共查询到19条相似文献，搜索用时 718 毫秒
1.
荧光光谱分析技术具有灵敏度高、检测快速等优点,三维荧光光谱提供的指纹荧光信息比普通荧光光谱更丰富,选择性更好,在多组分分离上更具优势.离散三维活体荧光光谱法通过提取水体蓝藻、绿藻、硅藻、甲藻和隐藻5个门类藻类荧光光谱的指纹特征,分类测量藻类叶绿素a浓度,经过加和得到总的水体叶绿素a浓度.将基于该方法研制的三维荧光光谱水体藻类原位测量仪用于太湖水体叶绿素a浓度的测定,并与YSI多参数水质检测仪、BBE藻类现场分析仪、分光光度法等测定结果对比,结果表明:该方法与分光光度法间无显著性差异,与分光光度法、BBE法间的相关性好,相关系数达0.96以上,精密度、准确率优于基于普通荧光法的原位测量仪,是一种快速有效的原位测量方法. 相似文献
2.
2012-2018年洪泽湖水质时空变化与原因分析 总被引：1，自引：0，他引：1
洪泽湖是南水北调东线工程的重要枢纽.为评估水环境长期变化,于2012-2018年开展逐月水质监测.结合水文气象与淮河水质水量数据,分析洪泽湖水质长期变化趋势及空间分异的驱动因素,结果显示:2012-2018年,洪泽湖总氮、总磷多年平均浓度为1.74和0.081 mg/L,分别为Ⅴ类水和Ⅳ类水,透明度均值为0.48 m,下降趋势不显著,而高锰酸盐指数、叶绿素a多年平均浓度分别为4.13和0.008 mg/L,呈显著下降趋势.在空间分布上,过水区总氮、总磷浓度显著高于成子湖、溧河洼;高锰酸盐指数、叶绿素a浓度则相对较低,透明度则是成子湖较高,溧河洼和过水区相近.3个湖区的叶绿素a浓度下降明显,但过水区的高锰酸盐指数呈上升趋势.洪泽湖与淮河水质相关性分析结果显示,洪泽湖总氮、总磷浓度与淮河水质呈强相关性,特别是过水区各个水质指标与淮河水质均有显著的相关性,而成子湖、溧河洼水质与淮河水质相关性较弱.广义可加模型(GAM)显示,过水区的总氮、总磷浓度等参数与淮河营养盐、高锰酸盐指数及悬浮物浓度变化的关系显著,成子湖和溧河洼的水质指标影响因素差异较大,成子湖、过水区的叶绿素a浓度与高锰酸盐指数相关性较强,而溧河洼的叶绿素a浓度与降水、透明度关系显著.相关性和GAM模型表明淮河对于洪泽湖,尤其是对过水区的水质影响极为明显,是洪泽湖维持较高营养水平和水质空间分异的重要原因.尽管不同湖区叶绿素a浓度下降趋势表明洪泽湖营养状态有所降低,但其氮、磷浓度仍维持在较高水平,存在富营养化风险.应持续关注淮河入湖水质变化,削减污染物输入,压缩湖泊围网、圈圩养殖规模,通过加强水污染防治和水域空间管控保障洪泽湖水环境安全. 相似文献
3.
淡水浮游植物计数与定量方法 总被引：1，自引：0，他引：1
显微镜计数法是淡水浮游植物计数最常用的经典方法,是浮游植物生物量测定的基本方法,也是衡量其他测定方法准确性的依据.随着科技的发展,可见分光光度法、荧光分光光度法、流式细胞显微镜计数法、库尔特计数法等新型细胞计数法相继问世.对各种方法的特点进行比较,结果表明:光密度法、流式摄像机计数法、流式细胞仪法、叶绿素a法等仅能够分析测定浮游植物生物量,而显微镜法是测量浮游植物粒径的经典方法,不仅可以测定浮游植物生物量,还可以进行浮游植物的种类及群落结构分析.以上这些方法都可以用于浮游植物的计数与定量,可以根据不同的需求来选择最佳的浮游植物计数方法,如分析方便性、样本处理速率、样本大小等.但显微镜计数法在淡水生态学中具有不可替代的作用. 相似文献
4.
洱海叶绿素a浓度的季节动态和空间分布 总被引：3，自引：0，他引：3
2010年5月至2011年4月,对洱海叶绿素a的季节动态、空间分布及其与环境因子的关系进行研究.结果表明,水体中叶绿素a浓度存在明显的季节变化,其变化范围为4.11~24.30μg/L,年平均值为10.4±6.5μg/L,最小值出现在2011年3月,最大值出现在2010年9月.叶绿素a浓度在夏、秋季较高,冬、春季较低.在空间变化上,叶绿素a浓度在南部湖区最大,其次是北部湖区,中部湖区最低.Pearson相关系数和主成分分析表明,洱海叶绿素a浓度在不同湖区中与水温和透明度均呈极显著相关.总氮在北部和南部湖区与叶绿素a浓度均存在一定的相关性,而总磷与叶绿素a浓度在南部湖区存在一定的相关性.根据修正的卡尔森营养状态指数,洱海综合TSI值为50.6,水质处于中营养状态. 相似文献
5.
洪泽湖叶绿素a浓度的时空变化特征 总被引：2，自引：0，他引：2
叶绿素a浓度是衡量藻类生物量及评价水体营养状态的重要指标.基于洪泽湖2012年12月至2013年11月的水质监测数据,利用统计手段分析湖区叶绿素a浓度的时空变化规律,并进一步探究叶绿素a浓度与各项水质理化因子的响应关系.从时间维度上看,洪泽湖叶绿素a浓度季节变化规律在不同湖区有所差异,东部湖区叶绿素a浓度随季节变化曲线呈"双峰型",分别在3月和8月达到峰值.北、西部湖区叶绿素a浓度在春季变化平缓,并在秋季达到峰值.从空间维度上看,3个湖区之间叶绿素a浓度在春、冬两季存在显著差异,其余季节差异不显著.典范对应分析表明洪泽湖不同月份、不同湖区叶绿素a浓度与水质理化因子之间存在不同的响应关系.本研究为探究洪泽湖藻类时空异质性原因、宏观掌控其营养状态以及制定相应水质改善措施提供参考依据. 相似文献
6.
浮游植物叶绿素a含量测定方法的比较测定 总被引：63，自引：7，他引：56
本文比较研究了浮游植物叶绿素ａ含量测定的２种常用方法－国内常用的丙酮萃取分光光度法和国际上较通用的热乙萃取分光光度法。实验结果显示：热乙醇法具有操作简便、快捷、萃取完全,低毒等优点。两种方法有显著统计差异及很好的相关性,其回归方程为：Ｃｈｌａ乙醇＝１．２６１Ｃｈｌａ丙醇－３．５（Ｒ＝０．９９８）。 相似文献
7.
天山天池水体季节性分层特征 总被引：4，自引：1，他引：3
于2014年6-10月,对高山深水湖泊天山天池水温、电导率、溶解氧、p H值、叶绿素a浓度和蓝绿藻细胞密度进行垂直剖面的连续监测,通过对其季节动态和垂直分层结构的分析,探讨天池水体季节性分层特征.天池出现明显水温分层的时间短(6-9月),夏季温跃层变化范围为2~18 m,而秋季温跃层不断下移,10月在18 m水深以下;受水温分层影响,天池水体溶解氧浓度、电导率、p H值、叶绿素a浓度和蓝绿藻细胞密度在垂直剖面表现出明显的季节性分层,尤其是夏季水温分层影响溶解氧浓度、叶绿素a浓度和蓝绿藻细胞密度在水体中的分布,对天池水质变化产生重要影响.天池浅水层(水深小于10 m)溶解氧浓度较高(大于8 mg/L),而深水层(水深超过18 m)溶解氧浓度9月接近4 mg/L,季节性缺氧导致底泥营养盐向上扩散,对水体水质产生不利影响.所以,应在夏、秋季节加强水质监测,以防止天池水华发生;天池叶绿素a浓度与蓝绿藻细胞密度的垂直剖面变化趋势相似,均随水深增加呈先增加后减小的趋势,但叶绿素a浓度在2~12 m水深处较高,蓝绿藻细胞密度在5~15 m水深处较高,表明5~15 m深度适合藻类生长,同时,电导率、p H值的垂直变化也说明藻类的生长情况,这为监测天池水体富营养化取样和分析提供依据. 相似文献
8.
9.
兴凯湖春季水体悬浮颗粒物和CDOM吸收特性 总被引：1，自引：0，他引：1
为了分析兴凯湖水体光学活性物质的吸收特性、来源和空间分布以及对400~700 nm范围内总吸收的贡献,于2013年5月对该水体进行野外实验,对水体中浮游藻类、非藻类颗粒物和有色可溶性有机物的吸收特性和水质参数进行测定.结果表明:总悬浮颗粒物的吸收光谱与非藻类颗粒物相似,色素颗粒物含量较少且单一,非藻类颗粒物在总悬浮颗粒物吸收中占主导地位,其贡献率始终在50%以上.CDOM吸收曲线的拟合函数斜率值Sg均高于其它水体.440 nm处总悬浮颗粒物和非藻类颗粒物的吸收系数ap(440)、ad(440)与总悬浮颗粒物、无机悬浮颗粒物和有机悬浮颗粒物浓度相关性均较好,与叶绿素a(Chl.a)浓度的相关性较差.兴凯湖与其它Ⅱ类水体的差异性表现在440 nm处CDOM吸收系数ag(440)与Chl.a浓度、溶解性有机碳(DOC)浓度均无显著相关性,说明DOC以无色部分为主.总体上,大兴凯湖各吸收系数和水质参数均值均低于小兴凯湖,后者水质受农耕区退水及周围渔业、旅游业的影响较大. 相似文献
10.
基于半分析算法的香港邻近海域叶绿素a浓度反演 总被引：2，自引：0，他引：2
为进一步了解香港近海水体特性及监测其水质状况,根据2001年3-5月在香港临近海域调查取得的实测资料,对该海域水体光谱进行解析,开发该海域叶绿素a浓度与色素吸收系数aph(675)的经验模型,具有较高相关性;用剖面数据外推及水体光谱模拟方法完成对水下表面遥感反射率光谱的推导;进而建屯反演低浓度区叶绿素a浓度的半分析算法,反演结果与实测值比较平均相对误差为45%,均方根差0.933,相关系数0.78,误差主要来源于外推演算及散射模型.结果表明该算法在低悬浮物低叶绿素浓度区域有一定适用性. 相似文献
11.
水面蒸发与散热系数公式研究(二) 总被引：16，自引：0，他引：16
根据自1976年以来全国水面蒸发与散热研究协作组在我国各典型地区的原体与室内实验资料和大量水文站历史资料,通过理论分析和统计检验,确定了影响水面蒸发的诸因子及其非线性相互作用,引入了新的无量纲参数和公式结构,用实测资料统计确定了公式中的常系数,得到了用开敞湖面一般水文气象资料计算逐日蒸发和散热系数的公式。经全国务典型气候带内务季节湖泊(水库)和受热污染水体上原体观测和室内专题实验共1860组日平均检验,公式的精度高于现有其他公式。全文分两部分,本文刊出第二部分,内容包括:公式的检验;水文气象要素对α的影响;水面散热系数的计算和结语。 相似文献
12.
水面蒸发与散热系数公式研究(一) 总被引：15，自引：1，他引：15
根据自1976年以来全国水面蒸发与散热研究协作组在我国各典型地区的原体与室内实验资料和大量水文站历史资料,通过理论分析和统计检验,确定丁影响水面蒸发的诸因子及其非线性相互作用,引入了新的无量纲参数(w_e、Pv、Pe)和公式结构,用实测资料统计确定厂公式中的常系数,得到了用开敞湖面一般水文气象资料计算逐日蒸发和散热系数的公式。经全国各典型气候带内各季节湖泊(水库)和受热污染水体上原体观测和室内专题实验共1860组口平均资料检验,公式的精度高于现有其他公式。全文分两部分,这是第一部分,内容包括:影响水面蒸发的土要无量纲参数;感热输送和大气饱和度对蒸发影响的修正;水面蒸发计算公式的结构及其经验系数。 相似文献
13.
Robert C. Buchmiller 《Ground Water Monitoring & Remediation》1989,9(3):126-130
A portable gas chromatograph was used to screen 32 ground water samples for volatile organic compounds. Seven screened samples were positive; four of the seven samples had volatile organic substances identified by second-column confirmation. Four of the seven positive, screened samples also tested positive in laboratory analyses of duplicate samples. No volatile organic compounds were detected in laboratory analyses of samples that headspace screening indicated to be negative. Samples that contained volatile organic compounds, as identified by laboratory analysis, and that contained a volatile organic compound present in a standard of selected compounds were correctly identified by using the portable gas chromatograph. Comparisons of screened-sample data with laboratory data indicate the ability to detect selected volatile organic compounds at concentrations of about 1 microgram per liter in the headspace of water samples by use of a portable gas chromatograph. 相似文献
14.
Effect of Slope Length and Rainfall Intensity on Runoff and Erosion Conversion from Laboratory to Field 总被引：3，自引：0，他引：3
Water Resources - Predictions of soil and water loss at large extents often relies on data obtained from laboratory flume experiments. It is necessary to have a reliable approach to extrapolate... 相似文献
15.
《Ground Water Monitoring & Remediation》1985,5(4):58-62
The recognition and assurance of the quality of ground water monitoring data are crucial to the correct assessment of the magnitude and extent of a ground water contamination problem. This article addresses an approach being developed to systematically evaluate the quality of a given set of ground water monitoring data collected during site investigation/ remedial action efforts. The system consists of a checklist of criteria, grouped into four major categories, which can be applied to laboratory or field measurements.
The first category, basis of measurement, considers whether the appropriate sampling, boring and/or analytical methods were chosen to obtain the measurement and the limitations of each method. Secondly, application of the method is assessed. This includes examination of the extent to which procedures were correctly performed, the use of quality control measures and calibration, and possible sources of error in the measurements. Third, evaluation of applied statistical methods is made, with consideration given to which statistics are meaningful in a given context and whether measurements are reproducible. The final category, corroborative information, considers whether independent data or other information are available that add credibility to the values measured.
In this approach, a "high quality" data value is defined as one in which accuracy is supported by meeting the preceding criteria. When accompanied by precision information, high quality data allow for defensible assessments and actions. This evaluation system is useful in developing monitoring programs and in guiding documentation of field and laboratory methods during data collection. It relies heavily on experienced judgment and can be catalyst for the beneficial exchange of knowledge and ideas among ground water professionals. 相似文献
The first category, basis of measurement, considers whether the appropriate sampling, boring and/or analytical methods were chosen to obtain the measurement and the limitations of each method. Secondly, application of the method is assessed. This includes examination of the extent to which procedures were correctly performed, the use of quality control measures and calibration, and possible sources of error in the measurements. Third, evaluation of applied statistical methods is made, with consideration given to which statistics are meaningful in a given context and whether measurements are reproducible. The final category, corroborative information, considers whether independent data or other information are available that add credibility to the values measured.
In this approach, a "high quality" data value is defined as one in which accuracy is supported by meeting the preceding criteria. When accompanied by precision information, high quality data allow for defensible assessments and actions. This evaluation system is useful in developing monitoring programs and in guiding documentation of field and laboratory methods during data collection. It relies heavily on experienced judgment and can be catalyst for the beneficial exchange of knowledge and ideas among ground water professionals. 相似文献
16.
This paper presents an in situ falling-head method for measuring hydraulic conductivity of beach sediments in tidal environment. A polyvinyl chloride (PVC) standpipe was vertically pushed into the submerged beach sediments so that its lower part was filled by a sediment column. During the experiment, the sediments were submerged by sea water and the standpipe top was higher than the sea level. The pipe was fully filled with sea water at the beginning of the experiment. Then the water level time series inside and outside the standpipe were recorded. Analytical solutions were derived to describe the relation among the sediment's hydraulic conductivity and the water levels inside and outside the standpipe and used to analyze the experiment data obtained from the intertidal zone of Puqian Bay, Haikou, Hainan Province, China. The water levels predicted by the analytical solution agreed very well with all the experiment data. Experiments for horizontal hydraulic conductivity estimation were also conducted using L-shaped standpipe which bends from vertical to horizontal in the beach sediments. The averaged hydraulic conductivity anisotropy ratio at the study area is about 2.9. After each in situ experiment, the sediments in the standpipe were stored in a plastic box and transported to university laboratory to measure the hydraulic conductivity using falling-head method. It is found that the in situ hydraulic conductivity averages one order of magnitude greater than the laboratory one, indicating that the original beach surface sediments were loose due to tidal and wave actions and that the samples were significantly compacted during the transportation to laboratory. 相似文献
17.
Elevated particulate concentrations in ground water samples can bias contaminant concentration data. This has been particularly problematic for metal analyses where artificially increased turbidity levels can affect metals concentrations and confound interpretation of the data. However, few studies have been conducted to determine the impact of particulates on trichloroethylene (TCE), cis-dichloroethylene (c-DCE), and vinyl chloride concentrations.
Laboratory batch studies and field investigations were conducted to evaluate the effects of suspended solids on VOC concentrations in ground water samples analyzed by purge-and-trap gas chromatography. Three different solids were used to assess the effects of suspended particulates. The solids were aquifer material from a field site in North Carolina and two reference clay minerals (kaolinite and Namontimorillonite). During the laboratory portion of this study, the solids were used to determine effects on TCE concentrations under controlled laboratory conditions.
The same solids were used in a field study to compare the laboratory results with field results. Solids were added to the sample vials prior it) sample collection to intentionally increase turbidity levels in the water samples. Results of the study indicate essentially no decrease in TCE, c-DCH, or vinyl chloride concentrations due to increased turbidity levels. 相似文献
Laboratory batch studies and field investigations were conducted to evaluate the effects of suspended solids on VOC concentrations in ground water samples analyzed by purge-and-trap gas chromatography. Three different solids were used to assess the effects of suspended particulates. The solids were aquifer material from a field site in North Carolina and two reference clay minerals (kaolinite and Namontimorillonite). During the laboratory portion of this study, the solids were used to determine effects on TCE concentrations under controlled laboratory conditions.
The same solids were used in a field study to compare the laboratory results with field results. Solids were added to the sample vials prior it) sample collection to intentionally increase turbidity levels in the water samples. Results of the study indicate essentially no decrease in TCE, c-DCH, or vinyl chloride concentrations due to increased turbidity levels. 相似文献
18.
Vladimir Smirnov Alexander Ponomarev Pascal Bernard Seid Bourouis 《Acta Geophysica》2013,61(6):1598-1625
The data of the known field experiment on water injection in the borehole were analyzed. Parameters of self-similarity of seismicity were estimated in comparison with the changes of water pressure. Changes of seismicity parameters that indicate the redistribution of the failure from lower scales to upper are revealed. The total number of earthquakes per series of the water initiation found to be depended exponentially on the water pressure and seismic activity maximum is delayed gradually relative to beginning of initiation. The growth of induced seismicity zone in time differs from diffusion model for water flow in the porous medium. Analysis carried out from laboratory data indicates that diffusion growth of the failure area may be realized in the dry specimen, without fluid. It could be assumed that both kinetic processes — water and the failure diffusion — can be significant for the development of seismicity induced by the water injection. 相似文献
19.
Lightweight Autonomous Underwater Vehicles (AUVs) performing coastal survey operations in REP 10A 总被引：2，自引：1，他引：1
Michael L. Incze 《Ocean Dynamics》2011,61(11):1955-1965
Lightweight Autonomous Underwater Vehicles (AUVs) were developed for Naval Special Warfare (NSW) Group 4 search and survey
missions from a commercial AUV baseline (Iver 2) through integration of commercial off-the-shelf (COTS) hardware components,
and through software development for enhanced on-board Command and Control functions. The development period was 1 year under
a project sponsored by the Office of Naval Research TechSolutions Program Office. Hardware integration was completed by the
commercial AUV vendor, OceanServer Technology, Inc., and software development was conducted by the Naval Undersea Warfare
Center, Naval Oceanographic Office, and U MASS Dartmouth, with support from hardware and software application providers (YSI,
Inc., Imagenex Technology Corp., and CARIS). At the conclusion of the integration and development period, an at-sea performance
evaluation was scheduled for the Lightweight NSW AUVs with NSWG-4 personnel. The venue for this evaluation was the NATO exercise
Recognized Environmental Picture 10A (REP 10A), hosted by Marinha Portuguesa, and coordinated by the Faculdade de Engenharia–Universidade
do Porto. REP 10A offered an opportunity to evaluate the performance of the new AUVs and to explore the Concept of Operations
(CONOPS) for employing them in military survey operations in shallow coastal waters. Shore- and ship-launched scenarios with
launch/recovery by a single operator in a one-to-many coordinated survey, on-scene data product generation and visualization,
data push to Reach Back Cells for product integration and enhancement, and survey optimization to streamline survey effort
and timelines were included in the CONOPS review. Opportunities to explore employment of hybrid AUV fleets in Combined Force
scenarios were also utilized. The Naval Undersea Warfare Center, Marinha Portuguesa, the Faculdade de Engenharia–Universidade
do Porto, and OceanServer Technology, Inc., were the primary participants bringing in-water resources to REP 10A. Technical
support and products were provided by the Naval Research Laboratory–Stennis Space Center, Naval Oceanographic Office, NATO
Undersea Research Centre, University of Massachusetts–Dartmouth, and YSI, Inc. REP 10A proved to be a very effective exercise
in meeting each of the critical goals. Results of the performance evaluation guided final development and Independent Verification
and Validation (IV&V) for the Lightweight NSW AUV, leading to on-time, successful Factory Acceptance Testing and delivery
of the three contracted vehicles to NSWG-4 in September, 2010. 相似文献