共查询到19条相似文献，搜索用时 203 毫秒
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采用积分安培-离子色谱法同时测定地下水中的溴离子和碘离子,该方法的相关性好（ r＞0．999）,精密度高（RSD％＜4．0）,样品加标回收率为90～110％,溴离子检出限为5．6μg/L ,碘离子检出限为2．1μg/L。本法简便、快速、准确且选择性好,可用于分析地下水中的溴离子和碘离子。 相似文献
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四极质谱测定流体包裹体中的气相成分 总被引：19，自引：0，他引：19
采用热爆法提取流体包裹体样品中的气体成分，以高灵敏的ＱＭＳ仪器测定流体包裹体样品中包括稀有等多种气体成分，该方法灵敏度和精度高、各组分的相对标准偏差（ＲＳＤ，ｎ＝６）在３％以下，方法已用于流体包裹体样品分析，分析结果符合地质研究的要求． 相似文献
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太湖、洞庭湖野生青虾肌肉中有机氯农药的气相色谱-质谱法测定 总被引：4，自引：0，他引：4
使用气相色谱质谱技术测定了青虾肌肉组织中的8种有机氯农药.包括六氯苯、氯丹、滴滴涕(ΣDDTs)、艾氏剂、狄氏剂、异狄氏剂、七氯和灭蚁灵,对太湖和洞庭湖15个点位29组野士青虾样品的测定结果显示,青虾肌肉组织内残留的有机氯农药主要是六氯苯和滴滴涕,六氯苯含量为nd-13.2μg/kg(湿重),滴滴涕含量为0.790-5.82μg/kg(湿重),洞庭湖青虾肌肉中有机氯农药的含量略高于太湖青虾,两湖青虾肌肉残留有机氯农药在枯水期时的含量多数大于丰水期时的含量. 相似文献
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湖北太白湖400多年来沉积硅藻记录及湖水总磷的定量重建 总被引：2，自引：3，他引：2
依据沉积物钻孔的高分辨率硅藻研究,利用长江中下游现代湖泊硅藻与总磷转换函数结果,定量重建了太白湖400余年来占湖水总磷浓度的变化．结果表明,约1630 AD前和1 800-1924 AD期间,湖水总磷浓度较低,在50-68μg／L之间;1630-1800 AD,总磷浓度偏高,总体上在50-160μg／L之间变化,变幅较大．1800-1924AD,总磷浓度明显下降为谷值段,且变化相对稳定(50μg／L左右);1924-1953AD,总磷浓度仍较低,但有增加趋势(50-63μg／L);20世纪50年代开始,总磷浓度出现快速增加;至1970年后,总磷浓度超过120μg／L左右.利用样品相似对比的方法发现约80％的样品具有较好的重建效果．古湖水总磷浓度值的变化揭示了该湖两次明显的富营养化过程,初步探讨了其驱动机制.根据重建结果提出:太白湖自然营养本底总磷值约为50μg／L左右,可作为该湖治理时的参考目标． 相似文献
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浅水湖泊沉积物脱氢酶活性的测定及其生态学意义 总被引：1，自引：0，他引：1
以武汉市浅水湖泊(月湖)为实验对象确定了沉积物脱氢酶活性(DHA)测定的最佳条件:以经甲醛灭菌的沉积物为对照,以氯化三苯基四氮唑为电子受体(0.4%),沉积物用量为0.5g,pH值为7.5,培养时间为3h.据上二述条件测定的DHA比未优化条件下的相应值高3-5倍,且表现出与沉积物有机质含量更为显著的正相关关系.武汉东湖3个子湖共23个采样点沉积物样品的测试结果进一步证实了上述方法的可行性,同时初步揭示了湖泊沉积物脱氢酶反映微生物活性与有机质状态的生态学意义. 相似文献
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水生高等植物马来眼子菜和金鱼藻的初级生产率(黑白瓶法) 总被引：2，自引：0，他引：2
用黑白瓶测氧法测定了水生高等植物马来眼子菜(竹叶眼子菜,Potamogeton malaianus)和金鱼藻(Ceratophyllum demersum)的初级生产。按单位鲜重或干重表示的毛生产率,马来眼子菜为0.43—1.50mg O_2/g FWt.h(3.76—13.03mg O_2/g DWt.h);金鱼藻为0.44—0.45mg O_2/g FWt.h(5.12—5.27mg O_2/g DWt.h)。净生产率则分别为0.15—1.44mg O_2/g FWt.h(1.31—12.51mg O_2/g DWt.h)和0.08—0.25mg O_2/g FWt.h(0.93—2.95mg O_2/g DWt.h)。讨论了测定时的样品重量和光照强度对生产率的影响。 相似文献
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宜兴太湖防护林对农业面源污染的减源增汇作用浅析 总被引：1，自引：1，他引：0
为探讨太湖沿岸防护林宜兴段对农业面源污染物的控制效果,通过在宜兴市太湖防护林采集土壤样品,测定其中营养元素含量,结合周边农业生产施肥概况,初步分析了该区域防护林对农业面源污染的减源—增汇效应.结果表明,2009年10月份防护林地上部分固定的C、N、P和K分别为2439.48、18.34、2.48和13.42 g/m2;2011年5月份固定量分别为3114.12、23.42、3.16和17.13 g/m2;而2013年8月份固定量分别为4722.46、35.53、4.81和25.99 g/m2.可见C、N、P和K的固定量是逐年增加的,相比2009年,分别增加了93.6%、93.7%、94.0%和93.7%.结果说明宜兴段太湖沿岸防护林对农业面源污染的控制效果较显著,有助于太湖水污染的治理. 相似文献
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对采自西藏金沙江缝合带的花岗岩样品进行了岩石学、岩石化学、稀土和微量元素分析以及年龄测定等。研究结果表明 ,这些花岗岩样品属于前人所划分的念青唐古拉岩带中的安多和班戈岩体 ,为花岗二长岩 ,属于钙系 -钙碱性系列。其中属于安多岩体的样品与前人在该地区所描述的稍有不同 ,主要表现在更为酸性和富钠 ;其稀土配分的右倾斜率较小 ,所测得的K -Ar年龄 (15 7Ma)也较前人的结果年轻。属于班戈岩体的其他样品均与前人的研究结果基本一致 ,所获K -Ar年龄数据(12 1Ma)也在前人测定的结果范围内。此外 ,对其中 1件样品的黑云母和钾长石的4 0 Ar/ 39Ar分段加热测定 ,获得了 (12 9± 1 9)Ma和 (131± 1 9)Ma的坪年龄 ,并揭示出岩体冷却速度较快、侵位较浅的特征 相似文献
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The coprecipitation method is widely used for the preconcentration of trace metal ions prior to their determination by flame atomic absorption spectrometry (FAAS). A simple and sensitive method based on coprecipitation of Fe(III) and Ni(II) ions with Cu(II)‐4‐(2‐pyridylazo)‐resorcinol was developed. The analytical parameters including pH, amount of copper (II), amount of reagent, sample volume, etc., were examined. It was found that the metal ions studied were quantitatively coprecipitated in the pH range of 5.0–6.5. The detection limits (DL) (n = 10, 3s/b) were found to be 0.68 µg L?1 for Fe(III) and 0.43 µg L?1 for Ni(II) and the relative standard deviations (RSD) were ≤4.0%. The proposed method was validated by the analysis of three certified reference materials (TMDA 54.4 fortified lake water, SRM 1568a rice flour, and GBW07605 tea) and recovery tests. The method was successfully applied to sea water, lake water, and various food samples. 相似文献
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As basis for the development of a sensitive analytical method for the determination of the insecticide alanycarb, a study of the differential pulse polarographic (DPP) reduction of alanycarb on a dropping mercury electrode (DME) was performed. The pesticide was found to give a single DP peak over the pH range 1.0 to 6.0 and the pH dependency of the peak potential showed a linear segment with a slope of 65.2 mV (at 20°C). For the analytical DPP method running at pH 6.0 (peak at –503.4 mV), the relationship between the peak current and alanycarb concentration was linear in the range of 1.10 to 9.76 μg mL–1 with a detection limit of 0.33 μg mL–1. The proposed method was applied for the determination of alanycarb in spiked dam water and orange juice samples. The recoveries calculated for both types of dam water and orange juice samples spiked with 12.0 μg mL–1 alanycarb were 96.3 and 99.0% with relative standard deviations of 5.2 and 1.3%, respectively. The sufficiently good recoveries and low relative standard deviations for the data reflect the high accuracy and precision of the proposed differential pulse polarographic method. The effects of diverse metal ions and other commonly used pesticides on the determination of alanycarb were also investigated. 相似文献
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The Maqarin site in Jordan has been investigated for three decades as a natural analogue for the long term changes of materials in contact with hyper-alkaline solutions. Similar processes are expected in radioactive waste disposal sites, where cement based materials are in contact with natural rocks or other e.g. clay based materials. In this context, a numerical reactive transport model was used to study local geochemical alterations and induced porosity changes for the Maqarin marl rock in contact with the hyper-alkaline solution. The geochemical setup for the rock mineralogy and the pore water was calibrated to match measurements from the Maqarin site. The setup includes several clay and zeolite minerals, considers cation exchange processes, and a state-of-the-art model for cement phases. Similar to earlier calculations by Steefel and Lichtner (1998) who used a much simpler geochemical model, the pore clogging occurred after several hundred years at a distance of 5–10 mm from the contact to the hyper-alkaline solution. In our calculations, this was caused by a massive precipitation of ettringite and C–S–H minerals. We performed a sensitivity study by varying the intrinsic diffusion coefficient, the Archie’s law exponential factor, and the mineral surface area available for dissolution and precipitation. We found that the dissolution of clay minerals controls the availability of Al, which is needed for ettringite and C–S–H phase precipitation. Thus, the amount and kinetically controlled dissolution of clay minerals controls the spatial and temporal evolution of porosity changes. The simulations reveal that neither cation exchange processes nor the formation of zeolite minerals strongly influence the geochemical evolution of the system. 相似文献
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An on‐line solid phase extraction method for the preconcentration and determination of Cu(II) by flame atomic absorption spectrometry has been described. The procedure is based on the retention of Cu(II) ions at pH 6.0 on a minicolumn packed with Amberlite XAD‐1180 resin impregnated with chrome azurol S. After preconcentration, Cu(II) ions adsorbed on the impregnated resin were eluted by 1 mol L?1 HNO3 solution. Several parameters, such as pH, type of eluent, flow rates of sample and eluent solutions, amount of resin were evaluated. At optimized conditions, for 3.5 min of preconcentration time, the system achieved a detection limit of 1.0 µg L?1, and a relative standard deviation of 1.2% at 0.2 µg mL?1 copper. An enrichment factor of 56‐fold was obtained with respect to the copper determination. The proposed method was successfully validated by the analysis of standard reference material (TMDA 54.4 lake water) and recovery studies. The method was applied to the preconcentration of Cu(II) in natural water samples. 相似文献
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Cyanuric acid is a suspected gastrointestinal or liver toxicant in humans. Therefore, determination of trace cyanuric acid is very important, in this work a novel, sensitive, and reliable method was developed using differential pulse polarography. Optimum conditions for analytical determination were found to be at a pH of 9.5, Britton–Robinson at a reduction potential of ?105 mV. Experimental results indicate an excellent linear correlation between the peak current and the concentration in the range of cyanuric acid from 0.5 to 27.0 µM (0.06–3.5 µg mL?1) with a correlation coefficient of 0.997. The limit of detection and limit of quantification were obtained as 0.15 and 0.5 µM (0.02–0.06 µg mL?1), respectively. The proposed method was successfully applied to the determination of cyanuric acid in pool water and in spiked milk. Cyanuric acid level in swimming pool water was found as 2.54 ± 0.47 µg mL?1 (19.7 ± 2.29 µM) in swimming pool water for N = 4 and 95% confidence interval. The recoveries were found to be sufficient. Also, the standard deviation of the data was low which shows high accuracy and precision of proposed differential pulse polarographic method. The influences of some other commonly found inorganic salts on the determination of cyanuric acid were also examined. Some interfering species were eliminated using complexing agents, e.g., EDTA. 相似文献
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为研究评估方法对量化半刚接钢框架内填暗竖缝RC墙结构(简称PSRCW)超强性能的影响,严格按我国现行抗震规范设计了一栋位于设防烈度为8度区的10层PSRCW标准算例。考虑钢材、钢筋、混凝土强度等材料力学性能的随机性,基于Latin超立方抽样方法将其扩展为40个PSRCW样本算例,采用广义乘方及均匀水平荷载分布模式的循环Pushover方法确定了40个PSRCW样本算例的滞回及骨架曲线,基于概率方法按置信水平为95%的单侧置信下限值确定PSRCW结构的超强系数。随后,选取ATC63规范建议的2组22条近场及远场地震波,对10层PSRCW标准算例进行增量动力时程分析(简称IDA),基于概率法确定了10层PSRCW标准算例的超强系数。分析结果表明:评估方法对量化PSRCW结构超强系数影响显著,考虑材料随机性按广义乘方分布循环Pushover方法确定10层PSRCW标准算例的超强系数为1.3,按均匀分布循环Pushover方法确定的10层PSRCW标准算例的超强系数为1.73。考虑近场及远场地震波随机性按IDA方法确定10层PSRCW标准算例的超强系数分别为2.45和2.42。 相似文献
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This work describes the modification of silica gel with dimethylglyoxime, in order to prepare an effective sorbent for the preconcentration and determination of copper. The sorption capacity of dimethylglyoxime‐modified silica‐gel (DMGMS) was 71.37 mg g–1 and the optimum pH for the quantitative recovery of copper was found to be 5.0. The optimum flow rate, sorbent amount, and sample volume were 1 mL min–1, 300 mg, and 50 mL, respectively. 10 mL of 0.1 mol L–1 HCl was the most suitable eluent. The detection limit of copper was 6.0 ng mL–1. The recommended method, for the determination of copper, is simple and reliable, without any notable matrix effect and can be successfully applied to environmental water samples. Copper recovery in the range from 99–100% was obtained from seawater and thermal spring water using this method. The method was applied to standard reference materials, NIST‐1515 (apple leaves) and NIST‐1643e (simulated fresh water), for the determination of copper and the results were in good agreement with certified values. 相似文献
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Determination of a Group Parameter for Organic Halogen Compounds in High Salt-laden Water Samples Using XAD-4 Resin Concerning the often discussed ‘chloride error’ in AOX determination, a method is described with allows the determination of the group parameter organic halogen compounds (OX) for chloride concentrations more than 1 g/L. In opposite to the standard method DIN 38409 part 14, no chloride influence up to a concentration of 10 g/L in real water samples occurs. The basis of the method is the adsorption of the organic compounds from the water sample on XAD-4 resin, a nonpolar copolymer of styrene and divinylbenzene. The organic compounds are concentrated on the XAD-4 resin conditioned with methanol. After the enrichment step, the adsorption columns are treated with sodium nitrate solution. Model experiments with p-chlorophenol and chloride concentrations of 50 g/L showed the effectiveness of this method. The loaded and washed adsorption columns are first eluated with acetone and then with ethyl acetate. Quantification of the OX compounds in the eluates is carried out by microcoulometric detection after combustion in a furnace equipped with a special injector for eluates. For optimal work, the instrument was modified and improved. The presented method was developed on model samples and tested on different real samples. 相似文献