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1.
At a low permeability clay till site contaminated with chlorinated ethenes (Gl. Kongevej, Denmark), enhanced reductive dechlorination (ERD) was applied by direct push injection of molasses and dechlorinating bacteria. The performance was investigated by long‐term groundwater monitoring, and after 4 years of remediation, the development of degradation in the clay till matrix was investigated by high‐resolution subsampling of intact cores. The formation of degradation products, the presence of specific degraders Dehalococcoides spp. with the vinyl chloride (VC) reductase gene vcrA, and the isotope fractionation of trichloroethene, cis‐dichloroethene (cis‐DCE), and VC showed that degradation of chlorinated ethenes occurred in the clay till matrix as well as in sand lenses, sand stringers, and fractures. Bioactive sections of up to 1.8 m had developed in the clay till matrix, but sections, where degradation was restricted to narrow zones around sand lenses and stringers, were also observed. After 4 years of remediation, an average mass reduction of 24% was estimated. Comparison of the results with model simulation scenarios indicate that a mass reduction of 85% can be obtained within approximately 50 years without further increase in the narrow reaction zones if no donor limitations occur at the site. Long‐term monitoring of the concentration of chlorinated ethenes in the underlying chalk aquifer revealed that the aquifer was affected by the more mobile degradation products cis‐DCE and VC generated during the remediation by ERD.  相似文献   

2.
Free-phase DNAPL recovery operations are becoming increasingly prevalent at creosote-contaminated aquifer sites. This paper illustrates the potential of both classical and innovative recovery methods. The UTCHEM multiphase flow and transport numerical simulator was used to predict the migration of creosote DNAPL during a hypothetical spill event, during a long-term redistribution after the spill, and for a variety of subsequent free-phase DNAPL recovery operations. The physical parameters used for the DNAPL and the aquifer in the model are estimates for a specific creosote DNAPL site. Other simulations were also conducted using physical parameters that are typical of a trichloroethene (TCE) DNAPL. Dramatic differences in DNAPL migration were observed between these simulations.  相似文献   

3.
In situ chemical oxidation (ISCO) followed by a bioremediation step is increasingly being considered as an effective biphasic technology. Information on the impact of chemical oxidants on organohalide respiring bacteria (OHRB), however, is largely lacking. Therefore, we used quantitative PCR (qPCR) to monitor the abundance of OHRB (Dehalococcoides mccartyi, Dehalobacter, Geobacter, and Desulfitobacterium) and reductive dehalogenase genes (rdh; tceA, vcrA, and bvcA) at a field location contaminated with chlorinated solvents prior to and following treatment with sodium persulfate. Natural attenuation of the contaminants tetrachloroethene (PCE) and trichloroethene (TCE) observed prior to ISCO was confirmed by the distribution of OHRB and rdh genes. In wells impacted by persulfate treatment, a 1 to 3 order of magnitude reduction in the abundances of OHRB and complete absence of rdh genes was observed 21 days after ISCO. Groundwater acidification (pH<3) and increase in the oxidation reduction potential (>500 mV) due to persulfate treatment were significant and contributed to disruption of the microbial community. In wells only mildly impacted by persulfate, a slight stimulation of the microbial community was observed, with more than 1 order of magnitude increase in the abundance of Geobacter and Desulfitobacterium 36 days after ISCO. After six months, regeneration of the OHRB community occurred, however, neither D. mccartyi nor any rdh genes were observed, indicating extended disruption of biological natural attenuation (NA) capacity following persulfate treatment. For full restoration of biological NA activity, additional time may prove sufficient; otherwise addition electron donor amendment or bioaugmentation may be required.  相似文献   

4.
Passive multilevel samplers (MLS) containing a solid matrix for microbial colonization were used as in situ microcosms in conjunction with a push-pull biostimulation experiment designed to promote biological U(VI) and Tc(VII) reduction. MLS were deployed at 24 elevations in the injection well and two downgradient wells to investigate the spatial variability in microbial community composition and growth prior to and following biostimulation. The microbial community was characterized by real-time quantitative polymerase chain reaction (Q-PCR) quantification of bacteria, NO(3)(-)-reducing bacteria (nirS and nirK), delta-proteobacteria, Geobacter sp., and methanogens (mcrA). Pretest cell densities were low overall but varied substantially with significantly greater bacterial populations detected at circumneutral pH (t-test, alpha= 0.05), suggesting carbon substrate and low pH limitations of microbial activity. Although pretest cell densities were low, denitrifying bacteria were dominant members of the microbial community. Biostimulation with an ethanol-amended ground water resulted in concurrent NO(3)(-) and Tc(VII) reduction, followed by U(VI) reduction. Q-PCR analysis of MLS revealed significant (1 to 2 orders of magnitude, Mann-Whitney U-test, alpha= 0.05) increases in cell densities of bacteria, denitrifiers, delta-proteobacteria, Geobacter sp., and methanogens in response to biostimulation. Traditionally, characterization of sediment samples has been used to investigate the microbial community response to biostimulation; however, collection of sediment samples is expensive and not conducive to deep aquifers or temporal studies. The results presented demonstrate that push-pull tests with passive MLS provide an inexpensive approach to determine the effect of biostimulation on contaminant concentrations, geochemical conditions, and the microbial community composition and function.  相似文献   

5.
Degradation of dissolved chlorinated solvents using granular iron is an established in situ technology. This paper reports on investigations into mixing iron and bentonite with contaminated soil for in situ containment and degradation of dense nonaqueous phase liquid source zones. In the laboratory, hypovials containing soil, water, bentonite, iron, and free-phase trichloroethene (TCE) were assembled. Periodic measurement of TCE, chloride, and degradation products showed progressive degradation of TCE to nondetectable levels. Subsequently, a demonstration was conducted at Canadian Forces Base Borden near Alliston, Ontario, Canada, where, in 1991, a portion of the surficial aquifer was isolated and free-phase tetrachloroethene (PCE) was introduced. Using a drill rig equipped with large-diameter mixing blades, three mixed zones were prepared containing 0%, 5%, and 10% granular iron by volume. The bentonite was added to serve as a lubricant to facilitate injection of the iron and to isolate the contaminated zone. Analysis of core samples showed reasonably uniform distributions of iron through the mixed zones. Monitoring over a 13-month period following installation showed, relative to the control, a decline in PCE concentrations to virtually nondetectable values. Reaction rates in the laboratory tests were similar to those reported in the literature, while the rate in the field test was substantially lower. The lower rate may be a consequence of mass transfer limitations under the static conditions of the field test. Results indicate that mixing iron and bentonite into source zones may be an effective means of source-zone remediation, with the particular advantage of being relatively immune to effects of geologic heterogeneity.  相似文献   

6.
A new method was developed for conducting aquifer tests in fractured-rock flow systems that have a pump-and-treat (P&T) operation for containing and removing groundwater contaminants. The method involves temporary shutdown of individual pumps in wells of the P&T system. Conducting aquifer tests in this manner has several advantages, including (1) no additional contaminated water is withdrawn, and (2) hydraulic containment of contaminants remains largely intact because pumping continues at most wells. The well-shutdown test method was applied at the former Naval Air Warfare Center (NAWC), West Trenton, New Jersey, where a P&T operation is designed to contain and remove trichloroethene and its daughter products in the dipping fractured sedimentary rocks underlying the site. The detailed site-scale subsurface geologic stratigraphy, a three-dimensional MODFLOW model, and inverse methods in UCODE_2005 were used to analyze the shutdown tests. In the model, a deterministic method was used for representing the highly heterogeneous hydraulic conductivity distribution and simulations were conducted using an equivalent porous media method. This approach was very successful for simulating the shutdown tests, contrary to a common perception that flow in fractured rocks must be simulated using a stochastic or discrete fracture representation of heterogeneity. Use of inverse methods to simultaneously calibrate the model to the multiple shutdown tests was integral to the effectiveness of the approach.  相似文献   

7.
Chlororespiration is common in shallow aquifer systems under conditions nominally identified as anoxic. Consequently, chlororespiration is a key component of remediation at many chloroethene‐contaminated sites. In some instances, limited accumulation of reductive dechlorination daughter products is interpreted as evidence that natural attenuation is not adequate for site remediation. This conclusion is justified when evidence for parent compound (tetrachloroethene, PCE, or trichloroethene, TCE) degradation is lacking. For many chloroethene‐contaminated shallow aquifer systems, however, nonconservative losses of the parent compounds are clear but the mass balance between parent compound attenuation and accumulation of reductive dechlorination daughter products is incomplete. Incomplete mass balance indicates a failure to account for important contaminant attenuation mechanisms and is consistent with contaminant degradation to nondiagnostic mineralization products like CO2. While anoxic mineralization of chloroethene compounds has been proposed previously, recent results suggest that oxygen‐based mineralization of chloroethenes also can be significant at dissolved oxygen concentrations below the currently accepted field standard for nominally anoxic conditions. Thus, reassessment of the role and potential importance of low concentrations of oxygen in chloroethene biodegradation are needed, because mischaracterization of operant biodegradation processes can lead to expensive and ineffective remedial actions. A modified interpretive framework is provided for assessing the potential for chloroethene biodegradation under different redox conditions and the probable role of oxygen in chloroethene biodegradation.  相似文献   

8.
Sea turtles migrate to various habitats where they can be exposed to different pollutants. Bacteria were collected from turtle eggs and their resistance to antibiotics was used as pollutant bio-indicators of contaminated effluents. Eggs were collected randomly from turtles when they were laying their eggs. A total of 90 eggs were collected and placed into sterile plastic bags (3 eggs/turtle) during June-December of 2003. The bacteria located in the eggshell, albumen and yolk were examined, and 42% of the eggs were contaminated with 10 genera of bacteria. Pseudomonas spp. were the most frequent isolates. The albumen was found to be the part of the egg to be the least contaminated by bacterial infection. Bacterial isolates tested with 14 antibiotics showed variations in resistance. Resistance to ampicillin was the highest. The presence of antibiotic resistant bacteria in eggs indicates that the green turtle populations were subjected to polluted effluents during some of their migratory routes and feeding habitats. Scanning electron microscopy revealed that Salmonella typhimurium penetrated all eggshell layers.  相似文献   

9.
The migration and entrapment of dense nonaqueous phase liquids (DNAPLs) in aquifer formations is typically believed to be controlled by physical heterogeneities. This belief is based upon the assumption that permeability and capillary properties are determined by the soil texture. Capillarity and relative permeability, however, will also depend on porous medium wettability characteristics. This wettability may vary spatially in a formation due to variations in aqueous phase chemistry, contaminant aging, and/or variations in mineralogy and organic matter distributions. In this work, a two-dimensional multiphase flow simulator is modified to simulate coupled physical and chemical formation heterogeneity. To model physical heterogeneity, a spatially correlated permeability field is generated, and then related to the capillary pressure-saturation function according to Leverett scaling. Spatial variability of porous medium wettability is assumed to be correlated with the natural logarithm of the intrinsic permeability. The influence of wettability on the hysteretic hydraulic property relations is also modeled. The simulator is then employed to investigate the potential influence of coupled physical and chemical heterogeneity on DNAPL flow and entrapment. For reasonable ranges of wettability characteristics, simulations demonstrate that spatial variations in wettability can have a dramatic impact on DNAPL distributions. Higher organic saturations, increased lateral spreading, and decreased depth of infiltration were predicted when the contact angle was varied spatially. When chemical heterogeneity was defined by spatial variation of organic-wet solid fractions (fractional wettability porous media), however, the resultant organic saturation distributions were more similar to those for perfectly water-wet media, due to saturation dependent wettability effects on the hydraulic property relations.  相似文献   

10.
Diisopropanolamine Biodegradation Potential at Sour Gas Plants   总被引：1，自引：0，他引：1  
The potential for aerobic and anaerobic biodegradation of a sour gas treatment chemical, diisopropanolamine (DIPA), was studied using contaminated aquifer materials from three sour gas treatment sites in western Canada. DIPA was found to be readily consumed under aerobic conditions at 8°C and 28°C in shake flask cultures incubated with aquifer material from each of the sites, and this removal was characterized by first-order kinetics. In addition, DIPA biodegradation was found to occur under nitrate-, Min(IV)., and Fe(III)-reducing conditions at 28°C, and in some cases at 8°C, in laboratory microcosms, DIPA loss corresponded to consumption of nitrate, and production of Mn(II) and Fe(II) in viable microcosms compared to corresponding sterile controls. A threshold DIPA concentration near 40 mg/L was observed in the anaerobic microcosms. This report provides the first evidence that DIPA is biodegraded under anaerobic conditions, and our data suggest that biodegradation may contribute to DIPA attenuation under aerobic and anaerobic conditions in aquifers contaminated with this sour gas treatment chemical.  相似文献   

11.
Groundwater beneath the former Nebraska Ordnance Plant (NOP) is contaminated with the explosive hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and trichloroethene (TCE). Previous treatability experiments confirmed that permanganate could mineralize RDX in NOP aquifer material. The objective of this study was to determine the efficacy of permanganate to transform RDX in the field by monitoring a pilot‐scale in situ chemical oxidation (ISCO) demonstration. In this demonstration, electrical resistivity imaging (ERI) was used to create two‐dimensional (2‐D) images of the test site prior to, during, and after injecting sodium permanganate. The ISCO was performed by using an extraction‐injection well configuration to create a curtain of permanganate. Monitoring wells were positioned downgradient of the injection zone with the intent of capturing the permanganate‐RDX plume. Differencing between ERI taken preinjection and postinjection determined the initial distribution of the injected permanganate. ERI also quantitatively corroborated the hydraulic conductivity distribution across the site. Groundwater samples from 12 downgradient wells and 8 direct‐push profiles did not provide enough data to quantify the distribution and flow of the injected permanganate. ERI, however, showed that the permanganate injection flowed against the regional groundwater gradient and migrated below monitoring well screens. ERI combined with monitoring well samples helped explain the permanganate dynamics in downgradient wells and support the use of ERI as a means of monitoring ISCO injections.  相似文献   

12.
We examine the effect of uncertainty due to limited information on the remediation design of a contaminated aquifer using the pump and treat method. The hydraulic conductivity and contaminant concentration distributions for a fictitious contaminated aquifer are generated assuming a limited number of sampling locations. Stochastic optimization with multiple realizations is used to account for aquifer uncertainty. The optimization process involves a genetic algorithm (GA). As the number of realizations increases, a greater extraction rate and more wells are needed. There was a total cost increase, but the optimal remediation designs became more reliable. Stochastic optimization analysis also determines the locations for extraction wells, the variation in extraction rates as a function of the change of well locations, and the reliability of the optimal designs. The number of realizations (stack number) that caused the design factors to converge could be determined. Effective stochastic optimization may be achieved by reducing computational resources. An increase in the variability of the conductivity distribution requires more extraction wells. Information about potential extraction wells can be used to prevent failure of the remediation task.  相似文献   

13.
Liu C  Ball WP 《Ground water》2002,40(2):175-184
Vertical profiles of tetrachloroethene (or perchloroethylene, PCE) and trichloroethene (TCE) were used to validate a diffusion process in a natural aquitard at Dover Air Force Base, Delaware. PCE and TCE distributions in the aquitard underlying an unconfined aquifer were sampled from core tubes obtained at four times over the course of a 35-month field investigation within "test cells" that were isolated from the surrounding ground water by means of grout-sealed steel sheetpile barriers (Mackay et al. 2000). For the final 23 months of this period, boundary conditions at the aquifer/aquitard interface were such that a "back diffusion" of contaminants from the aquitard was induced. Modeling predictions of concentration changes were made on the basis of the earliest coring results and an assumption of sorption-retarded diffusion and using laboratory information about sorption and diffusion characteristics of the media. The predictive modeling was complicated by the fact that "initial" and "final" PCE and TCE distributions in the aquitard were measured at different (albeit proximate) coring locations, such that results reflect spatial variations in aquitard characteristics. This problem was solved by means of an inverse interpretation that involved spatial "translation" of observed profiles on the basis of the laboratory characterizations and assuming a common aquifer-side contaminant history. Predictions indicated substantial change in PCE and TCE concentrations within the upper aquitard (near the aquifer/aquitard interface) and the development of a back-diffusion profile up into the aquifer. Modeling also predicted comparatively minor profile changes in the deeper aquitard, and especially in the deep layer where sorption was strongest. All of these predicted effects were observed in the coring results. Although not exact, the agreement between predictions and observations was sufficiently good to justify the basic tenets of the diffusion model and to support a conclusion that major processes of advection and/or transformation were unimportant within the 35-month time scale of this work.  相似文献   

14.
Approximately 190 kg of 2 μm‐diameter zero‐valent iron (ZVI) particles were injected into a test zone in the top 2 m of an unconfined aquifer within a trichloroethene (TCE) source area. A shear‐thinning fluid was used to enhance ZVI delivery in the subsurface to a radial distance of up to 4 m from a single injection well. The ZVI particles were mixed in‐line with the injection water, shear‐thinning fluid, and a low concentration of surfactant. ZVI was observed at each of the seven monitoring wells within the targeted radius of influence during injection. Additionally, all wells within the targeted zone showed low TCE concentrations and primarily dechlorination products present 44 d after injection. These results suggest that ZVI can be directly injected into an aquifer with shear‐thinning fluids to induce dechlorination and extends the applicability of ZVI to situations where other emplacement methods may not be viable.  相似文献   

15.
Partitioning interwell tracer tests (PITT) were used ID determine the spatial distribution and volume of residual trichloroethene (TCE) present in alluvium beneath the Portsmouth Gaseous Diffusion Plain in southern Ohio. Its first use at this site was in support of the design of a surfactant flood to remove the residual DNAPL (dense nonaqueous phase liquids) from the alluvial aquifer. The second application assessed the performance of the surfactant flood. The average DNAPL saturation in the first PITT was 0.1 to 0.2% in a swept pore volume of 4500 gallons (17.000 L). A second PITT was undertaken following the surfactant flood and yielded an average residual saturation of 0.06% in a swept pore volume of 3400 gallons (13.000 L), the reduction in pore volume being due to the confinement of the tracers to the lower sand and gravel unit of the alluvium. The design, operation, and analysis of the two PM Is provided strong evidence of a buried channel that controls the spatial distribution of the residual TCI: DNAPL in the basal sand and gravel aquifer and must be considered in the eventual full remediation of this aquifer.  相似文献   

16.
In a previous study, a denitrification wall was constructed in a sand aquifer using sawdust as the carbon substrate. Ground water bypassed around this sawdust wall due to reduced hydraulic conductivity. We investigated potential reasons for this by testing two new walls and conducting laboratory studies. The first wall was constructed by mixing aquifer material in situ without substrate addition to investigate the effects of the construction technique (mixed wall). A second, biochip wall, was constructed using coarse wood chips to determine the effect of size of the particles in the amendment on hydraulic conductivity. The aquifer hydraulic conductivity was 35.4 m/d, while in the mixed wall it was 2.8 m/d and in the biochip wall 3.4 m/d. This indicated that the mixing of the aquifer sands below the water table allowed the particles to re-sort themselves into a matrix with a significantly lower hydraulic conductivity than the process that originally formed the aquifer. The addition of a coarser substrate in the biochip wall significantly increased total porosity and decreased bulk density, but hydraulic conductivity remained low compared to the aquifer. Laboratory cores of aquifer sand mixed under dry and wet conditions mimicked the reduction in hydraulic conductivity observed in the field within the mixed wall. The addition of sawdust to the laboratory cores resulted in a significantly higher hydraulic conductivity when mixed dry compared to cores mixed wet. This reduction in the hydraulic conductivity of the sand/sawdust cores mixed under saturated conditions repeated what occurred in the field in the original sawdust wall. This indicated that laboratory investigations can be a useful tool to highlight potential reductions in field hydraulic conductivities that may occur when differing materials are mixed under field conditions.  相似文献   

17.
The spatial distribution of iron incrustations around an abandoned water well after 38 years of use was studied by analyzing the iron content of soil samples from 12 core borings. Three of these were performed inside the gravel pack, the rest at different distances in the adjacent aquifer. Incrustations had preferentially accumulated at the bottom of the screen coinciding with a zone of higher aquifer permeability. As expected, all cores from the annulus show buildup of iron oxides but the ones outside also showed elevated iron content up to 4 m away from the screen. Such distant incrustations are very difficult to remove, by mechanical or chemical methods. The common procedure of removing tubing and annulus material to install a new well at the same location could therefore give the replacement well a hydraulic disadvantage as the incrustations in the aquifer remain in place.  相似文献   

18.
Bayer P  Finkel M  Teutsch G 《Ground water》2004,42(6-7):856-867
A detailed analysis is presented of the hydraulic efficiency of plume management alternatives that combine a conventional pump-and-treat system with vertical, physical hydraulic barriers such as slurry walls or sheet piles. Various design settings are examined for their potential to reduce the pumping rate needed to obtain a complete capture of a given contaminated area. Using established modeling techniques for flow and transport, those barrier configurations (specified by location, shape, and length) that yield a maximum reduction of the pumping rate are identified assuming homogeneous aquifer conditions. Selected configurations are further analyzed concerning their hydraulic performance under heterogeneous aquifer conditions by means of a stochastic approach (Monte Carlo simulations) with aquifer transmissivity as a random space function. The results show that physical barriers are an appropriate means to decrease expected (mean) pumping rates, as well as the variance of the corresponding pumping rate distribution at any given degree of heterogeneity. The methodology presented can be transferred easily to other aquifer scenarios, provided some basic premises are fulfilled, and may serve as a basis for reducing the pumping rate in existing pump-and-treat systems.  相似文献   

19.
Analysis of recharge-induced geochemical change in a contaminated aquifer   总被引：1，自引：0，他引：1  
Recharge events that deliver electron acceptors such as O2, NO3, SO4, and Fe3+ to anaerobic, contaminated aquifers are likely important for natural attenuation processes. However, the specific influence of recharge on (bio)geochemical processes in ground water systems is not well understood. The impact of a moderate-sized recharge event on ground water chemistry was evaluated at a shallow, sandy aquifer contaminated with waste fuels and chlorinated solvents. Multivariate statistical analyses coupled with three-dimensional visualization were used to analyze ground water chemistry data (including redox indicators, major ions, and physical parameters) to reveal associations between chemical parameters and to infer processes within the ground water plume. Factor analysis indicated that dominant chemical associations and their interpreted processes (anaerobic and aerobic microbial processes, mineral precipitation/dissolution, and temperature effects) did not change significantly after the spring recharge event of 2000. However, the relative importance of each of these processes within the plume changed. After the recharge event, the overall importance of aerobic processes increased from the fourth to the second most important factor, representing the variability within the data set. The anaerobic signatures became more complex, suggesting that zones with multiple terminal electron-accepting processes (TEAPs) likely occur in the same water mass. Three-dimensional visualization of well clusters showed that water samples with similar chemical associations occurred in distinct water masses within the aquifer. Water mass distinctions were not based on dominant TEAPs, suggesting that the recharge effects on TEAPs occurred primarily at the interface between infiltrating recharge water and the aquifer.  相似文献   

20.
Preliminary risk assessment for prioritisation of site investigations requires efficient screening to reveal type and level of contamination. The screening methods, tree coring and soil gas sampling were applied and compared at two forested sites contaminated with tetrachloroethylene (PCE) or trichloroethylene (TCE) to evaluate their ability to locate source zones and contaminant hot spots. One test site represented a relatively homogeneous sandy soil and aquifer, and the second a more heterogeneous geology with both sandy and less permeable clay till layers overlying a chalk aquifer. Tree cores from different tree species were sampled and analysed, and compared to soil gas measurements and existing soil gas data. Both methods were found useful as screening tools to locate hot spots of PCE and TCE in the shallow subsurface. Tree coring was found to be particularly beneficial as a complement to soil gas sampling at sites with low permeable soils, and where contamination was located in the capillary rise or shallow groundwater. The shorter time required for tree coring reduced the costs compared to soil gas sampling, but the sensitivity and precision of tree coring were lower. However, this did not affect the feasibility of using tree coring to locate the hot spots. Moreover, a combination of the two methods can help to focus any subsequent investigations like soil or groundwater sampling. The use of tree coring to complement soil gas sampling for pre‐screening is expected to result in higher certainty for revealing hot spots and source zones at contaminated sites.  相似文献   

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