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1.
This paper provides for the first time an experimental study where the impact of sea‐level fluctuations and inland boundary head‐level variations on freshwater–saltwater interface toe motion and transition zone dynamics was quantitatively analysed under transient conditions. The experiments were conducted in a laboratory flow tank where various (inland and coastal) head changes were imposed to the system and the response of the key seawater intrusion parameters was analysed with high spatial and temporal resolution. Two homogeneous aquifer systems of different grain size were tested. The numerical code SEAWAT was used for the validation. The results show that in cases of sea‐level variations, the intruding wedge required up to twice longer time to reach a new steady‐state condition than the receding wedge, which thereby extend the theory of timescale asymmetry between saltwater intrusion and retreat processes in scenarios involving sea‐level fluctuations. The intruding and receding rates of the saltwater wedge were respectively similar in the scenario involving sea‐level and the freshwater‐level changes, despite change in transmissivity. The results show that, during the intrusion phase, the transition zone remains relatively insensitive, regardless of where the boundary head change occurs (i.e., freshwater drop or sea‐level rise) or its magnitude. By contrast, a substantial widening of the transition zone was observed during the receding phase, with almost similar amplitude in the scenario involving a rise of the freshwater level compared with that caused by a drop of the saltwater level, provided that an equivalent absolute head change magnitude was used. This transition zone widening (occurring during saltwater retreat) was greater and extended over longer period in the low hydraulic conductivity aquifer, for both freshwater‐level rise and sea‐level drop scenarios. The concentration maps revealed that the widening mechanism was also enhanced by the presence of some freshwater sliding and into the wedge during saltwater retreat, which was thereafter sucked upward towards the interface because of density difference effects.  相似文献   

2.
Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.  相似文献   

3.
Groundwater flow and chemical transport in subterranean estuaries are poorly understood despite their potentially important implications for chemical fluxes from aquifers to coastal waters. Here, a numerical study of the dynamics in a subterranean estuary subject to tidal forcing is presented. Simulations show that salt transport associated with tidally driven seawater recirculation leads to the formation of an upper saline plume in the intertidal region. Computed transit times and flow velocities indicate that this plume represents a more active zone for mixing and reaction than the dispersion zone of the lower, classical salt wedge. Proper conceptualisation of this surficial mixing zone extends our understanding of processes within the subterranean estuary. Numerical tracer simulations reveal that tidal forcing may reduce the threat of a land-derived contaminant discharging to the marine environment by modifying the subsurface transport pathway and local geochemical conditions. Mixing and stratification in the subterranean estuary are strongly affected by both inland and tidal forcing. Based on the estuarine analogy we present a systematic classification of subterranean estuaries.  相似文献   

4.
Simulation of Tidal Effects on Contaminant Transport in Porous Media   总被引：3，自引：0，他引：3  
A one-dimensional numerical model is developed with oscillating velocities and dispersions to simulate the migration process of a contaminant plume within tidally influenced aquifers. Model simulations demonstrate that a major effect the tidal fluctuation has on the migration process of a contaminant plume is the exit concentration discharging to the tidal estuary. Tidal fluctuation causes the exit concentration levels to be significantly diluted by the surface-water body of the estuary. Sensitivity analyses demonstrate that tidal fluctuation hastens the rate of plume migration near the bank of the estuary because of the relatively high advective and dispersive fluxes induced by tides. However, tides affect the migration process only over a short distance from the tidal-water interface (about 40 ft for the parameters used in this study). If the contaminant plume is located far beyond the interface, tidal fluctuations will not affect the rate of plume migration until an existing regional ground-water flow velocity brings the plume to the tidally active zone. With or without tides, the rate of contaminant migration increases with higher regional hydraulic gradient. Furthermore, the effects of tidal fluctuations on the transport process become insignificant with higher regional hydraulic gradients.  相似文献   

5.
A numerical study was conducted to investigate the influence of tides on the fate of terrestrially derived BTEX discharging through an unconfined aquifer to coastal waters. Previous studies have revealed that tide-induced seawater circulations create an active salt–freshwater mixing zone in the near-shore aquifer and alter the specific subsurface pathway for contaminants discharging to the coastal environment. Here the coupled density-dependent flow and multi-species reactive transport code PHWAT was used to examine the impact of these tidal effects on the aerobic biodegradation of BTEX released in a coastal aquifer and its subsequent loading to coastal waters. Simulations indicated that tides significantly enhance BTEX attenuation in the near-shore aquifer. They also reduce the rate of chemical transfer from the aquifer to the ocean and exit concentrations at the beach face. For the base case consisting of toluene transport and biodegradation, 79% of toluene initially released in the aquifer was attenuated prior to discharge with tides present, compared to only 1.8% for the non-tidal case. The magnitude of tidal forcing relative to the fresh groundwater flow rate was shown to influence significantly the extent of biodegradation as it controls the intensity of salt–freshwater mixing, period of exposure of the contaminant to the mixing zone and rate of oxygen delivery to the aquifer. The oxygen available for biodegradation also depends on the rate at which oxygen is consumed by natural processes such as organic matter decomposition. While simulations conducted with heterogeneous conductivity fields highlighted the uncertainties associated with predicting contaminant loadings, the study revealed overall that BTEX may undergo significant attenuation in tidally influenced aquifers prior to discharge.  相似文献   

6.
We conducted various field studies at the seawater intrusion monitoring wells located in the eastern part of Jeju Island, Korea, to observe the tidal effect on groundwater–seawater flow in the coastal aquifer. Studies included monitoring the fluctuations of groundwater and tide levels, electrical and temperature logging, and 2-D heat-pulse flowmeter tests. According to time-series analysis, tidal effects on groundwater level reached up to 3 km inland from the coastline. Water-level variation was more sensitive to tidal fluctuations near the coast, and more related to rainfall toward inland areas. Temporal and spatial variations in the shape and location of the freshwater–saltwater interface were analyzed using data from nine monitoring wells. The results indicated that the interface toe is located at a distance of 6–8 km from the coastline and its location was related to geological layers present. Long-term seasonal variations revealed no major changes in the interface; minor variations were due to moving boundary conditions induced by tidal fluctuations. Using the two-dimensional heat-pulse flowmeter, groundwater flow directions and velocities at four tidal stages were measured on three monitoring wells drilled into the multilayered aquifers. This direct measurement enabled us to relate the differences of flow velocities and directions with geology and tidal fluctuations. Combining the results of EC logging and flowmeter tests, we found a zone where freshwater and saltwater moved alternately in opposite directions, as influenced by the tidal fluctuations. Integrating various physical logging and flowmeter data with water-level fluctuations improved our understanding of the behavior of fresh and seawater flow in the coastal aquifers.  相似文献   

7.
The variation of seawater level resulting from tidal fluctuations is usually neglected in regional groundwater flow studies. Although the tidal oscillation is damped near the shoreline, there is a quasi‐steady‐state rise in the mean water‐table position, which may have an influence on regional groundwater flow. In this paper the effects of tidal fluctuations on groundwater hydraulics are investigated using a variably saturated numerical model that includes the effects of a realistic mild beach slope, seepage face and the unsaturated zone. In particular the impact of these factors on the velocity field in the aquifer is assessed. Simulations show that the tidal fluctuation has substantial consequences for the local velocity field in the vicinity of the exit face, which affects the nearshore migration of contaminant in coastal aquifers. An overheight in the water table as a result of the tidal fluctuation is observed and this has a significant effect on groundwater discharge to the sea when the landward boundary condition is a constant water level. The effect of beach slope is very significant and simplifying the problem by considering a vertical beach face causes serious errors in predicting the water‐table position and the groundwater flux. For media with a high effective capillary fringe, the moisture retained above the water table is important in determining the effects of the tidal fluctuations. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

8.
Resource extraction and transportation activities in subarctic Canada can result in the unintentional release of contaminants into the surrounding peatlands. In the event of a release, a thorough understanding of solute transport within the saturated zone is necessary to predict plume fate and the potential impacts on peatland ecosystems. To better characterize contaminant transport in these systems, approximately 13,000 L/day of sodium chloride tracer (200 mg/L) was released into a bog in the James Bay Lowland. The tracer was pumped into a fully penetrating well (1.5 m) between July 5 and August 18, 2015. Horizontal and vertical plume development was measured via in situ specific conductance and water table depth from an adaptive monitoring network. Over the spill period, the bulk of the plume travelled a lateral distance of 100 m in the direction of the slight regional groundwater and topographical slope. The plume shape was irregular and followed the hollows, indicating preferential flow paths due to the site microtopography. Saturated transport of the tracer occurred primarily at ~25 cm below ground surface (bgs), and at a discontinuous high hydraulic conductivity layer ~125 cm bgs due to a complex and heterogeneous vertical hydraulic conductivity profile. Plume measurement was confounded by a large amount of precipitation (233 mm over the study period) that temporarily diluted the tracer in the highly conductive upper peat layer. Longitudinal solute advection can be approximated using local water table information (i.e., depth and gradient); microtopography; and meteorological conditions. Vertical distribution of solute within the peat profile is far more complex due to the heterogeneous subsurface; characterization would be aided by a detailed understanding of the site‐specific peat profile; the degree of decomposition; and the type of contaminant (e.g., reactive/nonreactive). The results of this research highlight the difficulty of tracking a contaminant spill in bogs and provide a benchmark for the characterization of the short‐term fate of a plume in these complex systems.  相似文献   

9.
Xun Zhou  Chao Song  Ting Li 《水文科学杂志》2013,58(13):2367-2375
ABSTRACT

The inland extending length of the freshwater–saltwater interface toe is useful in studies of seawater intrusion in coastal areas. The submarine fresh groundwater discharge in coastal zones is affected not only by hydraulic conductivity and hydraulic gradient of the aquifer, but also by the position of the interface. Two observation wells at different distances from the coast are required to calculate the fresh groundwater flow rate in coastal unconfined aquifers. By considering that the submarine groundwater discharge is equal to the groundwater flow rate, the length of the interface toe extending inland can be estimated when the groundwater flow is at a steady-flow state. Aquifers with horizontal and sloping confined beds and without/with unique surface vertical infiltration are considered. Examples used to illustrate the application of these methods indicate that the inland extending lengths of the interface toe in aquifers with vertical surface infiltration are much shorter than those in aquifers without vertical surface infiltration, and the length of the interface in aquifers with a horizontal confining lower bed are smaller than those in aquifers with a confining lower bed sloping towards the sea. The extent of the interface on the northwestern coast near the city of Beihai in southern Guangxi, China, on 18 January 2013 was estimated as 471–478 m.
Editor M.C. Acreman Associate editor not assigned  相似文献   

10.
To supplement conventional geophysical log data, this study presents temporal variations in electrical conductivity (EC) and temperature with depth in a multilayered coastal aquifer, on the eastern part of Jeju Island, Korea. One‐month time‐series data obtained at eight points from a multi‐depth monitoring system showed that semidiurnal and semimonthly tidal variations induced dynamic fluctuations in EC and temperature. At some depths, EC ranged from 1483 to 26 822 µS cm?1, while some points showed no significant variations. The results of EC log and time‐series data revealed that a sharp fresh‐saltwater interface occurred at low tide, but the diffusion zone broadened to 20 m at high tide. EC, temperature, and tide level data were used for the cross‐correlation analysis. The response time of EC and temperature to tide appears to range from less than 30 min to 11 h. Using end‐member mixing analysis (EMMA), the fraction of variations of chloride concentration in the multilayered aquifer was explained, and a conceptual model was developed which subdivided the coastal aquifer into four vertical zones. The percentage of water derived from seawater varied from 2 to 48 at specific depth, owing to tidal fluctuations. Continuous observations of EC and temperature at multiple depths are powerful tools for quantifying the transport of saline water by tidal variations in multilayered coastal aquifers. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

11.
Studies investigating the effects of inland recharge on coastal groundwater dynamics were carried out typically in unconfined aquifers, with few in confined aquifers. This study focused on the groundwater dynamics in confined aquifers with seasonally sinusoidally fluctuated inland groundwater head and constant sea level by numerical simulations. It is known that the mixing zone (MZ) of saltwater wedge in response to the seasonal oscillations of inland groundwater head swings around the steady-state MZ. However, our simulation results indicate that even the most landward freshwater-saltwater interface over a year is seaward from the steady-state location when the hydraulic conductivity K is ≤10−4 m/s under certain boundary conditions with given parameter values. That is, seasonal oscillations of inland groundwater head may reduce seawater intrusion in confined coastal aquifers when K ≤ 10−4 m/s. Sensitivity analysis indicates that for aquifers of K ≤ 10−4 m/s, the larger the inland head fluctuation amplitude is, the less the seawater intrudes. This is probably due to the reason that the seawater intrusion time decreases with the increase of fluctuation amplitude when K ≤ 10−4 m/s. Numerical simulations demonstrate that seasonal inland groundwater head oscillations promote the annual averaged recirculated seawater discharge across the seaward boundary.  相似文献   

12.
Estimation of hydraulic parameters is essential to understand the interaction between groundwater flow and seawater intrusion. Though several studies have addressed hydraulic parameter estimation, based on pumping tests as well as geophysical methods, not many studies have addressed the problem with clayey formations being present. In this study, a methodology is proposed to estimate anisotropic hydraulic conductivity and porosity values for the coastal aquifer with unconsolidated formations. For this purpose, the one-dimensional resistivity of the aquifer and the groundwater conductivity data are used to estimate porosity at discrete points. The hydraulic conductivity values are estimated by its mutual dependence with porosity and petrophysical parameters. From these estimated values, the bilinear relationship between hydraulic conductivity and aquifer resistivity is established based on the clay content of the sampled formation. The methodology is applied on a coastal aquifer along with the coastal Karnataka, India, which has significant clayey formations embedded in unconsolidated rock. The estimation of hydraulic conductivity values from the established correlations has a correlation coefficient of 0.83 with pumping test data, indicating good reliability of the methodology. The established correlations also enable the estimation of horizontal hydraulic conductivity on two-dimensional resistivity sections, which was not addressed by earlier studies. The inventive approach of using the established bilinear correlations at one-dimensional to two-dimensional resistivity sections is verified by the comparison method. The horizontal hydraulic conductivity agrees with previous findings from inverse modelling. Additionally, this study provides critical insights into the estimation of vertical hydraulic conductivity and an equation is formulated which relates vertical hydraulic conductivity with horizontal. Based on the approach presented, the anisotropic hydraulic conductivity of any type aquifer with embedded clayey formations can be estimated. The anisotropic hydraulic conductivity has the potential to be used as an important input to the groundwater models.  相似文献   

13.
The proper management of coastal aquifers commonly requires an understanding of regional mass flow and complete seawater–freshwater circulation. In this study, time series observations of seawater intrusion and refreshing were conducted using a column experiment based on natural flow conditions in coastal groundwater and a sampled medium from a coastal sandy aquifer without chemical treatment. Ranges of hydrodynamic and hydrochemical variables were tested and analysed. The results showed that the zeta potential of suspended colloids in aqueous solution in an aquifer polluted with 0.5 g/kg of heavy metals exhibited an isoelectric point for pH values ranging from 5.70 to 6.07 when freshwater or seawater completely occupied the aquifer pores, which is representative of natural hydrochemical conditions. In this scenario, a high background concentration of heavy metals induced colloidal immobilization. Otherwise, seawater–freshwater circulation enabled colloid mobilization due to ionic strength and pH fluctuations. The migration of multiple heavy metals occurred at a characteristic time of approximately 1 pore volume after each intrusion stage began and when the peak rate of colloid release was reached. At these times, the colloid behaviour determined the quantity and pathway of heavy metal transport. On the basis of the influences of seawater and freshwater interactions, the quantity of mobilized particles generally decreased and was uniformly distributed in each fraction due to particle loss and decreased porous connectivity. We speculate that the decrease in the total surface area of the migratory colloids may cause colloid‐associated heavy metal transport to decrease. The experimental results provide a useful basis for testing coastal groundwater flow and mass transport models because these phenomena require full characterization to precisely evaluate the associated fluxes from the field scale to the microscopic dimension.  相似文献   

14.
The influence of small amounts of clay minerals on the hydraulic conductivity of sandy aquifer was investigated by laboratory experiments. Admixture of up to 1.5% by weight of clay minerals to sand did not cause any measurable decrease of hydraulic conductivity for seawater. Increasing the clay fraction from 1.5% to 10% decreased hydraulic conductivity by one order of magnitude. Montmorillonite caused the strongest decrease; the effect of kaolinite and illite was only half as large. When seawater was flushed by freshwater, hydraulic conductivity of the montmorillonite-sand mixture decreased drastically. However, flushing with freshwater did not measurably affect the hydraulic conductivity of an illite-sand or kaolinite-sand mixture. The explanation for this behaviour is the capability of various types of clay to adsorb different quantities of water between their platelets which induces a gel-droplet formation process. This is governed by the chemical composition and the ionic strength of the solution.  相似文献   

15.
This study is aimed to understand the hydraulic mechanism of coastal aquifer systems that include highly permeable layers (HPLs). These hydrologic conditions can be found in many volcanic islands that are composed of a series of lava flows discharged into sea or other standing body of water. In the first part, we developed a numerical model based on the geologic and hydrologic data obtained from the eastern Jeju Island, Korea, of which the aquifer contains clinker and hyaloclastite layers. The simulation results reproduced spatial location of fresh‐saline water interface, especially the abrupt decline of interface at the inland part and the thickness variation of transition zone along the cross‐section observed at the eastern Jeju coastal aquifer. We were able to find out that these phenomena are strongly related to the presence of the HPL. In the second part, quantitative analyses were conducted with the use of hypothetical models in order to understand the dynamic characteristics of coastal system that includes HPLs. A series of sensitivity studies were conducted to assess the effect of the horizontal length and vertical depth of HPL on the spatial location of the interface toe and the configuration of transition zone. Various case studies have shown that the seawater intruded into the inland more as the horizontal length of HPL was increased and its vertical depth was decreased. In other simulations including two HPLs, the vertical distance between these two HPLs primarily controlled the flow regime, flux variations, and the configuration of the transition zone. Finally, we performed simulations to evaluate the effect of a rising sea‐level. This study provides more understanding of how the presence of HPL controls the seawater intrusion processes, and the spatial configurations of fresh‐saline water interface at coastal aquifers. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

16.
Coastal areas are usually the preferred place of habitation for human beings. Anthropogenic activities such as the construction of high‐rise buildings and underground transport systems usually require extensive deep foundations and ground engineering works, which may unintentionally modify the coastal groundwater system because the construction materials of foundations are usually of low hydraulic conductivity. In this paper, the impact of these building foundations on the groundwater regime is studied using hypothetical flow and transport models. Various possible realizations of foundation distributions are generated using stochastic parameters derived from a topographical map of an actual coastal area in Hong Kong. The effective hydraulic conductivity is first calculated for different realizations and the results show that the effective hydraulic conductivity can be reduced significantly. Then a hypothetical numerical model based on FEFLOW is set up to study the change of hydraulic head, groundwater discharge, and saltwater‐fresh water interface. The groundwater level and flow are modified to various degrees, depending on the foundations percentage and the distribution pattern of the buildings. When the foundations percentage is high and the building foundations are aggregated, the hydraulic head is raised significantly and the originally one‐dimensional groundwater flow field becomes complicated. Seaward groundwater discharge will be reduced and some groundwater may become seepage through the ground surface. The transport model shows that, after foundations are added, overall the seawater and fresh groundwater interface moves landward, so extensive foundations may induce seawater intrusion. It is believed that the modification of the coastal groundwater system by building foundations may have engineering and environmental implications, such as submarine groundwater discharge, foundation corrosion, and slope stability. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
With global warming and sea level rise, many coastal systems will experience increased levels of inundation and storm flooding, especially along sandy lowland coastal areas, such as the Northern Adriatic coast (Italy). Understanding how extreme events may directly affect groundwater hydrology in shallow unconfined coastal aquifers is important to assess coastal vulnerability and quantify freshwater resources. This study investigates shallow coastal aquifer response to storm events. The transitory and permanent effects of storm waves are evaluated through the real time monitoring of groundwater and soil parameters, in order to characterize both the saturated and unsaturated portions of the coastal aquifer of Ravenna and Ferrara (southern Po Delta, Italy). Results highlight a general increase in hydraulic head and soil moisture, along with a decrease in groundwater salinity and pore water salinity due to rainfall infiltration during the 2 days storm event. The only exceptions are represented by the observation wells in proximity to the coastline (within 100 m), which recorded a temporary increase in soil and water salinity caused by the exceptional high waves, which persist on top of the dune crest during the storm event. This generates a saline plume that infiltrates through the vadose zone down to the saturated portion of the aquifer causing a temporary disappearance of the freshwater lens generally present, although limited in size, below the coastal dunes. Despite the high hydraulic conductivity, the aquifer system does not quickly recover the pre‐storm equilibrium and the storm effects are evident in groundwater and soil parameters after 10 days past the storm overwash recess.  相似文献   

18.
The Motooka region in the Fukuoka prefecture in western Japan is a coastal area, where groundwater is utilized as the main water resource for greenhouse agriculture and domestic use. Over-exploitation of groundwater has resulted in seawater intrusion and thus in the contamination of the freshwater aquifer. Fluctuations in electric conductivities caused by such intrusion are a crucial problem, since even slight changes in electric conductivities of the water used for agricultural purposes significantly affect the crops’ growth and yield. However, no study has thus far been conducted on the electric conductivity fluctuations caused by groundwater pumping and seasonal recharge of groundwater in the Motooka region. To this end, an attempt is made in the present study to develop a numerical variable-density solute transport model and then apply it to simulate the electric conductivity fluctuations with groundwater pumping and rainwater recharge. This model is developed under a finite difference scheme, and the method of characteristics is used as the numerical technique for solving the advection term of the advection–dispersion solute transport equation. The results from this numerical model are compared with the field measurements.  相似文献   

19.
The time domain electromagnetic method (TDEM) is applied to monitor, to delineate and to map the saltwater intrusion zones in the Mediterranean Plio‐Quaternary aquifer. Forty‐two TDEM soundings were carried out in the coastal plain of Nabeul–Hammamet region (NE Tunisia). TDEM resistivity data were correlated with the existing borehole logging data to assign them to a particular lithology and to provide information about the position of the freshwater–seawater transition zone. The geoelectric sections showing the vertical configuration of seawater intrusion, with the brackish‐salty‐saturated zones, have a resistivity ranging from ~0.1 to 5 Ω?m and are detected at a depth lower than 1.5 m. The salinized zones are located at Nabeul (Sidi Moussa, Sidi El Mahrsi, Al Gasba and Mrazgua) and at Hammamet (Touristic zone of Hammamet north and south, Baraket Essahel) and reached a distance of 4 km from the coastline, indicating a severe state for the aquifer in these zones. These TDEM results are confirmed by the increase of chloride concentration content in the analysed water samples of monitoring wells. Moreover, in the northeastern part, the presence of a saltwater front located far from the coast and along the NW–SE major surface fault can be explained by two hypothesis: (i) this fault seems to provide a conduit for seawater to move readily towards the water wells and (ii) the clay and gypsum infiltration of marine Messinian deposits through the fault plane leads to low resistivities. Finally, it comes out from this study that TDEM survey has successfully depicted salinized zones of this coastal aquifer. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

20.
The release of stored dissolved contaminants from low permeability zones contributes to plume persistence beyond the time when dense nonaqueous phase liquid (DNAPL) has completely dissolved. This is fundamental to successfully meeting acceptable low concentrations in groundwater that are driven by site‐specific cleanup goals. The study goals were to assess the role of DNAPL entrapment morphology on mass storage and plume longevity. As controlled field studies are not feasible, two‐dimensional (2D) test tanks were used to quantify the significance of mass loading processes from source dissolution and stored mass rebound. A simple two‐layer soil domain representing a high permeable formation sand overlying a zone of lower permeability sand was used in the tests. DNAPL mass depletion through dissolution was monitored via X‐ray photon attenuation, and effluent samples were used to monitor the plume. These data enabled analysis of the DNAPL distribution, the dissolved plume, and the dissolved phase distribution within the low permeability layer. Tests in an intermediate tank showed that mass storage contributes substantially to plume longevity. Detectable effluent concentrations persisted long after DNAPL depletion. The small tank results indicated that the DNAPL morphology influenced the flow field and caused distinctive transport mechanisms contributing to mass storage. Zones of high DNAPL saturation at the interface between the low and high permeability layers exhibited flow bypassing and diffusion dominated transport into the low permeability layer. In the absence of a highly saturated DNAPL zone near the soil interface the contaminant penetrated deeper into the low permeability layer caused by a combination of advection and diffusion.  相似文献   

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