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1.
A nitrogen mass balance, realized for the lower Oglio River basin (Po River Plain, northern Italy), suggested an elevated impact of agricultural activities in this watershed. Livestock manure, synthetic fertilizers, biological fixation, atmospheric deposition, and wastewater sludge contributed 51, 34, 12, 2, and 1% of total N (TN) input, respectively (basin average 450 kg N ha?1 arable land (AL) year?1, overall input 100 115 t N year?1). Crop uptake, ammonia volatilization and denitrification in soils contributed 65, 21, and 14%, respectively, of TN output (basin average 270 kg N ha?1 AL year?1, overall output 60 060 t N year?1). N inputs exceeded outputs by 40 056 t N year?1, resulting in a basin average surplus of about 180 kg N ha?1 AL year?1. About 34% of the N surplus was exported annually from the basin while the remaining amount (about 26 800 t N year?1) underwent other unaccounted for processes within the watershed. The relevance of nitrogen removal via denitrification in aquatic compartments within the watershed was evaluated. Denitrification in the secondary drainage network can represent a relevant nitrogen sink due to great linear extension (over 12 500 km), with estimated nitrogen loss up to 8500 t N year?1. Denitrification in the riverbed and in perifluvial wetlands have the potential to remove only a small fraction of the nitrogen surplus (<3%). Evidence suggests the relevance of groundwater as a site of nitrogen accumulation.  相似文献   

2.
Water and nutrient budgets in dryland agroecosystems are difficult to manage for efficiency and water quality. This is particularly true where complex terrain and soilscapes interact with pronounced hydrologic seasonality. The purpose of this research was to understand water and hydrologic nitrogen (N) export from a hillslope dryland agroecosystem in a semiarid region where most precipitation occurs outside the growing season. We studied 13 years (2001–2013) of records of water and N inputs and outputs from a 12 ha no‐till artificially drained catchment in the semiarid Palouse Basin of eastern Washington State, USA. Fall‐ and winter‐dominated annual precipitation averaged 462 mm. About 350 mm went to evapotranspiration; crops used ~160 mm from stored soil water during the summer dry‐down season. Soil water replenishment after crop senescence, during the fall wet‐up season, delayed the threshold onset of the high‐discharge season until December. Winter‐dominated drainage fluxes averaged 111 mm or 24% of annual precipitation. Nitrate export in drainage averaged 15 kg·N·ha?1·year?1, which was about 10 times the average rate of dissolved organic N export and 15% of the average rate of N application in chemical fertilizer. Fertilizer applications to the catchment were reduced, due to cropping changes, by 1/3 during the last 5 years of the study; however, no corresponding reduction was observed in the nitrate export flux. This lack of change could not be attributed to mineralization of the soil‐organic N legacy of fertilization nor to hydrologic lag of the catchment. Likeliest explanations are (a) despite the reduction, N application continued to exceed crop uptake and accumulation in organic matter; (b) seasonal and interannual variability of catchment connectivity resulted in year‐to‐year field‐scale nitrate storage and carryover. Water and N use efficiencies observed here may be near maximum obtainable for existing crops in this climate. Substantial improvements that would also address multiple environmental issues associated with the N cascade may involve shifts to perennial systems and/or rotations in which N is fixed biologically.  相似文献   

3.
Peatlands provide a setting that is well suited for cranberry agriculture in the Northeastern United States. However, misconceptions exist about the amounts and forms of nitrogen (N) and phosphorus (P) export from cranberry farms. In this study, we report inorganic and organic forms of N and P export from five peatlands cultivated for cranberry production in southeastern, Massachusetts, United States. We then compare N loading rates among cranberry farms in southeastern Massachusetts, row crop farms in the Midwestern United States, and uncultivated peatlands in the United States and United Kingdom. Based on a fluvial mass balance analysis, we find that nonriparian cranberry farms export 2.56 kg of P ha−1 year−1of total P and 12.1 kg of N ha−1 year−1of total N. Total N export from riparian or “flow through” farms is two times higher than nonriparian farms due to less retention of N fertilizer in the vadose zone of riparian farms. Gross total N export from riparian and nonriparian cranberry farms consists of 35% particulate organic N, 26% dissolved organic N, 31% ammonium (NH4+), and 8% nitrate (NO3−). The low proportions of NO3− export (13% of total dissolved N [TDN]) for cranberry farms differ from NO3− export for row crop farms (75% of TDN; p < .001) but not for uncultivated peatlands (17% of TDN; p = .61). Despite being highly modified by fertilizers and artificial drainage, low NO3− export (2.2 kg of N ha−1 year−1) from cranberry farms is consistent with field measurements of rapid N turnover in uncultivated peatlands. This finding suggests that state-funded wetland restoration efforts to restore denitrification in retired cranberry farms may be limited by NO3− rather than soil moisture or organic matter.  相似文献   

4.
This 2‐year study (2000, 2001) reports annual nutrient (phosphorus, nitrate) export from a first‐order agricultural watershed in southern Ontario based on an intensive monitoring programme. The importance of storm and melt events in annual export estimates is demonstrated and the temporal variability in nutrient loading during events is related to processes occurring within the catchment. The feasibility of predicting event‐related nutrient export from hydrometric data is explored. The importance of sampling frequency throughout events is also shown. Export of total phosphorus (TP), soluble reactive phosphorus (SRP) and nitrate ( ) for 2000 and 2001 averaged 0·35 kg ha?1 year?1, 0·09 kg ha?1 year?1, and 35 kg ha?1 year?1 (as N) respectively. Approximately 75% of annual TP export, 80% of annual SRP export and 70% of annual export occurred during 28 events per year. A small number of large‐magnitude events (>34 mm) accounted for 18–42% of annual TP export, 0–61% of annual SRP export and 13–33% of annual NO export. Our results show that temporal variability in nutrient export is largely governed by discharge in this basin, and export can be predicted from discharge. SRP and TP export can also be predicted from discharge, but only for events that are not large in magnitude. The sampling interval throughout events is important in obtaining precise estimates of nutrient export, as infrequent sampling intervals may over‐ or under‐estimate nutrient export by ± 45% per event for P. This study improves our understanding of and P export patterns and our ability to predict or model them by relating temporal variability in event nutrient export to discharge and processes occurring within the basin, and also by exploring the significance of sampling interval in the context of the importance of individual events, season and temporal variability during events. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

5.
Solute concentrations and fluxes in rainfall, throughfall and stemflow in two forest types, and stream flow in a 90 ha catchment in southern Chile (39°44′S, 73°10′W) were measured. Bulk precipitation pH was 6·1 and conductivity was low. Cation concentrations in rainfall were low (0·58 mg Ca2+ l?1, 0·13 mg K+ l?1, 0·11 mg Mg2+ l?1 and <0·08 mg NH4–N l?1), except for sodium (1·10 mg l?1). Unexpected high levels of nitrate deposition in rainfall (mean concentration 0·38 mg NO3–N l?1, total flux 6·3 kg NO3–N ha?1) were measured. Concentrations of soluble phosphorous in bulk precipitation and stream flow were below detection limits (<0·09 mg l?1) for all events. Stream‐flow pH was 6·3 and conductivity was 28·3 μs. Stream‐water chemistry was also dominated by sodium (2·70 mg l?1) followed by Ca, Mg and K (1·31, 0·70 and 0·36 mg l?1). The solute budget indicated a net loss of 3·8 kg Na+ ha?1 year?1, 5·4 kg Mg2+ ha?1 year?1, 1·5 kg Ca2+ ha?1 year?1 and 0·9 kg K+ ha?1 year?1, while 4·9 kg NO3–N ha?1 year?1 was retained by the ecosystem. Stream water is not suitable for domestic use owing to high manganese and, especially, iron concentrations. Throughfall and stemflow chemistry at a pine stand (Pinus radiata D. Don) and a native forest site (Siempreverde type), both located within the catchment, were compared. Nitrate fluxes within both forest sites were similar (1·3 kg NO3–N ha?1 year?1 as throughfall). Cation fluxes in net rainfall (throughfall plus stemflow) at the pine stand generally were higher (34·8 kg Na+ ha?1 year?1, 21·5 kg K+ ha?1 year?1, 5·1 kg Mg2+ ha?1 year?1) compared with the secondary native forest site (24·7 kg Na+ ha?1 year?1, 18·9 kg K+ ha?1 year?1 and 4·4 kg Mg2+ ha?1 year?1). However, calcium deposition beneath the native forest stand was higher (15·9 kg Ca2+ ha?1 year?1) compared with the pine stand (12·6 kg Ca2+ ha?1 year?1). Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

6.
This study involved a baseline evaluation of fluvial carbon export and degas rates in three nested rural catchments (1 to 80 km2) in Taboão, a representative experimental catchment of the Upper Uruguay River Basin. Analyses of the carbon content in stream waters and the catchment carbon yield were based on 4‐year monthly in situ data and statistical modeling using the United States Geological Survey load estimator model. We also estimated p CO2 and degas fluxes using carbonate equilibrium and gas‐exchange formulas. Our results indicated that the water was consistently p CO2 saturated (~90% of the cases) and that the steep terrain favors high gas evasion rates. The mean calculated fluvial export was 5.4 tC·km?2·year?1 with inorganic carbon dominating (dissolved inorganic carbon:dissolved organic carbon ratio >4), and degas rates (~40 tC km?2·year?1) were nearly sevenfold higher than the downstream export. The homogeneous land use in this nested catchment system results in similar water‐quality characteristics, and therefore, export rates are expected to be closely related to the rainfall–runoff relationships at each scale. Although the sampling campaigns did not fully reproduce storm‐event conditions and related effects such as flushing or dilution of in‐stream carbon, our results indicated a potential link between dissolved inorganic carbon and slower hydrological pathways related to subsurface water storage and movement.  相似文献   

7.
This paper characterizes a seasonally inundated Danish floodplain wetland in a state close to naturalness and includes an analysis of the major controls on the wetland water and nitrogen balances. The main inputs of water are precipitation and percolation during ponding and unsaturated conditions. Lateral saturated subsurface flow is low. The studied floodplain owes its wetland status to the hydraulic properties of its sediments: the low hydraulic conductivity of a silt–clay deposit on top of the floodplain maintains ponded water during winter, and parts of autumn and spring. A capillary fringe extends to the soil surface, and capillary rise from groundwater during summer maintains near‐saturated conditions in the root zone, and allows a permanently very high evapotranspiration rate. The average for the growing season of 1999 is 3·6 mm day?1 and peak rate is 5·6 mm day?1. In summer, the evapotranspiration is to a large degree supplied by subsurface storage in a confined peat layer underlying the silt–clay. The floodplain sediments are in a very reduced state as indicated by low sulphate concentrations. All nitrate transported into the wetland is thus denitrified. However, owing to modest water exchange with surrounding groundwater and surface water, denitrification is low; 71 kg NO3–N ha?1 during the study period of 1999. Reduction of nitrate diffusing into the sediments during water ponding accounts for 75% of nitrate removal. Biomass production and nitrogen uptake in above‐ground vegetation is high—8·56 t dry matter ha?1 year?1 and 103 kg N ha?1 year?1. Subsurface ammonium concentrations are high, and convective upward transport into the root zone driven by evapotranspiration amounted to 12·8 kg N ha?1year?1. The floodplain wetland sediments have a high nitrogen content, and conditions are very favourable for mineralization. Mineralization thus constitutes 72% of above‐ground plant uptake. The study demonstrates the necessity of identifying controlling factors, and to combine surface flow with vadose and groundwater flow processes in order to fully comprehend the flow and nitrogen dynamics of this type of wetland. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

8.
Soil loss, fluvial erosion, and sedimentation are major problems in semi‐arid environments due to the high associated costs of decreasing services such as provisioning and regulating water resources. The objective of this research is to analyse sediment yield in a mountainous semi‐arid basin, paying special attention to the sources of sediment, the associated uncertainties, and the transport processes involved. The segregation hypothesis along a reservoir of the sediment coming from hillslopes or fluvial systems is also evaluated. For this purpose, bottom‐set and deltaic deposits of a reservoir (110 hm3 ) in southern Spain have been measured and compared with basin erosion and fluvial transport monitoring over a 12‐year period. The volume of sediment stored at the bottomset of the reservoir shows a relative match with parametric predictions based on the Revised Universal Soil Loss Equation/Modified Universal Soil Loss Equation hillslope models and rating curves, estimated as being between 7 and 13 t·ha?1·year?1. Similarly, the measured volume of deltaic deposit fits the average value of stochastic simulations from different bedload transport equations. These contributions represent 50–65% of the total volume measured regarding suspended sediment inputs, way above that described in previous works. This highlights the importance of considering bedload when estimating the useful life of reservoirs in semi‐arid environments. The major differences in sediment grain size between hillslopes and river systems, and the size fractions measured along the reservoir, support the assertion of segregation hypothesis. Nonetheless, based on the processes observed and the uncertainty related to modelling, that assertion has to be taken with caution. At basin scale, a specific sediment yield of between 19 and 24 t·ha?1·year?1 has been estimated, which includes hillslopes and fluvial contributions. This rate is in the range of sediment yield reported for Mediterranean mountain areas of a torrential character. The pulse‐like nature of the system and the spatial heterogeneity of fluvial and hillslope erosion rates points out the importance of considering mid to long‐term and process‐based approaches and emphasizes the limitations of annual estimations for management purposes.  相似文献   

9.
Catchments with minimal disturbance usually have low dissolved inorganic nitrogen (DIN) export, but disturbances and anthropogenic inputs result in elevated DIN concentration and export and eutrophication of downstream ecosystems. We studied streams in the southern Appalachian Mountains, USA, an area dominated by hardwood deciduous forest but with areas of valley agriculture and increasing residential development. We collected weekly grab samples and storm samples from nine small catchments and three river sites. Most discharge occurred at baseflow, with baseflow indices ranging from 69% to 95%. We identified three seasonal patterns of baseflow DIN concentration. Streams in mostly forested catchments had low DIN with bimodal peaks, and summer peaks were greater than winter peaks. Streams with more agriculture and development also had bimodal peaks; however, winter peaks were the highest. In streams draining catchments with more residential development, DIN concentration had a single peak, greatest in winter and lowest in summer. Three methods for estimating DIN export produced consistent results. Annual DIN export ranged from less than 200 g ha?1 year?1 for the less disturbed catchments to over 2,000 g ha?1 year?1 in the catchments with the least forest area. Land cover was a strong predictor of DIN concentration but less significant for predicting DIN export. The two forested reference catchments appeared supply limited, the most residential catchment appeared transport limited, and export for the other catchments was significantly related to discharge. In all streams, baseflow DIN export exceeded stormflow export. Morphological and climatological variation among watersheds created complexities unexplainable by land cover. Nevertheless, regression models developed using land cover data from the small catchments reasonably predicted concentration and export for receiving rivers. Our results illustrate the complexity of mechanisms involved in DIN export in a region with a mosaic of climate, geology, topography, soils, vegetation, and past and present land use.  相似文献   

10.
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11.
Abstract

This study presents an analysis of three hydrological years (2007/08, 2008/09 and 2009/10) of precipitation, runoff and sediment yield collected from a small (669.7 ha) semi-arid watershed in southeastern Spain (Lanjarón). At the watershed outlet the runoff, suspended sediment concentration, total solute concentrations and dissolved nutrients (N-NO3, N-NH4, H2PO4 and K) in streamflow were continuously monitored. The runoff was highly variable, ranging between 53.4 and 154.7 mm year?1, with an average of 97.6 mm year?1. In contrast, sediment yields were more regular, averaging 1.8 Mg ha?1 year?1. The hydrological response of the watershed depended mainly on rainfall intensity. Formerly, 32% of the watershed was forested and runoff was more regular, despite the typical Mediterranean rainfall cycle; however, due to forest area reduction to 17% and the increase in abandoned farmland area (18%) in recent decades, the runoff variability has increased. Greater amounts of solutes (32.7 Mg ha?1 year?1) were exported, so that this water is considered as poor for irrigation use. The temporal nutrient export was related to seasonal discharge fluctuations as well as daily concentrations. In addition, the nutrient concentrations of the water discharged were lower than threshold limits cited in water-quality standards for agricultural use and for potable water, with the exception of K (65.9 mg L?1), which may degrade surface waters as well as irrigated soils. Thus, hydrological and erosive processes depended on the watershed features, but also on prior conditions in combination with the characteristics of rainfall episodes.

Citation Durán, Z.V.H., Francia, M.J.R., Garcia, T.I., Rodríguez, P.C.R., Martínez, R.A., and Cuadros, T.S., 2012. Runoff and sediment yield from a small watershed in southeastern Spain (Lanjarón): implications for water quality. Hydrological Sciences Journal, 57 (8), 1610–1625.  相似文献   

12.
Changes in stream chemistry were studied for 4 years following large wildfires that burned in Glacier National Park during the summer of 2003. Burned and unburned drainages were monitored from December 2003 through August 2007 for streamflow, major constituents, nutrients, and suspended sediment following the fires. Stream‐water nitrate concentrations showed the greatest response to fire, increasing up to tenfold above those in the unburned drainage just prior to the first post‐fire snowmelt season. Concentrations in winter base flow remained elevated during the entire study period, whereas concentrations during the growing season returned to background levels after two snowmelt seasons. Annual export of total nitrogen from the burned drainage ranged from 1·53 to 3·23 kg ha?1 yr?1 compared with 1·01 to 1·39 kg ha?1 yr?1 from the unburned drainage and exceeded atmospheric inputs for the first two post‐fire water years. Fire appeared to have minimal long‐term effects on other nutrients, dissolved organic carbon, and major constituents with the exception of sulfate and chloride, which showed increased concentrations for 2 years following the fire. There was little evidence that fire affected suspended‐sediment concentrations in the burned drainage. Sediment yields in subalpine streams may be less affected by fire than in lower elevation streams because of the slow release rate of water during spring snowmelt. Published in 2008 by John Wiley & Sons, Ltd.  相似文献   

13.
Streams can be classified as stable or unstable, depending on the stage of channel evolution. Many streams of the southern Piedmont in United States have high sediment loads and are listed as impaired under the total maximum daily load (TMDL) program and may be unstable. It is not clear as to what the target (reference) load or remediation measures should be for unstable streams. The objective of this study was to determine the relative channel stability for a typical southern Piedmont stream using rapid geomorphic assessments (RGAs) and sediment yield analysis. The results were supported through a sediment fingerprinting analysis. RGAs were performed along 52 reaches on the North Fork Broad River (NFBR) main stem and two tributaries. Annual sediment yields were calculated and compared with yields in the southern Piedmont for stable streams that are resilient to degradation or aggradation and unstable streams that are susceptible to such disturbances. Majority of the NFBR main stem was found to be unstable with signs of geomorphic instability in the form of degradation and aggradation. The estimated average annual sediment yield was 0·78 T ha?1 year?1. By comparison, the median annual yield is 0·20 T ha?1 year?1 for stable streams and 0·48 T ha?1 year?1 for unstable streams in the Piedmont ecoregion with comparable drainage basin size. We conclude that the NFBR is in an unstable stage of channel evolution. Sediment fingerprinting proved that majority of the stream‐suspended sediment emanated from eroding stream channels. The methods outlined in this study have implications for the reference condition and remediation efforts related to stream turbidity and stream channel restoration. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

14.
The increase of the nitrate concentration in surface waters used as water supply resources has been investigated with a view to the effects of agricultural activities and atmospheric precipitation. The nitrate concentration increased beyond the acceptable limit for infants after 1975, when due to the permanent augmentation of the synthetic fertilizer rates the organic humus quantities decreased to a minimum. The variability of nitrate concentrations in atmospheric precipitation is dependent on the magnitude of precipitation and the intensity of industry in the given region. At an average value of atmospheric precipitation the nitrogen value in agricultural regions varies within 6 to 12 kg · ha?1 · a?1, in regions with extended industries up to 24 kg · ha?1 · a?1.  相似文献   

15.
Knowledge of soil loss rates by water erosion under given climate, soil, topography, and management conditions is important for establishing soil conservation schemes. In Galicia, a region with Atlantic climatic conditions in Spain, field observations over the last decade indicate that interrill, rill and ephemeral gully erosion may be an important sediment source. The aim of this work was to assess concentrated erosion rates, describe types of rills and ephemeral gullies and determine their origin, evolution and importance as sediment sources. Soil surface state and concentrated flow erosion were surveyed on medium textured soils, developed over basic schists of the Ordenes Complex series (Coruña province, Spain) from 1997 to 2006. Soil surface state was characterized by crust development, tillage features and roughness degree. Soil erosion rate was directly measured in the field. Concentrated flow erosion took place mainly on seedbeds and recently tilled surfaces in late spring and by autumn or early winter. During the study period, erosion rates were highly variable and the following situations could be distinguished: (a) no incision or limited rill incision, i.e. below 2 Mg ha?1 year?1; (b) generalized rill and ephemeral gully incision in the class of mean values between 2·5 and 6·25 Mg ha?1 year?1, this was the most common erosion pattern; and (c) heavy erosion as observed during an extremely wet winter period, between October 2000 and February 2001, with erosion figures that may be about ten orders of magnitude higher, up to 55–60 Mg ha?1 year?1. Therefore, low values of soil losses are dominant, but also large values of rill and ephemeral gully erosion occurred during the study period. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

16.
Recent studies in the Mediterranean area have shown gully erosion to have a very significant contribution to total soil loss. In the Penedès vineyard region (NE Spain), between 15 and 27% of the land is affected by large gullies and gully‐wall retreat seems to be an ongoing process. Multi‐date digital elevation model (DEM) analysis has allowed computation of sediment production by gully erosion, showing that the sediment production rates are very high by the, up‐to‐date, usual global standards. Here, we present a study carried out using large‐scale multi‐date (1975 and 1995) aerial photographs (1 : 5000 and 1 : 7000) to monitor sediment yield caused by large gullies in the Penedès region (NE Spain). High‐resolution DEMs (1 m grid) were derived and analysed by means of geographical information systems techniques to determine the gully erosion rates. Rainfall characteristics within the same study period were also analysed in order to correlate with the soil loss produced. Mass movement was the main process contributing to total sediment production. This process could have been favoured by rainfalls recorded during the period: 58% of the events were of an erosive character and showed high kinetic energy and erosivity. A sediment production rate of 846 ± 40 Mg ha?1 year?1, a sediment deposition rate of 270 ± 18 Mg ha?1 year?1 and a sediment delivery ratio of 68·1% were computed for a gully area of 0·10 km2. The average net erosion within the study period (1975–95) was 576 ± 58 Mg ha?1 year?1. In comparison with other methods, the proposed method also includes sediment produced by processes other than only overland flow, i.e. downcutting, headcutting, and mass movements and bank erosion. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

17.
This study examines the effect of drawdown on the timing and magnitude of suspended solids and associated phosphorus export from a 12 ha reservoir located in an urbanized watershed in southern Ontario, Canada. Water level in Columbia Lake was lowered by 1·15 m over a 2‐week period in November 2001. The total phosphorus (TP) concentrations ranged from 63 to 486 µg L?1 in Columbia Lake and 71 to 373 µg L?1 at its outflow. All samples exceeded the Provincial Water Quality Objective of 30 µg TP L?1. Outflow concentrations of suspended solids and TP increased significantly with decreasing lake level and were attributed to the resuspension of cohesive bottom sediments that occurred at a critical threshold lake level (0·65 m below summer level). Suspended solids at the outflow consisted of flocculated cohesive materials with a median diameter (D50) of c. 5 µm. Particulate organic carbon accounted for 8·5% of the suspended solids export by mass. A total mass of 18·5 t of suspended solids and 62·6 kg TP was exported from Columbia Lake, which represents a significant pulse of sediment‐associated P to downstream environments each autumn during drawdown. The downstream impacts of this release can be minimized if the water level in Columbia Lake is lowered no more than 0·5 m below summer levels. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

18.
The chemistry of bulk precipitation and stream water was monitored in an acidic afforested catchment at Llyn Brianne in upland Wales between 1985 and 1990. Throughfall, stemflow and soil water chemistry were also monitored between 1988 and 1989. Marine-derived solutes dominated the ionic composition of precipitation and stream water, which had mean Cl concentrations of 113 μequiv. 1?1 and 245 μequiv. 1?1, respectively. The higher concentrations in stream water reflect occult and dry deposition on the forest canopy and the effect of interception and transpiration losses. Chloride variations in stream water (112-454μequiv. 1?1) were damped compared with bulk precipitation (28-762μequiv. 1?1) due to the mixing of event (‘new’) water with pre-event (‘old’) water in the catchment soils. A storm episode monitored in the catchment in April 1989 was associated with high sea salt inputs and Cl concentrations in throughfall (1466μequiv. 1?1) and storm runoff were exceptionally high (392μequiv. 1?1). The Cl signal in stream water during the episode was consistent with an event (‘new’) water contribution to the storm response. However, a short-term hydrochemical budget estimated that although Cl outputs from the catchment during the event (1.17 kg ha?1) were equivalent to 8% of inputs in throughfall and stemflow, the storm runoff was equivalent to 32% of effective precipitation. This indicates that pre-event (‘old’) water was the dominant source (> 75%) of storm runoff. Although sea salt inputs during the event had a marked impact on stream water chemistry, the anomalously high levels of acidity sometimes associated with sea salt events were not observed in this particular study.  相似文献   

19.
Abstract

The aim of this study was to assess the effect of land application of sewage sludge on phosphorus (P) losses during intense rainfall. Three rainfall simulations (40 mm h?1 of 30 min duration) were conducted on a field amended with sewage sludge. The overland flow water (OFW) was monitored and sampled every minute. The suspended solid, the dissolved and total phosphorus (respectively SS, TP and DP) concentrations were analysed. The forms of particulate bound P (PP) were investigated. Several results stem from this experiment: (a) sludge application induced a large increase in the DP content of the OFW; the concentrations obtained (0.15–0.57 mg l?1) were shown to result from desorption processes from the SS; and (b) in contrast, sludge application affected neither the SS content nor the TP concentration of OFW (9.5 g mg l?1 P, consisting of PP for 95%). However, sludge preserved the structure of soil surface and led to a 45% decrease in runoff rate (150 m3 ha?1 collected on the test surface compared to 290 m3 ha?1 on a reference). This indirectly reduced TP losses (2.7 kg ha?1 on the reference surface compared to 1.4 kg ha?1 on the test surface).  相似文献   

20.
Frequent algal blooms in surface water bodies caused by nutrient loading from agricultural lands are an ongoing problem in many regions globally. Tile drains beneath poorly and imperfectly drained agricultural soils have been identified as key pathways for phosphorus (P) transport. Two tile drains in an agricultural field with sandy loam soil in southern Ontario, Canada were monitored over a 28‐month period to quantify discharge and the concentrations and loads of dissolved reactive P (DRP) and total P (TP) in their effluent. This paper characterizes seasonal differences in runoff generation and P export in tile drain effluent and relates hydrologic and biogeochemical responses to precipitation inputs and antecedent soil moisture conditions. The generation of runoff in tile drains was only observed above a clear threshold soil moisture content (~0.49 m3·m?3 in the top 10 cm of the soil; above field capacity and close to saturation), indicating that tile discharge responses to precipitation inputs were governed by the available soil‐water storage capacity of the soil. Soil moisture content approached this threshold throughout the non‐growing season (October – April), leading to runoff responses to most events. Concentrations of P in effluent were variable throughout the study but were not correlated with discharge (p > 0.05). However, there were significant relationships between discharge volume (mm) and DRP and TP loads (kg ha?1) for events occurring over the study period (R2 ≥ 0.49, p ≤ 0.001). This research has shown that the hydrologic and biogeochemical responses of tile drains in a sandy loam soil can be predicted to within an order of magnitude from simple hydrometric data such as precipitation and soil moisture once baseline conditions at a site have been determined. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

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