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Implementation of aquifer storage recovery (ASR) for water resource management in Florida is impeded by arsenic mobilization. Arsenic, released by pyrite oxidation during the recharge phase, sometimes results in groundwater concentrations that exceed the 10 µg/L criterion defined in the Safe Drinking Water Act. ASR was proposed as a major storage component for the Comprehensive Everglades Restoration Plan (CERP), in which excess surface water is stored during the wet season, and then distributed during the dry season for ecosystem restoration. To evaluate ASR system performance for CERP goals, three cycle tests were conducted, with extensive water‐quality monitoring in the Upper Floridan Aquifer (UFA) at the Kissimmee River ASR (KRASR) pilot system. During each cycle test, redox evolution from sub‐oxic to sulfate‐reducing conditions occurs in the UFA storage zone, as indicated by decreasing Fe2+/H2S mass ratios. Arsenic, released by pyrite oxidation during recharge, is sequestered during storage and recovery by co‐precipitation with iron sulfide. Mineral saturation indices indicate that amorphous iron oxide (a sorption surface for arsenic) is stable only during oxic and sub‐oxic conditions of the recharge phase, but iron sulfide (which co‐precipitates arsenic) is stable during the sulfate‐reducing conditions of the storage and recovery phases. Resultant arsenic concentrations in recovered water are below the 10 µg/L regulatory criterion during cycle tests 2 and 3. The arsenic sequestration process is appropriate for other ASR systems that recharge treated surface water into a sulfate‐reducing aquifer.  相似文献   

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Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis (18O, 2H, 3H, 14C, 13C, 34S, 18O-SO4, 87Sr, 37Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with δ18O values (−9.6 to −12.4) similar to local, modern precipitation (−7.4 to −10), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted δ18O values (−16 to −18) relative to local, modern precipitation, and 14C ages 32,000 to more than 47,000 years before present. Sulfate, δ18O, δ2H, δ34S, and δ18O-SO4 concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between 14C and Darcy age estimates indicate that 14C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.  相似文献   

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Aquifer storage and recovery (ASR) can provide a means of storing water for irrigation in agricultural areas where water availability is limited. A concern, however, is that the injected water may lead to a degradation of groundwater quality. In many agricultural areas, nitrate is a limiting factor. In the Umatilla Basin in north central Oregon, shallow alluvial groundwater with elevated nitrate‐nitrogen of <3 mg/L to >9 mg/L is injected into the Columbia River Basalt Group (CRBG), a transmissive confined aquifer(s) with low natural recharge rates. Once recovery of the injected water begins, however, NO3‐N in the recovered water decreases quickly to <3 mg/L (Eaton et al. 2009), suggesting that NO3‐N may not persist within the CRBG during ASR storage. In contrast to NO3‐N, other constituents in the recovered water show little variation, inconsistent with migration or simple mixing as an explanation of the NO3‐N decrease. Nitrogen isotopic ratios (δ15N) increase markedly, ranging from +3.5 to > +50, and correlate inversely with NO3‐N concentrations. This variation occurs in <3 weeks and recovery of <10% of the originally injected volume. TOC is low in the basalt aquifer, averaging <1.5 mg/L, but high in the injected source water, averaging >3.0 mg/L. Similar to nitrate concentrations, TOC drops in the recovered water, consistent with this component contributing to the denitrification of nitrate during storage.  相似文献   

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Starting Conditions for Aquifer Simulations   总被引:1,自引:0,他引:1  
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Trace-Organics Biodegradation in Aquifer Recharge   总被引:1,自引:0,他引:1  
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S. Puri 《Ground water》1984,22(5):538-543
Flow simulations supplemented resource evaluation studies of the Lower Greensand aquifer. The annual recharge has hitherto been considered to be the resource available for development although a large confined storage exists. Pumping is principally in urban areas but recent monitoring suggests that the aquifer may have suffered excessive drawdowns. Therefore, simulation studies were carried out to refine the annual recharge estimate, to define the past effects of pumping and to obtain an indication of future trends. Catchment water balance indicates average annual recharge of 28 × 106 m3. One-dimensional (ID) ground-water flow simulation suggests that regional abstractions affect outcrop-water levels. The study showed that the aquifer reached a new equilibrium with the current pumping regime. An improved insight to the aquifer has permitted the formulation of strategies for future resource development.  相似文献   

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Geoelectric Soundings for Predicting Aquifer Properties   总被引:2,自引:0,他引:2  
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The Bayesian inverse approach proposed by Woodbury and Ulrych (2000) is extended to estimate the transmissivity fields of highly heterogeneous aquifers for steady state ground water flow. Boundary conditions are Dirichlet and Neumann type, and sink and source terms are included. A first-order approximation of Taylor's series for the exponential terms introduced by sinks and sources or the Neumann condition in the governing equation is adopted. Such a treatment leads to a linear finite element formulation between hydraulic head and the logarithm of the transmissivity-denoted as ln(T)-perturbations. An updating procedure similar to that of Woodbury and Ulrych (2000) can be performed. This new algorithm is examined against a generic example. It is found that the linearized solution approximates the true solution with an R2 coefficient = 0.96 for an ln(T) variance of 9 for the test case. The addition of hydraulic head data is shown to improve the ln(T) estimates, in comparison to simply interpolating the sparse ln(T) data alone. The new Bayesian code is also employed to calibrate a high-resolution finite difference MODFLOW model of the Edwards Aquifer in southwest Texas. The posterior ln(T) field from this application yields better head fit when compared to the prior ln(T) field determined from upscaling and cokriging. We believe that traditional MODFLOW grids could be imported into the new Bayes code fairly seamlessly and thereby enhance existing calibration of many aquifers.  相似文献   

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This study demonstrates the utilization of a multi-objective hybrid global/local optimization algorithm for solving managed aquifer recharge (MAR) design problems, in which the decision variables included spatial arrangement of water injection and abstraction wells and time-variant rates of pumping and injection. The objective of the optimization was to maximize the efficiency of the MAR scheme, which includes both quantitative and qualitative aspects. The case study used to demonstrate the capabilities of the proposed approach is based on a published report on designing a real MAR site with defined aquifer properties, chemical groundwater characteristics as well as quality and volumes of injected water. The demonstration problems include steady state and transient scenarios. The steady state scenario demonstrates optimization of spatial arrangement of multiple injection and recovery wells, whereas the transient scenario was developed with the purpose of finding optimal regimes of water injection and recovery at a single location. Both problems were defined as multi-objective problems. The scenarios were simulated by applying coupled numerical groundwater flow and solute transport models: MODFLOW-2005 and MT3D-USGS. The applied optimization method was a combination of global (the non-dominated sorting genetic algorithm [NSGA-2]) and local (the Nelder-Mead downhill simplex search algorithms). The analysis of the resulting Pareto optimal solutions led to the discovery of valuable patterns and dependencies between the decision variables, model properties, and problem objectives. Additionally, the performance of the traditional global and the hybrid optimization schemes were compared.  相似文献   

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