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1.
Numerous studies have demonstrated the efficacy of bioremediation for enhancing oil removal but the ecological effect on shoreline biota is unclear. Therefore, a field experiment was designed at an intertidal sandflat in SW England to assess the effects of nutrient addition to oiled sediments on meio- and macrofauna for a period of up to 45 weeks. Natural assemblages were exposed to different types of experimental treatments (no oil, oil alone, oil treated with slow-release fertiliser or liquid fertiliser). Bioremediation stimulated the microbial population and increased oil biodegradation. This, however, did not result in faster recolonisation rates of fertilised versus non-fertilised oiled sediments. Mild effects of oil and bioremediation treatments on benthic fauna were observed, including short-term shifts in dominance patterns. Decreased abundance of dominant species in the oiled compared to unoiled sediments resulted in significantly higher evenness of benthic assemblages within the first 11 weeks of the experiment.  相似文献   

2.
This study attempted to determine whether Patiriella exigua, an Australian seastar, could detect and/or avoid oiled sediment when given an equal choice of unoiled sediment. The sediment was spiked once to produce one of three concentrations of oiled sediment used in the test chambers versus unoiled sediment. Behavioral observations were repeated over a 32 day period to test the effects of aging the oiled sediment. Results show that Patiriella exigua was capable of detecting oiled sediment and/or an oiled environment. Seastars avoided oiled sediment, with significantly higher numbers choosing either to reside on the clean sediment (p<0.05) or to travel up the glass sides of the tanks (p<0.001). Avoidance of oiled sediment increased with increasing sediment oil concentrations. Aging the oiled sediment decreased the oil content of the sediment and increased the number of seastars able to inhabit it (p<0.001). A potential narcotic effect of exposure to oiled sediment was observed.  相似文献   

3.
Lithologic data compiled from Deep Sea Drilling Project and Ocean Drilling Program sites, when combined with orthogonal convergence rates at convergent plate boundaries, permit quantification of the mass flux of sediment into subduction zones. We have made such calculations for each major sediment component — terrigenous grains, calcium carbonate, opal, and water — for twelve trench systems. Results show that 1.4 × 1015 g/yr of sediment and 0.9 × 1015 g/yr of water enter the trenches in the oceanic sedimentary layer. Most of the entering sediment, 1.1 × 1015 g/yr, is terrigenous; the remainder is more carbonate than opal. For most of geologic time an order of magnitude more sediment enters the ocean than leaves it via subduction. The global sedimentary cycle need be in balance only over an entire Wilson cycle. Comparison of sediment fluxes into trenches with the magnitude of large earthquakes and with the composition of bulk volcanic rock shows no correlation.  相似文献   

4.
The fate of polycyclic aromatic hydrocarbon (PAH) contamination in a mangrove swamp (Yi O) in Hong Kong after an oil spill accident was investigated. The concentrations and profiles of PAHs in surface sediments collected from five quadrats (each of 10 m×10 m) covering different degrees of oil contamination and the most contaminated mangrove leaves were examined in December 2000 (30 days after the accident) and March 2001 (126 days later). The concentrations of total PAHs in surface sediments ranged from 138 to 2135 ng g−1, and PAHs concentrations decreased with time. In the most contaminated sediments, total PAHs dropped from 2135 (30 days) to 1196 ng g−1 (120 days), and the decrease was smaller in less contaminated sediments. The percentage reduction in sediment PAHs over three months (44%) was less significant than that in contaminated leaves (85%), indicating PAH in or on leaves disappeared more rapidly. The PAH profiles were very similar in sediments collected from quadrats Q1 and Q2 with benzo[a]anthracene and pyrene being the most abundant PAH compounds, but were different in the other three quadrats. The proportion of the light molecular weight PAHs to total PAHs increased after three months, especially phenanthrene. Results suggest that physical and photo-chemical weathering (tidal washing and photo-oxidation) of crude oil in surface sediments and on plant leaves were important processes in the first few months after the oil spill. The PAH contamination in Yi O swamp came from both petrogenic and pyrolytic sources. The petrogenic characteristic in the most contaminated sediment was confirmed with high values of phenanthrene to anthracene ratio (>10) and low values of fluoranthene to pyrene ratio (0.3–0.4).  相似文献   

5.
This field study was a combined chemical and biological investigation of the relative rates of weathering and biodegradation of oil spilled in sediments and testing the influence of a bioremediation protocol. The aim of the chemistry work presented here was to determine whether the bioremediation protocol affected the rate of penetration, dissipation or long-term retention of a medium range crude oil (Gippsland) and a Bunker C oil stranded in tropical Rhizophora sp. mangrove and Halosarcia sp. salt marsh environments. Permission for the planned oil spills was granted in the Port Authority area of Gladstone, Queensland (Australia). Sediment cores from three replicate plots of each treatment for mangroves and four replicate plots for the salt marsh (oil only and oil plus bioremediation) were analysed for total hydrocarbons (THC) and for individual alkane markers using gas chromatography with flame ionization detection (GC–FID). Sediments were collected at day 2, then 1, 2, 5 or 6 and 12 or 13 months post-spill for mangroves and day 2, 1, 3 and 9 months post-spill for salt marshes. Over this time, hydrocarbons in all of the oil treated plots decreased exponentially. There was no statistical difference in initial oil concentrations, penetration of oil to depth, or in the rates of oil dissipation between untreated oil and bioremediated oil in the mangrove plots. The salt marsh plots treated with the waxy Gippsland oil showed a faster rate of biodegradation of the oil in the bioremediated plots. In this case only, the degradation rate significantly impacted the mass balance of remaining oil. The Bunker C oil contained only minor amounts of highly degradable n-alkanes and bioremediation did not significantly impact its rate of loss in the salt marsh sediments. At the end of each experiment, there were still n-alkanes visible in the gas chromatograms of residual oils. Thus it was concluded that there was unlikely to be any change in the stable internal biomarkers of the oils over this time period. The predominant removal processes in both habitats were evaporation and dissolution, with a lag-phase of 1–2 months before the start of microbial degradation.  相似文献   

6.
Over a three-year period (1995–1998), we studied short-term effects of dispersant use and a bioremediation strategy in two consecutive field trials in sub-tropical Australian mangroves. In each case, weathered oil was applied, and a large spill simulated, in mature Rhizophora stylosa trees around 4–9 m tall. In the first trial, we used Gippsland light crude oil with or without dispersant, Corexit 9527. In the second, a bioremediation strategy followed application of Gippsland oil or Bunker C fuel oil. Bioremediation involved forced aeration with supplemental application of nutrients. Dispersant use had an overall positive benefit shown as reduced tree mortality. By contrast, there was no apparent reduction in mortality of trees with bioremediation. However, one year after oiling, leaf densities of surviving trees were greater in bioremediation plots than in controls, and less in oil-only plots. These and other results have been incorporated into spill response management strategies in Australia.  相似文献   

7.
A field study evaluated Spartina alterniflora sensitivity to oiling and to in situ burning of applied crude oil. Experimental plots (2.4 m × 2.4 m × 0.6 m) were constructed in the salt marsh for control, oiling (natural clean-up) and oiling/burning treatments. South Louisiana Crude was applied to oiling and oiling/burning treatment plots at 2 l m−2 and the burn conducted. S. alterniflora responses (height, live stem density, carbon fixation and biomass) were measured for 50 weeks after the August burn. Oiling and oiling/burning had short-term detrimental effects on the salt marsh. One year after the late summer burn, S. alterniflora responses measured in the oiled and oiled/burned plots were not significantly different compared to control values. Results suggest that, under our experimental conditions, intervention may not be required for marsh recovery. However, if spill conditions require a rapid response to control contaminant spread or protect other sensitive resources, burning may be a clean-up operation to consider.  相似文献   

8.
The activity ratios of Pu and radiocesium isotopes have been used to delineate the major sources (such as global and close-in (debris) fallout, nuclear fuel reprocessing and fabrication plant effluents) in the environment. We have measured 238Pu, 239,240Pu, 137Cs, and excess 210Pb concentrations in 107 surficial sediments as well as in 5 sediment cores collected in the summer months of 1993 and 1994 from the Ob and Yenisey Rivers (Russia) and the Kara sea. A comparison of the sediment core inventories of 239,240Pu and 137Cs, along with the 238Pu/239,240Pu activity ratios, with those expected from global fallout allows us to estimate the relative amounts, if any, of reactor-derived 238Pu and 239,240Pu from the dumped reactor sites in the study area.

In surficial sediment samples collected in 1993 and 1994, the 239,240Pu concentrations varied between 4.2 and 856 mBq kg−1, with a mean of 239 mBq kg−1. In samples with a measurable 238Pu, the 238Pu/239,240Pu activity ratios varied between 0.010 and 0.069, with an average value of 0.035 ± 0.014. This range can be compared to the average 238Pu/239,240Pu activity ratio of 0.030 for the year 1993 from nuclear weapons testing and SNAP fallout obtained from soil studies, indicating very little (≤ 5%) additional sources of 238Pu to the sediments in the study area. The inventories of Pu in the 5 sediment cores from the study area varied between 2.67 ± 0.67 and 24.5 ± 2.2 Bq m−2 with a mean value of 8.83 Bq m−2. The 137Cs concentrations in the upper 3 cm of the sediments varied between below detection limit to 71.4 Bq kg−1, with a mean of 14.9 Bq kg−1. The 137Cs inventories in the 5 sediment cores varied between 156.7 ± 28.3 and 1600 ± 153.3 Bq m−2, with a mean value of 583.3 Bq m−2. The mean ratio of inventories of Pu to that of 137Cs, 0.015, is comparable to the values in other places in the Arctic region. There is a significant correlation between total organic carbon and concentrations of 137Cs, 239,240Pu and 210Pb, suggesting that organic matter-enriched fine particles are a likely carrier phase for these nuclides. The ratio of 137Cs/239,240Pu also suggests that most of these nuclides are derived from global fallout.  相似文献   


9.
To investigate the effect of sediment contamination on the tellinid bivalve Macomona liliana, juvenile shellfish (about 1.3 mm long) were exposed to copper- and zinc-dosed sand, and sediments collected from several contaminated sites. The behavioural responses measured included burial rate, crawling and drifting. In copper-dosed sediment, a significant reduction in the number of shellfish burying after 10 min occurred at 25 mg Cu kg−1 (dry wt). After a 96-h exposure, shellfish crawled away from sediment with 10 mg Cu kg−1 (dry wt), and when a weak current was provided they left this 10 mg Cu kg−1 (dry wt) sediment by drifting. Zinc-dosed sediment slowed burial at 80 mg Zn kg−1 (dry wt), and stimulated crawling and drifting at 40 mg Zn kg−1 (dry wt). Some of the field-collected contaminated sediments slowed burial and stimulated drifting, but none affected crawling. It appears that juvenile drifting induced by sediment contamination could play a role in determining M. liliana distributions.  相似文献   

10.
The pattern and style of mantle convection govern the thermal evolution, internal dynamics, and large-scale surface deformation of the terrestrial planets. In order to characterize the nature of heat transport and convective behaviour at Rayleigh numbers, Ra, appropriate for planetary mantles (between 104 and 108), we perform a set of laboratory experiments. Convection is driven by a temperature gradient imposed between two rigid surfaces, and there is no internal heating. As the Rayleigh number is increased, two transitions in convective behaviour occur. First we observe a change from steady to time-dependent convection at Ra≈105. A second transition occurs at higher Rayleigh numbers, Ra≈5×106, with large-scale time-dependent flow being replaced by isolated rising and sinking plumes. Corresponding to the latter transition, the exponent β in the power law relating the Nusselt number Nu to the Rayleigh number (NuRaβ) is reduced. Both rising and sinking plumes always consist of plume heads followed by tails. There is no characteristic frequency for the formation of plumes.  相似文献   

11.
Cosmic-ray-produced26Al (t1/2 = 7.05 × 105 years) has been measured in the Apollo 15 long core (surface to 390 g/cm2—218 cm) for study of galactic cosmic ray production profiles, using accelerator mass spectrometry. The results are in general accord with non-destructive counting data obtained earlier, but systematically lower, and significantly higher precision. From this experiment the half-attenuation length for26Al production can be calculated to be 122 g/cm2 (150–400 g/cm2 region) after normalizing the data to average chemical composition. The53Mn (t1/2 = 3.7 × 106 years) production profile in deep cores was also compiled to date. The half-attenuation length for53Mn production was calculated to be 123 g/cm2 (150–400 g/cm2 region).  相似文献   

12.
Cosmic-ray-produced10Be (t1/2 = 1.6 × 106 years) and36Cl (t1/2 = 3.0 × 105 years) have been measured in the Apollo 15 long core for study of galactic cosmic ray production profiles using tandem accelerator mass spectrometry. From these experiments, the half-attenuation length for10Be production and36Cl production were calculated to be 120 g/cm2 and 132 g/cm2 (150–400 g/cm2 region). The measured half-attenuation length for10Be is slightly longer than that predicted by the Reedy-Arnold theoretical model. The flatter and somewhat deeper maximum seen in the36Cl profile compared to the10Be,26Al and53Mn profiles can be explained by production from secondary thermal neutrons on35Cl.  相似文献   

13.
Noble gases were extracted in steps from grain size fractions of microdiamonds ( < 100 μm) from the Kokchetav Massif, Northern Kazakhstan, by pyrolysis and combustion. The concentration of 4He in the diamonds proper (liberated by combustion) shows a 1/r dependence on grain size. For grain diameters > 15 μm the concentration also decreases with the combustion step. Both results are clear evidence that 4He has been implanted into the diamonds from -decaying elements in the surrounding matrix. The saturation concentration of 4He(5.6 × 10−4 cm3 STP/g) is among the very highest observed in any terrestrial diamonds. Fission xenon from the spontaneous fission of 238U accompanies the radiogenic 4He; the 136Xef/4He ratio of (2.5 ± 0.3) × 10−9 agrees well with the production ratio of 2.3 × 10−9 expected in a reservoir where Th/U 3.3. Radiogenic 40Ar is predominantly ( > 90%) set free upon combustion; it also resides in the diamonds and appears to have been incorporated into the diamonds upon their formation.

3He, on the other hand is mainly released during pyrolysis and hence is apparently carried by ‘contaminants’. The concentration in the diamonds proper is of the order of 4 × 10−12 cm3 STP/g, with a 3He/4He ratio of 1 × 10−8. Excess 21Ne, similarly, appears to be present in contaminants as well as in diamonds proper. These two nuclides in the contaminants must have a nucleogenic origin, but it is difficult to explain their high concentrations.  相似文献   


14.
Water sampling during the 1993 IV Russian–US Joint Expedition to the Bering and Chukchi Seas (BERPAC) indicates that Pacific Ocean burdens of the long-lived radionuclide 129I are relatively low in the Pacific-influenced Arctic, particularly compared to high latitude waters influenced by the North Atlantic. These low concentrations occur despite the presence of potential submerged anthropogenic sources in the East Sea (Sea of Japan), and in the northwest Pacific Ocean, east of the Kamchatka Peninsula. The concentration of 129I entering the Arctic Ocean through Bering Strait, 0.7×108 atoms kg−1, is only slightly higher than observed in deep Pacific waters. Similar concentrations (0.44–0.76×108 atoms kg−1) measured in Long Strait indicate no significant transfer of 129I eastward into the Chukchi Sea in the Siberian Coastal Current from the Siberian marginal seas to the west. However, the concentrations reported here are more than an order of magnitude higher than the Bering Strait input concentration estimated (1.0×106 atoms kg−1) from bomb fallout mass balances, which supports other existing evidence for a significant atmospheric deposition term for this radionuclide in surface ocean waters. Near-bottom water samples collected in productive waters of the Bering and Chukchi Seas also suggest that sediment regeneration may locally elevate 129I concentrations, and impact its utility as a water mass tracer. As part of this study, two deep 129I profiles were also measured in the East Sea in 1993–1994. The near-surface concentration of 129I ranged from 0.12 to 0.31×108 atoms kg−1. The 129I concentration showed a steady decrease with depth, although because of active deep water ventilation, the entire 3000 m water column exceeded natural concentrations of the radionuclide. Atom ratios of 129I/137Cs in the East Sea also suggest an excess of 129I above bomb fallout estimates, also possibly resulting from atmospheric deposition ultimately originating from nuclear facilities.  相似文献   

15.
The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1−1) in Bedford Basin seawater, and became dominant (3–5×106 cells 1−1) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×106 and 2.2×104 cells 1−1, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended.  相似文献   

16.
Bunker C, one of the most frequently spilled petroleum products in the US, is difficult to remove from oiled surfaces and is relatively recalcitrant to biodegradation; therefore, emulsification and biodegradability must be optimized before bioremediation can be considered a viable treatment option. Sand from a freshly oiled beach near Dutch Harbor, Alaska, was incubated at 10 degrees C with nutrients (Bushnell-Haas (BH)) or nutrients with crab shell chitin (BH-C). BH-C amendment resulted in greater numbers of bunker C emulsifiers and greater mineralization potentials for hexadecane, phenanthrene, and fluorene than with BH only. Compared to BH alone, mineralization potentials for bunker C also were higher in BH-C, with an estimated 8% of fuel oil mineralized after 6 weeks. Microbially emulsified oil was more toxic than in uninoculated controls (p < 0.05) as measured by Microtox assays. However, toxicity was significantly lower in BH-C than BH after 4 and 6 weeks incubation (p < 0.05).  相似文献   

17.
Dislocation microstructures in naturally deformed silicate garnets   总被引：1，自引：0，他引：1  
Dislocation microstructures of naturally deformed silicate garnets and olivines in garnet-peridotites and silicate garnets in eclogites from four localities have been observed with a transmission electron microscope (TEM) to clarify the dislocation characteristics of silicate garnets. We have obtained the following results: (1) dislocation densities of garnets in all the garnet-peridotites (ρ = 105−107 cm−2) are always nearly an order of magnitude lower than those of co-existing olivines; (2) dislocation densities of garnets in eclogites (ρ = 105−108 cm−2) which are embedded in garnet-peridotites are almost an order of magnitude higher than those of garnets in the surrounding garnet-peridotites; (3) the dominant Burgers vector, b, of mainly edge dislocations in garnet is 100 for specimens with dislocation density ρ = 105−106 cm−2, while b=1/2111 for specimens with ρ = 107−108 cm−2. Result (1) indicates that the observed dislocations in garnets were formed by plastic deformation under the same stresses as for co-existing olivines, and that there is a similar relationship between applied stress and dislocation density for garnets as for olivines. Result (2) suggests that the stress concentration occurred around eclogites embedded in garnet-peridotites, and the resulting differential stress in garnets in eclogites was further elevated by the interlocking of neighboring hard garnet grains. Finally, result (3) indicates that the dominant Burgers vector of mainly edge dislocations in garnet changes from 100 to 1/2111 with increasing applied differential stress.  相似文献   

18.
Analytical procedures in the determination of iodine-129 (half-life: 1.6×107 y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the 129I/127I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10−13. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10−11 as the ratio of stable iodine (129I/127I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine 129I in soil samples with low 129I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the 129I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10−5−4.5×10−3 Bq/kg as 129I concentrations and 3.9×10−11−2.2×10−8 as 129I/127I ratios. These values are useful in understanding the 129I levels in Japanese environments. Higher 129I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric 129I due to tree canopies. Relatively high 129I/127I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.  相似文献   

19.
Bacterial abundances and activity, estimated by 4′,6-diamidino-2-phenylindole staining (DAPI) and the reduction of 2-(p-iodophenyl)-3-(p-nitrophenyl)-5-phenyl tetrazolium chloride (INT), were investigated in two oligotrophic artificial groundwater lakes and the surrounding aquifers. To evaluate the effect of lake water on groundwater downstream, samples were taken from wells at different distances from the lakes, and the total number of bacteria and the number of active bacteria in these samples were compared with samples collected upstream. In addition, sterilized sandy sediments were exposed in groundwater wells to measure the number and activity of bacteria attached to particles. At one of the study sites, where the lake sediments were disturbed by dredging, total bacterial abundance and the number of respiring bacteria in the groundwater aquifer was clearly influenced by the lake water. The average bacterial abundances decreased from 2.6 ± 1.9 × 105 cells ml−1 in the well closest to the lake (S2) to 2.9 ± 3.8 × 104 cells ml−1 in the most distant one (S4), which was equivalent to cell numbers in the upstream well. The number of respiring bacteria showed a similar tendency with 1.3 ± 2.7 × 104 active cells ml−1 in S2 and 1.9 ± 1.5 × 103 active cells ml−1 in S4. At the second study site, which was not influenced by dredging, bacteria in the downstream wells seemed not to be affected by the lake water. The number and activity of bacteria, which colonized exposed sediments, were not significantly different in the upstream and downstream wells, indicating a minor influence of lake water on this habitat. Our results suggest that gravel-pit lakes may influence the free living bacterial assemblages in nearshore groundwater systems, but do not visibly affect numbers and activity of bacteria attached to the surface of aquifer sediments.  相似文献   

20.
Bioconcentration factors (Kbc) for petroleum hydrocarbons, PAHs, LABs and biogenic hydrocarbons in Mytilus edulis were measured in field experiments using time-integrating water samplers. Seven deployments at five sites gave lipid weight Kbcs for total hydrocarbons ranging from 0.99 × 106 to 3.1 × 106 (mean 1.6 × 106)—a narrower range than has been obtained previously. Bioconcentration factors for the PAHs were similar to those for total hydrocarbons where the major hydrocarbon source was oil. However, at other sites the factors for PAHs were an order of magnitude lower than those for petroleum and for hydrocarbons originating from algae. Compositional profiles for the linear alkyl benzenes (LABs) suggested that these compounds were assimilated primarily from the dissolved phase, despite their greater abundance on particles.  相似文献   

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