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1.
A study of the changes in the ionic loads of NO, NH, SO and H+ in a boreal forest snowpack at Lake Laflamme, Québec was carried out using hydrological and chemical data from field lysimeters. The results showed that depletion of the N-containing species occurs periodically in the snowpack during meltwater discharge. Rain-on-snow events led to in-pack losses of NO and NH at a rate of 130 μeq m?2 day?1 and 101·3 μeq m?2day?1 respectively. On dry days, however, dry deposition and deposition of organic debris from the canopy resulted in increases of 183·3 μeq m?2day?1 for NO and 4·5 μeq m?2day?1 for NH in the pack. In contrast, SO42? showed continual in-pack increases due to deposition of 5·0 μeq m?2day?1 for wet days and 92·6 μeq m?2day?1 for dry days. The depletion of NO and NH is due to microbiological uptake of these nutrients during periods when the free water content of the pack is high. Controlled melts in a laboratory snowmelt simulator containing snow and organic matter from the forest canopy at Lake Laflamme showed losses of NO and NH similar to those observed in the field. As the microbiological uptake proceeds at a rate comparable to that of ionic load increases in the pack by dry deposition, models of the chemical dynamics of snowmelt should take the former into account in any system where organic content of the snowpack is appreciable.  相似文献   

2.
The knowledge of total inorganic carbon concentration (c) is important for characterizing natural waters. It is usually measured by the titration alkalinity (“m-value”) and pH which depend on temperature and ionic strength. This paper demonstrates that Ca (and Mg) can influence the calculation of from titration alkalinity, too. Errors result from neglecting this influence. In such cases the share of ion pair CaCO amounts to more than 50 % of . General relationships among the influencing factors are given by tables calculated with the help of a BASIC computer programme for calculation from titration alkalinity, pH and Ca concentration.  相似文献   

3.
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4.
Small bounded plots were used to investigate dissolved nutrient losses in overland flow in eucalyptus and pine forests in northern Portugal following understorey fires. Losses of NON, POCa2+, Mg2+ and K+ were measured over 19 months during the first 2–3 years after fire. Solute losses in overland flow increased after fire in eucalyptus and pine terrain due to the mineralization of litter and vegetation and increased overland flow. The data suggest that (i) elevated losses persist for at least 2 and 3 years at the pine and eucalyptus sites respectively and (ii) soluble losses of POK+ in a post‐fire cycle may exceed those adsorbed to eroded material. Losses of POalthough relatively small, are potentially the most detrimental to soil fertility and forest productivity because of the limited opportunity for P replenishment and correspondingly high P losses adsorbed to eroded sediment. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

5.
Our objective was to discover the effect of variations in fluid properties and fracture geometry on the velocity of seismic wave propagation in fluid‐saturated media with parallel planar fractures. We used numerical models calculated by analytical solutions to examine the behaviour of P‐wave phase velocity dispersion in the normal direction to layering, in non‐porous and porous media with planar fractures. We also examined the anisotropy of low frequency phase and group velocities of fast and slow P‐waves and angular‐dependent reflection coefficients in media with planar fractures, under conditions of saturation by fluids with varying bulk moduli, densities, and fracture apertures. We defined several parametre , , and characterising dispersion, characterising anisotropy, characterising the difference between fast and slow modes, and R0 and characterising reflection. Our results show that the behaviour of dispersion shows wider stopbands in the case of gas saturation. Concavity indicator of dispersion for gas saturation was greater than that for liquid saturation and is usually greater than one. Anisotropy is more sensitive to bulk modulus contrast than to density contrast between the solid and the fluid, and is more sensitive to density contrast than to bulk modulus contrast. The case of gas saturation usually had a greater negative R0 and a greater value of compared with those of brine and heavy and light oil saturations. Our results are helpful in distinguishing fluid types saturating geophysical fractures and estimating the aperture and spacing of planar fractures. In seismic exploration, bulk modulus and fluid density can provide useful information in distinguishing among brine, oil, and gas; fracture geometry is important to estimate the permeability of reservoirs.  相似文献   

6.
The uptake of phosphorus by Potamogeton pectinatus, P. lucens, Ranunculus fluitans, Elodea canadensis, Myriophyllum spicatum and Ceratophyllum demersum is investigated in batch tests at 0.02, 0.04, 0.4 and 4.0 mg/l PO in the medium for 4, 28 and 52 h. Uptake is strictly dependent on concentration, a saturation function being discernible already after 52 h. At rising concentration the mechanism of uptake is determined by a decreasing rate of incorporation. The rates of uptake are dependent also on the actual and maximum cell nutrient contents. Species with a low phosphorus content of <5 mg PO/g dry weight as Elodea canadensis, Potamogeton pectinatus and Myriophyllum spicatum show their maximum phosphorus incorporation at low substrate concentrations. At phosphorus contents >5 mg PO/g dry weight the phosphorus incorporation is increased only at substrate concentrations of 0.04… 0.4 mg/l PO.  相似文献   

7.
Errors in the kinematic wave and diffusion wave approximations for time-independent (or steady-state) cases of channel flow were derived for three types of boundary conditions: zero flow at the upstream end, and critical flow depth and zero depth gradient at the downstream end. The diffusion wave approximation was found to be in excellent agreement with the dynamic wave approximation, with errors in the range 1–2% for values of KF (? 7.5), where K is the kinematic wave number and F0 is the Froude number. Even for small values of KF (e.g. KF20 = 0.75), the errors were typically less than 15%. The accuracy of the diffusion wave approximation was greatly influenced by the downstream boundary condition. The error of the kinematic wave approximation was found to be less than 13% in the region 0.1 ? x ? 0.95 for KF = 7.5 and was greater than 30% for smaller values of KF (? 0.75). This error increased with strong downstream boundary control.  相似文献   

8.
It is shown that the new definition1 of strong motion local magnitude M leads to stable estimates of magnitudes for earthquakes in Yugoslavia, with epicentral distances R <100 km and for 2.5 < M < 6.5. Tables with magnitudes computed using this new procedure are presented for all earthquakes contributing to the strong motion accelerogram files in EQINFOS for Yugoslavia.2 The similarity of our findings with the analogous analyses for California suggests new possibilities for relative calibration between various local magnitude scales, which are used in southeastern Europe, and ML in California.  相似文献   

9.
One mechanism by which biochar application enhances soil nutrient availability is through direct nutrients release from biochar. However, factors controlling the release processes are poorly understood. In this study, the effects of pH, biochar to water ratio, temperature, ionic strength, and equilibration time on the release of PO, NO, NH, K+, Na+, Ca2+, and Mg2+ from biochar were evaluated in simulated experiments. The release of PO, K+, Ca2+, and Mg2+ was significantly affected by extraction pH, suggesting that their release from biochar was pH dependent or an H+‐consuming process. Correlation analysis indicated that PO and Ca2+, PO and Mg2+, and Ca2+ and Mg2+ were co‐solubilized with increasing soil acidity. To a lesser extent, the recovery of the nutrients was also affected by the ratio of biochar to water: more nutrients were soluble with more water supply. In contrast, the release of Na was not affected by pH while the concentration increased with decreasing biochar to water ratio. Meanwhile, other factors (temperature, ionic strength, and equilibration time) had less effect on nutrient release from biochar. Under the influence of pH, the patterns of NO and PO release from biochar were different: extractable NO concentration was not affected by the pH but more PO was released in strongly acidic conditions. Our data suggested that P was mainly retained in inorganic forms while N was in organic forms in biochar. We conclude that environmental factors have marked influences on nutrients release from biochar.  相似文献   

10.
We investigate fracture‐induced attenuation anisotropy in a cluster of events from a microseismic dataset acquired during hydraulic fracture stimulation. The dataset contains 888 events of magnitude ?3.0 to 0.0. We use a log‐spectral‐amplitude‐ratio method to estimate change in over a half‐hour time period where fluid is being injected and an increase in fracturing from S‐wave splitting analysis has been previously inferred. A Pearson's correlation analysis is used to assess whether or not changes in attenuation with time are statistically significant. P‐waves show no systematic change in during this time. In contrast, S‐waves polarised perpendicular to the fractures show a clear and statistically significant increase with time, whereas S‐waves polarised parallel to the fractures show a weak negative trend. We also compare between the two S‐waves, finding an increase in with time. A poroelastic rock physics model of fracture‐induced attenuation anisotropy is used to interpret the results. This model suggests that the observed changes in t* are related to an increase in fracture density of up to 0.04. This is much higher than previous estimates of 0.025 ± 0.002 based on S‐wave velocity anisotropy, but there is considerably more scatter in the attenuation measurements. This could be due to the added sensitivity of attenuation measurement to non‐aligned fractures, fracture shape, and fluid properties. Nevertheless, this pilot study shows that attenuation measurements are sensitive to fracture properties such as fracture density and aspect ratio.  相似文献   

11.
Processes driving carbonate diagenesis in islands of the northern Bahamas are investigated using major ion, dissolved oxygen and dissolved organic carbon analyses of water samples from surface and ground waters, and measurements of soil gas P. Meteoric waters equilibrate with aragonite, but reactions are water controlled rather than mineral‐controlled and drive dissolution rather than concurrent precipitation of calcite. Surface runoff waters equilibrate with atmospheric P and rapidly recharge the vadose zone, limiting subaerial bedrock dissolution to only 6·6–15 mg l?1 Ca. P of soil gas measured in the summer wet season ((7·4 ± 3·7) × 10?3 atm) is elevated compared with that of the atmosphere, despite the thin skeletal organic nature of the soil and the discontinuous soil cover. Soil waters retained in surface pockets are equilibrated with respect to aragonite and have dissolved 51 ± 19 mg l?1 Ca. This is substantially less than the 93 ± 18 mg l?1 Ca in samples from pumping boreholes that sample meteoric waters from the freshwater lens. The high P of the freshwater lens ((16 ± 8·3) × 10?3 atm for pumping boreholes) suggests that significant additional CO2 may be derived by oxidation of soil‐ and surface‐derived organic carbon within the lens. The suboxic nature of the majority of the freshwater lens and the observed depletion in sulphate support this suggestion, and indicate that both aerobic and anaerobic oxidation may take place. Shallow lens samples from observation boreholes are calcite supersaturated and have a lower P than deeper lens waters, indicating that CO2 degasses from the water table, driving precipitation of calcite cements. We suggest that the geochemical evolution of waters in the vadose zone and upper part of the freshwater lens may be determined by the presence of a body of ground air with P controlled by production in the freshwater lens and soil and by degassing to the atmosphere. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

12.
Contamination of water due to bromate is a severe health hazard. The aim of the present study was to remove bromate from water using a crosslinked polystyrene based strongly basic anion exchange resin De‐Acidite FF‐IP. Batch experiments were performed to study the influence of various experimental parameters such as effect of pH, contact time, temperature, and effect of competing anions on bromate removal by De‐Acidite FF‐IP resin. At optimum parameters, the removal rate of bromate was very fast and 90% removal took place in 5 min and equilibrium was established within 10 min. The presence of competitive anions reduced the bromate adsorption in the order of Cl? > F? > CO > SO > NO > PO. The practical utility of this resin has been demonstrated by removing bromate in some of the commercial bottled water from Saudi Arabia. The level of bromate was determined using a very sensitive, precise and rapid method based on ultra‐performance liquid chromatography‐tendem mass spectrometry (UPLC‐MS/MS).  相似文献   

13.
Species composition, abundance, and seasonal distribution of the Gastropoda fauna and the physical and chemical variables of Upper Sakarya River System have been investigated between October 1998 and August 1999. Gastropod fauna in the Upper Sakarya River System was represented by 9 species of Prosobranchia and 7 species of Pulmonata. Diversity, dominance, and abundance of the Gastropoda species were recorded seasonally. The abundance of some of the 16 species was correlated positively with temperature, dissolved oxygen and negatively or positively with pH and nitrate. It was observed that Gyraulus albus (Müller, 1774), Physa acuta Draparnaud, 1805, Valvata pulchella Studer, 1820, and Oxyloma elegans (Risso, 1826) can tolerate a high level of NO‐N while V. piscinalis (Müller, 1774) spread out in unpolluted water. Although the species and their numbers change at the stations, the maximum numbers were found during autumn, while minimums were identified during the winter sampling. Gyraulus albus was the most widespread species in our research area. Only 5 species (Gyraulus albus, Physa acuta, Valvata cristata (Muller, 1774), Valvata pulchella, Melanopsis praemorsa costata (Olivier, 1804)) were determined each season. However, no Gastropoda were found at the station 3 that has high BOD, NO‐N, NO‐N, and NH3 levels.  相似文献   

14.
The conventional velocity scan can be computationally expensive for large‐scale seismic data sets, particularly when the presence of anisotropy requires multiparameter scanning. We introduce a fast algorithm for 3D azimuthally anisotropic velocity scan by generalizing the previously proposed 2D butterfly algorithm for hyperbolic Radon transforms. To compute semblance in a two‐parameter residual moveout domain, the numerical complexity of our algorithm is roughly as opposed to of the straightforward velocity scan, with N being the representative of the number of points in a particular dimension of either data space or parameter space. Synthetic and field data examples demonstrate the superior efficiency of the proposed algorithm.  相似文献   

15.
Ag‐modified TiO2 nanotube arrays (Ag/TiO2 NAs) were prepared and employed as a photocatalyst for degradation of 17α‐ethinylestradiol (EE2) and inactivation of Escherichia coli. The as‐synthesized Ag/TiO2 NAs were characterized by field‐emission scanning electron microscope (FESEM), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). It was found that metallic Ag nanoparticles were firmly deposited on the TiO2 NAs with the pore diameter of 100 nm and the length of 550 nm. Photocatalytic degradation of EE2 and inactivation of E. coli were enhanced effectively in an analogical trend using Ag/TiO2 NAs. In particular, Ag/TiO2 NAs exhibited the antimicrobial activity even in the absence of light. The Ag acted as a disinfection agent as well as the dopant of the modified TiO2 NAs photocatalysis by forming a Schottky barrier on the surface of TiO2 NAs. Inorganic ions suppressed the rates of photocatalytic degradation of EE2, with HCO having a more pronounced effect than NO or SO. Humic acid (HA) was found to increase the rate of EE2 degradation.  相似文献   

16.
The atmospheric chloride mass balance (CMB) method allows spatial evaluations of the average diffuse aquifer recharge by rainfall () in large and varied territories when long‐term steady conditions can be assumed. Often, the distributed average CMB variables necessary to calculate have to be estimated from the available variable‐length data series, which may be of suboptimal quality and spatial coverage. This paper explains the use of these data and the reliability of the results in continental Spain, chosen as a large and varied territory. The CMB variables have been regionalized by ordinary kriging at the same 4976 nodes of a 10 km × 10 km grid. Nodal values vary from 14 to 810 mm year–1, 90% ranging from 30 to 300 mm year–1. The recharge‐to‐precipitation ratios vary from 0.03 in low‐permeability formations and semiarid areas to 0.65 in some carbonate massifs. Integrated average results for the whole of continental Spain yield a potential aquifer recharge of 64 km3 year?1, the net recharge over permeable formations (40% of the territory) being 32 km3 year?1. Two main sources of uncertainty affecting (given by the coefficient of variation, CV), induced by the inherent natural variability of the variables (CVR) and from mapping (), have been segregated. The average CVR is 0.13 and could be improved with longer data series. The average is 0.07 and may be decreased with better data coverage. The estimates were compared with other regional and local recharge estimates, being 4% and 1% higher, respectively. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

17.
The nonlinearity of the seismic amplitude‐variation‐with‐offset response is investigated with physical modelling data. Nonlinearity in amplitude‐variation‐with‐offset becomes important in the presence of large relative changes in acoustic and elastic medium properties. A procedure for pre‐processing physical modelling reflection data is enacted on the reflection from a water‐plexiglas boundary. The resulting picked and processed amplitudes are compared with the exact solutions of the plane‐wave Zoeppritz equations, as well as approximations that are first, second, and third order in , , and . In the low angle range of 0°–20°, the third‐order plane‐wave approximation is sufficient to capture the nonlinearity of the amplitude‐variation‐with‐offset response of a liquid‐solid boundary with , , and ρ contrasts of 1485–2745 m/s, 0–1380 m/s, and 1.00–1.19 gm/cc respectively, to an accuracy value of roughly 1%. This is in contrast to the linear Aki–Richards approximation, which is in error by as much as 25% in the same angle range. Even‐order nonlinear corrective terms are observed to be primarily involved in correcting the angle dependence of , whereas the odd‐order nonlinear terms are involved in determining the absolute amplitude‐variation‐with‐offset magnitudes.  相似文献   

18.
The present study deals with the application of the hierarchical cluster analysis and non‐parametric tests in order to interpret the Gdańsk Beltway impact range. The data set represents concentration values for major inorganic ions (Na+, NH, K+, Mg2+, Ca2+, F−, Cl−, NO, and SO) as well as electrolytic conductivity and pH measured in various water samples [precipitation, throughfall water, road runoff, and surface water (drainage ditches, surface water reservoirs, and spring water)] collected in the vicinity of the beltway. Several similarity groups were discovered both in the objects and in the variables modes according to the water sample. In the majority of cases clear anthropogenic (fertilizers usage and transport, road salting in winter) and semi‐natural (sea salt aerosols, erosion of construction materials) impacts were discovered. Spatial variation was discovered for road runoff samples and samples collected from surface water reservoirs and springs. Surprisingly no clear seasonal variability was discovered for precipitation chemistry, while some evidences for existing of summer and winter specific chemical profile was discovered for road runoff samples. In general, limited range of the Gdańsk Beltway impact was proven.  相似文献   

19.
Under certain circumstances, seismic propagation within porous media may be associated to the conversion of mechanical energy to electromagnetic energy, which is known as a seismo‐electromagnetic phenomenon. The propagation of fast compressional P‐waves is more specifically associated to the manifestations of a seismoelectric field linked to the fluid flows within the pores. The analysis of seismoelectric phenomena, which requires the combination of the theory of electrokinetics and Biot's theory of poroelasticity, provides us with transfer function that links the coseismic seismoelectric field E to the seismic acceleration . To measure the transfer function, we have developed an experimental setup enabling seismoelectric laboratory observation in unconsolidated quartz sand within the kilohertz range. The investigation focused on the impact of fluid conductivity and water saturation over the coseismic seismoelectric field. During the experiment, special attention was given to the accuracy of electric field measurements. We concluded that, to obtain a reliable estimate of the electric field amplitude, the dipole from which the potential differences are measured should be of much smaller length than the wavelength of the propagating seismic field. Time‐lapse monitoring of the seismic velocities and seismoelectric transfer functions were performed during imbibition and drainage experiments. In all cases, the quantitative analysis of the seismoelectric transfer function was in good agreement with theoretical predictions. While investigating saturation variations from full to residual water saturation, we showed that the ratio undergoes a switch in polarity at a particular saturation , which also implies a sign change of the filtration, traducing a reversal of the relative fluid displacement with respect to the frame. This sign change at critical saturation stresses a particular behaviour of the poroelastic medium: the dropping of the coseismic electric field to zero traduces the absence of relative pore/fluid displacements representative of a Biot dynamically compatible medium. We concluded from our experimental study in loose sand that the measurements of the coseismic seismoelectric coupling may provide information on fluid distribution within the pores and that the reversal of the seismoelectric field may be used as an indicator of the dynamically compatible state of the medium.  相似文献   

20.
Source apportionment of particulate matter <10 µm in diameter (PM10), having considerable impacts on human health and the environment, is of high priority in air quality management. The present study, therefore, aimed at identifying the potential sources of PM10 in an arid area of Ahvaz located in southwest of Iran. For this purpose, we collected 24‐h PM10 samples by a high volume air sampler. The samples were then analyzed for their elemental (Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Se, Si, Sn, Sr, Li, Ti, V, Zn, Mo, and Sb) and ionic (NH, Cl?, NO, and SO) components using inductively coupled plasma optical emission spectrometry and ion chromatography instruments, respectively. Eight factors were identified by positive matrix factorization: crustal dust (41.5%), road dust (5.5%), motor vehicles (11.5%), marine aerosol (8.0%), secondary aerosol (9.5%), metallurgical plants (6.0%), petrochemical industries and fossil fuel combustion (13.0%), and vegetative burning (5.0%). Result of this study suggested that the natural sources contribute most to PM10 particles in the area, followed closely by the anthropogenic sources.  相似文献   

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