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1.
This study aimed to improve the understanding of hydrological processes in a humid (sub)tropical area in Africa with Inselberg topography. Additionally, the study intended to develop an approach for selective discharge data acquisition to determine water availability for smallholder irrigation in similar data-scarce catchments. During the December 2012–August 2013 field campaign meteorological and river stage data were collected at the Messica catchment in Central Mozambique. The 220 km2 catchment has an estimated 1000 ha of irrigated land, developed by smallholder farmers. Baseflow in the perennial tributary streams on the slopes of a meta-sedimentary Inselberg is the source of irrigation water. The baseflow recession curve of one of these tributaries is analysed and the water balance of an average year was determined. Precipitation, potential evapotranspiration, actual evapotranspiration and discharge were estimated to be 1224, 1462, 949 and 266 mm/year respectively. Differential gauging showed that the perennial tributaries gain water; the groundwater contribution increased with approximately 50% over two and a half month relative to the downstream discharge from March to May. In the downstream parts the groundwater contribution per metre stream length is between 30% and 100% higher compared to the upstream parts for two of the tributaries. Nevertheless, due to natural streambed infiltration and irrigation canals, discharge varies over the length of these tributaries. A rainfall–runoff model (HBV) was calibrated using the field data to examine the relation between precipitation characteristics and discharge at the start of the dry season. For precipitation scenarios with low and high intensity precipitation, discharges from June onwards were approximately similar in size according to the calibrated model. This suggest that discharge at the start of the dry season is mainly determined by total precipitation and the timing of precipitation (i.e. early or late in the wet season), not by individual rainfall events or rainfall intensity. It is concluded that the use of selective discharge measurements and low frequency precipitation measurements can effectively be used for water availability assessments in Inselberg catchments. Further research should be conducted to verify the validity of the used techniques in other humid sub-tropical Inselberg areas.  相似文献   

2.
Humans have strongly impacted the global water cycle, not only water flows but also water storage. We have performed a first global-scale analysis of the impact of water withdrawals on water storage variations, using the global water resources and use model WaterGAP. This required estimation of fractions of total water withdrawals from groundwater, considering five water use sectors. According to our assessment, the source of 35% of the water withdrawn worldwide (4300 km3/year during 1998–2002) is groundwater. Groundwater contributes 42%, 36% and 27% of water used for irrigation, households and manufacturing, respectively, while we assume that only surface water is used for livestock and for cooling of thermal power plants. Consumptive water use was 1400 km3/year during 1998–2002. It is the sum of the net abstraction of 250 km3/year of groundwater (taking into account evapotranspiration and return flows of withdrawn surface water and groundwater) and the net abstraction of 1150 km3/year of surface water. Computed net abstractions indicate, for the first time at the global scale, where and when human water withdrawals decrease or increase groundwater or surface water storage. In regions with extensive surface water irrigation, such as Southern China, net abstractions from groundwater are negative, i.e. groundwater is recharged by irrigation. The opposite is true for areas dominated by groundwater irrigation, such as in the High Plains aquifer of the central USA, where net abstraction of surface water is negative because return flow of withdrawn groundwater recharges the surface water compartments. In intensively irrigated areas, the amplitude of seasonal total water storage variations is generally increased due to human water use; however, in some areas, it is decreased. For the High Plains aquifer and the whole Mississippi basin, modeled groundwater and total water storage variations were compared with estimates of groundwater storage variations based on groundwater table observations, and with estimates of total water storage variations from the GRACE satellites mission. Due to the difficulty in estimating area-averaged seasonal groundwater storage variations from point observations of groundwater levels, it is uncertain whether WaterGAP underestimates actual variations or not. We conclude that WaterGAP possibly overestimates water withdrawals in the High Plains aquifer where impact of human water use on water storage is readily discernible based on WaterGAP calculations and groundwater observations. No final conclusion can be drawn regarding the possibility of monitoring water withdrawals in the High Plains aquifer using GRACE. For the less intensively irrigated Mississippi basin, observed and modeled seasonal groundwater storage reveals a discernible impact of water withdrawals in the basin, but this is not the case for total water storage such that water withdrawals at the scale of the whole Mississippi basin cannot be monitored by GRACE.  相似文献   

3.
Self-potential (SP) and electrical resistivity measurements are used to investigate seepage at a remote moraine dam in the Sierra Nevada of California. The site is a small terminal moraine impounding roughly 300,000 m3 of water at ~ 3400 m a.s.l. Suspicious fine sediment in a small lake at the dam's downstream toe prompted initial concerns that anomalous seepage may be eroding matrix material from the moraine. 235 individual SP measurements covering the surface of the dam were collected in order to investigate electrokinetic current sources resulting from seepage, while resistivity soundings probed moraine stratigraphy and suggest that the till contains interstitial ice. Contoured SP data reveal a non-uniform voltage distribution over the moraine dam and two distinct negative SP anomalies. The first, located in the central area of the moraine, shows a broad negative SP zone around the crest and increasingly positive SP moving downhill towards both the upstream and downstream toes. This anomaly can be explained by shallow gravitational groundwater flow in the near subsurface combined with upward groundwater flux through evapotranspiration; numerical simulation of the combined effect matches field data well. The second SP anomaly has a tightly localized distribution and can be explained by vertically descending flow into a bedrock fault conduit. Our conceptual seepage model suggests that flow travels from Dana Lake first at the boundary of ice-filled moraine and bedrock before converging on a concentrated channel in the subvertical fault zone. Positive SP near the dam abutments results from groundwater inflow from adjacent hillslopes. Combined analyses suggest that seepage erosion is not currently affecting the moraine dam, and that the sediment observed on the bed of the downstream toe lake is likely a remnant of past outflow events.  相似文献   

4.
《Journal of Hydrology》1999,214(1-4):8-17
Understanding the influence of irrigation methods on solute transport is essential to properly manage chemical use in agricultural soils. In this study, we compare the transport of a conservative solute (bromide) under sprinkler and flood irrigations on a sandy clay loam (mixed Ustollic Haplargid) under no-till condition. After spraying 148.8 kg/ha of KBr on the surface, ≈25 cm of irrigation water was applied in six increments over two months as flood irrigation on one plot and as sprinkler irrigation on another plot. The net applied water (NAW=irrigation+precipitation−evaporation) was similar for both plots, which allowed the comparison of the Br profiles for the two types of irrigation. Water content and Br concentration were sampled at 5, 19, 34, and 68 days after chemical application.The recovered mass of Br and the location of center of mass were comparable for the two types of irrigation. The spread around the center of mass, however, was higher for the flood-irrigated plot. On the flood-irrigated plot, more mass leached below the depth of 90 cm, with the differences being statistically significant. The velocity of the Br center of mass was consistently 10%–20% larger than the piston displacement velocity. Dispersion and velocity coefficients varied substantially between sampling time. A recent quasi-steady solution of the convection–dispersion equation [M.H. Nachabe, L.R. Ahuja, Quasi-analytical solution for predicting the redistribution of surface-applied chemicals. Trans. ASAE 39(5) (1996) 1659–1664], which accounts for variable flow and dispersion, simulates the Br profiles fairly well.  相似文献   

5.
Soda lakes and pans represent saline ecosystems with unique chemical composition, occurring on all continents. The purpose of this study was to identify and characterise the main environmental gradients and trophic state that prevail in the soda pans (n = 84) of the Carpathian Basin in Central Europe. Underwater light conditions, dissolved organic matter, phosphorus and chlorophyll a were investigated in 84 pans during 2009–2010. Besides, water temperature was measured hourly with an automatic sensor throughout one year in a selected pan. The pans were very shallow (median depth: 15 cm), and their extremely high turbidity (Secchi depth median: 3 cm, min: 0.5 cm) was caused by high concentrations of inorganic suspended solids (median: 0.4 g L−1, max: 16 g L−1), which was the dominant (>50%) contributing factor to the vertical attenuation coefficient in 67 pans (80%). All pans were polyhumic (median DOC: 47 mg L−1), and total phosphorus concentration was also extremely high (median: 2 mg L−1, max: 32 mg L−1). The daily water temperature maximum (44 °C) and fluctuation maximum (28 °C) were extremely high during summertime. The combination of environmental boundaries: shallowness, daily water temperature fluctuation, intermittent hydroperiod, high turbidity, polyhumic organic carbon concentration, high alkalinity and hypertrophy represent a unique extreme aquatic ecosystem.  相似文献   

6.
The gravitational effects of water storage variations driven by local precipitation events are modeled for the Walferdange Underground Laboratory for Geodynamics (WULG) in the Grand Duchy of Luxembourg. A modified mass continuity model is implemented, which uses rainfall data from Walferdange as input. In the absence of soil moisture and groundwater level information, the model is empirically parameterized. Model outputs are compared to the gravity time series registered with the Observatory Superconducting Gravimeter CT040 located in the WULG. We find that the model explains 77% of the gravity residuals. In addition, a statistical analysis is carried out to determine the relationship between precipitation, gravity variations and water level changes in the nearby Alzette River. A time delay of 88 ± 34 min between the maximum variation rates of the water level and gravity signal has been calculated. The signals have an admittance of 45 ± 5 cm μGal?1.  相似文献   

7.
Model calibration is important for streamflow simulations using distributed hydrological models, especially in highland and cold areas of northwest China with scarce data. Quantitative analysis of water balance based on the accurate simulation is also essential for reasonably planning and managing water resources in these river basins facing a severe water shortage. In this study, a comprehensive method was proposed to calibrate the Soil and Water Assessment Tool (SWAT) model in the Yingluoxia watershed, upstream area of the Heihe River basin; it was based on multi-temporal, multi-variable and multi-site integrated drainage characteristics. Meanwhile a fresh approach of the parameter transferability and model validation was used by applying the set of calibrated parameters in its tributary to other area of the watershed. The results indicated that the method was effective and feasible; the values of Nash–Sutcliffe Efficiency (NSE) and Coefficient of Determination (r2) were greater than 0.81 and as high as 0.94 and the absolute values of the Percent Bias (PBIAS) were less than 2. Based the output of model the water balance in the Yingluoxia watershed was analyzed, that the mean annual precipitation, evapotranspiration, and discharge of the watershed from 1990 to 2000 were 491.8 mm, 334 mm, and 157.8 mm, respectively. The comprehensive calibration method based on multi-temporal, multi-variable and multi-site integrated drainage characteristics can better portray the hydrological processes of watershed and improve the model simulation; and the output of the model then provide a reliable reference for assessing and managing water resource of the watershed.  相似文献   

8.
This paper examines groundwater hydrochemical characteristics during mixing between thermal and non-thermal groundwater in low-to-medium temperature geothermal fields. A case study is made of Daying and Qicun geothermal fields in the Xinzhou basin of Shanxi province, China. The two geothermal fields have similar flow patterns, with recharge sourced from precipitation in mountain areas heated through a deep cycle, before flowing into overlying Quaternary porous aquifers via fractures. Hydrochemical features of 60 ground- and surface water samples were examined in the context of hydrogeologic information. The average temperatures of the deep geothermal reservoirs are estimated to be 125 °C in Daying field, and 159 °C in Qicun field, based on Na–K–Mg geothermometry, while slightly lower estimates are obtained using silica geothermometers. Hydrochemical features of thermal water are distinct from cold water. Thermal groundwater is mainly Cl·SO4–Na type, with high TDS, while non-thermal groundwater is mostly HCO3–Ca·Mg and HCO3–Ca type in the Daying and Qicun regions, respectively. Hydrogeochemical processes are characterized by analyzing ion ratios in various waters. Higher contents of some minor elements in thermal waters, such as F, Si, B and Sr, are probably derived from extended water–rock interaction, and these elements can be regarded as indicators of flow paths and residence times. Mixing ratios between cold and thermal waters were estimated with Cl, Na, and B concentrations, using a mass balance approach. Mixing between ascending thermal waters and overlying cold waters is extensive. The proportion of water in the Quaternary aquifer derived from a deep thermal source is lower in Daying geothermal field than in Qicun field (5.3–7.3% vs. 6.3–49.3%). Mixing between thermal and non-thermal groundwater has been accelerated by groundwater exploitation practices and is enhanced near faults. Shallow groundwater composition has also been affected by irrigation with low-temperature thermal water.  相似文献   

9.
In this study, Surface Energy Balance Algorithm for Land (SEBAL) was evaluated for its ability to derive aerodynamic components and surface energy fluxes from very high resolution airborne remote sensing data acquired during the Bushland Evapotranspiration and Agricultural Remote Sensing Experiment 2008 (BEAREX08) in Texas, USA. Issues related to hot and cold pixel selection and the underlying assumptions of difference between air and surface temperature (dT) being linearly related to the surface temperature were also addressed. Estimated instantaneous evapotranspiration (ET) and other components of the surface energy balance were compared with measured data from four large precision weighing lysimeter fields, two each managed under irrigation and dryland conditions. Instantaneous ET was estimated with overall mean bias error and root mean square error (RMSE) of 0.13 and 0.15 mm h−1 (23.8 and 28.2%) respectively, where relatively large RMSE was contributed by dryland field. Sensitivity analysis of the hot and cold pixel selection indicated that up to 20% of the variability in ET estimates could be attributed to differences in the surface energy balance and roughness properties of the anchor pixels. Adoption of an excess resistance to heat transfer parameter model into SEBAL significantly improved the instantaneous ET estimates.  相似文献   

10.
The Central American volcanic arc supplies a significant proportion of the persistent annual global sulphur dioxide emissions from volcanoes. In November/December 2003, we completed a survey of the arc section from Mombacho to San Cristóbal in Nicaragua recording individual mean fluxes of 800, 530 and 220 Mg day− 1 in the plumes from San Cristóbal, Telica and Masaya, respectively. An assessment of fluxes published since 1997 along the entire Central America arc yields a mean total arc flux of SO2 of 4360 Mg day− 1 or 8–16% of the annual estimated global volcanic SO2 flux to the troposphere. New field data shows that Masaya volcano continues to show stable HCl/SO2 and HF/SO2 ratios, suggesting a sustained flux of these components of ∼ 220 and 30 Mg day− 1, respectively (1997 to 2004). Masaya's plume composition also appears to have been stable, between 2001 and 2003, with respect to all the particulate species measured, with significant fluxes of SO42− (4 Mg day− 1), Na+ (0.9–1.3 Mg day− 1) and K+ (0.7 Mg day− 1). Extrapolating the Masaya plume species ratios to the entire Central American arc gives mean HCl and HF fluxes of 1300 and 170 Mg day− 1 and a particulate sulphate flux of 40 Mg day− 1 for 1997 to 2004, although without further understanding of the degassing processes and sources at depth of these different volatiles, these arc-scale estimates should be treated with caution. Combining our arc scale mean SO2 flux with published measurements of volcanic gas compositions with respect to CO2 and H2O allows us to estimate mean CO2 fluxes of 4400–9600 Mg day− 1 and H2O fluxes of 70,000–78,000 Mg day− 1 for the arc. Preliminary comparisons of these estimates of outgassing rates with published volatile input fluxes into the Central American subduction zone, suggest that Cl is more efficiently recycled through the subduction zone than CO2. The results for H2O are inconclusive.  相似文献   

11.
Integrated electrical resistance tomography (ERT) and short-offset transient electromagnetic (TEM) measurements were carried out to investigate a geothermal area in the Main Central Thrust (MCT) zone of Garhwal Himalayan region, India. The study area is located around Helang on either side of Alaknanda River and it is dotted with hot water springs with water temperature of 45°–55 °C emerging at the surface.To assess the geothermal potential and its lateral and vertical extension in and around the hot water springs in the study area, 7 ERT profiles and 21 TEM stations on 7 profiles were established around the hot water spring and at far distant locations. The 2D inversion of ERT data indicates a low resistivity (< 50 Ωm) zone in the vicinity of hot springs, which appears to be associated with an underground water channel through the fractured rock. The bedrock resistivity is very high (> 1000 Ωm) whereas the resistivity of the weathered near surface soil at a far distant location from the hot spring is low (< 100 Ωm) again. A common feature of all TEM data is the sign reversal observed at roughly 10 μs. The consistent sign reversal in all TEM data indicates the existence of the multi-dimensionality of the geoelectrical structure. Therefore, the TEM data were treated by using the SLDM (Spectral Lanczos Decomposition Method) 2D/3D forward modeling code based on the finite difference algorithm. The resistivity structure obtained from ERT data was used as an input for the modeling of TEM data. Based on the joint analysis of the ERT and TEM data it can be inferred that geothermal anomalies associated with the hot spring in the MCT zone are a local feature appearing as a low resistivity zone (< 50 Ωm) at shallow depth (< 100 m) in the vicinity of the hot spring region.  相似文献   

12.
The fluorescence and molecular weight characteristics of dissolved organic matter (DOM) in groundwater of Bangladesh were investigated to evaluate its multiple roles on arsenic (As) mobilization and poisoning. Fluorescence properties of DOM were measured in groundwater samples collected from two As contaminated areas of Bangladesh (Faridpur at the Ganges floodplain and Sonargaon at the Meghna floodplain) from different locations and depths. The three dimensional excitation–emission matrix (3DEEM) fluorescence spectra of groundwater samples showed two characteristic peaks around Ex/Em = 335–365 nm/435–480 nm for fulvic-like peaks and peak at around Ex/Em = 275–290 nm/310–335 nm for the protein-like materials. The similarity of fluorescence spectra of groundwater and surface water of both the study areas with high intensity of fluorescence and its strong correlation with DOC reflect the in situ generation of fluorescent DOM from sedimentary organic matter (SOM) and recent recharge of terrestrial labile organic carbon into shallow aquifer. High performance size-exclusion chromatography (HPSEC) analysis of DOM shows positive correlations between fluorescence intensities (FI) of small molecular fractions (0.65 kDa) and As concentrations, with the signatures of protein-like peaks of DOM in groundwater. This result provides new evidence that small molecular weight fraction of DOM in groundwater of Bangladesh can play an important role on As mobilization and toxicity. In addition, high concentration of fluorescence materials in DOM of As contaminated groundwater of Bangladesh may pose a threat to public health.  相似文献   

13.
Shallow groundwater plays a key role in agro‐hydrological processes of arid areas. Groundwater often supplies a necessary part of the water requirement of crops and surrounding native vegetation, such as groundwater‐dependent ecosystems. However, the impact of water‐saving irrigation on cropland water balance, such as the contribution of shallow groundwater to field evapotranspiration, requires further investigation. Increased understanding of quantitative evaluation of field‐scale water productivity under different irrigation methods aids policy and decision‐making. In this study, high‐resolution water table depth and soil water content in field maize were monitored under conditions of flood irrigation (FI) and drip irrigation (DI), respectively. Groundwater evapotranspiration (ETg) was estimated by the combination of the water table fluctuation method and an empirical groundwater–soil–atmosphere continuum model. The results indicate that daily ETg at different growth stages varies under the two irrigation methods. Between two consecutive irrigation events of the FI site, daily ETg rate increases from zero to greater than that of the DI site. Maize under DI steadily consumes more groundwater than FI, accounting for 16.4% and 14.5% of ETa, respectively. Overall, FI recharges groundwater, whereas DI extracts water from shallow groundwater. The yield under DI increases compared with that under FI, with less ETa (526 mm) compared with FI (578 mm), and irrigation water productivity improves from 3.51 kg m?3 (FI) to 4.58 kg m?3 (DI) through reducing deep drainage and soil evaporation by DI. These results highlight the critical role of irrigation method and groundwater on crop water consumption and productivity. This study provides important information to aid the development of agricultural irrigation schemes in arid areas with shallow groundwater.  相似文献   

14.
《Journal of Hydrology》1999,214(1-4):130-143
Forest drainage is recognized as a means of improving soil conditions for tree growth, but it may also have environmental impacts. This article presents the 5-y time trend of soil and surface water quality observed in a drainage experiment conducted in a black spruce (Picea mariana (Mill.) BSP) peatland of eastern Québec, Canada, using the paired watershed approach. Nutrient content of peat soil water was enhanced by drainage. The effect was generally proportional to ditch closeness for S and Mg, while increases of N, Na, K and Ca were mainly observed within 5 m of the ditches, even though high levels of K and Ca were occasionally observed at 15-m distance. Drainage increased and sustained summer low flows by 25% through a 80 m3 d−1 increase of base flow on the 8 ha basin. The concentration of suspended sediments significantly increased and exceeded acceptable limits for aquatic organisms only during ditching and during the peak flows of the following weeks. No effect on suspended sediments was detected during the spring following ditching but an increase was observed during a storm 2 y after ditching. Drainage modified the basin outflow temperature fluctuations by lowering the average weekly minimum and increasing the maximum, by 2°C and 7°C, respectively. Water temperature increases to 25°C or more at the outlet of the drained basin were above the preferred range for brook trout. The treatment significantly increased specific conductivity of surface water, which was clearly related to increases in mineral N (NH4+NOx), Ca, Mg, Na and S concentrations. However, conductivity and the increased nutrient concentrations remained within the acceptable criteria for aquatic organisms. Drainage also produced a pH increase of one unit, a result attributed to increased runoff from the upland part of the treated watershed. No effect related to drainage was found for Zn, Fe and Al contents.  相似文献   

15.
The distinctly different, εNd(0) values of the Atlantic, Indian, and Pacific Oceans requires that the residence time of Nd in the ocean (i.e., τNd) be on the order of, or less than, the ocean mixing time of ∼ 500–1500 yr. However, estimates of τNd, based on river influxes, range from 4000 to 15,000 yr, thus exceeding the ocean mixing time. In order to reconcile the oceanic Nd budget and lower the residence time by roughly a factor of 10, an additional, as yet unidentified, and hence “missing Nd flux” to the ocean is necessary. Dissolution of materials deposited on continental margins has previously been proposed as a source of the missing flux. In this contribution, submarine groundwater discharge (SGD) is examined as a possible source of the missing Nd flux. Neodymium concentrations (n = 730) and εNd(0) values (n = 58) for groundwaters were obtained from the literature in order to establish representative groundwater values. Mean groundwater Nd concentrations and εNd(0) values were used along with recent estimates of the terrestrial (freshwater) component of SGD (6% of river discharge on a global basis) to test whether groundwater discharge to the coastal oceans could account for the missing flux. Employing mean Nd concentrations of the compiled data base (i.e., 31.8 nmol/kg for all 730 analyses and 11.3 nmol/kg for 141 groundwater samples from a coastal aquifer), the global, terrestrial-derived SGD flux of Nd is estimated to range between 2.9 × 107 and 8.1 × 107 mol/yr. These estimates are of the same order of magnitude, and within a factor of 2, of the missing Nd flux (i.e., 5.4 × 107 mol/yr). Applying the SGD Nd flux estimates, the global average εNd(0) of SGD is predicted to be − 9.1, which is similar to our estimate for the missing Nd flux (− 9.2), and in agreement with the mean (± S.D.) εNd(0) measured in groundwaters (i.e., εNd(0) = −8.9 ± 4.2). The similarities in the estimated SGD Nd flux and corresponding εNd(0) values to the magnitude and isotope composition of the missing Nd flux are compelling, and suggest that discharge of groundwater to the oceans could account for the missing Nd flux. Future investigations should focus on quantifying the Nd concentrations and isotope compositions of groundwater from coastal aquifers from a variety of coastal settings, as well as the important geochemical reactions that effect Nd concentrations in subterranean estuaries in order to better constrain contributions of SGD to the oceanic Nd budget.  相似文献   

16.
Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime.  相似文献   

17.
The Chilean Patagonian fjords region (41–56°S) is characterized by highly complex geomorphology and hydrographic conditions, and strong seasonal and latitudinal patterns in precipitation, freshwater discharge, glacier coverage, and light regime; all of these directly affect biological production in the water column. In this study, we compiled published and new information on water column properties (primary production, nutrients) and surface sediment characteristics (biogenic opal, organic carbon, molar C/N, bulk sedimentary δ13Corg) from the Chilean Patagonian fjords between 41°S and 55°S, describing herein the latitudinal pattern of water column productivity and its imprint in the underlying sediments. Based on information collected at 188 water column and 118 sediment sampling sites, we grouped the Chilean fjords into four main zones: Inner Sea of Chiloé (41° to ～44°S), Northern Patagonia (44° to ～47°S), Central Patagonia (48–51°S), and Southern Patagonia (Magellan Strait region between 52° and 55°S). Primary production in the Chilean Patagonian fjords was the highest in spring–summer, reflecting the seasonal pattern of water column productivity. A clear north–south latitudinal pattern in primary production was observed, with the highest average spring and summer estimates in the Inner Sea of Chiloé (2427 and 5860 mg C m?2 d?1) and Northern Patagonia (1667 and 2616 mg C m?2 d?1). This pattern was closely related to the higher availability of nutrients, greater solar radiation, and extended photoperiod during the productive season in these two zones. The lowest spring value was found in Caleta Tortel, Central Patagonia (91 mg C m?2 d?1), a site heavily influenced by glacier meltwater and river discharge loaded with glacial sediments. Biogenic opal, an important constituent of the Chilean fjord surface sediments (SiOPAL ～1–13%), reproduced the general north–south pattern of primary production and was directly related to water column silicic acid concentrations. Surface sediments were also rich in organic carbon content and the highest values corresponded to locations far away from glacier influence, sites within fjords, and/or semi-enclosed and protected basins, reflecting both autochthonous (water column productivity) and allochthonous sources (contribution of terrestrial organic matter from fluvial input to the fjords). A gradient was observed from the more oceanic sites to the fjord heads (west–east) in terms of bulk sedimentary δ13Corg and C/N ratios; the more depleted (δ13Corg ?26‰) and higher C/N (23) values corresponded to areas close to rivers and glaciers. A comparison of the Chilean Patagonian fjords with other fjord systems in the world revealed high variability in primary production for all fjord systems as well as similar surface sediment geochemistry due to the mixing of marine and terrestrial organic carbon.  相似文献   

18.
Inversion of local earthquake travel times and joint inversion of receiver functions and Rayleigh wave group velocity measurements were used to derive a simple model for the velocity crustal structure beneath the southern edge of the Central Alborz (Iran), including the seismically active area around the megacity of Tehran. The P and S travel times from 115 well-located earthquakes recorded by a dense local seismic network, operated from June to November 2006, were inverted to determine a 1D velocity model of the upper crust. The limited range of earthquake depths (between 2 km and 26 km) prevents us determining any velocity interfaces deeper than 25 km. The velocity of the lower crust and the depth of the Moho were found by joint inversion of receiver functions and Rayleigh wave group velocity data. The resulting P-wave velocity model comprises an upper crust with 3 km and 4 km thick sedimentary layers with P wave velocities (Vp) of ～5.4 and ～5.8 km s?1, respectively, above 9 km and 8 km thick layers of upper crystalline crust (Vp ～6.1 and ～6.25 km s?1 respectively). The lower crystalline crust is ～34 km thick (Vp ～ 6.40 km s?1). The total crustal thickness beneath this part of the Central Alborz is 58 ± 2 km.  相似文献   

19.
This work presents a solid phase extraction (SPE) method for simultaneous preconcentration of trace elements in water samples prior to their ICP-OES determination. Dowex 50W-x8 and Chelex-100 resins were used as SPE sorbent materials for preconcentration of trace Cd, Co, Cr, Cu, Fe, Ni, Pb and Zn. The optimum sample pH, eluent concentration and sample flow rates were found to 6, 3.0 mol L−1 and 3.0 mL min−1, respectively. In terms of multi-element preconcentration capabilities, Dowex 50W-x8 appeared to be a better sorbent. The recoveries for all the tested analytes were >95%. However, Chelex-100 showed a better performance in terms of recovery (>95%) towards Cu, Fe and Zn. Under optimized conditions using Dowex 50W-x8, the relative standard deviations for different metals were <3%. The limits of detection and limits of quantification ranged from 0.01–0.39 μg L−1 and 0.05–0.1.3 μg L−1, respectively. The accuracy of the preconcentration method was confirmed by spike recovery test and the analysis of certified reference materials. The SPE method was applied for preconcentration of the analyte ions in tap water, bottled water and wastewater samples.  相似文献   

20.
The demand for clean water is on the increase as the population increases. One of the ways to address the water shortage is to treat the polluted water through removal of the contaminants. The use of adsorbents for pollutant removal is one of the promising methods. Seaweed is an aquatic plant and its sorption ability for selected metals in water was investigated in this study. We report the performance of the seaweed (Caulerpa serrulata) before and after modification with ethylenediamine (EDA), on adsorption of copper, lead and cadmium in aqueous solution. The adsorption capacities for Cu, Cd and Pb were 5.27 mg g−1, 2.12 mg g−1 and 2.16 mg g−1, respectively, with the EDA-modified seaweed, and 3.29 mg g−1, 4.57 mg g−1 and 1.06 mg g−1, with the unmodified weed, respectively. The pH for maximum adsorption was found to be within the range of pH 4–pH 6. In a separate investigation, it was found that 0.1 g of dried seaweed leached 20 mg of dissolved organic carbon (DOC) using 100 ml of distilled-deionised water. The resulting solution was green. The leaching phenomenon contributes to secondary pollution. Modification of the seaweed with EDA reduced the DOC content by half (50%) and also removed the green colouration. Kinetic studies showed that the adsorbent was able to take up to 95% of the metals (in synthetic standard solutions) in less than 10 min. The adsorbed metals were then stripped using a solution of 0.5 M HNO3 indicating that the adsorbent can be regenerated. In addition, the study revealed that modification improved the thermal stability of the adsorbent such that even when the temperature was raised to 1000 °C, more than 80% (compared to <50% for unmodified weed) of the modified adsorbent was not degraded, indicating that modification had a significant influence on the thermal stability of seaweed. The modified seaweed has been shown to have great potential for the removal of metals and DOC in polluted water. The modified adsorbent can therefore be applied for the removal of metals in polluted waters hence suitable for treatment of water for domestic consumption at a point of use.  相似文献   

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