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1.
黏土矿物古气候意义研究的现状与展望 总被引：6，自引：1，他引：5
系统地分析了利用海洋沉积物、古土壤、湖盆沉积物中黏土矿物进行古气候环境研究的现状、存在问题和发展趋势。海洋沉积物的物源范围广,影响因素复杂,其中的碎屑黏土矿物所指示的古气候参数只能用于解释母源区的气候变化,而只有自生黏土矿物才能指示沉积区的气候;古土壤形成于特定的地质背景条件下,尤其是发育于火山物质母岩之上的风化自生黏土矿物,可以准确地指示该区的古气候条件;湖盆沉积物的物源范围小,沉积物中的黏土矿物可以更有效地运用于古气候环境的分析。对于沉积物中黏土矿物来源的分析,可以借助晶体中cv空位和tv空位的精细结构特征进行判断;在风化改造的红土剖面研究中,因强烈的化学风化、淋滤和迁移,黏土矿物方法具有独特的优势。风化过程中形成的一些亚种或过渡性黏土矿物,以及同生沉积过程中形成的黏土矿物,对气候环境的变化更加敏感,应加强这方面的研究。此外,在造山带的气候环境演化研究中,自生黏土矿物稳定同位素可以更可靠地指示气候环境的变化。 相似文献
2.
Little Colorado White Ware (LCWW) is a decorated black-on-white ceramic constructed by the Anasazi in the southwestern United States from approximately A. D. 1050 to 1250. LCWW potsherds are found in archaeological sites located throughout the Little Colorado River valley of northern Arizona. Two major volcanic fields which are located on opposite sides of the Little Colorado River, the San Francisco Peaks in the west and the Hopi Buttes in the east, have been proposed as source areas for LCWW production. Petrographic, X-ray diffraction, and electron microprobe analyses of this ware's raw material constituents and geologic samples indicate that LCWW could only have been produced in the Hopi Buttes area. This study is presented as an example of a research design whose sample size, geographic scale, and methodologies can be effective in determining the source of prehistoric ceramics from the southwestern United States and elsewhere. © 1993 John Wiley & Sons, Inc. 相似文献
3.
采用超临界抽提(SFE)新技术和氯仿抽提(CE)以及粘土分离等手段对东营凹陷沙四段低熟油烃源岩进行不同处理,得到3种粘土样品:(1)含有机质的粘土原样;(2)氯仿抽提去有机质的样品;(3)不同实验条件下超临界抽提后的样品。然后,分别对这3种粘土样品进行X射线衍射分析(XRD)和傅利叶转换红外光谱分析(FT-IR).研究发现烃源岩中可溶有机质除了吸附于矿物表面外,还吸附于粘土矿物尤其是蒙皂石层的层间,后者主要为碳数相对较低的饱和烃类。这一发现对认识沉积岩中可溶有机质对粘土矿物结构和特性的影响有着重要意义,对烃源岩评价和探讨泥质烃源岩烃类的初次运移提供了新思路。 相似文献
4.
采用超临界抽提(SFE)新技术和氯仿抽提(CE)以及粘土分离等手段对东营凹陷沙四段低熟油烃源岩进行不同处理,得到3种粘土样品:(1)含有机质的粘土原样;(2)氯仿抽提去有机质的样品;(3)不同实验条件下超临界抽提后的样品。然后,分别对这3种粘土样品进行X射线衍射分析(XRD)和傅利叶转换红外光谱分析(FT-IR).研究发现烃源岩中可溶有机质除了吸附于矿物表面外,还吸附于粘土矿物尤其是蒙皂石层的层间,后者主要为碳数相对较低的饱和烃类。这一发现对认识沉积岩中可溶有机质对粘土矿物结构和特性的影响有着重要意义,对烃源岩评价和探讨泥质烃源岩烃类的初次运移提供了新思路。 相似文献
5.
D.G. Brookins 《Engineering Geology》1972,6(4):251-259
A preliminary review of the literature indicates that the chemistry of the water from relief wells south of Tuttle Creek Dam (T.C.D.) is favorable for the formation of authigenic montmorillonitic and mixed-layer clays whereas the chemistry of the waters of Tuttle Creek Reservoir (T.C.R.) indicates only kaolinite as a possible authigenic phase. The montmorillonitic and mixed-layer clays are very undesirable in a dam's structure due to their ion exchange capacity and swellability-compressibility; both factors can possibly shorten the life of an earthfill dam.
Further study indicates that the water chemistry of the relief wells is close to that for many of the wells in the Blue River Valley and Kansas River Valley from below the dam and that this criterion alone cannot be used to answer the critical question of authigenesis. Clay mineralogic study coupled with a Rb-Sr geochronologic study indicates that, despite some real differences in the types of clays found in both T.C.R. and T.C.D., an allogenic origin for the clays is probable. This refutes the idea that the dam is being weakened by authigenic clay deposition, but more chemical date are needed to confirm the Rb-Sr work. 相似文献
6.
Elen Roaldset 《Lithos》1973,6(4):349-372
Rare earth elements (REE) in the clay fraction (< 2μ) of the Quaternary deposits in the Numedal area, southern Norway, have been determined by a spark source mass spectrometric method. The REE content was studied in relation to weathering and sedimentological factors.
The total REE content varies from 100 to 1300 ppm. An average of the similar fraction of 16 non-marine clays, mostly tillitic, gave 527 ppm REE. An average of 38 glacial and postglacial marine clays from the lower part of the Numedal valley gave 335 ppm REE (max. 781 ppm). After removal of adsorbed ions the average total REE content of morainian and marine clays decreased to 186 ppm.
The content and distribution of the REE in the Numedal clays are strongly influenced by environmental factors. Under neutral and alkaline conditions the REE are accumulated by adsorption on clay minerals, and by increasing the hydrogen ion concentration the adsorbed ions are readily removed. 相似文献
7.
干湿循环作用下压实黏土力学特性与微观机制研究 总被引：1，自引：0，他引：1
针对干湿循环作用下填埋场封场覆盖系统压实黏土防渗结构损伤等问题,系统开展了干湿循环作用下（室内模拟填埋场气候环境）压实黏土力学特性及微观结构特征试验研究,从微观层次揭示了压实黏土在干湿循环作用下变形特性和强度衰减内在本质。研究结果表明：随着干湿循环次数的增加,压实黏土初始变形段区间割线模量增加,末段区间割线模量大幅度降低,变化幅度随初始压实度的增加而增加;同时,压实黏土剪切强度呈减小趋势,但减小幅度随初始压实度和围压的增加而减小。经过3次干湿循环后,压实黏土发生不可逆的体积收缩,体积收缩比例随压实度的增加而减小,低压实黏土和高压实黏土的体积收缩20.5%和11.5%。同时,低压实黏土和高压实黏土的大孔体积增加25.7%和53.9%,微裂隙体积增加3.1%和41.7%,增加幅度随初始压实度的增加而增加。压实黏土不可逆的体积收缩致使土体更加密实,从而导致压实黏土初始切线模量和强度增加。同时,大孔体积增多和微裂隙的发育,导致压实黏土剪切强度和末端切线模量降低,干湿循环对不同压实度黏土力学特性影响是二者的综合表现。 相似文献
8.
用有机粘土化学研究生油理论 总被引：2，自引：1，他引：2
有机粘土化学反应是自然界广泛存在的一种具有重要意义的反应。有机粘土化学因得到广泛应用和发展而被认为是２１世纪的科学。沉积物中的有机质绝大部分以粘土－有机质复合体形成存在。粘土吸附有机质是促使有机质富集和沉积的最重要因素。 相似文献
9.
粘土矿物对有机质生烃的催化作用 总被引：4，自引：1，他引：3
烃源岩的有机质主要以有机粘土复合体的形式存在。有机质生烃是一种有机粘土化学反应。反应过程中,有机质与粘土之间存在质子和电子迁移,粘土通过对水分子的吸附和离解为有机质加氢裂解提供H+,而有机质生成的有机酸激活了粘土的催化活性,也为蒙皂石伊利石化反应创造了条件。烃源岩不同粘土矿物的选择性催化特征是影响油气组成的最重要因素。粘土的催化活性大小和发育时间是决定烃源岩生烃潜力大小的因素。由于烃源岩在蒙皂石伊利石化阶段具有最大的催化活性,而且与有机质生烃反应同步,因此富含伊$蒙混合层的烃源岩是世界含油气盆地的最有利烃源岩。不同地质时期的烃类地质储量与烃源岩膨胀性粘土的丰度有密切关系。 相似文献
10.
Loess occurs widely in Northwestern China, covering Neogene clay and other sedimentary units that overlie the bedrock. The Neogene clays of the Baoji Region of Shaanxi Province, north China, including the eolian Hipparion and paleo-Sanmen Lake fluvial deposits, are typical clays of the southern Chinese Loess Plateau. These clays are also sensitive key strata controlling the development of large-scale landslides along the slope of the loess tableland surrounding the Guanzhong Basin. To investigate the Neogene clay types and landslides in the region, soil samples were tested and the macro- and micro-structures of the clay strata were analyzed. Comprehensive analysis methods, including the pipette method and fine X-ray diffraction, were applied to quantitatively analyze the sample composition and determine the clay mineral types. The Neogene clays are mainly composed of illite and montmorillonite mixed-layer minerals. On the Williams’ discrimination diagram of swelling potential, both types of clay are medium to strongly expansive soil. Two case studies illustrate that rainfall reduces the shear strength of the Neogene clay and raises the groundwater level. Rainfall has gradually destroyed the structure of the Neogene clay, transforming it to sliding belt soil. The sliding belt lies mainly within the Neogene clay layers, significantly affecting the occurrence and characteristics of landslides in Baoji. The rise in groundwater level and weakening of the shear strength of the Neogene clay are important factors in the occurrence of landslides. The long-term strength is a key factor affecting the development of loess landslides along the loess tableland in Baoji. 相似文献
11.
This paper presents an overview of the modification of clay minerals by propping apart the clay layers with an inorganic complex. This expanded material is converted into a permanent two-dimensional structure, known as pillared clay or shortly PILC, by thermal treatment. The resulting material exhibits a two-dimensional porous structure with acidic properties comparable to that of zeolites. Synthetic as well as natural smectites serve as precursors for the synthesis of Al, Zr, Ti, Fe, Cr, Ga, V, Si and other pillared clays as well as mixed Fe/Al, Ga/Al, Si/Al, Zr/Al and other mixed metal pillared clays. Biofuels form an interesting renewable energy source, where these porous, catalytically active materials can play an important role in the conversion of vegetable oils, such as canola oil, into biodiesel. Transesterification of vegetable oil is currently the method of choice for conversion to biofuel. The second part of this review focuses on the catalysts and cracking reaction conditions used for the production of biofuel. A distinction has been made in three different vegetable oils as starting materials: canola oil, palm oil and sunflower oil. 相似文献
12.
D.T. Vaniman S.J. ChiperaD.L. Bish M.C. DuffD.B. Hunter 《Geochimica et cosmochimica acta》2002,66(8):1349-1374
The upper 25 m of Bandelier Tuff at Pajarito Mesa, New Mexico, include soils, shallow fractures, deeper fractures, and tuff matrices in which clays provide a record of transport and alteration. The principal pathways within this system are fractures that penetrate the tuff. Large fractures that host deep root penetration provide a setting in which clay deposits accumulate through particulate or colloidal migration from the soil zone. Clays throughout the system are predominantly expandable interstratified illite/smectites (I/S), but clays of the tuff matrix at depth are distinctly Fe-rich and are not mixed with clays transported from the surface into fractures. Chemical alteration superimposed on clay particles transported into fractures results in clays with lower Al : Si ratios, higher Na, and higher lanthanide content with increasingly negative Eu anomalies with depth. These changes are accompanied by invasion and precipitation of Mn oxides, principally birnessite, within clay bodies. Investigation of the Mn oxides by synchrotron X-ray fluorescence (SXRF) shows that Mn is associated with Ba, Ce, Ni, and Pb. In addition, synchrotron X-ray absorption near-edge structure (XANES) spectra show that Ce in Mn oxides occurs as Ce3+ and Ce4+, with average Ce oxidation state of ∼3.75. The Mn oxides intergrown with clays actively participate in removal of Ce from solution, accompanied by oxidation of Ce3+ to Ce4+. Other lanthanides are accumulated by the clays but are not concentrated along with Ce in the Mn oxides. Extraction of Ce from solution by Mn oxides is more effective than lanthanide accumulation in clay, a process that is variable and likely influenced by defects, extent of recrystallization, and particle sizes. This dichotomy in lanthanide interaction results in locally constant Ce content but either negative or positive Ce anomalies in the clay-Mn oxide system as a consequence of variability in the abundance of the other lanthanides. Nevertheless, the net lanthanide pattern for the sum of all clay-Mn oxide samples in either shallow or deep fractures has no Ce anomaly, indicating that other lanthanides segregated from Ce are not transported beyond the range of either the shallow or deep fracture systems. Evidence from Eu anomalies indicates that lanthanides accumulated in the fracture clays are acquired from the local tuff. The clay-Mn oxide assemblage is more effective than clay alone in accumulating of a wide variety of heavy metals. 相似文献
13.
Petrology and sedimentation of the middle siwalik clays at dholkhand,saharanpur district,U.P., India
Nityananda Bhattacharya Sarada Saran Misra 《Contributions to Mineralogy and Petrology》1963,9(2):139-147
The Middle Siwalik clays at Dholkhand, Saharanpur district, U. P., in India were studied to investigate the nature of Siwalik (middle Miocene to lower Pleistocene) sedimentation in relation to the tectonism associated with the Himalayan orogenesis. The clays are reddish brown to buff in color containing montmorillonite, expandable mixed-layers, degraded chlorite, and illite. The clays were studied byX-ray diffractometry using standard techniques with copper radiation. The clay mineral distribution of the Middle Siwaliks indicates that the material was deposited under continental conditions in stream channels during periods of minimum current activity. The clays were deposited by slow sedimentation and are little affected by diagenesis. Further work in this area and elsewhere are now under progress to establish the relation of Siwalik sedimentation with the uplift of the Himalayas in the Tertiary period. 相似文献
14.
A new laboratory set-up for measurements of electrical, hydraulic, and osmotic fluxes in clays 总被引：4，自引：0，他引：4
Katja Heister Pieter J. Kleingeld Thomas J.S. Keijzer J.P. Gustav Loch 《Engineering Geology》2005,77(3-4):295-303
If clays are subjected to flows of fluid, electrical charge, chemicals, or heat, in most cases, flows of different types occur simultaneously, even if only one driving force is acting. These are so-called coupled flows. Examples of coupling phenomena are streaming potential and electroosmosis, induced by the flows of fluid and electrical charge, respectively.
Since the 1960s, laboratory devices have been constructed to measure streaming potentials and/or electroosmosis in clays or clayey soils. Due to their mechanical and hydraulic properties, clays are not easy to work with. Consequently, laboratory devices have to deal with various complications. A new design for an experimental set-up is proposed. Contrary to earlier devices, the clay sample is mounted in a flexible wall permeameter, which avoids sidewall leakage caused by the possible swell or shrink of the clay. Gold-coated gauze electrodes completely cover the surfaces of the sample, which are in contact with the solution reservoirs that ensure one-dimensional flow. In addition, the thickness of the sample is monitored during the experiment. The chemical composition of the reservoir fluids is controlled during the experiment. The device is flexible with respect to changing the solutions of both reservoirs independently, applying different hydraulic gradients, and measuring or applying electrical potentials. Finally, it is possible to mount undisturbed clay samples in the set-up, keeping them in situ during the whole experiment.
With this set-up, an extensive program of measurements of coupling phenomena like streaming potentials, electroosmosis, and membrane potentials in a sodium montmorillonite is started. Preliminary results of streaming potential measurements are presented and demonstrate that the build-up of a streaming potential due to a hydraulic gradient is a reproducible process that influences the water flow through the clay, and that the extent of the streaming potential depends on the salt concentration of the permeating solution. 相似文献
15.
This paper presents an analytical study of LateBronze andIronAge ceramics and natural clay deposits from the archaeological site ofPuig deSa Morisca in southwestMallorca,Spain. In our study, we combine petrographic, micropaleontological, mineralogical (X‐ray powder diffraction) and textural (laser particle size) analyses of sherds and local clays that may have been used as raw material in ceramic production. This approach allowed us to compare the ceramics’ formal characteristics with those observed in nearby plastic clays and assess raw clay procurement and paste preparation. The results indicate the use of local (<500 m distance) calcareous clays throughout theLateBronze andIron ages. This raw material was mixed with other coarser clays or crushed calcite, as well as other calcareous tempers, such as breccias or calcarenites, located close to the site. The results demonstrate that the same clay deposit was used to make ceramic vessels following different technological choices and recipes. Thus, local communities established a strong connection with the same raw materials through time that were located within the potters’ preferential range of exploitation. 相似文献
16.
E. I. Enu 《Geological Journal》1986,21(2):93-99
The Late Cretaceous sedimentary sequence in the Upper Benue Trough consists of seven formations. Outcrop samples from the type localities of these units were analysed by X-ray diffraction for their day mineral content. The composition and distribution of the clay minerals are influenced by tectonics, relief and water depth. Three main depositional phases are recognizable on the basis of clay mineral assemblages, two of which are associated with tectonic movements. The first phase, characterized by the presence of chlorite, illite, kaolinite and mixed-layer clays is common to Albian-Cenomanian sediments. This phase is succeeded by mixed-layer clays and smectite-rich, Turonian-Early Santonian sediments. The re-occurrence of chlorite and illite in association with kaolinite and mixed-layer clays in the Post-Santonian sediments constitutes the third depositional phase. These clay mineral assemblages are indicative of two periods of tectonism (Albian and Late Santonian) and an intervening Turonian-Early Santonian period of quiescence in the Upper Benue Trough. 相似文献
17.
As the only place simultaneously occupied by the Middle Horizon (A.D. 600–1000) Andean states, the Tiwanaku and the Wari, the Moquegua Valley in southern Peru is of critical importance to understanding relations between the two states. Visual studies of Tiwanaku and Wari ceramics in the valley have elucidated differences in form and decoration. The procurement of raw clays was central to the production of these ceramics, and understanding where people procured their clay may provide insight into the social and economic interactions between these two states. Survey of the Moquegua Valley indicates the extensive availability of raw clays. Results of laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) analyses of clays indicate that there is heterogeneity in the chemical signature of the valley's clays and that at least five different clay groups can be distinguished. Comparison of these clays with LA‐ICP‐MS analysis of ceramics from a Tiwanaku site and a Wari site demonstrates that although Tiwanaku and Wari colonists in Moquegua used locally available clays during the Middle Horizon, the clay sources exploited by potters from each state were different and derived from areas located within their respective middle and upper valley territories. This information provides a basis for future chemical analysis of ceramics from the Moquegua Valley and improved understanding of past social and economic interactions. © 2009 Wiley Periodicals, Inc. 相似文献
18.
An important question in Southwestern archaeological research is how social and economic ties between prehistoric groups changed through time. The chemical and mineralogical matching of stone tools and ceramics to source areas is one approach to addressing this question. Here we challenge the assumption that igneous rocks used for manufacturing stone tools and ceramics in the Mesa Verde region of Colorado were originally derived from the Chuska Mountains of New Mexico. Recent geological surveys suggest that small igneous features present in and around Mesa Verde National Park and Ute Mountain Ute Tribal Park contain similar lithologies and may represent a local source. We systematically visited seven of these igneous exposures and nine downstream gravel deposits, looking for geological sources and quarry sites matching the lithology of analyzed debitage from this region. Our results suggest that the ancestral Puebloans could have procured such igneous rocks as aphanitic minette and trachybasalt pottery temper from local areas. Because the trachybasalt is usually thought to have been imported from the Chuska Mountains, this discovery may require a revision of interpreted trade networks based on pottery temper and lithic raw material distinctions. © 2009 Wiley Periodicals, Inc. 相似文献
19.
为研究长江中下游红土剖面中粘土矿物的特征及其成因意义, 对安徽宣城红土剖面中粘土矿物进行深入、系统的X射线衍射分析.结果表明, 宣城剖面各土壤层中粘土矿物成分基本一致, 主要为蛭石、伊利石、高岭石, 以及粘土矿物过渡相. 由采自剖面上部样品的X射线衍射图可知, 经乙二醇饱和后7 ?衍射峰可分解为7.15、7.60和7.92 ?三部分, 表明除了高岭石(7.15 ?)外, 还存在高岭晶层含量分别为~80%和~95%的2种高岭-蒙脱石过渡相, 并以前者为主; 剖面下部样品在乙二醇饱和后, 7 ?衍射峰可分解为7.16、7.79和8.35 ?等3个衍射峰, 其中8.35 ?峰衍射强度很小, 表明除了高岭石外, 样品中存在高岭晶层含量为~90%和~43%的高岭-蒙脱石过渡相, 后者含量甚少.甲酰胺饱和结果表明, 高岭-蒙脱石混层粘土矿物相中高岭晶层为埃洛石相.加热试验的衍射图中10 ?衍射峰强度明显增强, 证实高岭相中含有一定数量的来源于绿泥石风化的蒙脱石间层; 而10 ?衍射峰的低角度一侧没有出现拖尾现象, 则指示高岭-蒙脱石混层矿物中的蒙脱石不是简单的羟基间层蒙脱石.此外, 红土剖面中还普遍出现过渡性粘土矿物伊利石-蒙脱石混层和伊利石-蛭石混层粘土矿物.大量过渡性粘土矿物相的出现, 从成土作用的角度上说明红土沉积物经历了沉积-风化、以及多期风化作用叠加, 而且在沉积-风化成土过程中, 气候环境变化于强烈化学风化的温暖、季节性干旱和强烈风化淋滤的温暖而更加潮湿的条件.蛭石-伊利石混层粘土矿物仅发育于红土剖面上部, 表明总体上剖面上部的化学风化程度低于剖面下部. 相似文献
20.
T. Hueckel 《国际地质力学数值与分析法杂志》1997,21(1):43-72
Isothermal chemo-elasto-plasticity of clays is discussed, to describe strains induced in clay by permeation of it with a low dielectric constant organic contaminant, in the presence of stress. The strain is crucial in controlling permeability changes in chemically affected clay barriers of landfills and impoundments. The theory encompasses chemical softening or yield surface reduction, coefficient of chemical reversible expansion or contraction due to mass concentration increase, as well as chemical sensitivity of bulk plastic modulus. The experiments on chemistry and stress dependent permeability of Sarnia clay performed by Fernandez and Quigley (1985, 1991) are interpreted using this model. The numerical representations of the chemo-plastic softening function and the chemo-elastic strain function, as well as plastic bulk modulus sensitivity to concentration are evaluated for dioxane and ethanol. Specific requirements for the tests for chemo-plastic behavior of clays are discussed. © 1997 by John Wiley & Sons, Ltd. 相似文献