共查询到20条相似文献，搜索用时 140 毫秒
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Astronomy Reports - Improvement of the prediction accuracy of the Earth’s rotation parameters (ERP) is one of the main problems of applied astrometry. In order to solve this problem, various... 相似文献
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Turchanina Oksana Satin Vladimir Derevyanko Aleksey 《中国地球化学学报》2006,25(B08):51-52
As is well known, a high content of sulphur in coals is an effect of the post-depositional history of coal seams and one of the most important criteria of its use as a fuel. Sulphur in coals can cause a serious environmental and technological problem during their utilization. This problem is very actual for the Donetsk Basin because 734 mined seams out of the total of 1009 （73%） are comprised of coals with sulphur content -2%. The chemical pre-treatment as a first stage in their processing is widely used in order to effectively obtain the thermal destruction products of coals （such as semi-coke, coke, adsorbents, etc.） and to simultaneously utilize coal wastes. Development in pre-treatment methods for high-sulphur, low-rank coals is especially desirable for reducing the sulphur contents of the solid products. The aim of the present work is to investigate the influence of coal pre-treatment on the yield and composition of thermal destruction products, and the sulphur distribution among different components of the coals of different genetic types by reductivity （low-reduced LRC and reduced RC coals）. The thermal behavior of the coals was studied by means of the Fisher method （heated to 520℃, at a rate of 7℃/min）. The composition of the semi-coking gas was investigated by means of a VTI gas analyzer. The coal samples were chemically treated directly before thermal destruction by the introduction of 1-% solutions of radical polymerization initiator AAD （acrylic acid dinitrile C8H12N4） and products of coal-tar distillation （absorber oil）. Coal pre-treatment increases the semi-coke yield and its coking ability, and changes the liquid/gaseous product ratio. 相似文献
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Yoko Shimamoto Yoshio Takahashi 《中国地球化学学报》2006,25(B08):114-114
Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid （PA） is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry （HPLC-ICP-MS）. 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS （column： Tosoh TSKgel SuperlC-AP, eluent： 0.01 M HNO3）. It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system. 相似文献
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Zonal distribution of seepage hydrocarbon-induced altereb carbonates over oil/gas reservoirs is a common phenomenon observed in the field.The authors considered that the continuous production of CO2 within the “alteration chimney ”gives rise to a significant difference in physical and chemical properties between its interior and the surrounding country rocks.And it is this difference that has promoted the erosion and precipitation of carbonates,thus leading to the zonal distribution of seepage hydrocarbon-induced altered carbonates over oil/gas reservoirs.This may be a reasonable interpretation of the phenomenon described above. 相似文献
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Doklady Earth Sciences - The influence of variations in fo-, fa-, en-, fs-, di-, an-, and ab-components in a high-Mg basaltic melt on the topology of the spinellide liquidus was analyzed using the... 相似文献
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Based on the data developed from various s natural waters in the Qinghai Lake area and ostracode shells present in drill core QH-16A of recent lake-floor sediments ,this paper discusses the distribution of stable isotopes in the modern water body of Qinghai Lake,and the initial isotopic composition of the lake water has been deduced ,Studies of δ^18O,δ^13C,Mg/Ca and Sr/Ca in ostracode shells provide the basis for the establishment of the model of climatic fluctuation in the Qinghai Lake area since the postaglacial age,as well as for the elucidation of the environmental evolution of the water body of Qinghai Lake since the postglacial age. 相似文献
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The applicability of the natural abundance of nitrogen gas isotope ratios was used to indicate the spatial distribution of
nitrogen transformations in the water column and sediment pore waters of Lake Ngapouri, a small (area 0.19 km2), monomictic, eutrophic lake in the Taupo Volcanic Zone, North Island, New Zealand. Samples were collected from the epilimnion,
hypolimnion, benthic boundary layer and at 5-cm intervals from the sediment pore waters at monthly intervals for 1 year. Values
of δ15N [N2] ranged from −1 to 0.28‰ in the epilimnion, −1.5 to 1.25‰ in the hypolimnion, −1.8 to 12.2‰ in the benthic boundary layer
and −0.7 to 3.5‰ in sediment pore waters. Values of δ15N [N2] showed a strong seasonal pattern that was related to the loss of dissolved oxygen in the hypolimnion during seasonal stratification.
Increases in 15N-enriched dinitrogen take place in the benthic boundary layer during the periods of anoxia (taken to be dissolved oxygen
concentrations <6.3 μM) and may be related to abundant ammonium substrate (up to 275 μM) to support denitrification. Nitrate
concentrations increased up to 36 μM with increasing duration of anoxia. We hypothesise that an alternative electron acceptor
besides oxygen is required to support the nitrification needed for the production of nitrate. Iron and manganese hydroxides
and oxides from material sedimenting out of the water column may have induced chemo-nitrification sufficient to oxidise ammonium
in the anoxic benthic boundary layer. The nitrate formed would mostly be rapidly denitrified so that the δ15N [N2] would continue to become enriched during the presence of anoxia, as observed in hypolimnion and benthic boundary layer of
Lake Ngapouri. The changes in δ15N [N2] values indicate the potential use of isotope ratios to identify and quantify potential chemo-nitrification/denitrification
in the water column and sediment pore waters of lakes. 相似文献
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The sedimentary succession of Gallocanta lake, a closed saline lake located in the Iberian Range (NE Spain), documents two
successive lacustrine stages: (1) brackish lake stage and (2) shallow saline lake stage. The saline stage corresponds to the
present-day situation in which the lake water properties are mainly controlled by a strongly negative annual water balance.
The carbonates of the brackish lake stage have relatively constant δ18O values, however, they are rather high (δ18ODo = 2.4‰ and δ18OCc = 4.5‰ mean values) suggesting a hydrologically closed lake with a long residence time of the waters. δ18O values of carbonates from the saline stage vary greatly, and are lighter than in the previous stage (δ18ODo = 0.5‰, δ18OCc = −0.7‰, δ18OMgs = −2.3‰ mean values). These carbonates also precipitated in a hydrologically closed lake, but in equilibrium with a lake
water of more variable isotopic composition. The δ13C values for carbonates of both stages reflect a mixing of different pools of carbon, but during saline stage δ13C values have been more controlled by the equilibrium of the lake waters with atmospheric CO2. During the current stage, calcite and dolomite precipitate in Gallocanta lake mainly during spring and summer, although
dolomite precipitation is more favoured towards the summer. Magnesite precipitates at the beginning of autumn, when the first
rainfall re-dissolves the saline surface crust, producing saline waters with a high Mg2+ content. The isotopic composition of lake waters sampled in 2005 are far higher than those calculated from the carbonates.
It is considered that this could be due to two factors: either because there have not been many extremely dry years (like
the year 2005) during the development of the lake, or because the physical and chemical characteristics of the lake waters
in such conditions are not appropriate for the development of these minerals. 相似文献
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Zhijun Yao Jian Liu He-Qing Huang Xianfang Song Xiaohui Dong Xin Liu 《Environmental Geology》2009,57(3):551-556
The stable hydrogen and oxygen of lake, river, rain and snow waters were investigated to understand the water cycle characteristics
of the drainage basin of Manasarovar Lake in Tibet. Both δD and δ
18O of river water are larger than those of lake water and the effect of altitude on both δD and δ
18O is not very significant. This phenomenon was suggested to occur because Manasarovar basin is located in Qinghai–Tibet Plateau
which has low latitude, high altitude, abundant glaciers, thin air and intensive solar radiation, resulting in higher evaporation
in lake water. 相似文献
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Barbara Vokal-Nemec Janina Szaran Andrzej Trembaczowski Stanislaw Halas Tadej Dolenec Sonja Lojen 《Aquatic Geochemistry》2006,12(3):199-220
Measurements were made of sulphur and oxygen isotope ratios of sulphate in some Slovenian rivers, lakes and tap waters. δ34S ranged from −0.2 to + 13.3‰, δ18O ranged from +4.9 to + 13.6‰, and the sulphate content varied from 0.8 to 41.4 mg/L. Rivers flowing from the Julian Alps
contain a very low amount of sulphate that is leached from a thin horizon of soil by rain. As confirmed by their low δ18O values, these sulphates do not enter the rivers directly in rain, but arise from biochemical cycling in the soil. The low
δ34S of this sulphate indicates that it originates from the oxidation of sedimentary sulphides. The evolution of sulphates along
the river course was investigated for the Sava and Ljubljanica rivers. The variations observed in sulphate from the waters
studied result from variations in the contribution of sulphates of different origin. Downstream the Sava River sulphate is
depleted in the heavy isotopes of both sulphur and oxygen, with δ-values gradually tending toward the δ-values of groundwater
sulphates in the watershed. In contrast, the δ-values of sulphate in the Ljubljanica River are almost constant and similar
to those of sulphate in local groundwater. Introduction of water from Italian and Slovenian mines was recorded in the Soča
River, where the lowest δ34S value of sulphate sulphur (−0.2‰) was observed. In addition, the influence of sulphate from the oxidation of sedimentary
sulphides was recorded in the Sotla River. No evidence was found for introduction of sulphate from factories. 相似文献
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Mark E. Brandriss Richard J. Nevle Dennis K. Bird James R. O’Neil 《Contributions to Mineralogy and Petrology》1995,121(1):74-86
Hydrogen and oxygen isotope analyses have been made of hydrous minerals in gabbros and basaltic xenoliths from the Eocene
Kap Edvard Holm intrusive complex of East Greenland. The analyzed samples are of three types: (1) primary igneous hornblendes
and phlogopites that crystallized from partial melts of hydrothermally altered basaltic xenoliths, (2) primary igneous hornblendes
that formed during late–magmatic recrystallization of layered gabbroic cumulates, and (3) secondary actinolite, epidote and
chlorite that formed during subsolidus alteration of both xenoliths and gabbros. Secondary actinolite has a δ18O value of −5.8‰ and a δD value of −158‰. These low values reflect subsolidus alteration by low–δ18O, low–δD hydrothermal fluids of meteoric origin. The δD value is lower than the −146 to −112‰ values previously reported
for amphiboles from other early Tertiary meteoric–hydrothermal systems in East Greenland and Scotland, indicating that the
meteoric waters at Kap Edvard Holm were isotopically lighter than typical early Tertiary meteoric waters in the North Atlantic
region. This probably reflects local climatic variations caused by formation of a major topographic dome at about the time
of plutonism and hydrothermal activity. The calculated isotopic composition of the meteoric water is δD=−110 ± 10‰, δ18O ≈−15‰. Igneous hornblendes and phlogopites from pegmatitic pods in hornfelsed basaltic xenoliths have δ18O values between −6.0 and −3.8‰ and δD values between −155 and −140‰. These are both much lower than typical values of fresh
basalts. The oxygen isotope fractionations between pegmatitic hornblendes and surrounding hornfelsic minerals are close to
equilibrium fractionations for magmatic temperatures, indicating that the pegmatites crystallized from low–δ18O partial melts of xenoliths that had been hydrothermally altered and depleted in 18O prior to stoping. The pegmatitic minerals may have crystallized with low primary δD values inherited from the altered country
rocks, but these values were probably overprinted extensively by subsolidus isotopic exchange with low–δD meteoric–hydrothermal
fluids. This exchange was facilitated by rapid self–diffusion of hydrogen through the crystal structures. Primary igneous
hornblendes from the plutonic rocks have δ18O values between +2.0 and +3.2‰ and δD values between −166 and −146‰. The 18O fractionations between hornblendes and coexisting augites are close to equilibrium fractionations for magmatic temperatures,
indicating that the hornblendes crystallized directly from the magma and subsequently underwent little or no oxygen exchange.
The hornblendes may have crystallized with low primary δD values, due to contamination of the magma with altered xenolithic
material, but the final δD values were probably controlled largely by subsolidus isotopic exchange. This inference is based
partly on the observation that coexisting plagioclase has been extensively depleted in 18O via a mineral–fluid exchange reaction that is much slower than the hydrogen exchange reaction in hornblende. It is concluded
that all hydrous minerals in the study area, whether igneous or secondary, have δD values that reflect extensive subsolidus
isotopic equilibration with meteoric–hydrothermal fluids.
Received: 22 March 1994 / Accepted: 26 January 1995 相似文献
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文章对在青藏高原腹地可可西里地区的苟鲁错封闭湖盆中心部位获取深1m的湖底沉积岩芯进行137Cs,210Pb测年和高分辨率的碳酸盐含量、地球化学等方面的分析。结果表明:该湖泊沉积记录揭示出青藏高原腹地在近1000年时间尺度上气候变化的模式呈冷湿和温(暖)干组合为主。该岩芯覆盖了过去近1000年左右的时间尺度,其碳酸盐含量、元素地球化学的变化对中世纪暖期和小冰期的3次冷期和期间的多次暖期都有明显反映。从苟鲁错沉积记录来看,中世纪暖期的盛期处于公元1060～1140年;小冰期第1次冷期在公元1140～1340年,但在1250～1290年存在1次暖波动;第2次冷期在公元1510～1680年,但在1580～1590年和1610年左右存在暖波动;第3次冷期在公元1790～1900年;暖期主要在公元1340～1510年和1680～1790年间,但在公元1400年、1410年左右和1440～1480年间以及1710～1740年存在冷波动;20世纪暖期和全球记录相一致。该湖泊记录与古里雅冰芯记录和祁连山树轮记录以及我国东部气候历史记录都有较好的可对比性,只是在起迄年代上还存在一些差异有待深入研究。 相似文献
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青藏高原苟鲁错湖泊沉积记录的小冰期气候变化 总被引：34，自引：15，他引：19
文章对在青藏高原腹地可可西里地区的苟鲁错封闭湖盆中心部位获取深1m的湖底沉积岩芯进行137Cs,210Pb测年和高分辨率的碳酸盐含量、地球化学等方面的分析。结果表明:该湖泊沉积记录揭示出青藏高原腹地在近1000年时间尺度上气候变化的模式呈冷湿和温(暖)干组合为主。该岩芯覆盖了过去近1000年左右的时间尺度,其碳酸盐含量、元素地球化学的变化对中世纪暖期和小冰期的3次冷期和期间的多次暖期都有明显反映。从苟鲁错沉积记录来看,中世纪暖期的盛期处于公元1060～1140年;小冰期第1次冷期在公元1140～1340年,但在1250～1290年存在1次暖波动;第2次冷期在公元1510～1680年,但在1580～1590年和1610年左右存在暖波动;第3次冷期在公元1790～1900年;暖期主要在公元1340～1510年和1680～1790年间,但在公元1400年、1410年左右和1440～1480年间以及1710～1740年存在冷波动;20世纪暖期和全球记录相一致。该湖泊记录与古里雅冰芯记录和祁连山树轮记录以及我国东部气候历史记录都有较好的可对比性,只是在起迄年代上还存在一些差异有待深入研究。 相似文献
19.
Wang Yong Hou Zengqian Mo Xuanxue Dong Fangliu Bi Xianmei Zeng Pusheng 《Frontiers of Earth Science》2007,1(3):322-332
More than 140 middle-small sized deposits or minerals are present in the Weishan-Yongping ore concentration area which is
located in the southern part of a typical Lanping strike-slip and pull-apart basin. It has plenty of mineral resources derived
from the collision between the Indian and Asian plates. The ore-forming fluid system in the Weishan-Yongping ore concentration
area can be divided into two subsystems, namely, the Zijinshan subsystem and Gonglang arc subsystem. The ore-forming fluids
of Cu, Co deposits in the Gonglang arc fluid subsystem have δD values between −83.8‰ and −69‰, δ18O values between 4.17‰ and 10.45‰, and δ13C values between −13.6‰ and 3.7‰, suggesting that the ore-forming fluids of Cu, Co deposits were derived mainly from magmatic
water and partly from formation water. The ore-forming fluids of Au, Pb, Zn, Fe deposits in the Zijinshan subsystem have δD
values between −117.4‰ and −76‰, δ18O values between 5.32‰ and 9.56‰, and Δ13C values between −10.07‰ and −1.5‰. The ore-forming fluids of Sb deposits have δD values between −95‰ and −78‰, δ18O values between 4.5‰ and 32.3‰, and Δ13C values between −26.4‰ and −1.9‰. Hence, the ore-forming fluids of the Zijinshan subsystem must have been derived mainly
from formation water and partly from magmatic water. Affected by the collision between the Indian and Asian plates, ore-forming
fluids in Weishan-Yongping basin migrated considerably from southwest to northeast. At first, the Gonglang arc subsystem with
high temperature and high salinity was formed. With the development of the ore-forming fluids, the Zijinshan subsystem with
lower temperature and lower salinity was subsequently formed.
Translated from Mineral Deposits, 2006, 25(1): 60–70 [译自: 矿床地质] 相似文献
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Geochemical mixing models were used to decipher the dominant source of freshwater (rainfall, canal discharge, or groundwater
discharge) to Biscayne Bay, an estuary in south Florida. Discrete samples of precipitation, canal water, groundwater, and
bay surface water were collected monthly for 2 years and analyzed for salinity, stable isotopes of oxygen and hydrogen, and
Sr2+/Ca2+ concentrations. These geochemical tracers were used in three separate mixing models and then combined to trace the magnitude
and timing of the freshwater inputs to the estuary. Fresh groundwater had an isotopic signature (δ
18O = −2.66‰, δD −7.60‰) similar to rainfall (δ
18O = −2.86‰, δD = −4.78‰). Canal water had a heavy isotopic signature (δ
18O = −0.46‰, δD = −2.48‰) due to evaporation. This made it possible to use stable isotopes of oxygen and hydrogen to separate canal water
from precipitation and groundwater as a source of freshwater into the bay. A second model using Sr2+/Ca2+ ratios was developed to discern fresh groundwater inputs from precipitation inputs. Groundwater had a Sr2+/Ca2+ ratio of 0.07, while precipitation had a dissimilar ratio of 0.89. When combined, these models showed a freshwater input
ratio of canal/precipitation/groundwater of 37%:53%:10% in the wet season and 40%:55%:5% in the dry season with an error of
±25%. For a bay-wide water budget that includes saltwater and freshwater mixing, fresh groundwater accounts for 1–2% of the
total fresh and saline water input. 相似文献