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1.
贵州遵义地区黄家湾矿是黑色页岩型镍钼多金属元素矿床。镜下观察及电子探针分析首次发现了矿石中红藻囊果及其与各金属硫化物之间密切的共生关系,为生物参与成矿作用提供了证据。结合前人研究结果,认为镍、钼等金属元素的来源及富集可能与藻类生物作用有关。  相似文献   

2.
报道了塔里木盆地北部下寒武统底部黑色页岩的Re-Os和Nd同位素地球化学特征, 并通过其Re-Os和Nd同位素特征探讨了该黑色页岩的物源性质. 塔里木盆地北部下寒武统底部黑色页岩的Re/Os比值为7.18; 187Re/188Os为5.6438; 187Os/188Os为1.9616. 这些特征反映了该黑色页岩具有壳源性质. 其εNdεNd(540 Ma)值为-7.32; Nd模式年龄TDM集中在1.535 Ga. 黑色页岩中Nd同位素的这些特征与盆地基底岩石的Nd同位素参数十分吻合. 综合Re-Os和Nd同位素特征, 说明塔里木盆地北部下寒武统底部的这套黑色页岩的物源中应包括以盆地基底为主要组成的大陆地壳. 同时, 通过与扬子地台下寒武统底部黑色页岩Re-Os同位素的对比, 发现两者之间存在着较大的不同, 可能反映了两者在沉积背景上的差异. 这为正确分析塔里木地台与扬子地台的成因关系提供了Re-Os同位素方面的信息.  相似文献   

3.
首次对塔里木盆地北部下寒武统底部黑色页岩的微量元素、稀土元素和铂族元素地球化学进行了系统分析, 其基本特征是与深部流体有关的微量元素明显富集, Th/U和Th/Sc等元素比值降低; 球粒陨石标准化后的稀土元素分布模式中轻稀土富集程度降低, Eu负异常减小, Ce具有明显的负异常; 铂族和Au元素含量增高. 这些特点表明黑色页岩沉积时, 盆内有富铁镁质的深部物源的存在. 这种深部物源的存在通常指示岩石圈拉张的构造背景. 微量元素、铂族元素和稀土元素特征在剖面中的变化规律表明, 该黑色页岩沉积的早期, 来自地球深部的物源不断增加, 至4号样品达到高峰, 此后逐渐降低. 这种现象可能指示本区早寒武世早期岩石圈具有幕式拉张作用的特点.  相似文献   

4.
扬子地台南缘早寒武世黑色岩系中形态硫特征及成因意义   总被引:12,自引:1,他引:11  
对扬子地台南缘早寒武世黑色岩系中黄铁矿硫和有机硫进行了分析和测试. 结果显示, 其含量和同位素组成在横向和纵向均有明显的变化规律. 靠近陆源区的西部剖面, 样品黄铁矿含量高、有机质含硫少, 剖面从下向上, 前者表现为由高变低; 后者由低变高. 此剖面的硫同位素组成相对较轻, 并且从下向上黄铁矿硫和有机硫均显示不断变重的趋势. 远离陆源区的东部剖面中, 形态硫的富集规律与此相反, 即黄铁矿的数量减少、有机质富集了更多的硫, 尽管两者在剖面纵向上的变化与西部剖面的相似. 东部剖面的形态硫同位素组成明显富集重硫, 并且在剖面中由下向上逐渐变轻. 结合样品的铁含量、有机碳含量数据及岩石学特点, 推断控制黑色岩系中形态硫具如此变化规律的因素包括海平面变化、金属离子(主要是铁离子)供给、大地构造背景及海洋化学特点.  相似文献   

5.
上扬子区早古生代全岩Ce异常与海平面长缓变化   总被引:15,自引:2,他引:13  
65个全岩稀土样品采自湖北省宜昌地区下寒武统至下志留统的经典剖面 .样品测试由单通道扫描等离子光谱仪 (ICP AES)完成 .REE含量依北美页岩组合(NASC)标准化 ,并按log[3Cen/ ( 2Lan Ndn) ]计算Ce异常值 .以全岩Ce异常作为海平面变化的定量指标 ,识别出 5个明显的海平面升降旋回 ,发现多幕次黑色岩系与海侵事件严格对应 .鉴于同期黑色岩系的全球性分布和华南特定的古地理格局 ,提出华南早古生代多幕次黑色岩系的最小含氧层扩展成因模式 .  相似文献   

6.
龙马溪组黑色页岩在贵州、重庆等地广泛分布,是志留系生物地层研究和页岩气勘探的重要对象.本文针对黔渝地区从贵阳、遵义、桐梓、綦江至华蓥山这一由南向北的廊带,以其中生物地层研究程度较高的典型剖面为基础,总结出龙马溪组黑色笔石页岩的阶段性渐进展布模式.在横向上利用笔石带对比框架,将遵义至华蓥山划分为四个发育不同黑色页岩层段的廊带,并研究它们随时间展布的规律;同时,也较为准确地获得了龙马溪组黑色页岩与其上混合相地层和碳酸盐岩地层之间互相消长的相变过程.此外,本文还利用笔石深度分带的通用模式,论述了黔渝龙马溪组连续沉积的笔石页岩层段随时间其沉积水深不断加深的过程,从而将其划分为从LM1到LM5的海侵渐进阶段和LM5之后的均衡扩展阶段,在每一阶段龙马溪组黑色页岩的分布受控于不同的主导因素.这一阶段性渐进展布模式,对研究四川盆地南缘龙马溪组黑色页岩的时空分布具有重要的参考意义.  相似文献   

7.
华东地区矿产资源潜力评价工作走过了风风雨雨8个年头,工作专题涉及成矿规律、矿产预测、地球物理、地球化学、遥感、自然重砂、综合信息与集成等7个子专题组。通过各省及大区工作人员的努力,目前华东地区矿产资源潜力评价工作已分层次、分阶段完成了铁、铜、锌、铅、金、磷、钨、锑、稀土、锰、镍、锡、铬、钼、银、硼、锂、硫、萤石、菱镁矿、重晶石等21个矿种(组)的潜力评价工作任务。  相似文献   

8.
渝东、鄂西和湘西北志留系兰多维列统鲁丹阶至埃隆阶下部的地层存在不同程度的缺失,因此这一地区性的抬升被称为宜昌上升.本文通过丰富的剖面地层资料,阐明了宜昌上升的时空分布模式.由于与之相关的龙马溪组底部黑色页岩的不同程度的缺失,关系到对其中赋存的页岩气的勘探,因此,宜昌上升的分布模型对该地区及其周缘页岩气的勘探开发布局有指导作用.本文与"黔渝地区志留系龙马溪组黑色页岩的阶段性渐进展布模式"一文,共同提供了中国中上扬子区奥陶-志留系之交黑色页岩地层的一个完整的分布模式.  相似文献   

9.
近几年受地震属性分析技术的启发,出现了利用测井属性分析泥页岩裂缝油气藏的新方法.为了避免常规测井信号受到噪声干扰影响裂缝识别效果,利用小波变换的高频属性对裂缝识别展开研究.以贵州岑巩地区下寒武统牛蹄塘组的泥页岩裂缝性油气藏为例,观察和分析野外黑色页岩露头、岩心薄片及镜下照片,总结了该地区裂缝发育特征和成因;然后着重利用研究区的测井资料,运用小波阈值去噪和小波高频属性方法对裂缝进行了识别.研究结果表明:研究区主要发育高角度剪性缝、张剪性缝、低角度滑脱缝及层间缝,采用的小波阈值去噪方法具有高信噪比和低均方差特点,在保留原始信号特点的基础上得到更加真实的信号;通过小波高频属性方法提取了声波时差信号中的高频信号,识别出了常规测井方法无法识别的泥页岩裂缝,该套方法成功在贵州岑巩页岩气裂缝识别中得到成功应用,并具有一定的借鉴意义.  相似文献   

10.
成联正  王赟  张川 《地球物理学报》2021,64(9):3344-3357
电法勘探因其成本低、效率高的优势,常被作为寻找页岩气储层的辅助手段.然而,到目前为止,页岩的电性特征,特别是复电阻率各向异性特征,以及其与页岩气储层参数的关系研究甚少,这在一定程度上阻碍了电法勘探在页岩气勘探中的应用.基于此,本文采集了黔东地区几种典型黑色页岩岩样,并测量了 6块黑色页岩在走向、倾向和垂直层理方向的复电阻率,分析了其各向异性特性,讨论了电阻率与总有机碳(TOC)含量、脆性矿物含量、最大镜质组反射率等页岩气储层参数之间的关系.研究表明:(1)页岩复电阻率振幅各向异性存在频率依赖的特征,在中低频阶段,页岩复电阻率振幅各向异性明显,垂直层理方向复电阻率振幅显著大于走向、倾向方向复电阻率振幅,但随频率增加,页岩复电阻率振幅各向异性差异减小,甚至趋于各向同性;(2)复Cole-Cole模型能很好地拟合页岩三方向的复电阻率数据;(3)走向、倾向方向电阻率与TOC含量存在显著的线性正相关关系,通过走向、倾向方向电阻率预测TOC含量有一定可行性;(4)电阻率与脆性矿物含量、黏土矿物含量、最大镜质组反射率关系复杂,未发现简单的线性相关关系.上述研究结果对我们全面了解黔东地区黑色页岩的电性特征,促进电法勘探在页岩气勘探中的应用大有裨益.  相似文献   

11.
The Lower Cambrian on the Yangtze Platform in South China (internationally equivalent to the Nerreneuvian and 2nd series of the Cambrian) is valuable for understanding the early evolution of life, the global biogeochemical circles, and the major changes of the ocean. In particular, a precise radiometric calibration of the Lower Cambrian of this region is a critical realm in its multidisciplinary studies. A SHRIMP U-Pb geochronology study of the K-bentonite in the topmost Laobao Formation at the Pingyin section, Guizhou, South China yielded an age of 536±5 Ma (MSWD = 0.75), suggesting that the K-bentonite here can be correlated with the intensely studied K-bentonite within the middle Zhongyicun Member (Bed 5) of the Zhujiaqing Formation at the Meishucun section in Yunnan. Such a regional correlation result reveals that the Bed 5 K-bentonite also extends into deeper-water environments rather than being deposited merely in the shallow platform interior of the Yangtze Platform. The age of the K-bentonite at the Pingyin section also implies that its overlying polymetallic Ni-Mo layer should be younger than 536±5 Ma. Hence the previous placement of the Precambrian/Cambrian boundary at this layer is inappropriate. Combined with the results of stratigraphic correlations, it is suggested that the K-bentonites in the middle Zhongyicun Member of the Zhujiaqing Formation (or the equivalents) and the base of the Shiyantou Formation (or its equivalents), together with the polymetallic Ni-Mo layer, serve as three important marker beds. Their self-consistent radiometric ages have established an improved geochronologic framework for the Lower Cambrian in South China.  相似文献   

12.
At the bottom of the Lower Cambrian, there widely develops a suit of rock association com-posed of black shales interbedded with thin silicalite in the India, northern Pakistan, Iran, southern France, England, northern Oman, the former USSR, southern Kaza…  相似文献   

13.
There are different sulfur forms in the black shales from the Early Cambrian of the Yangtze platform. With its emphasis on pyrite and organosulfur, this paper discusses their distribution and formation. The research shows that sulfur phases take regular variations laterally as well as vertically in the research areas. In western researched profile with high terrigenous supply at the time it formed, there exists a larger amount of pyrite and less organosulfur, and pyrite amount declines while organosulfur content increases upwards along the profile. This black shale profile is characterized by relatively light sulfur isotope composition with evolution trend of becoming heavier both for pyrite and organosulfur from bottom to top along the profile. Opposite situation occurs in eastern profiles which were located farther away from terrigenous land. Here pyrite amount obviously decreases and organic matter has combined more sulfur, although these two kinds of sulfur species take similar trend in content variation along profiles to that for western profile. At the same time more34S is accumulated in sulfur species of black shale samples from eastern profile, and sulfur isotope composition gradually turns lighter from bottom to top. In combination with other information of iron, organic carbon contents and petrographic features, it can be established that sea-level change, supply of terrigenous matters, tectonic background and natures of paleoceanic chemistry have exerted great influence on the distribution of sulfur species in these black shales.  相似文献   

14.
The bottom of the Lower Cambrian series is an important bed typical of boundary event. The bed had been enriched with many useful elements such as Ni, Mo, Cu, Pb, Zn, Au, Ag, Ru, Rh, Pd, Os, Ir and Pt, many rare and dispersed elements such as Cd, Se, Tl, …  相似文献   

15.
“十三五”规划中桂地区页岩气基础地质调查地球物理勘探正有序开展。桂地区页岩油气地球物理勘探基础较薄弱,如何有效开展地球物理勘探是当前基础地质调查重要课题。着重阐述了桂周边地区页岩油气地球物理勘探研究现状,指出桂周边地区页岩油气地球物理勘探技术成熟并取得了进展性突破。基于桂地区与其周边地区页岩油气地质条件具有较好可比性,重点讨论了周边地区页岩油气地球物理勘探成功经验对桂地区页岩油气地球物理勘探工作开展的几点认识及展望。指出今后开展桂地区页岩油气地球物理勘探及评价项目中需要注意的几个研究方向,即稳健推广二维地震勘探、优先发展2.5维电磁勘探、加强系统物性测试与分析、重磁电震综合为终极目标,为实际勘探开展奠定理论基础。   相似文献   

16.
The 65 whole-rock REE samples studied come from the classic sections of Early Cambrian to Early Silurian in the Yichang area, Hubei Province. REE concentrations tested on ICP-AES are normalized to the North American Shale Composite (NASC), and Ce anomaly values are calculated based on log[ 3Cen/(2Lan+Ndn)] . With the whole-rock Ce anomaly used as a quantitative index of sea-level changes, 5 prominent eustatic circles are recognized, and a good corresponding relationship is observed between the black shale episodes and the transgressive events. On account of the global distributions of coeval black shales and the specified paleogeographic background of South China, a genetic hypothesis based on the model of O2-minimum zone expansion is suggested for the Early Paleozoic multi-episode black shales in South China.  相似文献   

17.
Stratigraphic hiatuses of variable time intervals within the Rhuddanian to early Aeronian (Llandovery, Silurian) are identified in the area bordering East Chongqing, West Hubei and Northwest Hunan in central China. Their distribution suggested the existence of a local uplift, traditionally named the Yichang Uplift. The diachronous nature of the basal black shale of the Lungmachi Formation crossing different belts of this Uplift signifies the various developing stages during the uplifting process. The present paper defines the temporal and spatial distribution pattern of the Yichang Uplift, which might be one of the important controlling factors for the preservation and distribution of the shale gas in this region, as it has been demonstrated that the shale gas exploration is generally less promising in the areas where more of the basal part of the Lungmachi Formation is missing. Therefore, better understanding of the circumjacent distribution pattern developed throughout the uplifting process may provide the important guidance for the shale gas exploration. The present work is a sister study to the published paper, “Stage-progressive distribution pattern of the Lungmachian black graplolitic shales from Guizhou to Chongqing, Central China”. These two studies thus provide a complete Ordovician-Silurian black shale distribution pattern in the Middle and Upper Yangtze, a region with the major shale gas fields in China.  相似文献   

18.
Several oil shale beds, over 10 m thick, occur at the base of the first member of the Upper Cretaceous Qingshankou Formation (K2qn1) in the Songliao Basin. They act both as excellent source rocks for conventional oil and as potential oil deposit for shale oil production. Here we combine micropaleon-tology with organic geochemistry to investigate the paleo-depositional environment and organic source characteristics of the oil shales and black shales. Our results indicate that algal remains are dominant micro...  相似文献   

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