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太湖北部梅梁湾水域水质因子聚类 总被引：7，自引：5，他引：7
计算了沿梁溪河河口到太湖湖心断面上１０个监测点１７个水质因子９３组数据的Ｐｅａｒｓｏｎ相关系数和Ｋｅｎｄａｌｌ秩相关系数，进而运用最小距离法进行了因子聚类，正态分布检验和聚类结果表明，采用Ｋｅｎｄａｌｌ秩相关进行了聚类为宜，结果将诸因子聚为五大类：ＴＤＮ，ＴＮ，ＣＯＮ，ＮＯ２－Ｎ，ＮＨ４－Ｎ，ＯＨ和ＣＯＤＭｎ归为一类，ＴＤＰ，ＴＰ，ＰＯ＾３＋４和ｐＨ值归为一类；ＳＳ和ＳＤ归为一类，反映了该水域环境 相似文献
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阳澄湖若干水质资料的分析与评价 总被引：12，自引：0，他引：12
根据１９９４年５月于阳澄湖湖区７个采样点水质分析结果，表明湖水中矿化度较高，硬度较大，主要离子以ＨＣＯ３＾－，Ｎａ＾＋为主，分别占阴阳离子摩尔总数的５７．６１％、６３．９％。湖水水型西湖、中湖为重碳酸盐钠组Ⅰ型，东湖为重碳酸盐钠组Ⅱ型水。湖水中Ｎ、Ｐ营养元素丰富，ＮＨ３－Ｎ、ＮＯ２－Ｎ指标与７０年代相比明显增高，表明水体已曹室不程度地轻污染。 相似文献
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对柴达木盆地察尔汗盐湖区外围沙下盐湖的卤水及沉积进行了综合研究。沙下盐湖卤水化学组成与地表径流和开放性盐湖卤水之间存在明显的差异性，具有高Ｎａ＾＋＋Ｃｌ＾－、低Ｍｇ＾２＋＋Ｃａ＾２＋＋ＳＯ４＾２－、贫Ｋ＾＋＋ＣＯ３＾２－＋ＨＣＯ３＾－等特征。沙下盐湖析盐层位含有新生矿物并夹带碎屑矿物，其盐类矿物组合为：石盐＋羟氯镁铝石＋光卤石。２５℃等温蒸发相图表明，其卤水演化方向往光卤石析出区迁移，在穿越上覆盖 相似文献
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绍兴鉴湖水域环境功能区区划 总被引：47，自引：6，他引：41
研究了２５Ｃ条件上太湖北部湖区水－沉积界面的物质交换．结果表明：五里湖沉积物中的氮,磷和ＣＯＤmn的释放程度明显高于梅梁湖,其ＮＨ４＋－Ｎ、ＤＴＰ和ＤＣＯＤ的平均溶出速率分别人１５８．２,２．０５和２７．８mg／（m2.d）;梅梁湖北部湖区形态氮处于“负释放”状态,ＤＴＰ和ＤＣＯＤ溶出速率分别为０．５８４mg／（m2.d）和８．９mg／（m2.d）,此外,形态氮,磷和ＤＣＯＤＲ的水－沉积物界面物质交换量与底泥中氮,总 相似文献
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江西红山隐爆角砾岩—斑岩型铜矿床的成因 总被引：1，自引：0，他引：1
红山铜矿成矿流体δＤ在－５２．７‰－－８７．８‰,‰δ＾１８ＯＨ２ｏ在＋１‰－＋６‰,δ＾３４ＳＨ２Ｓ在０－２．５‰之间。矿石铜同位素表明铅主要来自岩浆岩,两阶段模式计算出第一阶段比值为４．２１,第二阶为３．８２±０．１１。 相似文献
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本文定义地震的时空距ＤＳＴ格时空转换系数Ｃ为：Ｄ＾２ＳＴ＝ｄ＾２＋Ｃ＾２（△ｔ）＾２，ｄ为序列中连续发生的两次地震的空间距，△ｔ为时间间隔。采用６０年代来发生在我国５级以上有详细目录的地震序列２３个，分别计算了主震后１天，２－３天，４－７天内Ｃ的值Ｃ１，Ｃ３，Ｃ７，计算中取ＤＳＴ为相应时间段内地震空间距的最大值。结果表明：（１）若Ｃ１＞Ｃ３＞Ｃ７，则无强余震发生；（２）若Ｃ１≌Ｃ３，或Ｃ１＜Ｃ３＜ 相似文献
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Fluxes of dissolved inorganic nutrients: NH4+, NO2-, NO3-, PO4(3-) and Si(OH)4 from nearshore sediments of Gazi Bay were measured in situ within mangrove, seagrass and coral reef biotopes using benthic flux bell-jar chambers of cross-sectional area 0.066 m2 and volume 0.0132 m3. The objectives were: (1) to determine the influence of benthic fluxes, fluvial discharge and seasonal variations on the nutrient budget in the Bay waters; (2) to determine the effect of tidal and spatial variations on nutrient loads in the water column and (3) to establish the relative importance of the nutrient sources with regard to total community production of the Bay. The directly measured fluxes ranged from -270 to +148 micromol NH4+-N/m2/h; -60 to +63 micromol NO2(-)-N/m2/h; -79 to +41 micromol NO3(-)-N/m2/h; -79 to +75 micromol PO4(3-)-P/m2/h and +30 to +350 micromol Si(OH)4-Si/m2/h for and respectively. It was established that benthic fluxes are the major sources of dissolved inorganic NH4+, NO2- and Si(OH)4 while fluvial sources are important for NO3- and PO4(3-) into Gazi Bay waters. Seasonal variations had an appreciable effect on the PO4(3-) fluxes, N:Si ratio, river nutrient discharge, plankton productivity and important environmental factors such as salinity and temperature. Tidal and spatial variations had no significant effect on nutrient concentrations and net fluxes within the water column. The results imply that benthic fluxes are largely responsible for the nutrient dynamics of the nearshore coastal ecosystems especially where direct terrestrial inputs do not contribute significantly to the nutrient budget. 相似文献
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LUO Liancong QIN Boqiang ZHU Guangwei SUN Xiaojing HONG Dalin GAO Yajun XIE Rui 《中国科学D辑(英文版)》2006,49(Z1)
A wave flume experiment was conducted to study nutrient fluxes at water-sediment interface of Meiliang Bay under different hydrodynamic conditions. The results reveal that hydrodynamics has remarkable effects on nutrient fluxes in this area. With a bottom wave stress of 0.019 N m-2 (equivalent to disturbance caused by wind SE 5-7 m s-1 at the sediment sample site of Meiliang Bay), the fluxes of TN, TDN and NH4+-N were separately 1.92× 10-3, -1.81 × 10-4 and 5.28× 10-4 mg m-2 s-1(positive for upward and negative for downward), but for TP, TDP and SRP, the fluxes were 5.69 × 10-4, 1.68 × 10-4 and -1.29 × 10-4 mgm-2 s-1. In order to calculate the released amount of nutrients based on these results, statistic analysis on the long-term meteorological data was conducted.The result shows that the maximum lasting time for wind SE 5-7 m s-1 in this area is about 15 h in summer. Further calculation shows that 111 t TN, 32 t NH4+-N, 34 t TP and 10 t TDP can be released into water (the sediment area was 47.45% of the whole surface area), resulting in concentration increase of 0.025, 0.007, 0.007 and 0.002 mg L-1 separately. With stronger disturbance (bottom wave stress is 0.217 N m-2 which is equivalent to disturbance caused by wind SE 10-11 m s-1 at the same site), there has been significant increase of nutrient fluxes (1.16× 10-2, 6.76×10-3, 1.14× 10-2 and 2.14× 10-3 mgm-2 s-1 for TN, DTN and NH4+-N and TP). The exceptions were TDP with flux having a decrease (measured to be 9.54× 10-5 mgm-2 s-1 ) and SRP with flux having a small increase (measured to be 5.42 × 10-5 mgm-2 s-1). The same statistic analysis on meteorological data reveal that the maximum lasting time for wind SE 10-11 m s-1 is no more than 5 h. Based on the nutrient fluxes and the wind lasting-time, similar calculations were also made suggesting that 232 t TN, 134.9 t TDN, 228 t NH4+-N, 42.7 t TP, 2.0 t TDP and 1.1 t SRP will be released from sediment at this hydrodynamic condition resulting in the concentration increases of 0.050, 0.029, 0.049, 0.009, 0.0004 and 0.0002 mg L-1. Therefore in shallow lakes, surface disturbance can lead to significant increase of nutrient concentrations although some components in water column had negative flux with weak disturbance (e.g. TDN and SRP in this experiment). In this case, sediment looks to be a source of nutrients. These nutrients deposited in sediment can be carried or released into water with sediment resuspension or changes of environmental conditions at water-sediment interface, which can have great effects on aquatic ecosystem and is also the characteristics of shallow lakes. 相似文献
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ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions 总被引：10，自引：0，他引：10
Koop K Booth D Broadbent A Brodie J Bucher D Capone D Coll J Dennison W Erdmann M Harrison P Hoegh-Guldberg O Hutchings P Jones GB Larkum AW O'Neil J Steven A Tentori E Ward S Williamson J Yellowlees D 《Marine pollution bulletin》2001,42(2):91-120
Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies. 相似文献
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微生物对太湖微囊藻的好氧降解研究 总被引：5，自引：1，他引：5
通过模拟实验研究了微生物对微囊藻残体的降解作用。水体内悬浮质和各主要形态磷浓度的变化结果表明：微囊藻的好氧分解符合一级动力学，其乳浮质和颗粒性磷的浓度呈指数关系递减，降解速度分别为０．２２７／ｄ和０．０８８／ｄ。经３２ｄ降解后，水体内的总溶解磷和可达总磷的５３％，而ＴＤＰ的主要成分为ＰＯ＾３－Ｒ。 相似文献
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Based on field investigation of wave, sediment suspension and the changes in nutrient concentration of the water column in Lake Taihu, China, we proposed two release models to quantify nutrient release under static and dynamic conditions, respectively. Under static conditions, nutrient release from sediments to the overlying water mainly depends on chemical diffusion induced by concentration gradient, in which the nutrient release is controlled by the temperature, dissolved oxygen concentration in the sediment-water interface, oxidation-reduction potential and the concentration difference between porewater and overlying water. Under dynamic condition (or disturbed condition), both dissolved and particulate nutrients in sediments are released into the water column because of wind-induced sediment suspension. The amount of nutrient release under dynamic conditions is larger than that under the static condition. The release of dissolved nutrients, however, does not increase because the wind induced turbulence made oxidation of metallic elements such as Fe (ferric iron), Mn which are capable of precipitating soluble reactive phosphate (SRP). Under dynamic conditions, therefore, the release of total phosphorus (TP) increases dramatically but the release of SRP is close to those under static conditions. In sediments of Lake Taihu, high Fe content leads to a high ratio of Fe to P contents in sediments (Fe:P ratio). Under dynamic conditions, therefore, nutrient release is controlled by the intensity of disturbance, sediment consolidation and nutrient content in sediments. As for dissolved nutrients, especially SRP, the release is also controlled by the intensity of dynamic re-oxidation, Fe content in sediments and nutrient concentration gradient between porewater and overlying water. Based on these two release modes, the release flux in Lake Taihu has been estimated. In the static condition (i.e. laboratory experimental condition), total release of NH4 -N for whole lake is ca. 10,000 ton/a, and PO43--P is ca. 900 ton/a. In the dynamic condition, nutrient release following sediment suspension was estimated according to three different intensities of wind forcing which were defined as "calm" (wind speed is less than 2 m/s), "gentle" (wind speed is greater than 2 m/s and less than 6 m/s) and "gust" (wind speed is greater than 6 m/s). The release rate in the condition of "calm" was estimated in terms of the nutrient release in the laboratory experimental static condition; whereas the release rate in conditions of "gentle" and "gust" was estimated in terms of measurement during sediment resuspension conducted in flume experiments. With the observation of wind velocity and frequency in 2001, each type of wind forcing took the frequency of 12%, 82% and 6% for "calm", "gentle" and "gust", respectively. The yearly release of nitrogen was 81,000 ton and phos- phorus was 21,000 ton, which is about 2-6 folds of annual external loading, respectively. 相似文献
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氧化还原条件对红枫湖沉积物磷释放影响的微尺度分析 总被引：7，自引：0，他引：7
选取贵州红枫湖为研究对象,在实验室条件下模拟了自然、好氧和厌氧条件下沉积物内源磷的释放过程,联合应用微电极技术和沉积物磷形态分析对沉积物—水界面开展了微尺度观测与研究.结果表明,厌氧条件下红枫湖沉积物总磷含量显著降低,且主要是NaOH提取态磷(NaOH-P)和残渣态磷(rest-P)含量降低所致,厌氧条件下沉积物孔隙水中磷酸盐浓度明显升高,而好氧条件下沉积物孔隙水磷酸盐浓度显著降低,反映厌氧条件显著促进了红枫湖沉积物磷释放.厌氧条件下沉积物内部溶解氧浓度下降、硫还原活动增强可能是导致NaOH-P释放的主要原因.O_2浓度的降低加速了沉积物还原作用并产生大量H2S,进而与二价铁离子形成硫化亚铁沉淀,最终导致NaOH-P(Fe-P)释放到孔隙水中.好氧条件向厌氧条件的转换可通过改变沉积物内部pH值分布和微生物活动促使rest-P释放:厌氧条件下,厌氧微生物不仅可以消耗硫酸根产生H_2S,导致pH值降低,还可消耗有机质,将有机磷转变为无机磷.上述研究结果表明,沉积物—水界面氧化还原环境可影响沉积物氧渗透深度、pH值分布、微生物活动、硫循环以及有机质降解过程,进而控制沉积物磷的形态转化与释放.联合应用微电极技术和沉积物磷形态分析对湖泊沉积物—水界面开展微尺度观测研究是揭示沉积物内源磷释放机制与控制因素的有效途径. 相似文献
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Biological mechanisms driving the seasonal changes in the internal loading of phosphorus in shallow lakes 总被引：1，自引：6，他引：1
XIE Ping 《中国科学D辑(英文版)》2006,49(Z1)
Because of the obvious importance of P as a nutrient that often accelerates growth of phytoplankton (including toxic cyanobacteria) and therefore worsens water quality, much interest has been devoted to P exchange across the sediment-water interface. Generally, the release mode of P from the sediment differed greatly between shallow and deep lakes, and much of the effort has been focused on iron and oxygen, and also on the relevant environmental factors, for example, turbulence and decomposition, but a large part of the P variation in shallow lakes remains unexplained. This paper reviews experimental and field studies on the mechanisms of P release from the sediment in the shallow temperate (in Europe) and subtropical (in the middle and lower reaches of the Yangtze River in China) lakes, and it is suggested that pH rather than DO might be more important in driving the seasonal dynamics of internal P loading in these shallow lakes, i.e., intense photosynthesis of phytoplankton increases pH of the lake water and thus may increase pH of the surface sediment, leading to enhanced release of P (especially iron-bound P) from the sediment. Based on the selective pump of P (but not N) from the sediment by algal blooms, it is concluded that photosynthesis which is closely related to eutrophication level is the driving force for the seasonal variation of internal P loading in shallow lakes. This is a new finding. Additionally, the selective pump of P from the sediment by algal blooms not only explains satisfactorily why both TP and PO4-P in the hypereutrophic Lake Donghu declined significantly since the mid-1980s when heavy cyanobacterial blooms were eliminated by the nontraditional biomanipulation (massive stocking of the filter-feeding silver and bighead carps), but also explains why TP in European lakes decreased remarkably in the spring clear-water phase with less phytoplankton during the seasonal succession of aquatic communities or when phytoplankton biomass was decreased by traditional biomanipulation. Compared with deep lakes, wax and wane of phytoplankton due to alternations in the ecosystem structure is also able to exert significant influences on the P exchange at the sediment-water interface in shallow lakes. In other words, biological activities are also able to drive P release from sediments, and such a static P release process is especially more prominent in eutrophic shallow lakes with dense phytoplankton. 相似文献
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The water quality in Biscayne Bay has been significantly affected by past and continuing coastal and watershed development. The nutrient concentrations in the Bay have been dramatically changed by the conversion of natural creeks and sheet flow freshwater inputs to rapid and episodic canal inputs from the large and rapidly expanding Miami metropolitan area. This study is an evaluation of nutrient loadings to Biscayne Bay for 1994-2002 from canal, atmospheric, and groundwater sources. Dissolved inorganic nitrogen (DIN, as nitrate, nitrite, and ammonium) and total phosphorus (TP) loadings by the canals were influenced by their geographic locations relative to discharge amount, watershed land use, stormwater runoff, and proximity to landfills. Annual budgets showed that canals contributed the bulk of N loading to the bay as 1687.2 metric ton N yr(-1) (88% total load). Direct atmospheric DIN load for Biscayne Bay was only 231.7 ton N yr(-1), based on surface area. Of the canal DIN load, nitrate+nitrite (NO(x)(-)) loading (1294.5 ton N yr(-1)) made up a much greater proportion than that of ammonium (NH(4)(+), 392.6 ton N yr(-1)). In the urbanized north and central Bay, canal DIN load was evenly split between NO(x)(-) and NH(4)(+). However, in the south, 95% of the DIN load was in the form of NO(x)(-), reflecting the more agricultural land use. Contrary to N, canals contributed the only 66% of P load to the bay (27.5 ton P yr(-1)). Atmospheric TP load was 14 ton Pyr(-1). In the north, canal P load dominated the budget while in the south, atmospheric load was almost double canal load. Groundwater inputs, estimated only for the south Bay, represented an important source of N and P in this zone. Groundwater input of N (141 ton N yr(-1)) was about equal to atmospheric load, while P load (5.9 ton P yr(-1)) was about equal to canal load. 相似文献