首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determination of its crystal structure, the empirical formula is (Fe4.12Cr3.84Ni0.96)8.92C3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392(2) nm, c = 0.44690(9) nm, pace group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12, forming an alternate stacking sequence of flat and puckered layers along the c axis. Some metallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2525-0.2666 nm, and the distances between Fe, Cr, Ni and C are 0.1893-0.2169 nm. The coordination number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonalprismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.  相似文献   

2.
《Astronomy& Geophysics》2005,46(2):2.37-2.38
  相似文献   

3.
《Astronomy& Geophysics》2005,46(5):5.04-5.08
  相似文献   

4.
The Italian volcano, Vesuvius, erupted explosively in AD 79. Sanidine from pumice collected at Casti Amanti in Pompeii and Villa Poppea in Oplontis yielded a weighted-mean 40Ar/39Ar age of 1925±66 years in 2004 (1σ uncertainty) from incremental-heating experiments of eight aliquants of sanidine. This is the calendar age of the eruption. Our results together with the work of Renne et al. (1997) and Renne and Min (1998) demonstrate the validity of the 40Ar/39Ar method to reconstruct the recent eruptive history of young, active volcanoes.  相似文献   

5.
Quality factor Q, which describes the attenuation of seismic waves with distance, was determined for South Africa using data recorded by the South African National Seismograph Network. Because of an objective paucity of seismicity in South Africa and modernisation of the seismograph network only in 2007, I carried out a coda wave decay analysis on only 13 tectonic earthquakes and 7 mine-related events for the magnitude range 3.6?≤?M L ?≤?4.4. Up to five seismograph stations were utilised to determine Q c for frequencies at 2, 4, 8 and 16 Hz resulting in 84 individual measurements. The constants Q 0 and α were determined for the attenuation relation Q c(f)?=?Q 0 f α . The result was Q 0?=?396?±?29 and α?=?0.72?±?0.04 for a lapse time of 1.9*(t s???t 0) (time from origin time t 0 to the start of coda analysis window is 1.9 times the S-travel time, t s) and a coda window length of 80 s. This lapse time and coda window length were found to fit the most individual frequencies for a signal-to-noise ratio of at least 3 and a minimum absolute correlation coefficient for the envelope of 0.5. For a positive correlation coefficient, the envelope amplitude increases with time and Q c was not calculated. The derived Q c was verified using the spectral ratio method on a smaller data set consisting of nine earthquakes and one mine-related event recorded by up to four seismograph stations. Since the spectral ratio method requires absolute amplitudes in its calculations, site response tests were performed to select four appropriate stations without soil amplification and/or signal distortion. The result obtained for Q S was Q 0?=?391?±?130 and α?=?0.60?±?0.16, which agrees well with the coda Q c result.  相似文献   

6.
We analyze the anelasticity of the earth using group delays of P-body waves of deep (>200 km) events in the period range 4–32 s for epicentral distances of 5–85 degrees. We show that Time Frequency Analysis (TFA), which is usually applied to very dispersive surface waves, can be applied to the much less dispersive P-body waves to measure frequency-dependent group delays with respect to arrival times predicted from the CMT centroid location and PREM reference model. We find that the measured dispersion is due to: (1) anelasticity (described by the P-wave quality factor Q p ), (2) ambient noise, which results in randomly distributed noise in the dispersion measurements, (3) interference with other phases (triplications, crustal reverberations, conversions at deep mantle boundaries), for which the total dispersion depends on the amplitude and time separation between the different phases, and (4) the source time function, which is dispersive when the wavelet is asymmetrical or contains subevents. These mechanisms yield dispersion ranging in the order of one to 10 seconds with anelasticity responsible for the more modest dispersion. We select 150 seismograms which all have small coda amplitudes extending to ten percent of the main arrival, minimizing the effect of interference. The main P waves have short durations, minimizing effects of the source. We construct a two-layer model of Q p with an interface at 660 km depth and take Q p constant with period. Our data set is too small to solve for a possible frequency dependence of Q p . The upper mantle Q 1 is 476 [299–1176] and the lower mantle Q 2 is 794 [633–1064] (the bracketed numbers indicate the 68 percent confidence range of Q p –1). These values are in-between the AK135 model (Kennett et al., 1995) and the PREM model (Dziewonski and Anderson, 1981) for the lower mantle and confirm results of Warren and Shearer (2000) that the upper mantle is less attenuating than PREM and AK135.  相似文献   

7.
The aim of this article is to describe the double resonance magnetometer system designed and built by the Division de Magnétométrie of the C.E.N. Grenoble, and used by the Département des Recherches Minières du CE.A. For the measurement of magnetic anomalies of geological origin it is necessary to make differential measurements between a mobile instrument which scans the region of interest and a fixed compensatory instrument. The apparatus described here features the following main characteristics: — it gives a direct numerical measurement of the differential magnetic field between the two instruments with an accuracy of 0.01 gamma (10-7 Oe). — it is designed to be easily operated in geological field work (light weight, low power, possibility to make continuous measurements along a given profile, the measuring signals being radio-linked there are no wires connecting the instruments). Firstly we describe the components of the magnetometer itself namely: double resonance magnetometer heads and differential numerical magnetometer. Secondly we describe the measuring technique.  相似文献   

8.
785 traces of vertical components from shallow earthquakes recorded by 10 CDSN (Chinese Digital Seismographic Network) stations and 5 GSN (Global Seismographic Network) stations were collected to study the attenuation characteristics ofL g coda in the Chinese continent and its adjacent regions. The records were processed first using the stack spectral ratio method to obtain the average values ofQ 0 (Q at 1Hz) and η, the frequency dependence, ofL g coda in the ellipses corresponding to the paths. The back-projection technique was then employed to obtain the tomographic maps ofQ 0 and η values, and the distribution of their errors. Results indicate that in the studied areaQ 0 varies between 200 and 500. The lowest value ofQ 0 exists in the Yun-nan-Tibetan region, while the highest value ofQ 0 occurs in the southern edge of Siberian platform. η varies between 0.3 and 0.8. For most part of the studied area η varies inversely withQ 0.  相似文献   

9.
We describe analytical details and uncertainty evaluation of a simple technique for the measurement of the carbon isotopic composition of CO2 in volcanic plumes. Data collected at Solfatara and Vulcano, where plumes are fed by fumaroles which are accessible for direct sampling, were first used to validate the technique. For both volcanoes, the plume-derived carbon isotopic compositions are in good agreement with the fumarolic compositions, thus providing confidence on the method, and allowing its application at volcanoes where the volcanic component is inaccessible to direct sampling. As a notable example, we applied the same method to Mount Etna where we derived a δ13C of volcanic CO2 between −0.9 ± 0.27‰ and −1.41 ± 0.27‰ (Bocca Nuova and Voragine craters). The comparison of our measurements to data reported in previous work highlights a temporal trend of systematic increase of δ13C values of Etna CO2 from ~ −4‰, in the 1970’s and the 1980’s, to ~ −1‰ at the present time (2009). This shift toward more positive δ13C values matches a concurrent change in magma composition and an increase in the eruption frequency and energy. We discuss such variations in terms of two possible processes: magma carbonate assimilation and carbon isotopic fractionation due to magma degassing along the Etna plumbing system. Finally, our results highlight potential of systematic measurements of the carbon isotopic composition of the CO2 emitted by volcanic plumes for a better understanding of volcanic processes and for improved surveillance of volcanic activity.  相似文献   

10.
本文利用保角映射方法对两种二维地形作了推导:一种是半圆弧形的边界,另一种是拋物线形的边界。并作了一些数值计算。  相似文献   

11.
The recent seismicity catalogue of metropolitan France Sismicité Instrumentale de l’Hexagone (SI-Hex) covers the period 1962–2009. It is the outcome of a multipartner project conducted between 2010 and 2013. In this catalogue, moment magnitudes (M w) are mainly determined from short-period velocimetric records, the same records as those used by the Laboratoire de Détection Géophysique (LDG) for issuing local magnitudes (M L) since 1962. Two distinct procedures are used, whether M L-LDG is larger or smaller than 4. For M L-LDG >4, M w is computed by fitting the coda-wave amplitude on the raw records. Station corrections and regional properties of coda-wave attenuation are taken into account in the computations. For M L-LDG ≤4, M w is converted from M L-LDG through linear regression rules. In the smallest magnitude range M L-LDG <3.1, special attention is paid to the non-unity slope of the relation between the local magnitudes and M w. All M w determined during the SI-Hex project is calibrated according to reference M w of recent events. As for some small events, no M L-LDG has been determined; local magnitudes issued by other French networks or LDG duration magnitude (M D) are first converted into M L-LDG before applying the conversion rules. This paper shows how the different sources of information and the different magnitude ranges are combined in order to determine an unbiased set of M w for the whole 38,027 events of the catalogue.  相似文献   

12.
Pesticides in Austrian Running Waters – a Country-wide Overview The analyses of pesticides in Austrian running waters are major part of the country-wide water quality monitoring system which has been established in 1991. This paper summarizes the data which were collected for 29 substances between December 1991 and June 1995. The monitoring activities focus on herbicides because they are the most important pesticide group in Austria. Substances of the triazines and phenoxyalkanecarboxylic acid group analyzed within the programme represent the major part of the total amount of herbicides applied. The most detected pesticides were atrazine and its metabolite deethylatrazine. Peak concentrations were obtained in rivers situated in the eastern and southern regions of Austria with intensive agriculture. Other substances play a minor role as contaminants in running waters. These findings correspond to the data obtained by investigations of groundwater in porous media.  相似文献   

13.
  相似文献   

14.
Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ 18O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ 18O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ 18O and temperature suggests that δ 18O can be used as an indicator of temperature in this region. The δ 18O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.  相似文献   

15.
Urea from natural and anthropogenic sources is one of the most interesting nitrogen compounds in an aquatic environment. Results of experimental investigations are presented for the successive biochemical urea transformation into nitrates via ammonium and nitrite species. Kinetic models based on a combination of Michaelis-Menten and Monod equations have been derived which describe reasonably well the course of the enzymatic reactions and the concentration-time profiles of different N oxydation states. Main factors affecting the rates of nitrogen metabolization are the initial concentration of ureolytic bacteria, the physical state of the nitrifying microorganisms, and the concentration of toxic organics added to the system under study.  相似文献   

16.
Improving Water Quality by submerged and emergent Macrophytes. — A Review of Ecotechnological Application. Measures of ecotechnology using submerged and emergent macrophytes in native stands or planted littoral stands on the one hand, ingenious swimming plant mats on the other, may be assessed to be successful if applied in combination with additional measures, for instance — reorganization (sanition) of all the area collecting water — biomanipulation of pelagic food chains. Plantation of submerged macrophytes as oxygenators in standing and impounded waters to improve water quality should be avoided. To the contrary, the strategy should be taking measures in order to maximize the light penetrated euphotic zone (zeu) and simultaneously minimize the mixed zone (zmix) in order to improve spontaneous settlements of submerged macrophyte stands.  相似文献   

17.
Soil H2 and CO2 surveys were carried out along seven active faults and around the aftershock region of the 2000 Tottori-ken Seibu earthquake in Japan. Diffuse CO2 effluxes were also measured along one fault and around the 2000 aftershock region. The results show highly variable H2 concentration in space and time and it seems that the maximum H2 concentration at each active fault correlates with fault activity as exemplified by the time of the latest big earthquakes. Even though observed H2 concentrations in four faults were markedly lower than those collected previously in the latter half of the 1970s, it is evident that the higher H2 concentrations in this study are due to the addition of the fault gases. Comparing the chemical composition of trapped gases (H2: 5–20% and CO2/H2: 0.5–12) in fractured rocks of drill cores bored at the Nojima fault, a soil gas sample with the highest H2 concentration showed large amounts of the trapped fault gas, diluted with atmospheric component. The profile experiment across a fracture zone at the Yamasaki fault showed higher H2 concentrations and lower CO2/H2 ratios as was observed in soil gas from the fracture zone. A few days after the 2000 Tottori-kei Seibu earthquake, no CO2 effluxes related to the occurrence of earthquakes were observed at the aftershock region. However, only above the epicenter zone, relatively high H2 concentrations in soil gases were observed.  相似文献   

18.
Site response in the aftershock zone of 2001 Bhuj Mw 7.7 earthquake has been studied using the H/V spectral ratio method using 454 aftershocks (Mw 2.5–4.7) recorded at twelve three-component digital strong motion and eight three-component digital seismograph sites. The mean amplification factor obtained for soft sediment sites (Quaternary/Tertiary) varies from 0.75–6.03 times for 1–3 Hz and 0.49–3.27 times for 3–10 Hz. The mean amplification factors obtained for hard sediment sites (hard Jurassic/Mesozoic sediments) range from 0.32–3.24 times for 1–3 Hz and 0.37–2.18 times for 310 Hz. The upper bounds of the larger mean amplification factors for 1–3 Hz are found to be of the order of 3.13–6.03 at Chopadwa, Vadawa, Kavada, Vondh, Adhoi, Jahwarnagar and Gadhada, whereas, the upper bounds of the higher mean amplification factors at 3–10 Hz are estimated to be of the order of 2.00–3.27° at Tapar, Chopadwa, Adhoi, Jahwarnagar, Gandhidham and Khingarpur. The site response estimated at Bhuj suggests a typical hard-rock site behavior. Preliminary site response maps for 1–3 Hz and 310 Hz frequency ranges have been prepared for the area extending from 23–23.85 °N and 69.65–70.85°E. These frequency ranges are considered on the basis of the fact that the natural frequencies of multi-story buildings (3 to 10 floor) range between 1–3 Hz, while the natural frequencies for 1 to 3 story buildings vary from 3–10 Hz. The 1–3 Hz map delineates two distinct zones of maximum site amplification (>3 times): one lying in the NW quadrant of the study area covering Jahwarnagar, Kavada and Gadadha and the other in the SE quadrant of the study area with a peak of 6.03 at Chopadwa covering an area of 70 km × 50 km. While the 3–10 Hz map shows more than 2 times site amplification value over the entire study area except, NE quadrant, two patches in the southwest corner covering Bhuj and Anjar, and one patch at the center covering Vondh, Manfara and Sikara. The zones for large site amplification values (∼3 times) are found at Tapar, Chopadwa, Adhoi and Chobari. The estimated site response values show a good correlation with the distribution of geological formations as well as observed ground deformation in the epicentral zone.  相似文献   

19.
The solubility measurements of WO3 in NaCl-H2O system with 4.0% by weight salt were carried out to study the supercritical phenomena of solubility. These experiments were carried out using rapid-quench pressure vessels, with quantitative Na2WO4-2H2O, HCl, NaCl and H2O in Pt capsule to determine the solubility of WO3 from supersaturated solution. The pressure was kept at 34 MPa, which was near the critical pressure 31.4 MPa and the temperatures varied from 250°C to 550°C. The experimental results indicate that the solubility of WO3 has the features of supercritical phenomenon in critical region and is sensitive to the change of system temperature and solvent density. The temperature and pressure in this experiment are close to those of ore-forming fluids in many tungsten deposits, so the features of supercritical geofluids can be helpful to investigating the ore-forming mechanism of tungsten deposit.  相似文献   

20.
Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号