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1.
总磷是长江流域备受关注的污染物。来自长江上游的物质输送对长江中下游、对入海口水域水生态都具有重要影响。研究了1998—2019时期长江上游和中下游之间的衔接断面暨三峡水库出水断面的磷通量及形态变化。整个研究时段分为3个阶段:1998—2002(阶段Ⅰ,三峡水库运行之前),2003—2013(阶段Ⅱ,作为过渡时期)及2014—2019(阶段Ⅲ,三峡水库实现175m正常蓄水位且金沙江下游段向家坝和溪洛渡水库运行后),以阶段Ⅰ、Ⅲ为重点时段进行对比分析。研究表明,2014—2019年总磷年通量平均为5.67万t/a,比1998—2002年减少了38.0%;溶解态磷年通量为4.02万t/a,增加了60.0%;颗粒态磷年通量为1.67万t/a,减少了74.9%。磷的主导形态由颗粒态变为溶解态,溶解态磷通量占比由27.5%上升为70.9%;相应地,颗粒态磷通量占比由72.5%下降为29.1%。总磷、溶解态磷和颗粒态磷通量均表现为丰水期>平水期>枯水期。近20年来,水沙关系发生了巨大变化,含沙量(SS)与水量(Q)正相关性大幅下降,其拟合方程的斜率由1.44下降为0.10,R2... 相似文献
2.
甲烷(CH4)是一种重要的温室气体,对全球气候变化有不可忽视的影响.三峡水库是中国最大的水库,其潜在的CH4释放近年来备受关注.然而,此地区现存研究主要集中于水气界面通量观测,对库底沉积物同底层水体CH4浓度变化之间关系的认知仍然欠缺.为探究三峡水库泥沙主要沉降淤积的中段区域库底水体CH4浓度变化及其主要影响因素,本研究于2017年8月2018年11月在涪陵南沱镇、忠县石宝寨、万州小周镇采集库底上覆水体和底泥样本,并结合三峡水库调度运行特征进行分析.结果表明,三峡水库中段库底上覆水CH4浓度范围为0.02~0.91μmol/L,二氧化碳(CO 2)浓度范围为0.006~0.105 mmol/L,沉积物有机碳含量范围为7~90 g/kg,总氮含量范围为0.27~45.6 g/kg.另外,三峡水库低水位运行时期(59月),上游及陆源输入大量异源性有机碳是该时期三峡库中段底部CH4积累的充分条件.在水库高水位运行时期(10月次年4月),水位与径流变化对三峡水库中段底部CH4的影响并不明显,库底自源性有机质相对比重有所增加,温度是该时期影响水库底层水体CH4浓度分布的主要水环境因素. 相似文献
3.
以三峡水库香溪河库湾为研究对象,采用原位加密采样(2021年5月)和室内培养方法,结合沉积物特性与水环境因子分析,探讨了香溪河库湾沉积物甲烷(CH4)释放潜力、沉积物-水界面CH4产生和氧化通量空间分布规律及其影响因素。结果表明:三峡水库泄水期间,香溪河库湾沉积物CH4释放潜力的变化范围是6.35-2029.37 mg/(kg·d),沉积物-水界面CH4产生通量和氧化通量的变化范围分别为0.04～0.73、0.03～0.62 mmol/(m2·d);空间上,沉积物CH4释放潜力、沉积物-水界面CH4产生及氧化通量在香溪河库湾和各典型横切面(XX02、XX05和XX06)间表现出空间差异性,主要受水深、TOC和温度的影响。垂向上,CH4产生速率随沉积物深度的增加而减小,表层20 cm沉积物CH4释放潜力占整柱沉积物的70%,可以用于估算库湾沉积物CH4释放潜力。此外,沉积... 相似文献
4.
千岛湖(新安江水库)表层水中全氟化合物的残留水平及分布特征 总被引：1，自引：0，他引：1
为查明千岛湖水体中全氟化合物(PFCs)的污染特征,于2017年丰水期和枯水期分别采集13个监测断面的表层水样品,采用固相萃取净化、富集水样,超高效液相色谱串联质谱联用法测定水中16种PFCs,研究其残留水平和分布特征监测结果表明,千岛湖表层水共检出5种中短链PFCs,包括C_4全氟烷基磺酸以及C_4、C_5、C_6和C_8 4种全氟烷基羧酸ΣPFCs浓度范围为1.70～6.21 ng/L,以全氟辛酸(PFOA)为主要污染物,其浓度范围为0.52～3.61 ng/L,全氟辛烷磺酸(PFOS)则未检出与国内外同类水体相比,PFOA和PFOS浓度水平均处于低污染水平枯水期千岛湖水中PFCs污染程度高于丰水期,整体上呈现点源污染特征各断面水体中ΣPFCs浓度枯水期差异较大,而丰水期基本处于同一浓度水平空间分布上主要入湖河流新安江上游断面街口和威坪的PFCs浓度明显高于其他主要入湖河流断面以及湖区断面. 相似文献
5.
自成库以来,三峡水库CO2、CH4等温室气体通量较蓄水前发生明显改变。如何科学认识和客观评估三峡水库修建及运行对其CO2、CH4等温室气体通量的影响备受关注。本文简要回顾了自2009年以来在三峡水库开展CO2、CH4等温室气体通量监测与分析工作,综述认为,现阶段三峡水库温室气体排放以水-气界面扩散释放为主要途径。陆源输入的有机碳是主导三峡水库CO2、CH4产生的主要碳源,但在局部区段或时段自源性有机碳的贡献亦十分显著。同蓄水前相比,三峡水库碳排放量呈现为净增加,淹没效应约占水库C净增量的20%,库区内点面源污染负荷并未对CO2排放的净增量产生显著贡献,阻隔效应和生态系统重建效应对三峡水库碳排放的净增量产生显著贡献。近10年来,监测方法比对、监测点位优化等工作在一定程度上完善了三峡水库温室气体通量监测体系。新方法、新技术的引入也为三峡水库温室气体通量监测分析提供了有利支撑和保障,但复杂水文环境... 相似文献
6.
为了解太湖流域上游支流水体的营养状态特征及流域附近土地利用对水质的影响,选取了入湖水系西苕溪的10条主要支流进行了野外采样和实验室研究.研究结果表明,支流总磷(TP)、颗粒磷(PP)、总溶解性磷(TDP)、总氮(TN)、铵态氮(NH+4-N)、硝态氮(NO-3-N)含量季节间差异较大,TP含量范围为0.033~0.205 mg/L,PP含量范围为0.007~0.104 mg/L,TN含量范围为2.014~5.921 mg/L,NH+4-N含量范围0.021~1.659 mg/L,NO-3-N含量范围1.082~3.415mg/L,COD范围为6.5~15.5 mg/L.总体上呈现为枯水期平水期丰水期.部分支流受到不同程度的氮污染.利用水质参数进行聚类分析,可以将10条支流分成4类,其水体营养特征与周围环境相联系.支流营养盐、COD的通量明显受流量控制,表现为丰水期平水期枯水期.土地利用类型的差异是导致其水质变化的主要原因,耕地和居民地主要起源的作用,林地和草地主要起汇的作用.在丰水期和枯水期,对各指标影响最大的土地利用类型为耕地和林地;在平水期,对TP影响最大的是居民地,而对TN影响最大的是林地. 相似文献
7.
于特枯水情年对三峡水库溶解硅和长江干流自涪陵至河口段悬浮颗粒物、溶解硅、生物硅和叶绿素a浓度等进行调查.研究表明,在平水期和汛期末,长江干流水体溶解硅和生物硅浓度和通量在其上游受大坝"滞留"效应的影响呈现沿程降低的趋势,中、下游受"两湖"和汉江等的补充作用有明显升高.在枯水年,长江干流水体生物硅浓度占活性硅(溶解硅和生物硅之和)浓度的2%~5%,显著低于平水年的比例(13%),同时也低于世界河流的平均水平(16%).三峡水库在4-12月份减少溶解硅向下游的输送通量,而在1-3月份增加溶解硅的输送通量;水库在枯水年滞留了大约3%~6%的溶解硅.三峡水库内低的初级生产水平和高的生物硅再生速率是其难以对溶解硅形成有效滞留的主要因素.大坝下游会因清水下泄产生潜在的滞留效应,不过还需要更多的数据去量化. 相似文献
8.
2006年3、5、8月,对三峡水库成库后5条支流的上游区和回水区水质参数及营养因子分布进行了初步研究.研究结果表明,支流高锰酸盐指数范围在1.00-2.50mg/L、COD范围为6.00-26.5mg/L,上游区与回水区有机物含量差异不大,支流目前未受到有机物污染影响.NH_4~+-N范围为0.039-0.367mg/L,各支流含量均为丰水期最大.TN范围在0.58-1.67mg/L,TP范围在0.005-0.133mg/L,支流回水区TN和TP含量均远高于水体发生富营养化的最低限制值,水体存在发生富营养化的风险.大多支流N/P比值处于适宜藻类生长范围.Chl.a浓度范围为0.94-28.9mg/m~3,各支流回水区Chl.a浓度均为5月最大河流回水区Chl.a浓度高于上游区,上游区、回水区Chl.a含量有显著差异.选用修正的Carlson营养状态指数(Trophic State Index)TSI_M法,评价了支流水体营养状态,TSI_M指数范围在36.0-64.2,上游区除龙河、澎溪河5月达到富营养水平外,其余支流均为贫-中营养水平.回水区各支流均达到中-富营养水平.支流回水区营养状态指数均高于上游区,但各支流增加幅度不同.支流回水区水体营养状态明显受三峡水库蓄水水体流速减缓的影响.Chl.a与COD(n=15,P0.01)呈极显著正相关,与其它营养因子无明显相关关系.三峡水库完工后,支流回水区水体流速减缓,富营养化趋势可能加重. 相似文献
9.
气泡释放是天然水体中水-气交换的重要途径之一.采用改进的倒置漏斗型气泡通量监测装置于2012年3-8月期间对三峡支流澎溪河高阳平湖库湾水域进行气泡释放通量的监测研究.研究期间,研究水域CH4气泡释放通量变化范围为0.01 ～ 23288.64 μmol/(m2·d);CO2气泡释放通量变化范围为0～799.89 μmol/(m2·d).不同常规采样点CH4、CO2气泡释放通量均呈现出高度的时空异质性特征.但CH4气泡释放通量显著高于CO2气泡释放通量,且二者释放过程具有同步性.同国外已有水库监测结果相比,澎溪河回水区高阳平湖库湾水域CH4、CO2气泡释放通量位于中等水平.CH4气泡释放通量约为同期CH4扩散通量的0～ 1893.90％,超量释放下CH4气泡释放通量可达同水域CH4扩散通量的6270.5％±390.0％.CO2气泡释放通量仅占同期扩散通量绝对值的0～ 21.74‰,超量释放下,CO2气泡释放通量亦仅为同期扩散通量绝对值的40.33‰ ±0.93‰.CH4气泡释放通量在支流库湾水域对总通量的贡献不可忽视. 相似文献
10.
为揭示岩溶湿地表层水体二氧化碳分压(pCO2)的时空分布规律及其扩散通量,以我国最大的岩溶湿地贵州威宁草海为研究对象,分别于2019年7月(丰水期)和12月(枯水期)通过网格布点法,系统采集草海表层湿地水体,测定水样理化指标和离子组成,利用PHREEQCI软件计算水体pCO2,并基于Cole提出的气体扩散模型估算水-气界面二氧化碳(CO2)的扩散通量.结果表明:草海湿地表层水体丰水期pCO2的变化范围为0.44~645.65μatm,平均值为(55.94±124.73)μatm;枯水期变化范围为35.48~707.95μatm,平均值为(310.46±173.54)μatm;丰水期水体整体pCO2低于枯水期,空间上两期水体均呈现东部区域及河流入湖口处pCO2较高,而中西部区域pCO2欠饱和的特征.水-气界面CO2的扩散通量在丰水期变化范围为-43.27~27.16 mmol/(m2·d),平均值(-34.49±12.93)mmol/(m2·d),枯水期变化范围为-33.36~28.15 mmol/(m2·d),平均值(-8.02±15.85)mmol/(m2·d),与其他岩溶湖库相比,水生植物丰富的草海在两个极端水文期CO2扩散通量相对较低,总体表现为大气CO2的汇. 相似文献
11.
收集、整理四川省地震台网2013年5月至2017年9月产出的震相观测报告数据，采用单台多震和达法，重点分析2017年8月8日九寨沟MS 7.0强震前龙门山断裂带中北段地区波速比变化特征。结果表明：龙门山断裂带中段西侧的茂县地震台，在发震前2年左右，波速比出现一次持续时间约一年半的下降异常；发震前半年左右，波速比出现明显回返特征，波速比回返至均值上下时即发生九寨沟MS 7.0地震；震源区周边其他6个地震台波速比在发震前变化较平稳。茂县地震台波速比低值异常对判定九寨沟MS 7.0强震前龙门山断裂带中北段可能存在孕震体具有重要参考价值。 相似文献
12.
Data from 753 earthquakes are used to determine a relationship between surface-wave magnitude (M
s) and bodywave magnitude (m
b), and from 541 earthquakes to determine a relationship between surface-wave magnitude (M
s) and local magnitude (M
L) for China and vicinity: M
s=0.9883 m
b-0.0420, M
s=0.9919 M
L-0.1773. The relationship of M
s
versus m
b is obtained for 292 events occurred in the Chinese mainland in the time period from 1964 to 1996, 291 events occurred in
Taiwan in the time period from 1964 to 1995 and 170 events occurred in the surrounding area. Standard deviation of the fitting
is 0.445. Relationship of M
s
versus M
L is obtained for 36 events occurred in the Chinese mainland, 293 events occurred in Taiwan, China and 212 events occurred
in the surrounding area. The total amount is 541 events. Standard deviation of the fitting is 0.4673.
The uncertainties of the converted M
s in different magnitude intervals can be estimated using complementary cumulative distribution function (CCDF). In the relationship
of M
s
versus m
b, taking ±0.25 as a range of uncertainties, in magnitude interval m
b 4.0–4.9, the probabilities for the converted M
s taken value less than (M
s-0.25) and more than (M
s+0.25) are 17% and 27% respectively. Similarly, we have probabilities for m
b 5.0–5.9 are 34% and 20% and that for m
b 6.0–6.9 are 11% and 47%.
In the relationship of M
s
versus M
L, if the range of uncertainties is still taken as ±0.25, the corresponding probabilities for magnitude interval M
L 4.0–4.9 are 22% and 38%, for M
L 5.0–5.9 are 20% and 15% and for magnitude interval M
L 6.0–6.9, are 15% and 29%, respectively.
The relationships developed in this paper can be used for the conversion of one magnitude scale into another magnitude scales
conveniently. The estimation of uncertainties described in this paper is more accurate and more objective than the usual estimation
expressed by deviation. The estimations described in this paper indicate various dispersions in different magnitude intervals
of original data. The estimations of uncertainties described by probabilities can be well connected with the total estimations
of uncertainties in seismic hazard assessment. 相似文献
13.
A tomographic study of the V
p and V
p/V
s structures in the crust and upper mantle beneath the Taiwan region of China is conducted by simultaneous inversion of P and
S arrival times. Compared with the previous tomographic results, the spherical finite difference technique is suitable for
the strong heterogeneous velocity structure, and may improve the accuracy in the travel time and three-dimensional ray tracing
calculations. The V
p and V
p/V
s structures derived from joint inversion and the relocated earthquakes can provide better constraints for analyzing the lateral
heterogeneity and deep tectonic characters in the crust and upper mantle. Our tomographic results reveal significant relations
between the seismic wavespeed structure and the tectonic characters. In the shallow depth, sedimentary basins and orogen show
distinct wavespeed anomalies, with low V
p, high V
p/V
s in basins and high V
p, low V
p/V
s in orogen. As the suture zone of Eurasian Plate and Philippine Sea Plate, Longitudinal Valley is characterized by a significant
high V
p/V
s anomaly extending to the middle-lower crust and upper mantle, which reflects the impact of rock cracking, partial melting,
and the presence of fluids. In the northeast Taiwan, the V
p, V
p/V
s anomalies and relocated earthquakes depict the subducting Philippine Sea Plate under the Eurasian Plate. The high V
p of oceanic plate and the low V
p, high V
p/V
s atop the subducted oceanic plate extend to 80 km depth. Along the east-west profiles, the thickness of crust reaches 60 km
at the east of Central Range with eastward dipping trend, which reveals the eastward subduction of the thickened and deformed
crust of the Eurasian continental plate.
Supported by Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX3-SW-234-2), National Basic Research
Program of China (Grant No. 2007CB411701), National High Technology Research and Development Program of China (Grant No. 2006AA09A101-0201)
and National Natural Science Foundation of China (Grant Nos. 40804016, 40704013) 相似文献
14.
Jay D. Bass 《Physics of the Earth and Planetary Interiors》1984,36(2):145-156
The adiabatic single-crystal elastic moduli of SmAlO3, GdAlO3 and ScAlO3, all with the orthorhombic perovskite structure, have been measured by Brillouin spectroscopy under ambient conditions. These 3 compounds display various degrees of crystallographic distortion from the ideal cubic perovskite structure. We find that longitudinal moduli in directions parallel to the axes of a pseudocubic subcell are nearly equal and insensitive to distortions of the crystal structure from cubic symmetry, whereas, the moduli C11 and C22, parallel to the orthorhombic axes, display pronounced anisotropy with the exception of ScAlO3. The shear moduli also correlate with distortion from cubic symmetry, as measured by rotation, or tilt angles, of the AlO6 octahedra. Our data support the observations of Liebermann et al. that perovskite-structure compounds define consistent elasticity trends relating bulk modulus and molar volume, and sound speed and mean atomic weight. These relationships have been used to estimate bulk and shear moduli for the high-pressure polymorphs of CaSiO3 and MgSiO3 with the perovskite structure. 相似文献
16.
In this paper we study the variation of Vp/Vs and Poisson's ratio (δ) in the Yellowstone National Park region, using earthquakes which were well recorded by a local seismic network. We find that the average Vp/Vs value within the geothermally active Yellowstone caldera is about 7% lower than in the area outside the caldera. Within the caldera itself there may be a further 2–7% reduction of Vp/Vs in the hydrothermally active Norris Geyser Basin, the Upper and Lower Geyser Basins, and the Yellowstone Lake and Mud Volcano regions. After considering various possible causes for Vp/Vs changes, such as geologic and structural differences, thermal effects, partial melting, and hydrothermal activity, we conclude that the most plausible explanation for the observed Vp/Vs reduction is the presence of hot-water at temperatures and pore-pressures near the water steam transition in the caldera geothermal reservoirs. 相似文献
17.
用中国地磁台站的资料,研究了Sq逐日变化的形态学特征,用理论模型计算了磁层环电流、部分环电流、场向电流、磁尾电流、Chapman-Ferraro电流的地磁效应.在消除了这些磁层电流体系的影响之后,得到了电离层潮汐风发电机电流产生的磁场Sq变化.对1973年的资料研究表明,Sq发电机电流的逐日变化主要表现在强度上,即使在磁扰期间,也可以分离出形态稳定的Sq变化.由此提出了一种新的地磁指数--Sq指数,用来描述Sq发电机电流强度的逐日变化. 相似文献
18.
基于首都圈数字地震台网的宽频带资料，首先采用CAP方法确定了永清MS4.3地震和廊坊MS3.0地震的震源机制解:永清地震节面Ⅰ的走向、倾角和滑动角分别为52°，62°和?140°，节面Ⅱ的走向、倾角和滑动角分别为300°，55°和?35°；廊坊地震节面I的走向、倾角和滑动角分别为48°，57°和?147°，节面Ⅱ的走向、倾角和滑动角分别为299°，63°和?38°。两次地震的震源机制解较为一致，推测它们可能具有相同的发震断层。利用近震转换波获得两次地震的震源深度，分别为19 km和13 km。利用双差法对两次地震的主余震进行重新定位，结果显示:两个地震序列的震中均呈NE向分布，余震震源深度均浅于主震震源深度，震源深度分别集中在17—20 km和12—13 km范围内，两个序列的短轴剖面揭示了震源分布均呈现倾向SE，倾角陡立的特点。将地震序列的分布与震源机制解的结果进行对比，认为两个序列的水平展布方向与其对应的主震震源机制解中节面Ⅰ的走向比较接近，深度分布的高倾角特征也与节面Ⅰ比较相似，因此认为发震断层面均为节面Ⅰ。通过将震源机制解中节面Ⅰ的参数和地震序列的分布与区域活动断层的产状性质进行比较，取得了一些关于发震构造和地震成因的重要认识:① 永清MS4.3地震和廊坊MS3.0地震的发震构造不是上地壳的先存正断裂?河西务断裂，不排除与中下地壳的新生构造或深大断裂有关；② 永清、廊坊地震发生在13—19 km深度上，结合地壳结构、断裂构造以及区域流变结构等资料，推测该深度范围可能是廊固凹陷的壳内脆性?韧性转换区域，是地震孕育和发生的有利构造部位。 相似文献
19.
Leonie E.A. Jones 《Physics of the Earth and Planetary Interiors》1977,15(1):77-89
The elastic moduli of single-crystal CaF2, SrF2 and BaF2 have been determined by the ultrasonic pulse superposition technique as a function of temperature from T = 298 to T = 650°K. These new data are consistent with other data obtained by ultrasonic pulse techniques in the region of room temperature and are superior to previous high-temperature data from resonance experiments. The elastic moduli (c) are represented by quadratic functions in T over the experimental temperature range with the curvature in the same sense for all the moduli. Evaluation of the temperature derivatives of the elastic moduli at constant volume indicates that the dominant temperature effect is extrinsic for (?KS/?T)P and intrinsic for (?μ/?T)P, where KS and μ are the isotropic bulk and shear moduli, respectively. For the series CaF2SrF2BaF2, |(?c/?T)p| decreases with increasing molar volume for all moduli; however there are no theoretical or empirical grounds on which to derive a simple relationship between (?c/?T)P and crystallographic parameters. 相似文献
20.
本文分析了1975年2月4日海城7.3级地震前后147次地震的资料。结果表明,主震前地震波速比有明显的异常变化。纵横波速比Vp/Vs表现为“下降-回升”的异常形态,负异常至少在主震前四年已出现,最大异常幅度为10％左右,负异常结束后十个月发生主震。主震前波速比异常区较大;而震源附近的小区域,仅在全区波速比回升后的临震前才出现了急剧的负异常。主震前横波速度变化不大,纵波和虚波速度出现异常变化。在一次4.8级强余震前两个月,波速比也出现了负异常。 本文还分析了8次人工爆破,但未发现主震前波速比的异常变化。 关于波速比异常的原因,初步认为是岩石在构造应力的集中作用下,弹性性质发生变化、内部出现大量微裂隙而造成的。 相似文献