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1.
Thermodynamic and kinetic investigations were performed to determine the influence of coalescence of chemically dispersed crude oil droplets in saline waters. For the range of pH (4-10) and salinity (10 per thousand, 30 per thousand, 50 per thousand ) values studied, zeta-potential values ranged from -3 to -10 mV. As the interaction potential values calculated using Derjaguin-Landau-Verway-Overbeek (DLVO) theory were negative, the electrostatic barrier did not produce significant resistance to droplet coalescence. Coalescence kinetics of premixed crude oil and chemical dispersant were determined within a range of mean shear rates (Gm = 5, 10, 15, 20 s(-1)) and salinity (10 per thousand, 30 per thousand ) values. Coalescence reaction rates were modeled using Smoluchowski reaction kinetics. Measured collision efficiency values (alpha = 0.25) suggest insignificant resistance to coalescence in shear systems. Experimentally determined dispersant efficiencies (alpha = 0.35) were 10-50% lower than that predicted using a non-interacting droplet model (alpha = 0.0). Unlike other protocols in which the crude oil and dispersant are not premixed, salinity effects were not significant in this protocol. This approach allowed the effects of dispersant-oil contact efficiency eta(contact) to be separated from those of water column transport efficiency (eta(transport)) and coalescence efficiency (eta(coalescence)).  相似文献   

2.
In order to better model the fate and transport of material in a combined sewer overflow (CSO), hydrologic and geochemical measurements were made during a storm event in Flushing Bay, NY, USA. Particle size, total suspended solids concentrations, and CSO solid density are used to calculate the settling velocity of aggregates of the CSO material. Roughly half of the material that is discharged from the outfall sinks rapidly to the bottom, while the other half forms a turbid surface plume in fresher water. The dry solid density of the CSO material was 1589 kg m(-3) and the volume fraction of solid material to total aggregate volume ranged from 0.1 to 1.0. The settling velocity estimates of aggregated material in the surface plume ranged from about 0.5 to 9.0 mm s(-1) with a median settling velocity of 2.9 mm s(-1). A strong inverse relationship between the size of the aggregates and the aggregate density resulted in a fractal dimension of the aggregates of 2.3.  相似文献   

3.
The aerodynamic behaviour of volcanic aggregates   总被引：1，自引：1，他引：0  
A large proportion of solid material transported within the atmosphere during volcanic eruptions consists of particles less than 500 m in diameter. The majority of these particles become incorporated into a wide range of aggregate types, the aerodynamic behaviour of which has not been determined by either direct observation or in the laboratory. In the absence of such data, theoretical models of fallout from volcanic plumes make necessarily crude assumptions about aggregate densities and fall velocities. Larger volcanic ejecta often consists of pumice of lower than bulk density. Experimental data are presented for the fall velocities of porous aggregates and single particles, determined in systems analogous to that of ejecta falling from a volcanic plume. It is demonstrated that the fall of aggregates may be modelled in identical fashion to single particles by using a reduced aggregate density dependent on the porosity, and a size corresponding to an enclosing sphere. Particles incorporated into aggregates attain a substantially higher fall velocity than single particles. This is due to the larger physical dimensions of the aggregate, which overcomes the effect of lower aggregate density. Additionally, the internal porosity of the aggregate allows some flow of fluid through the aggregate and this results in a small increase in fall velocity. The increase in fall velocity of particles incorporated into aggregates, rather than falling individually, results in the enhanced removal of fine material from volcanic plumes.  相似文献   

4.
Within the hydrodynamic modelling community, it is common practice to apply different modelling systems for coastal waters and river systems. Whereas for coastal waters 3D finite difference or finite element grids are commonly used, river systems are generally modelled using 1D networks. Each of these systems is tailored towards specific applications. Three-dimensional coastal water models are designed to model the horizontal and vertical variability in coastal waters and are less well suited for representing the complex geometry and cross-sectional areas of river networks. On the other hand, 1D river network models are designed to accurately represent complex river network geometries and complex structures like weirs, barrages and dams. A disadvantage, however, is that they are unable to resolve complex spatial flow variability. In real life, however, coastal oceans and rivers interact. In deltaic estuaries, both tidal intrusion of seawater into the upstream river network and river discharge into open waters play a role. This is frequently approached by modelling the systems independently, with off-line coupling of the lateral boundary forcing. This implies that the river and the coastal model run sequentially, providing lateral discharge (1D) and water level (3D) forcing to each other without the possibility of direct feedback or interaction between these processes. An additional disadvantage is that due to the time aggregation usually applied to exchanged quantities, mass conservation is difficult to ensure. In this paper, we propose an approach that couples a 3D hydrodynamic modelling system for coastal waters (Delft3D) with a 1D modelling system for river hydraulics (SOBEK) online. This implies that contrary to off-line coupling, the hydrodynamic quantities are exchanged between the 1D and 3D domains during runtime to resolve the real-time exchange and interaction between the coastal waters and river network. This allows for accurate and mass conserving modelling of complex coastal waters and river network systems, whilst the advantages of both systems are maintained and used in an optimal and computationally efficient way. The coupled 1D–3D system is used to model the flows in the Pearl River Delta (Guangdong, China), which are determined by the interaction of the upstream network of the Pearl River and the open waters of the South China Sea. The highly complex upstream river network is modelled in 1D, simulating river discharges for the dry and wet monsoon periods. The 3D coastal model simulates the flow due to the external (ocean) periodic tidal forcing, the salinity distribution for both dry and wet seasons, as well as residual water levels (sea level anomalies) originating from the South China Sea. The model is calibrated and its performance extensively assessed against field measurements, resulting in a mean root mean square (RMS) error of below 6% for water levels over the entire Pearl River Delta. The model also represents both the discharge distribution over the river network and salinity transport processes with good accuracy, resolving the discharge distribution over the main branches of the river network within 5% of reported annual mean values and RMS errors for salinity in the range of 2 ppt (dry season) to 5 ppt (wet season).  相似文献   

5.
The distributions of contact areas in single, natural fractures in quartz monzonite (Stripa granite) are found to have fractal dimensions which decrease fromD=2.00 to values nearD=1.96 as stress normal to the fractures is increased from 3 MPa up to 85 MPa. The effect of stress on fluid flow is studied in the same samples. Fluid transport through a fracture depends on two properties of the fracture void space geometry. the void aperture; and the tortuosity of the flow paths, determined through the distribution of contact area. Each of these quantities change under stress and contribute to changes observed in the flow rate. A general flow law is presented which separates these different effects. The effects of tortuosity on flow are largely governed by the proximity of the flow path distribution to a percolation threshold. A fractal model of correlated continuum percolation is presented which quantitatively reproduces the flow path geometries. The fractal dimension in this model is fit to the measured fractal dimensions of the flow systems to determine how far the flow systems are above the percolation threshold.  相似文献   

6.
Protein digestibility was determined via two feeding trials in glass aquaria by the indicator (Chromium oxide) method using a mixture of shrimp powder with oil cake and wheat bran respectively (1: 1 W/W) as food. Analyses of feed were made to calculate the crude protein, carbohydrate, lipid and ash contents. Feces were analysed to determine their total nitrogen and chromium oxide. Protein digestibility was studied in relation to salinity of the medium size and weight of the fish body. The apparent digestibility of crude protein of a corresponding die has shown that 1st: Younger fish do possess a lower capability of protein digestion than fish having a medium weight and medium size; 2nd: Older fish with a high weight and large size exhibit no improvement in efficiency to digest the food protein, though their weight and size are significantly greater than those of middle weight and medium size fish; 3rd: The replacement of oil cake by wheat bran decreases the protein digestibility of shrimp powder mixture with them; 4th: A salinity (NaCl) of the aquatic medium at or above 3 g/l depletes the protein digestibility when fish of the same size were experimented with; but a salinity up to 2 g/l does not result in a significant decrease in the protein digestion rate.  相似文献   

7.
结构非均匀性理论模型的关联维描述   总被引：1，自引：0，他引：1  
李锰  杨峰 《内陆地震》2010,24(3):193-198
利用二维contor三分"非空"集合生成方法构建了非均匀结构理论模型。通过不断改变分形元三段访问概率及其空间构型,得到了样本值强度及其空间分布各不相同的24种样本,并采用推广G-P法分别求解了关联维。研究结果表明,利用关联维不仅可以表征结构的匀质程度,同时也可以描述其几何分布的非均匀程度,分维值越小反映了结构强度及其空间分布的不均匀性增大的物理本质。作为一种简化、有效刻画几何结构非均匀性的指标,关联维是一种较为合适的选择。  相似文献   

8.
A methodology for rock classification is presented that considers lithology and reservoir parameters on the basis of a combined fractal analysis of well logs and mercury porosimetry results with nuclear magnetic resonance outcomes. A sandy‐shaly thinly‐bedded Miocene gas bearing formation in the Carpathian Foredeep is investigated. Fractal correlation dimensions D2 calculated for standard logs are used to distinguish sandstone as the most homogeneous lithological group with the highest porosity. The fractal analysis also confirmed observations of gas accumulations in sandstone, shaly sandstone and sandy claystone as rocks of high porosity. The results of two laboratory methods are combined to improve reservoir properties assessment and evaluate movable media in pore space; this technique was based on the similarity of mercury porosimetry results plotted as cumulative intrusion volume versus pressure or pore diameter and also the curves of cumulative porosity and transverse relaxation time distributions using nuclear magnetic resonance. Close values of porosity from logs, recorded in situ and in laboratory measurements, provide the link between fractal analysis and porosimetry and nuclear magnetic resonance measurements.  相似文献   

9.
Using synchronous cultures of the unicellular green alga Chlamydomonas reinhardti, the toxicities of mixtures of Ekofisk crude oil and oil dispersants were measured. Sixteen so-called concentrates and 10 solvent-based dispersants were tested. The dispersing effectiveness of these compounds with respect to the Ekofisk crude oil was also measured. The concentrates were tested undiluted as well as diluted using algal growth medium (2‰ salinity) and artificial sea water (33‰ salinity) as dispersing liquid. The solvent-based compounds were tested in algal medium. For all compounds we found significant correlations between their toxicity and their effectiveness in dispersing the Ekofisk oil, such that the more effective the compound, the more toxic it was.  相似文献   

10.
在模糊集理论与分形理论的基础上,引进了模糊分维的概念;给出了模湖容量维D0与模糊关联维D2的定义与确定方法;讨论了模糊分维与常用的分维（清晰分维）的关系.给出了模糊分维在地震研究中的应用结果: 1.根据模糊容量维D0随时间的上升趋势变化,可以划分出大地震活动的高潮期;由模糊容量维D0与模糊关联维D2随时间变化的曲线,可以分析识别大地震前的中长期前兆异常. 2.根据模糊容量维D0随空间和时间的变化,可以划分出未来大震所在的地区,并可发现大震前数年D0呈现增大或减小的趋势. 3.根据前兆数据的模糊时间分维D0随时间的变化,可以发现大地震的短期前兆异常.  相似文献   

11.
Fluvial suspended sediment typically consists of a variety of complex, composite particles referred to as flocs. Floc characteristics are determined by factors such as the source, size and geochemical properties of the primary particles, chemical and biological coagulation processes in the water column and shear stress and turbulence levels in the stream. Studies of floc morphology have used two contrasting methods of sampling and analysis. In the first method, particles settle on a microscope slide and are observed from below using an inverted microscope. The second method uses filtration at no or low vacuum and particles deposited on the filter are observed with a microscope. Floc morphology can be quantified using fractal dimensions. The aims of the present study were to examine the effect of the two sampling methods on the fractal dimensions of particle populations, and to evaluate for each method how well the fractal dimensions at the various sampling sites reflect basin conditions. Suspended solids were collected in triplicate on inverted microscope slides and on 0·45 μm Millipore HA filters in two southern Ontario streams with contrasting riparian zones during a minor runoff event resulting from the melt of a freshly fallen snowpack. An image analysis system was used to determine area, longest axis and perimeter of particles. The morphology of the particle population of each sample was characterized using four fractal dimensions (D, D1, D2 and DK). Systematic differences in fractal dimensions obtained with the two methods were observed. For the settling method, outlines of larger particles were frequently blurred because of the distance between the focal plane (the top of the inverted microscope slides) and the plane of the particle outline. In this method, the blurring of large particles can cause an increase in the projected area and length of the particle. The effect on the particle perimeter is unpredictable because it depends on the amount of detail lost through blurring and its effect on the apparent increase in particle size. Because of blurring, D and D1 tend to be systematically lower for the settling method, whereas the net effect on D2 is unpredictable. Particle size distributions derived from settling are typically coarser because small, low density particles may remain in the water column and all particles may not deposit on the slides. This loss of fines results in systematically lower DK values for the settling method compared with the filtration method. Fractal dimensions and particle size distributions obtained with the filtration method were sensitive to and clearly indicated differences between drainage basins and between sites within each basin. These differences were explained by basin characteristics and conditions. Fractal dimensions and particle size distributions obtained with the settling method were less sensitive to drainage basin characteristics and conditions, which limits their usefulness as process indicators. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

12.
台湾地区地震的空间关联维特征与构造环境研究   总被引：2，自引：0，他引：2       下载免费PDF全文
采用关联维方法对台湾地区地震活动的空间特征进行了研究。先利用 10 0a来台湾的地震目录计算各个地震区、带的关联维数 ,将地震空间分布的分形特征定量表达出来 ,然后综合分析地震空间分布的关联维数和孕震构造环境之间的关系 ,得出了以下结论 :1)台湾东、西部地震区由于地震属于不同的大地构造单元 ,因此关联维数有较大的差异 ;2 )在各地震区内部的各个地震带由于板块构造、地壳结构、活断层分布上的差异 ,而具有与其构造特征相对应的关联维数 ;3)各地震带内部的各个不同的部位又由于不同的构造应力场 ,而导致地震分布上出现不同的丛集性 ,表现为不同的关联维数。这些结论充分说明通过关联维分析所得到的地震活动的空间图像与地震活动所代表的不同地质构造背景有着良好的对应关系  相似文献   

13.
本文利用分维几何学方法对祁连山和龙首山断层进行了定量性研究。结果表明,分维数可以表征断层的不均匀性、不规则性和复杂性等,但是,与地震活动无明显的相关关系。分维数的大小与断层分枝数、断层迹线的展布面积有一定关系。  相似文献   

14.
The Río de la Plata waters form a low salinity tongue that affects the circulation, stratification and the distributions of nutrients and biological species over a wide extent of the adjacent continental shelf. The plume of coastal waters presents a seasonal meridional displacement reaching lower latitudes (28°S) during austral winter and 32°S during summer. Historical data suggests that the wind causes the alongshore shift, with southwesterly (SW) winds forcing the plume to lower latitudes in winter while summer dominant northeasterly (NE) winds force its southward retreat. To establish the connection between wind and outflow variations on the distribution of the coastal waters, we conducted two quasi-synoptic surveys in the region of Plata influence on the continental shelf and slope of southeastern South America, between Mar del Plata, Argentina and the northern coast of Santa Catarina, Brazil. We observed that: (A) SW winds dominating in winter force the northward spreading of the plume to low latitudes even during low river discharge periods; (B) NE winds displace the plume southward and spread the low salinity waters offshore over the entire width of the continental shelf east of the Plata estuary. The southward retreat of the plume in summer leads to a volume decrease of low salinity waters over the shelf. This volume is compensated by an increase of Tropical waters, which dominate the northern shelf. The subsurface transition between Subantarctic and Subtropical Shelf Waters, the Subtropical Shelf Front, and the subsurface water mass distribution, however, present minor seasonal variations. Along shore winds also influence the dynamics and water mass variations along the continental shelf area. In areas under the influence of river discharge, Subtropical Shelf Waters are kept away from the coastal region. When low salinity waters retreat southward, NE winds induce a coastal upwelling system near Santa Marta Cape. In summer, solar radiation promotes the establishment of a strong thermocline that increases buoyancy and further enhances the offshore displacement of low salinity waters under the action of NE winds.  相似文献   

15.
The germination behavior of Sporobolus iocladus seeds including germination percentage, accumulated germination percentage, the average incubation period to germination and germination velocity was studied under laboratory conditions. Treatments included six salinity regimes (0, 70, 140, 210, 280 and 350 mM NaCI) and three sources of oil hydrocarbons; Light Arabian Crude, polynuclear aromatic hydrocarbons (PAHs) including diaromatic or triaromatic hydrocarbons (in crude oil equivalent concentrations, COEC). The average incubation period needed for seeds to germinate was significantly longer for seeds germinated in 350 mM NaCl (6 +/- 1.16 days) compared with the control (4 +/- 00 days). The accumulated germination percentage gradually decreased with increasing salinity (control: 90 +/- 10, while 350 mM NaCl: 63 +/- 8.8). Oil hydrocarbons significantly affected all germination parameters of S. iocladus seeds regardless of salinity levels. COEC of di- and triaromatic hydrocarbons suppressed seed germination more than crude oil. Seeds exposed to diaromatic hydrocarbons failed to germinate. Hydrocarbon's salinity interaction significantly reduced the number of germinated S. iocladus seeds. It is concluded that hydrocarbon pollutants adversely affect S. iocladus through reducing germination. It is also suggested that the toxic effect of hydrocarbons on seeds is not solely mediated through their interaction with salinity. The ecological implications of these findings are discussed in relation to other studies on the post-spill recovery of halophytes.  相似文献   

16.
Petroleum mainly comprises carbon and hydrogen elements. The stable carbon isotopic analysis for whole oil was undertaken as early as the 1930s. After decades, the stable carbon isotopic analytical methods have been developed from analysis for whole oil and oil fractions (e.g., saturated, aromatic and polar frac-tions) into compound-specific isotopic analysis with the emergence of the newly developed GC-C-IRMS analytical technique. Especially, by using com-pound-specific isotopic analytical…  相似文献   

17.
Two methods for sampling aggregates in the soil surface under simulated rain were compared using two soil types. Results showed that aggregate size distributions obtained by spatula sampling were not significantly different from those obtained using rings buried in the soil surface, provided both were sampled to the same depth. The effect of transporting samples over a distance of 60 km was non-significant when samples were placed in bottles half-filled with rainwater and transported in an upright position. The per cent aggregates > 0.125 mm was found to be the most suitable index of aggregate stability for both soils.  相似文献   

18.
Influences of Aquifer Properties on Flow Dimensions in Dolomites   总被引：1，自引：0，他引：1  
The paper focuses on analyses and correlations of flow dimensions in different dolomite aquifers in Slovenia. Flow dimensions are obtained through the reinterpretation of 72 pumping tests with the generalized radial flow model, based on the fractional flow dimension. The average value of flow dimensions is 2.16 for all dolomites. A study of flow dimensions in individual aquifers categorized according to their lithological properties shows that higher dimensions occur in massive late-diagenetic Cordevolian and Anisian dolomites compared with bedded Main, Bača, and especially Lower Triassic dolomites, which contain a greater proportion of noncarbonate minerals. Partially penetrating wells have higher flow dimensions than fully penetrating wells. Flow dimensions are poorly correlated with hydraulic conductivities of fractures. When comparing the quantities of major dissolved minerals, obtained by hydrogeochemical inverse modeling, with the values of flow dimensions, the Cordevolian and Anisian dolomites are found to exhibit the highest values of both dissolved dolomite and flow dimensions, indicating that greater dissolution occurs at higher flow dimensions. For other aquifers, data points are more scattered and the correlation is mostly poor. When compared with three-dimensional fractal dimensions of fracture networks, there is no correlation with flow dimensions. However, almost all the values of flow dimensions are lower than the corresponding fractal dimensions in dolomites (average D = 2.77), possibly indicating the channeling of flow within the available space of the fracture networks, consequently reducing the flow dimensions.  相似文献   

19.
Meteoric smoke forms in the mesosphere from the recondensation of the metallic species and silica produced by meteoric ablation. A photochemical flow reactor was used to generate meteoric smoke mimics using appropriate photolytic precursors of Fe and Si atoms in an excess of oxidant. The following systems were studied: (i) Fe+O3/O2, (ii) Fe+O3/O2+H2O, (iii) Fe+Si/SiO+O3/O2 and (iv) Si/SiO+O3/O2. The resulting nano-particles were captured for imaging by transmission electron microscopy, combined with elemental analysis using X-ray (EDX) and electron energy loss (EELS) techniques. These systems generated particle compositions consistent with: (i) Fe2O3 (hematite), (ii) FeOOH (goethite), (iii) Fe2SiO4 (fayalite) and (iv) SiO2 (silica). Electron diffraction revealed that the Fe-containing particles were entirely amorphous, while the SiO2 particles displayed some degree of crystallinity. The Fe-containing particles formed fractal aggregates with chain-like morphologies, whereas the SiO2 particles were predominantly spherical and compact in appearance. The optical extinction spectra of the Fe-containing particles were measured from 300 nm<λ<650 nm. Excellent agreement was found with the extinction calculated from Mie theory using the refractive indices for the bulk compounds, and assuming that the fractal aggregates are composed of poly-disperse distributions of constituent particles with radii ranging from 5 to 100 nm. These sizes were confirmed from measurements of the particle size distributions and microscopic imaging. Finally, the particle growth kinetics of the Fe-containing systems exhibit unexpectedly rapid agglomerative coagulation. This was modelled by assuming an initial period of coalescent particle growth resulting from diffusional (Brownian) coagulation to form primary particles; further growth of these particles is then dominated by long-range magnetic dipole–dipole interactions, leading to the fractal aggregates observed. The atmospheric implications of this work are then discussed.  相似文献   

20.
Pore structure heterogeneity is a critical parameter controlling mechanical, electrical and flow transport behaviour of rock. Multi-fractal analysis method was used for a heterogeneity comparison of three-dimensional rock samples with different lithology. Six real digital samples, containing three sandstones and three carbonates, were used. Based on the mercury injection capillary pressure test on these samples, we found that the carbonate samples are more heterogeneous than sandstones, but primary results of multi-fractal behaviours for all samples were similar. We show that if multi-fractal is used to evaluate and compare heterogeneity of different samples, one needs to follow some considerations such as (1) all samples must have the same size in pixel, (2) samples volume must be bigger than representative volume element, (3) multi-fractal dimensions should be firstly normalized to a determined porosity value and (4) multi-fractal results should be interpreted based on resolution of the imaging tool (effects of fine scale sub-resolution pores are missed). Results revealed that using normalized fractal dimensions, the real samples were divided to less and high heterogeneous groups. Moreover, the study of scale effect also showed that porous structures of these samples are scale invariant in a wide range of scales (from one to eight times bigger).  相似文献   

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