+K2O(6.53–8.98 wt%) contents, with enrichment in Rb, Th, U, Pb and LREE, and depletion in Nb, Ta, P and Ti. Three rhyolite samples, one rhyolite porphyry sample, and one volcanic breccia sample yield weighted mean 206Pb/238 U ages of 135.1±1.2 Ma, 116.5±1.1 Ma, 121.9±1.0 Ma, 118.1±0.9 Ma and 116.9±1.4 Ma, respectively. All these rocks have moderate(87Sr/86Sr)i values of 0.704912 to 0.705896, slightly negative εNd(t) values of –1.4 to –0.1, and positive εHf(t) values of 3.7 to 8. Their zircon Hf and whole-rock Nd isotopic model ages range from 594 to 1024 Ma. These results suggest that the Early Cretaceous volcanic rocks were originated from melting of subducted oceanic crust and associated sediments during the closure of the Mongol-Okhotsk Ocean.  相似文献   

5.
石榴子石原位U-Pb定年是近年来新发展的低铀矿物同位素定年方法,目前在矿床中成功应用的实例较少,尤其是在非金属矿床中更为罕见.基于详细的岩相学观察,在鄂东南高椅山硅灰石（-铜）矿床中厘定出两期石榴子石,分别为第一期深棕色石榴子石Grt1和第二期浅棕色石榴子石Grt2.电子探针成分分析（EMPA）表明,两期石榴子石均属于钙铁榴石-钙铝榴石固溶体系列,其中Grt1相对富Fe（Adr62.4Gro36.5~Adr94.4Gro0）,而Grt2相对富Al（Adr32.6Gro66.4~Adr40.2Gro58.6）.对Grt1和Grt2石榴子石进行LA-ICP-MS U-Pb定年,获得T-W下交点206Pb/238U年龄分别为142.5±2.0 Ma（2σ,MSWD=1.30,n=38）和136.0±14.0 Ma（2σ,MSWD=0.42,n=17）,与矿区内广泛出露的石英二长闪长岩锆石206Pb/238U加权平均年龄（139.8±1.5 Ma;2σ,MSWD=0.10,n=22）在误差范围内一致,证明二者之间存在密切的成因联系.高椅山Grt1石榴子石具有较高的U含量和较低的普通铅含量,此为U-Pb同位素测年成功的主要因素.   相似文献   

6.
新疆准噶尔北缘北塔山组火山岩年龄及岩石成因   总被引：9，自引：7，他引：2  
对准噶尔北缘北塔山组辉石玄武岩进行了LA-ICP-MS锆石U-Pb 年龄测定, 获得了玄武岩的喷发年龄380.5±2.2Ma,表明北塔山组火山岩形成于中泥盆世。该地层火山岩中辉石玄武岩和无斑玄武岩的SiO2含量为47.55%~52.97%、Al2O3的含量为8.44%~20.00%、TiO2为0.5%~1.2%,MgO含量为2.8%~15.35%、CaO为3.98%~14.83%、FeOT为9.46%~19.23%,具有亚碱性拉斑玄武岩的特征。其微量元素显示富集大离子亲石元素(LILE)和轻稀土元素(LREE),亏损Nb、Ta和Ti,Eu异常不明显。它们具有极低的初始87Sr/86Sr同位素比值(0.703835~0.704337)和高的εNd(381Ma)值(+6.84~+12.3,t=381Ma)的亏损地幔源区特征。结合区域地质背景,北塔山组火山岩形成于与俯冲作用相关的构造环境,是准噶尔古洋盆于泥盆世时发生的俯冲-消减所引发的岛弧岩浆作用的地质记录。岩浆源区为被流体或沉积物熔体交代改造的地幔楔和软流圈地幔,不同类型的岩石系不同成分的原始岩浆经不同演化过程的产物。  相似文献   

7.
We have investigated the potential of hübnerite for U-Pb dating. Hübnerite forms typically at medium to low-temperatures in a wide range of pneumatolytic-hydrothermal mineral deposits, particularly porphyry molybdenum and Sn-specialized granites. Hübnerite from the Sweet Home Mine (Alma, Colorado) formed in a Pb-rich, U-poor environment, but still developed relatively radiogenic Pb isotopic compositions. The low Pbcommon contents in hübnerite (0.075 to 0.155 ppm) demonstrate that Pb is efficiently excluded from the crystal lattice. In contrast, U may substitute for Mn. The U-Pb data of hübnerite scatter. Most of the scatter originates from samples with 206Pb/204Pb values below 50, where Pbblank contributes up to 30% to Pbtotal. Using the least radiogenic galena Pb, samples with 206Pb/204Pb values above 70 have overlapping 206Pb∗/238U and 207Pb∗/235U values and yield a 206Pb/238U age of 25.7 ± 0.3 Ma (2σ). Late stage apatite from the Sweet Home Mine yields a 206Pb/204Pb-238U/204Pb isochron corresponding to an age of 24.8 ± 0.5 Ma (2σ). A comparison of the U-Pb hübnerite ages with literature 40Ar/39Ar ages on earlier sericite and the U-Pb age on later apatite suggests that (i) hübnerite yields accurate U-Pb ages and (ii) the evolution of the Sweet Home mineralization from greisen-type mineralization to medium-temperature hydrothermal vein mineralization took place in a few hundred thousand years at most. Aqueous low-N2-bearing and aqueous inclusions in the dated hübnerite have homogenization temperatures between 325 and 356 °C and moderate salinity (up to 6.7 wt% NaCl equiv.). Thus, hübnerite represents one of the rare examples of a mineral that can be dated accurately and carries petrological information.  相似文献   

8.
The Lovozero alkaline massif—an agpaitic nepheline syenite layered intrusion—is located in the central part of the Kola Peninsula, Russia, and belongs to the Kola ultramafic alkaline and carbonatitic province (KACP) of Devonian age. Associated loparite and eudialyte deposits, which contain immense resources of REE, Nb, Ta, and Zr, constitute a world class mineral district. Previous Sr, Nd, and Hf isotope investigations demonstrated that these rocks and mineral deposits were derived from a depleted mantle source. However, because the Sr, Nd, and Hf abundances in the Kola alkaline rocks are significantly elevated, their isotopic compositions were relatively insensitive to contamination by the underlying crustal rocks through which the intruding magmas passed. Pb occurring in relatively lower abundance in the KACP rocks, by contrast, would have been a more sensitive indicator of an acquired crustal component. Here, we investigate the lead isotopic signature of representative types of Lovozero rocks in order to further characterize their sources. The measured Pb isotopic composition was corrected using the determined U and Th concentrations to the age of the crystallization of the intrusion (376?±?28 Ma, based on a 206Pb/204Pb versus 238U/204Pb isochron and 373?±?9 Ma, from a 208Pb/204Pb versus 232Th/204Pb isochron). Unlike the previously investigated Sr, Nd, and Hf isotopes, the lead isotopic composition plot was well outside the FOZO field. The 206Pb/204Pb values fall within the depleted MORB field, with some rocks having lower 207Pb/204Pb but higher 208Pb/204Pb values. Together with other related carbonatites having both lower and higher 206Pb/204Pb values, the combined KACP rocks form an extended linear array defining either a?~2.5-Ga secondary isochron or a mixing line. The projection of this isotopic array toward the very unradiogenic composition of underlying 2.4–2.5-Ga basaltic rocks of the Matachewan superplume and associated Archean granulite facies country rock provides strong evidence that this old lower crust was the contaminant responsible for the deviation of the Lovozero rocks from a presumed original FOZO lead isotopic composition. Evaluating the presence of such a lower crustal component in the Lovozero rock samples suggests a 5–10% contamination by such rocks. Contamination by upper crustal rock is limited to only a negligible amount.  相似文献   

9.
Recent statistical analyses on the isotopic compositions of oceanic, arc, and continental basalts have revealed that the Earth's mantle is broadly divided into eastern and western hemispheres. The present study aimed to characterize the isotopically defined east–west geochemical hemispheres using trace-element concentrations. Basalt data with Rb, Sr, Nd, Sm, Pb, Th, and U in addition to the isotopic ratios 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb were selected mostly from the GEOROC and PetDB databases. A total of 4787 samples were used to investigate the global geochemical variations. The results show that the wide trace-element variations are broadly explained by the melting of melt-metasomatized and fluid-metasomatized mantle sources. The larger amount of the fluid component derived from subducted plates in the eastern hemisphere than that in the western hemisphere is inferred from the basalts. These characteristics support the hypothesis that focused subduction towards the supercontinent created the mantle geochemical hemispheres.  相似文献   

10.
长江中下游是中国东部中生代大规模成矿的重要地区之一,是我国东部一个重要的Cu-Fe-Au-Mo多金属成矿区带。本文以鄂东南地区铁山岩体和金山店岩体为研究对像,利用原位LA-ICP-MS锆石U-Pb测年和锆石Hf同位素分析方法,探讨该地区岩体成因以及岩浆作用与成矿作用。铁山石英闪长岩LA-ICP-MS锆石U-Pb年龄加权平均值为138.9±0.96Ma(样品jls1-110)、138.2±0.94Ma(样品jls3)、131.0±1.2Ma(样品jls4)和118.9±1.2Ma(样品jls5),金山店石英闪长岩LA-ICP-MS锆石U-Pb年龄加权平均值为128.6±0.88Ma(样品jsd),为早白垩世、燕山晚期。铁山岩体石英闪长岩εHf(0)为负值,εHf(t)为负值(-17.3707~-8.31555),一阶段Hf模式年龄(tDM1)平均为1.33Ga,二阶段Hf模式年龄(tDM2)平均为2.03Ga;金山店岩体石英闪长岩εHf(0)为负值,εHf(t)为负值(-7.81135~-3.45982),一阶段Hf模式年龄(tDM1)平均为1.03Ga,二阶段Hf模式年龄(tDM2)平均为1.56Ga。铁山和金山店石英闪长岩样品中锆石Hf同位素组成特征显示该地区为岩体形成时有壳源物质参加的这一可能性,为长江中下游壳源岩浆提供补充。在结合已有的岩石学、地球化学以及矿床同位素年龄资料基础上,可以推断出鄂东南地区早白垩世矽卡岩型铁矿床形成于岩石圈伸展-减薄环境。  相似文献   

11.
道伦达坝矿床位于大兴安岭南段,是一个铜钨锡矿床,其铜、钨、锡储量均达中型。矿体呈脉状,主要产于二叠系砂板岩中的断裂破碎带中,华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。文章选取2件石英-萤石-白云母-电气石-锡石-黑钨矿阶段的矿石样品对其中的进行了LA-ICP-MS U-Pb定年,获得2件样品的~(207)Pb/~(206)Pb-~(238)U/~(206)Pb谐和年龄分别为(134.7±6.6)Ma(MSWD=1.4)和(136.8±7.4)Ma(MSWD=1.7),~(206)Pb/~(207)Pb-~(238)U/~(207)Pb等时线年龄分别为(132±12)Ma(MSWD=0.76)和(135±13)Ma(MSWD=0.9)。锡石定年结果表明,道伦达坝矿床形成于早白垩世。对矿区外围张家营子岩体中的斑状细粒花岗岩进行了LA-ICP-MS锆石U-Pb测年,获得的~(206)Pb/~(238)U加权平均年龄为(135±1)Ma(MSWD=1.3),该岩体的形成年龄与道伦达坝矿床的成矿年龄在误差范围内一致。本次定年结果表明道伦达坝矿床形成于早白垩世,与同期的花岗质岩浆活动有密切的成因联系,该矿床属于与花岗岩有关的岩浆热液脉型矿床。  相似文献   

12.
The U-Pb(Pb-Pb) age was determined for limestone from member III of the Sorna Formation out- cropped on the Azyr-Tal Range, Kuznetsk Alatau. The weighted average value from three calculated values is 523 ± 5 Ma (MSWD = 0.02, 2σ). This age coincides with the Early Cambrian age interval determined with Sr isotopic chemostratigraphy (87Sr/86Sr ratio is 0.70850–0.70852). The low value of μ2 = 238U/204Pb for limestone is due to the evolution of diagenetic fluid containing lead from the mantle reservoir into the Sorna sediments.  相似文献   

13.
ABSTRACT

Zircon U–Pb ages, major element and trace element compositions, and Sr, Nd, and Pb isotopic compositions for late Mesozoic granites from the southern Jiaodong Peninsula (eastern China) were determined. Ages for the Wulianshan, Xiaozhushan, and Dazhushan plutons are 119.1–122.3, 114.2, and 108.9 Ma, respectively. Major and trace element characteristics show that these granitic rocks belong to alkaline, A-type granites formed in an extensional setting. Trace element compositions show strong, variable negative anomalies in Ba, K, P and Ti, and positive anomalies in Rb, Th, U, Pb, Ce, Zr, and Hf, which are typical characteristics of A-type granites. Variable Sr and Nd isotopic compositions, 87Sr/86Sr(i) = 0.70540–0.7071 and εNd(t) = ?14.5 to ?20.9. Whole-rock Pb isotopic compositions have the following ranges, (206Pb/204Pb)t = 15.707–16.561, (207Pb/204Pb)t = 15.376–16.462, and (208Pb/204Pb)t = 36.324 to 37.064. Isotopic modelling indicates an origin that lies between mantle tapped by Cenozoic basalts around the Tan-Lu megafault and lower continental crust (LCC), and which can be explained by mixing of 11–18% mantle and 82–89% LCC. Based on new and compiled data, we suggest that the southern Jiaodong Peninsula, as well as the Laoshan area, was in a regional extensional setting of an orogenic belt during 106–126 Ma. The granitic rocks may be the result of late Mesozoic lithospheric thinning and decratonization (i.e. late Mesozoic craton destruction event occurring throughout eastern China).  相似文献   

14.
Gem quality andradite-rich garnet (IUC-1), obtained from the Miocene trachyte dome near Ankara city (Turkey), has been identified as a potential natural secondary reference material for U-Pb dating. In this study, U-Pb dating was performed in five different laboratories using isotope dilution TIMS and laser ablation ICP-MS to determine the homogeneity of euhedral garnet crystals. The U-Pb ID-TIMS data for IUC-1 yielded 207Pb/235U and 206Pb/238U ages of 20.9 ± 0.4 and 20.6 ± 0.8 Ma respectively, and these values are consistent with U-Pb LA-ICP-MS analyses, in which different garnet crystals yielded ages of 20.8 ± 0.1, 20.7 ± 0.1, 20.7 ± 0.2 and 20.2 ± 0.1 Ma. An andradite (IUC-2) from the Serçeören wollastonite skarn (Turkey) can be used as a secondary reference material provided detailed imaging of the crystals is undertaken. ID-TIMS data yielded 207Pb/235U and 206Pb/238U ages of 20.4 ± 0.4 and 20.9 ± 1.0 Ma respectively, and yielded U-Pb ages on different grains of 20.5 ± 0.1, 20.7 ± 1.0, 20.8 ± 1.7 and 20.9 ± 1.6 Ma. The assigned weighted mean age of IUC-1 (20.4 ± 0.5 Ma, 2s) is proposed as a 2023 reference value. IUC-1 garnet is expected to contribute significantly to rapidly developing garnet geochronology in the near future.  相似文献   

15.
对青海省纳日贡玛斑岩钼铜矿床开展了锆石LA-ICP-MS U-Pb同位素定年研究,结果表明,纳日贡玛矿区2个黑云母花岗斑岩样品的锆石206Pb/238U同位素加权平均年龄分别为(43.4±0.4)Ma和(42.9±0.3)Ma,锆石形态、结晶振荡环带结构及元素含量均显示出岩浆成因特点;因此,锆石U-Pb年龄可代表斑岩的岩浆结晶年龄,纳日贡玛含矿斑岩岩浆的侵位年代可精确地限定于新生代喜马拉雅期,相当于中始新世。1件辉钼矿样品Re-Os同位素模式年龄为(40.8±0.4)Ma,结合前人的辉钼矿测试结果,认为在纳日贡玛岩浆活动约2.6 Ma后,岩浆热液成矿流体开始产生成矿作用。三江走滑断裂构造系统控制斑岩矿床的分布,青海三江北段斑岩钼铜矿具有很大的找矿潜力。  相似文献   

16.
新疆东准噶尔老鸦泉岩体的锆石U-Pb年龄和地球化学组成   总被引：5，自引：0，他引：5  
韩宇捷  唐红峰  甘林 《矿物学报》2012,32(2):193-199
老鸦泉岩体是贝勒库都克锡矿带内最大的花岗岩体,它主要由黑云母钾长花岗岩组成。通过对2件样品的锆石LA-ICP-MS U-Pb同位素年龄测定,获得其206Pb/238U年龄值分别为301±2 Ma和300±5 Ma,指示该岩体侵位时代为晚石炭世。岩石地球化学组成表明,老鸦泉碱长花岗岩具有富硅、富碱,相对富集Rb、K、Th、U、Nd、Hf等元素,而贫Ba、Sr、P、Ti等元素,具强负Eu异常,总体显示A型花岗岩的地球化学特征。锆石U-Pb年龄及岩石地球化学特征都表明老鸦泉岩体的形成与晚石炭世北疆强烈的后碰撞岩浆活动有着密切关系。  相似文献   

17.
西南天山特克斯科桑溶洞火山岩的锆石U-Pb年代学研究   总被引：9，自引：5，他引：4  
朱永峰  安芳  薛云兴  陈博  张立飞 《岩石学报》2010,26(8):2255-2263
新疆特克斯县乌孙山科桑溶洞火山-沉积岩剖面由变质岩、火山-沉积岩(中酸性火山熔岩、火山碎屑岩、生物碎屑灰岩)和侵入其中的花岗质岩石组成,花岗岩中保留着英安岩-安山岩顶垂体。夹在火山岩地层之间的厚层生物碎屑灰岩(其中发育溶洞)发生褶皱变形。在剖面多处见到逆冲构造,断裂带局部塑性变形。采自剖面下部英安岩样品的锆石232Th/238U比值为0.4～0.6,U-Pb谐和年龄368.3±1.7Ma(MSWD=1.5,n=15)。剖面上部流纹岩中锆石的232Th/238U比值为0.8～2.2,U-Pb谐和年龄为356.4±1.7Ma(MSWD=1.3,n=19)。大约12Ma的时差说明存在两次火山喷发事件,在这两次火山喷发的间歇形成了巨厚生物碎屑灰岩(1000m)。这种间歇性的火山喷发在西天山地区普遍发育,形成了规模巨大的滨海相火山-沉积盆地。剖面下部的英安岩与剖面上部的流纹岩的锆石具有不同的微量元素组成,预示着其岩浆源区性质的差异。  相似文献   

18.
The Dexing porphyry copper deposit, part of the circum-Pacific porphyry copper ore belt, is the largest porphyry copper deposit in China. We present new LA–ICP–MS zircon U–Pb and molybdenite Re–Os dating, bulk-rock elemental and Sr–Nd–Pb isotopic as well as in situ zircon Hf isotopic geochemistry for these ore-bearing porphyries, in an attempt to better constrain their petrogenesis. LA–ICP–MS zircon U–Pb dating shows that the Dexing porphyries were emplaced in the early Middle Jurassic (～171 Ma); molybdenite Re–Os dating indicates that the associated Cu–Mo mineralization was contemporaneous (～171 Ma) with the igneous intrusion. The rocks are mainly high-K calc-alkaline and show adakitic affinities, including high Sr and low Y and Yb contents, high Sr/Y and La/Yb ratios, and high Mg# (higher than pure crustal melts). These porphyries have initial 87Sr/86Sr ratios of 0.7044?0.7047, ?Nd(T) values of –1.5 to?+0.6, and ?Hf(T) (in situ zircon) values of?+2.6 to?+4.6. They show unusually radiogenic Pb isotopic compositions with initial 206Pb/204Pb ratios up to 18.41 and 207Pb/204Pb up to 15.61. These isotopic compositions are distinctly different from either Pacific MORB or Yangtze lower crust but are similar to the subducting sediments in the western Pacific trenches. Detailed elemental and isotopic data suggest that the Dexing porphyries were emplaced in a continental arc setting coupled with westward subduction of the palaeo-Pacific plate. Partial melting involved the subducted slab (mainly the overlying sediments), with generated melts interacting with the lithospheric mantle wedge, thereby forming the investigated high-K calc-alkaline porphyry magmas.  相似文献   

19.
Although garnet UPb dating method has been reported recently, yet the accurate concordia 206Pb/238U ages and growth histories of multi generation of garnets based on ages were still lacked. LA-ICP-MS UPb dating on multi-generational grandite (grossular-andradite) garnet from the large Tonglvshan Cu-Fe-Au skarn deposit was applied in this study. Based on petrographic observation, in chronological order, three generation garnets have been distinguished, namely homogeneous Grt1-exo (in the exoskarn zone) and Grt1-endo (in the endoskarn zone), oscillatory zoning Grt2 and vein-type Grt3 cutting magnetite ores. LA-ICP-MS UPb dating on four grandite samples from the Grt1-exo, Grt1-edno, Grt2 and Grt3 yields Tera-Wasserburg lower intercept 206Pb/238U ages of 139.1 ± 1.0 Ma (2σ, MSWD = 0.79), 134 ± 11 Ma (2σ, MSWD = 2.5), 143.4 ± 8.3 Ma (2σ, MSWD = 2.3) and 140.3 ± 1.4 Ma (2σ, MSWD = 0.95), respectively. More importantly, two concordia 206Pb/238U ages of 139.2 ± 0.6 Ma (2σ, MSWD = 1.4) and 139.8 ± 1.5 Ma (2σ, MSWD = 0.13) were firstly obtained from the sample of Grt1-exo with highest U concentrations ([U]avg > 80 ppm) contents. The precision UPb ages of 139–140 Ma from Grt1-exo and Grt3 can be considered as the timing of Cu-Fe-Au skarn mineralization, and consistent with the majority of published zircon UPb ages of the quartz dioritic stock and 40Ar39Ar plateau ages of phlogopite at Tonglvshan (142–140 Ma). The precision grandite UPb ages also indicate that the entire metasomatic hydrothermal mineralization activity in the Tonglvshan Cu-Fe-Au skarn deposit occurred within a relatively short time span of <1 (or 2.5 considering errors) Myr. In addition, we found that the grandite garnet is more easily to be enriched in U and can obtain the high-precision concordia UPb ages with higher andradite Mol%, euhedral and larger crystals, and relevant oxidized magmatic rocks or skarns.  相似文献   

20.
沽源-红山子铀成矿带河北沽源张麻井铀-钼矿床赋存在张家口组第三段流纹岩与流纹斑岩、石英斑岩的接触带附近,主要受隐爆角砾岩控制。研究表明,张麻井铀-钼矿床赋矿流纹岩、流纹斑岩和石英斑岩的锆石具有清晰的环带结构,Th/U比值高,属典型的岩浆成因锆石。SHRIMP锆石U-Pb测年结果显示,流纹岩12颗锆石的206Pb/238U年龄变化范围为136~144 Ma,加权平均年龄为(138.6±1.4)Ma(MSWD=2.4);流纹斑岩11颗锆石的206Pb/238U年龄变化范围为136~145 Ma,加权平均年龄为(140.2±1.6)Ma(MSWD=2.2);石英斑岩11颗锆石的206Pb/238U年龄变化范围为132~147 Ma,加权平均年龄为(136.2±2.9)Ma(MSWD=1.8)。由此可见,流纹岩、流纹斑岩和石英斑岩的同位素年龄在误差范围内一致,指示火山喷发和斑岩就位发生在早白垩世早期,与滨西太平洋成矿域以火山岩为赋矿主岩的热液型铀矿的围岩形成时代一致,沽源-红山子铀成矿带早白垩世早期次火山岩与同期火山岩的接触带附近是寻找铀矿的有利空间。  相似文献   

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