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1.
Waste printed circuit boards are complex heterogeneous mixture consisting of organic material, metal and glass fiber, therefore, it is quite difficult for the recovery of valuable materials from waste printed circuit boards. In this study, waste printed circuit boards without electronic components (known as bare boards) are submerged into dimethyl sulfoxide solvent at 170 °C using refluxing process. Metallographic microscope shows that waste printed circuit boards produce the delamination after treated with dimethyl sulfoxide solvent for 15 min. When waste printed circuit boards are treated with dimethyl sulfoxide solvent for 30 min, the separation of waste printed circuit boards is complete to obtain metals and glass fibers. Moreover, the used dimethyl sulfoxide solvent is vaporized by the rotary decompression which obtains regenerative dimethyl sulfoxide and solid residues. Comparing two Fourier transform infrared spectroscopies, it is found that the regenerative dimethyl sulfoxide is the same as original dimethyl sulfoxide. Thermal analyses combined with Fourier transform infrared spectroscopy show that the solid residues are bromine epoxy resins. These findings suggest that this innovative technology offers an environmental friendly process with no pollution and high efficiency for separating valuable materials from waste printed circuit boards.  相似文献   

2.
Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.  相似文献   

3.
为了解决上覆岩层中无明显厚硬岩层、采动过程中难以产生较大尺寸离层空间、离层注浆充填率低的问题,提出采动覆岩离层多层位注浆技术。通过相似材料模拟实验对多层位离层注浆覆岩时空演化规律进行研究,并在淮北矿区某工作面进行现场试验。结果表明:在无较大采动覆岩离层情况下,采用增加钻孔数目的多层位离层注浆方法,在采动覆岩内部形成不同扩散半径的注浆充填体,共同叠加支撑上覆岩层,可以有效减小覆岩破坏程度。实施多层位离层注浆方法,可以有效提高注浆总量和注采比,地表减沉率可达79.92%。提出的离层注浆量计算公式可以精确预计浆液灌注量,准确率超过91%,可为覆岩离层注浆工程提供指导,并为注浆减沉率预计提供参考。这为解决煤炭资源开采引起的地表沉陷问题提供了一种有效和经济的方法,同时扩大覆岩注浆技术的应用范围。   相似文献   

4.
Combination of flotation and magnetic separation methods is widely used for enrichment of feldspar ores by purifying from dark-colored gangue minerals such as iron and titanium. In this study, the removal of dark-colored minerals from feldspar ore (Aydin Cine region of Turkey) was studied using a dry magnetic separator. The effect of several parameters such as feed particle size, blade angle, and roll speed on the removal efficiency was investigated in detail. In addition, the gangue contents of the magnetic and non-magnetic products were determined by a digital image processing (DIP) method in terms of using color differences between the feldspar sample and gangue minerals. The results obtained from this study clearly indicated that the dry magnetic separation method can be successfully applied in enrichment of feldspar. Meanwhile, the particle size of the sample showed no significant influence on the separation recovery. According to the results obtained from the digital image processing process, the sample with 0.04% cross sectional area of dark-colored minerals can be obtained at roll speed of 100 rpm and 130° of blade angle using the original particle size of 500×106 μm. Additionally, most importantly, these results showed that digital image processing method can be used to determine gangue content (dark-colored minerals) of the magnetic separation products compared to conventional methods as a simple, a reliable, and a repeatable method.  相似文献   

5.
Procedures for 3D mineral liberation analysis by X-ray micro CT (XMT) are presented and discussed including the construction of liberation-limited grade/recovery curves for specific feed materials. In this way, actual separation efficiencies can be compared to what might be expected for a perfect separation limited only by the extent of liberation. It is shown that 3D mineral liberation analysis based on XMT is preferred to 2D section analysis which overestimates the extent of liberation. By way of example, procedures and experimental results are presented and discussed for feed material in the case of phosphate rock flotation.  相似文献   

6.
A major operating cost in dense-medium separation is in replacement of lost medium solids. The loss of medium solids, being costly, plays a crucial role in determining the economics of any preparation operation. Coal washeries that employ dense-medium cyclones often attempt optimization of the processes by varying the vortex or the spigot diameter and the feed relative density. While these changes help in closer control of the separation process, they also result in medium losses due to changes in the medium split ratio (ratio of the medium flow rate in overflow to underflow). Since medium solids are lost by adhesion to products and as magnetic separator effluent, the effect of the change in medium split ratio on the drain-and-rinse screens and, hence, the magnetic separator circuit needs to be studied. In Tata Steel's coal washeries, at Jharkhand India, which employs primary and secondary dense-medium cyclones in series to produce clean coal, middlings and rejects, reducing the relative density of feed medium, had an insignificant effect on the medium split ratio. On the other hand, changing the cone ratio (ratio of the overflow diameter to the underflow diameter) changed the relative density and the flow rates through the cyclone outlets, thus affecting the performance of the magnetite recovery circuit.A systematic study through laboratory tests and a detailed plant sampling campaign helped in identifying the causes of magnetite loss. Upon implementation of the recommendations, the magnetite losses decreased, resulting in a saving of approximately US$27,500 per annum. The study also helped in evolving some checkpoints for plant operators for identifying magnetite losses.  相似文献   

7.
Direct reduction of iron ore to produce electric furnace feed for steelmaking is becoming economically important on a worldwide scale. For this application an iron ore superconcentrate containing less than 2% silica is demanded. Pilot plant and commercial operations have shown that high-intensity wet magnetic separation is well adapted to meet this specification with high recovery and attractive capital and operating costs. Tests with the Jones separator have produced superconcentrates containing less than 1.5% silica with over 90% iron recovery from preconcentrates produced by sizing or by gravity or low-intensity magnetic separation. Estimated total capital and operating costs to produce a ton of superconcentrate by high-intensity wet magnetic separation are $0.43 for retreatment of specular hematite spiral concentrate, $0.47 for Brazilian hematite fines, and $0.49 for magnetite.  相似文献   

8.
运用灰色优势分析法对摇床选矿过程中冲程、床面坡度、给矿浓度和给矿量等操作参数对选矿效果（精矿品位和业矿回收率）的影响进行了研究,获得了摇床选别细粒砂矿影响因素的显著性序次;对精矿品位影响的显著性依次是冲程、床面坡度、给矿量和给矿浓度;对精矿回收率影响的显著性依次是冲程、给矿量、床面坡度和给矿浓度。该结论为摇床选别细粒砂矿进一步调优试验指明了方向。  相似文献   

9.
The possibility of increasing the concentration of gibbsite in ferruginous bauxite by means of high-gradient magnetic separation (HGMS) has been studied. The effects of particle size, type of matrix, magnetic field and flow rate were tested. Enrichments of up to 13% were obtained under the experimental conditions used. The importance of selection of optimum operating conditions is evidenced by the results and empirical equations for data correlation are suggested.  相似文献   

10.
ABSTRACT Particles projecting from the bed of an alluvial channel distort the fluid stream to produce a distinctive pressure field. This has considerable significance for both the entrapment and entrainment of other particles and is a primary cause of the widespread occurrence of pebble clusters and boulder shadows. Lift and drag forces are determined on clustered hemispherical particles of varying size. In the wake of an obstructing particle both forces are shown to vary directly with particle separation in a linear fashion. On the stoss side of the cluster, drag is uniform regardless of the separation of the component particles, but lift is shown to increase when particle separation is small, so affecting stability. This mutual interference of neighbouring clustered bed particles is a vital consideration of incipient motion and is shown by field evidence to cause a wide range in transport stage for particles of similar size and shape. On average, 46% of clustered particles are entrained by flood flow compared to 87% of particles in open plane-beds. The influence of clusters is a major determinant of sedimentary sorting.  相似文献   

11.
Whereas high-grade dolomites and limestones find extensive use in the refractory and steel industries, high-silica dolomitic limestones are of little use and can cause disposal problems as mining rejects. The removal of silica and magnesia to certain specified limits can make them suitable for cement manufacture. Magnesia can be removed by a carbonation process after semi-calcination of dolomite but the removal of a large amount of silica prior to MgO separation, by the flotation process alone, is uneconomical. Here the results are presented of the investigations of hydrocyclone separation of silica from one such type of mining rejects. The results show that after grinding the feed material to suitable levels of liberation of quartz and carbonate grains, two cycles of operation in a 4′′ hydrocyclone, can recover about 45% of the limestone feed material with a lime/silica ratio adequate for cement manufacture.  相似文献   

12.
In mineral processing and coal cleaning operations, there are two classes of unit operations used in the separation processes. The first type — crushing, grinding, pelletizing and settling — modifies the size distribution of the feed. The second type — heavy media, sizing, flotation, magnetic, electrostatic and jigging — separates the particles. In these latter unit operations, the size distribution is not changed; rather, the feed stream is split into a product and waste stream based on subtle physical and physicochemical differences between the different types of feed particles. In separation unit operations, the mathematical functions, representing the behavior of the unit operations, are easy to manipulate. Thus, a number of theorems, useful to both the plant designer, and the plant engineer, can be proven.The work presented in this paper makes the fundamental assumption of linearity as do all current plant design analysis systems. The linearity assumption states that in a separation operation, there is no particle-particle interaction effecting the probability that a particle will be selected for the product or waste stream. In other words, if one doubles or triples the feed rate to a unit operation, the fraction of particles of a given characteristic selected to appear in the product stream remains unchanged. In actuality, this assumption is not true because higher feed rates affect the behavior of separation operations. However, when designing a plant, one can calculate the feed rate to a given unit operation and then select a piece of equipment large enough to handle the computed tonnage. Thus, the designed circuit behaves linearly.  相似文献   

13.
The separation process in a “falling curtain” of particles is investigated in detail. Each particle experiences gravity, air drag and magnetic forces, as well as collisions with other particles. A simple kinetic theory model is used to model these processes and the separation distance between two different minerals is calculated. The maximum throughput of a superconducting magnet can be as high as 10 tons/hour per meter of effective magnet length, with a recovery in excess of 90%.  相似文献   

14.
《Sedimentology》2018,65(2):561-581
Layered deposits of relatively light and heavy minerals can be found in many aquatic environments. Quantification of the physical processes which lead to the fine‐scale layering of these deposits is often limited with flumes or in situ field experiments. Therefore, the following research questions were addressed: (i) how can selective grain entrainment be numerically simulated and quantified; (ii) how does a mixed bed turn into a fully layered bed; and (iii) is there any relation between heavy mineral content and bed stability? Herein, a three‐dimensional numerical model was used as an alternative measure to study the fine‐scale process of density segregation during transport. The three‐dimensional model simulates particle transport in water by combining a turbulence‐resolving large eddy simulation with a discrete element model prescribing the motion of individual grains. The granular bed of 0·004 m in height consisted of 200 000 spherical particles (D50 = 500 μ m). Five suites of experiments were designed in which the concentration ratio of heavy (5000 kg m−3) to light particles (i.e. 2560 kg m−3) was increased from 6%, 15%, 35%, 60% to 80%. All beds were tested for 10 sec at a predefined flow speed of 0·3 m sec−1. Analysis of the particle behaviour in the interior of the beds showed that the lighter particles segregated from the heavy particles with increasing time. The latter accumulated at the bottom of the domain, forming a layer, whereas the lighter particles were transported over the layer forming sweeps. Particles below the heavy particle layer indicated that the layer was able to armour the particles below. Consequentially, enrichment of heavy minerals in a layer is controlled by the segregation of a heavy mineral fraction from the light counterpart, which enhances current understanding of heavy mineral placer formation.  相似文献   

15.
Some drainage ditches in the intensively managed row-crop agricultural region of southern Minnesota evolved from a trapezoidal form to multi-staged channel forms similar to natural streams. Older ditches constructed in cohesive sediment of the Des Moines Lobe till tend to follow a channel evolution model developed by Simon and Hupp. Site cross sections, longitudinal water and bed profiles and bed material particle size were determined according to Harrelson and others at 24 older ditch reaches, 5 newly constructed ditch reaches and 13 natural stream reaches. Morphological features were hypothesized to change from trapezoidal form to flat bench banks, similar to benches found in natural stream channels. All data were statistically analyzed with respect to drainage area using regression, because channel form is directly related to drainage area for a given climate, geology and land use. Results show similar regression slope and intercept for bankfull channel width and bankfull cross-sectional area (CSA) of older ditches and natural streams compared to typical trapezoidal designed ditches. Evolved ditches developed a small floodplain bench above the ditch bed and adjusted their bankfull widths similar to natural stream channels with respect to drainage area. Old ditches showed a relatively strong R 2 (0.82, 0.68) for channel CSA and width, a weaker R 2 (0.45) for water surface slope, and little to no correlation with bed particle size. Channel form appears to have adjusted more quickly than bed facets and/or bed particle size distribution. However, stepwise regression determined that D84, width/depth ratio and mean bankfull depth explained 83?% of the variability of channel features across varying drainage areas. Findings suggest a possible reduction of long-term maintenance costs if older ditches are allowed to evolve over time. A stable ditch form similar to natural streams is typically self-sustaining, suggesting that prior to a scheduled clean-out, the ditch should be examined for hydraulic capacity, sediment transport and bank stability.  相似文献   

16.
The results of experiments on a 40 cm × 40 cm grate-discharge ball mill have been analysed for variation of mill hold-up weight of solids with solids feed rate, weight percent solids, mean feed particle size, material specific gravity and work-index. It is shown that mill hold-up weight is independent of the material specific gravity and mean feed particle size, and it varies linearly with solids feed rate and weight percent solids, at least over the range of practical interest. The variations in the transport behaviour of different materials have been attributed to the differences in the size distribution of the mill hold-up solids. It is shown that work-index can be used as the material characteristic for the development of an empirical correlation. Variation of mean residence time of solids with solids feed rate and weight-percent solids is also discussed.  相似文献   

17.
Bed forms were studied in Goodwin Creek and a laboratory flume channel. The bed sediment of the field site and flume had median diameters of 8·3 (modes of 0·4, 22·6 mm) and 1·82 mm (modes of 0·5, 5·6 mm), respectively. The laboratory and field channels had similar values of bimodal parameters, ratios of flow depth to median bed material diameter, and ratios of shear stress to critical shear stress and were judged to be comparable in the transport of bed load sediment and the resulting bed forms. Three groupings of bed forms from the laboratory flume experiments (ripple-like bed forms, bed load sheets, low-relief bed waves) were identified using the height and period of the bed forms. For the range of flow depths and discharges investigated in the flume, bed forms became higher and longer with increasing bed shear stress. Bed forms from Goodwin Creek were similar to those from the flume with comparable ratios between bed form length, height, and flow depth. The bed forms in the flume provide a positive link between rate and size fluctuations measured in the field and the bed forms. The smaller bed forms identified were sediment starved and are not considered to be dunes, while the largest bed forms in which all of the bed material sizes were mobilized in the field and laboratory were judged to be dunes.  相似文献   

18.
谷拴成  丁潇 《岩土力学》2013,34(9):2649-2654
巷道围岩由于变形不协调而产生离层,离层对锚杆产生附加应力。在已有弹性分析的基础上,根据岩层相对移动时拉拔载荷对锚杆的作用机制,建立了离层进一步扩展、锚固体界面进入弹塑性阶段的锚杆受力模型。通过选取二阶段线性函数剪切滑移模型,确定了离层左右两侧的滑移范围,并得出锚固体的应力分布形式。总结出离层作用下锚固体的受力过程一般分为4个阶段：弹性阶段、单侧进入弹塑性阶段、离层两侧均进入弹塑性阶段和一侧全部滑移、另一侧滑移范围增大阶段。通过对不同离层值和离层位置的参数分析得出：在相同离层位置条件下,离层值越大,离层对锚杆产生的附加应力就越大;在相同离层值条件下,弹塑性阶段基本趋势和弹性阶段相同,表现为锚杆中心处应力最小,越靠近边缘离层产生的附加应力越大。  相似文献   

19.
An extremely large rock avalanche occurred on April 9, 2000 at Yigong, Tibet, China. It started with an initial volume of material of 90?×?106 m3 comprising mainly of loose material lying on the channel bed. The rock avalanche travelled around 10 km in horizontal distance and formed a 2.5-km-long by 2.5-km-wide depositional fan with a final volume of approximately 300?×?106 m3. An energy-based debris flow runout model is used to simulate the movement process with a new entrainment model. The entrainment model considers both rolling and sliding motions in calculating the volume of eroded material. Entrainment calculation is governed by a second order partial differential equation which is solved using the finite difference method. During entrainment, it is considered that the total mass is changed due to basal erosion. Also the profile of the channel bed is adjusted accordingly due to erosion at the end of each calculation time step. For Yigong, the profile used in the simulation was extracted from a digital elevation model (DEM) with a resolution of 30 m?×?30 m. Measurements obtained from site investigation, including deposition depth and flow height at specific location, are used to verify the model. Ground elevation-based DEM before and after the event is also used to verify the simulation results where access was difficult. It is found that the calculated runout distance and the modified deposition height agree with the field observations. Moreover, the back-calculated flow characteristics based on field observations, such as flow velocity, are also used for model verifications. The results indicate that the new entrainment model is able to capture the entrainment volume and depth, runout distance, and deposition height for this case.  相似文献   

20.
Bed separation can occur in overlying strata, especially in hard and soft interbedded roof strata. If these strata prone to form bed separation are rich aquifers, water can accumulate into bed separation and maybe cause a serious water hazard under the condition of water inflow passages existence. Therefore, studying these types of roof water inrush mechanisms, forecasting roof water inrush, and formulating preventive and control measures in advance are extremely important to a mine. In this paper, we takes the typical case of water inrush in the workface number 1121 at Hongliu coal mine as an example, and study the mechanism of water inrush in detail. Primarily, field drilling with water leakage and color TV observations showed that the maximum height of the water conducting fractured zone was 12.50 times the thickness of the coal seams, which spread to the overlying coarse-grained sandstone aquifer. Secondly, the numerical simulation indicated that bed separation storage space was prone to form under the combination of coarse-grained sandstone and mudstone geological structure. The detection using UWTEM revealed that the groundwater accumulated in this bed separation and formed a water bag (bed separation water). When the water bag reached a certain degree, water bursting happened with the main roof collapsing. Finally, prevention, effective drainage methods, and successful experiences with bed separation water have been summarized, and it will have a major significance to coal mines suffering from bed separation water inrush.  相似文献   

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