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1.
A large groundwater system in the Amadeus Basin, central Australia, discharges to a chain of playa lakes 500 km long. The playas contain highly concentrated brines; these are sodium-chloride rich waters with appreciable magnesium and sulphate and very low concentrations of calcium and bicarbonate. Gypsum, glauberite, and other evaporite minerals are precipitating in the playas. The groundwaters evolve to brine by concurrent processes of dissolution, evaporative concentration, mineral precipitation, and mineralogical change. Chemical evolution is considered with reference to a concentration factor based on chloride. Ion transfer calculations demonstrate losses of magnesium and bicarbonate throughout, as a result of precipitation. Sodium, potassium, calcium, and sulphate are gained initially as a result of dissolution but lost subsequently as a result of precipitation. Larger playas in the chain, exemplified by Lake Amadeus, have dual shallow and deep groundwater flow paths whereas the smaller playas, exemplified by Spring Lake, have only shallow flow paths. Brines in the larger playas are diluted by deep groundwaters and this is reflected in the degree of saturation attained with respect to particular minerals. Thus, saturation with respect to gypsum and glauberite is attained earlier in Spring Lake than in Lake Amadeus. Saturation with respect to halite is attained in Spring Lake but not in Lake Amadeus. Both playas are undersaturated with respect to hexahydrite and sylvite although these minerals occur in efflorescent crusts in Spring Lake.  相似文献   

2.
This paper evaluates the utility of the shoreline preservation index (s.p.i.) for estimating the age of late Pleistocene palaeolake shorelines, the relative influence of various factors on shoreline preservation, and whether shoreline preservation varies significantly with shoreline aspect. Sampled shorelines from the 3300 km2 study area, which includes the Skull, Tule and Puddle Valley portions of the Lake Bonneville basin, range in age from approximately 26 to 12 ka. Their total s.p.i. values range from 23 to 69 per cent, average 46 per cent, and do not vary significantly with shoreline aspect. The data from Skull and Tule Valleys, where studied shorelines are of known age, are analysed first in order to determine if there are statistically significant associations between variables representing shoreline preservation, age, degree of geomorphic development and duration of subaerial exposure. Pairwise correlation is then repeated using observations from all three valleys in order to determine how data from the Puddle Valley shorelines, whose hypothesized ages are not supported by radiocarbon analyses, affect the results. Results show that s.p.i. is useful as a relative-age dating tool, that the postulated ages of the Puddle Valley shorelines are ordinally correct, and that geomorphic development is not an important influence on the preservation of these late Pleistocene shorelines. The relative importance of shoreline age and the relative unimportance of duration of subaerial exposure with respect to shoreline preservation suggest that subaqueous processes play a more substantial role in shoreline obliteration than is generally suggested.  相似文献   

3.
Well-dated bedrock surfaces associated with the highstand and subsequent catastrophic draining of Pleistocene Lake Bonneville, Utah, during the Bonneville flood are excellent locations for in situ cosmogenic nuclide production rate calibration. The CRONUS-Earth project sampled wave-polished bedrock and boulders on an extensive wave-cut bench formed during the Bonneville-level highstand that was abandoned almost instantaneously during the Bonneville flood. CRONUS-Earth also sampled the Tabernacle Hill basalt flow that erupted into Lake Bonneville soon after its stabilization at the Provo level, following the flood. New radiocarbon dating results from tufa at the margins of Tabernacle Hill as part of this study have solidified key aspects of the exposure history at both sites. Both sites have well-constrained exposure histories in which factors such as potential prior exposure, erosion, and shielding are either demonstrably negligible or quantifiable. Multi-nuclide analyses from multiple labs serve as an ad hoc inter-laboratory comparison that supplements and expands on the formalized CRONUS-Earth and CRONUS-EU inter-laboratory comparisons (Blard et al., 2015; Jull et al., 2015; Vermeesch et al., 2015). Results from 10Be, 26Al, and 14C all exhibit scatter comparable to that observed in the CRONUS-Earth effort. Although a 36Cl inter-laboratory comparison was not completed for Jull et al. (2015), 36Cl from plagioclase mineral separates exhibits comparable reproducibility. Site production rates derived from these measurements provide valuable input to the global production rate calibration described by Borchers et al. (2015). Whole-rock 36Cl concentrations, however, exhibit inter-laboratory variation exceeding analytical uncertainty and outside the ranges observed for the other nuclides (Jull et al., 2015). A rigorous inter-laboratory comparison studying the systematics of whole-rock 36Cl extraction techniques is currently underway with the goals of delineating the source(s) of this discrepancy and standardizing these procedures going forward.  相似文献   

4.
Gypsum and halite crystals, together with saponite and phillipsite, were found in a vein in a basalt sill 625 m below the sea floor at DSDP Site 395A, located 190 km west of the crest of the Mid-Atlantic Ridge. The δ34S value of the gypsum (+19.4‰) indicates a seawater source for the sulfate. The δ18O values of the saponite (+19.9‰) and phillipsite (+18.1‰) indicate either formation from normal seawater at about 55°C or formation from18O-depleted seawater at a lower temperature.The gypsum (which could be secondary after anhydrite) was formed by reaction between Ca2+ released from basalt and SO42? in circulating seawater. The halite could have formed when water was consumed by hydration of basalt under conditions of extremely restricted circulation. A more probable mechanism is that the gypsum was originally precipitated as anhydrite at temperatures above 60°C. As the temperature dropped the anhydrite converted to gypsum. The conversion would consume water, which could cause halite precipitation, and would cause an increase in the volume of solids, which would plug the vein and prevent subsequent dissolution of the halite.  相似文献   

5.
Notwithstanding the great deal of attention that the Messinian evaporites of the Mediterranean region have received from an observational point of view, there is, to date, no consensus as to their mechanism of formation. We aim to contribute to the investigation through a quantitative analysis of the processes of desiccation and re-filling. These processes are thought to have played a role in particular during the deposition of the upper part of the evaporite sequence. We calculate the evolution of sea level and average salinity based on both the present-day geometry and a paleogeographic reconstruction and assess the sensitivity to variations in the freshwater budget. Our results support previous inferences that desiccation and re-filling are fast; desiccation occurs on a time scale of 3-8 kyr, re-filling probably even faster. Equilibrium sea levels imply that most water has gone from the western basin while a significant water column remains in the eastern basin. Whether or not the eastern basin reaches the level of halite saturation depends critically on, in particular, the freshwater budget. The fast rate of desiccation and re-filling imply that temporal differences in the onset of salt precipitation between western and eastern basin and between marginal basins and basin centres are below the resolution of (astronomical) dating. Also, when Atlantic sea level periodically varied from below to above the level of the intervening sill, the Mediterranean basin will have responded with repeated desiccation and re-filling. Fast re-filling is found to require only a small connection to the Atlantic Ocean. This, in combination with the previous results, suggests the Mediterranean is unlikely to attain stable intermediate water levels.  相似文献   

6.
Permafrost degradation in the peat‐rich southern fringe of the discontinuous permafrost zone is catalysing substantial changes to land cover with expansion of permafrost‐free wetlands (bogs and fens) and shrinkage of forest‐dominated permafrost peat plateaux. Predicting discharge from headwater basins in this region depends upon understanding and numerically representing the interactions between storage and discharge within and between the major land cover types and how these interactions are changing. To better understand the implications of advanced permafrost thaw‐induced land cover change on wetland discharge, with all landscape features capable of contributing to drainage networks, the hydrological behaviour of a channel fen sub‐basin in the headwaters of Scotty Creek, Northwest Territories, Canada, dominated by peat plateau–bog complexes, was modelled using the Cold Regions Hydrological Modelling platform for the period of 2009 to 2015. The model construction was based on field water balance observations, and performance was deemed adequate when evaluated against measured water balance components. A sensitivity analysis was conducted to assess the impact of progressive permafrost loss on discharge from the sub‐basin, in which all units of the sub‐basin have the potential to contribute to the drainage network, by incrementally reducing the ratio of wetland to plateau in the modelled sub‐basin. Simulated reductions in permafrost extent decreased total annual discharge from the channel fen by 2.5% for every 10% decrease in permafrost area due to increased surface storage capacity, reduced run‐off efficiency, and increased landscape evapotranspiration. Runoff ratios for the fen hydrological response unit dropped from 0.54 to 0.48 after the simulated 50% permafrost area loss with a substantial reduction of 0.47 to 0.31 during the snowmelt season. The reduction in peat plateau area resulted in decreased seasonal variability in discharge due to changes in the flow path routing, with amplified low flows associated with small increases in subsurface discharge, and decreased peak discharge with large reductions in surface run‐off.  相似文献   

7.
Permian evaporite deposits have been extensively dissolved beneath the perimeter of the Southern High Plains in the Texas Panhandle. Hydrologic and geochemical data were collected from six test wells to determine hydrogeochemical processes involved and the source and flow paths of ground water moving in salt-dissolution zones. Geochemical similarities and hydraulic-head relationships indicate that ground water dissolving halite and anhydrite moves downward from aquifers in post-Permian formations and follows flow paths influenced by topography. Holocene salt-dissolution rates probably are lower than Tertiary and Pleistocene rates owing to regional changes in physiography and climate that probably decreased the amount of recharge to salt-dissolution zones. Present as well as palaeohydrologic ground-water velocities and salt-dissolution rates are probably less beneath the Southern High Plains than in adjacent, peripheral salt-dissolution zones because of lower hydraulic conductivities and lower hydraulic-head gradients. Salinities in peripheral salt-dissolution zones are low (67 000 to 95 000 mg L?1) despite high solubility of halite, reflecting relatively open circulation of ground water. In interior salt-dissolution zones beneath the Southern High Plains, ground-water circulation is low and water composition tends to reach halite saturation.  相似文献   

8.
It is widely accepted that the deposition of mineral facies of evaporite basins is controlled by the average annual relative humidity of the contiguous atmosphere, which dictates the equilibrium activity of the evaporating brine. This concept has far reaching implications in salt works and for the investigation of paleoenvironmental settings affecting depositional sequences within evaporite basins. The above concept, which dominated the scientific thought of evaporite basin investigations, suffers from two serious flaws: (a) the assumption of a static decoupled atmosphere and (b) the total neglect of energy input and thermodynamic feedbacks resulting from evaporation suppression. The present investigation will resolve the underlying mechanisms controlling the equilibrium activity of hypersaline solutions using a theoretical framework that combines energy and mass transport across the surface–atmosphere boundary. Calculations of the equilibrium activity of hypersaline solutions under isothermal conditions, as implied in the original concept, are not in line with the basic physical principles defining heat and mass exchange across the brine–atmosphere boundary and lead to substantial overestimation of actual evaporation and the activity itself. It is demonstrated that in addition to atmospheric relative humidity, the activity of hypersaline solutions is determined by numerous meteorological forcings along with hydrological, geochemical, and thermodynamic feedback mechanisms. Evaporation suppression resulting from a drop in brine activity causes substantial increase in brine temperature, which enhances vapour pressure differential across the interface, leading to more evaporation. This negative feedback shifts the brine activity downward for equilibrium to be attained. It is also demonstrated that evaporation from a brine surface usually proceeds when the relative humidity of the contiguous atmosphere is similar or even higher than that of the brine due to energy input and the strong negative feedback caused by evaporation suppression. The present investigation re‐establishes a new paradigm concerning the processes controlling evaporite basin sedimentation and palaeoclimate reconstruction as deduced from evaporite/hypersaline basin deposits. Findings have operational ramifications in the industrial applications of dissolved salt mineral extraction.  相似文献   

9.
Remote mapping and measurement of surface processes at high spatial resolution is among the frontiers in Earth surface process research. Remote measurements that allow meter‐scale mapping of landforms and quantification of landscape change can revolutionize the study of landscape evolution on human timescales. At Mill Gulch in northern California, USA, an active earthflow was surveyed in 2003 and 2007 by airborne laser swath mapping (ALSM), enabling meter‐scale quantification of landscape change. We calculate four‐year volumetric flux from the earthflow and compare it to long‐term catchment average erosion rates from cosmogenic radionuclide inventories from adjacent watersheds. We also present detailed maps of changing features on the earthflow, from which we can derive velocity estimates and infer dominant process. These measurements rely on proper digital elevation model (DEM) generation and a simple surface‐matching technique to align the multitemporal data in a manner that eliminates systematic error in either dataset. The mean surface elevation of the earthflow and an opposite slope that was directly influenced by the earthflow decreased 14 ± 1 mm/yr from 2003 to 2007. By making the conservative assumption that these features were the dominant contributor of sediment flux from the entire Mill Gulch drainage basin during this time interval, we calculate a minimum catchment‐averaged erosion rate of 0·30 ± 0·02 mm/yr. Analysis of beryllium‐10 (10Be) concentrations in fluvial sand from nearby Russian Gulch and the South Fork Gualala River provide catchment averaged erosion rates of 0·21 ± 0·04 and 0·23 ± 0·03 mm/yr respectively. From translated landscape features, we can infer surface velocities ranging from 0·5 m/yr in the wide upper ‘source’ portion of the flow to 5 m/yr in the narrow middle ‘transport’ portion of the flow. This study re‐affirms the importance of mass wasting processes in the sediment budgets of uplifting weak lithologies. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

10.
Karst collapse sinkholes (KCS) are a peculiar karst morphology resulting from the collapse of the topographic surface caused by subsurface karstification. In the Southern Apennines these phenomena are not randomly distributed but concentrate in several zones, named High Sinkhole Concentration Areas (HSCA), showing peculiar geological, structural and hydrogeological conditions. Gas vents and mineral springs occur widely in these HSCA, and are often stricty related to the KCS. Starting from four representative areas, the aim of this study is to ascertain if there is a genetic link between peculiar mineralogical vs geochemical features of densely fractured/altered rocky masses in KCS, gas vents/springs occurrences and diffuse hypogenic karstification. By means of a multidisciplinary approach (geological/geomorphological, mineralogical and geochemical) we selected and analysed four different kinds of samples related to KCS, gas vent and spring occurrences: (i) altered to deeply altered limestones sampled in the sinkholes; (ii) unaltered limestones sampled in close proximity to sinkhole areas; (iii) gypsum-rich crusts/patinae, precipitated near to gas vents; (iv) gypsum- and calcite-rich precipitates occurring at springs or inside caves. Among neoformed non-carbonate minerals, gypsum is virtually ubiquitous, halides (fluorite, halite, sylvite) also occur in small to trace amounts. The mineralogical assemblages of the different samples show similarities and may also be compatible with hypogenic speleogenesis and with a process of alteration of the carbonate bedrock by means of uprising mineralizing fluids along structural discontinuities. Stable isotopic compositions (S, O) display strong variability in δ34S and δ18O for sulfate in the different areas, but a deep-seated sulfur source can be hypothesized for many of the studied KCS-related samples. This study has important implications for the relationships between areas of high concentration of sinkholes, regional fault systems, mechanical characteristics of rocks and the high seismicity typical of these areas of the Southern Apennines. © 2018 John Wiley & Sons, Ltd.  相似文献   

11.
The unique topography of the pothole region of the North American prairies creates challenges for properly determining basin contributing area. Numerous depressions or potholes within the landscape impound runoff. However, potholes can ‘fill‐spill’ resulting in surface water connections between the potholes. Surface water connectivity between potholes ultimately influences basin contributing area. Currently, automated methods, such as landscape analysis tools, treat depressions in the landscape as artifacts and simply fill the depressions to delineate a drainage basin. Using this method to calculate contributing area assumes that all surface storage has been satisfied (threshold) and the drainage basin will contribute 100% of its area for all runoff events. However, most runoff events in the prairie pothole region are pre‐threshold events that contribute only a portion of surface runoff to the outlet. These pre‐threshold events have surface storage that varies because of antecedent water levels and have a variable or dynamic potential to store further runoff in the basin. Government agencies have developed methodologies for determining pre‐threshold contributing areas, but these methodologies do not incorporate current technologies and, as a result, have limitations. We propose an automated method for determining contributing area that incorporates the fill‐spill of prairie potholes. The algorithm, which uses the D‐8 drainage direction method, automates a methodology for identifying and quantifying runoff contributing area. Any algorithm that determines pre‐threshold contributing area, must allow the DEM to be filled in an incremental manner. This will simulate increasing pond levels, and the resulting decrease in available storage in the basin, in response to runoff events. The SPILL algorithm is an iterative solution that increases the magnitude of input runoff events and records the decreasing change in available surface storage and the increase in contributing area until the storage threshold is reached and the contributing area reaches 100%. Through application of the algorithm on prairie pothole region basins, we test proposed conceptual curves that describe a hypothesized non‐linear relationship between decreasing potential storage in the landscape and contributing area. Results indicate that the proposed conceptual curves represent the relationship between potential surface storage and contributing area in the test basins very well. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

12.
经验方法研究下垫面变化对洪水的影响   总被引：1，自引：1，他引：0  
1980s以来,人类活动对下垫面的影响加剧,研究下垫面变化对流域产汇流规律的影响具有重要意义.通过对海河流域中紫荆关、阜平两个流域分别用经验方法进行洪水模拟演算,并把洪水资料按照年代不同分时段,建立P+Pa～Rs相关关系图,分析流域下垫面变化对降雨径流相关关系的影响.建立产流量R与洪峰Qm之间的相关关系,通过统计比较不同年代的趋势线发现,在产流量相同情况下,1980s后的洪峰流量较1980s前有所减少,说明海河流域的调蓄作用有增强的趋势.同时建立流域下垫面条件改变后产流量与洪峰变化幅度的相关关系,发现流域产流量变化与洪峰变化呈正相关关系.  相似文献   

13.
Gypsum rocks are widely exploited in the world as industrial minerals. The purity of the gypsum rocks (percentage in gypsum mineral in the whole rock) is a critical factor to evaluate the potential exploitability of a gypsum deposit. It is considered than purities higher than 80% in gypsum are required to be economically profitable. Gypsum deposits have been studied with geoelectrical methods; a direct relationship between the electrical resistivity values of the gypsum rocks and its lithological composition has been established, with the presence of lutites being the main controlling factor in the geoelectrical response of the deposit. This phenomenon has been quantified in the present study, by means of a combination of theoretical calculations, laboratory measurements and field data acquisition. Direct modelling has been performed; the data have been inverted to obtain the mean electrical resistivity of the models. The laboratory measurements have been obtained from artificial gypsum-clay mixture pills, and the electrical resistivity has been measured using a simple electrical circuit with direct current power supply. Finally, electrical resistivity tomography data have been acquired in different evaporite Tertiary basins located in North East Spain; the selected gypsum deposits have different gypsum compositions. The geoelectrical response of gypsum rocks has been determined by comparing the resistivity values obtained from theoretical models, laboratory tests and field examples. A geoelectrical classification of gypsum rocks defining three types of gypsum rocks has been elaborated: (a) Pure Gypsum Rocks (>75% of gypsum content), (b) Transitional Gypsum Rocks (75–55%), and (c) Lutites and Gypsum-rich Lutites (<55%). From the economic point of view, the Pure Gypsum Rocks, displaying a resistivity value of >800 ohm.m, can be exploited as industrial rocks. The methodology used could be applied in other geoelectrical rock studies, given that this relationship between the resistive particles embedded within a conductive matrix depends on the connectivity of the matrix particles.  相似文献   

14.
Point of the Mountain spit and Fingerpoint spit are two of the largest geomorphic features of Pleistocene Lake Bonneville of the western Great Basin, USA. The spits and their associated shorelines show distinctly different geomorphic expression and genesis; this is a function of their positions within the lake and the dynamics of the waves and storms that formed them. Mapping of geomorphic features, geometry of erosional features, and detailed lithologic analysis of shoreline deposits are used to determine dominant modes of sediment erosion and deposition. The Point of the Mountain spit, located in the eastern portion of the basin, was formed as a result of highly fractured bedrock in a salient of the Wasatch Front being exposed to wave trains that approached from the north‐northwest causing north‐to‐south longshore sediment transport. Shoreline development and sediment transport on the southern portion of the spit were minimal. The Fingerpoint spit, located on an island in the northwest portion of the basin, was formed by bidirectional longshore sediment transport as the result of waves that approached from both the north‐northeast and the south‐southwest. Spit development is a function of surface wave energy and direction which in turn is the integrated result of wind direction, wind intensity, and fetch. Wave transport direction determined from ?eld measurements at Point of the Mountain spit corresponds very well to the direction of maximum fetch (c. 200 km). For the Fingerpoint spit, the hypothesized wave transport direction from the south corresponds with the direction of maximum fetch (c. 350 km). However, wave energy transport from the north had limited fetch (c. 100 km), implying that wind intensity from the north was relatively large. The geometry of the two large Bonneville spits suggests the predominant wind direction from storms during the Pleistocene was from the north and points the way for future studies that can aid in further understanding the nature of Pleistocene wind ?elds in the Great Basin. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

15.
We document, analyse, and interpret direct and rapid infiltration of precipitation to the southern margin of the Salar de Atacama halite‐hosted brine aquifer during two intense precipitation events in 2012–2013. We present physical, geochemical, and stable and radioactive isotope data to detail this influx of water. The two events differ distinctly in the mechanisms of recharge. The 2012 event did not produce direct precipitation onto the salar surface, while the 2013 event did. Both events are recorded by abrupt changes in head in observation wells along the halite aquifer margin. Spatially distributed water levels rose by over 30 cm during the larger 2013 event consistent with remotely sensed observations of surface water extent. The lithium concentration and stable isotopic composition of water indicate dilution of brine and dissolution of salt with fresh water. Tritium measurements of precipitation, surface water, and groundwater all indicate modern influx of water to the halite aquifer along the southern margin. We extend these observations by examining the response of the halite aquifer as a whole to precipitation events during the period of 2000–2010. This study suggests that local recharge to the aquifer during sporadic precipitation onto the halite nucleus is an important component of the modern water budget in this hyper‐arid environment. The rapid dissolution and salinization along the southern margin of the salar halite nucleus are aided by such precipitation events contributing a modern fresh water component to the water budget of the economically valuable lithium‐rich brine. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

16.
在集水区尺度利用景观生态学的原理进行分析和管理是现代生态学与地理科学的一个重要课题.在人口增长和经济发展的压力下,集水区的格局和过程己受到人类活动越来越强烈地干扰.赛勒支盆地是一个典型的美国太平洋西北部沿海地区的集水区,本文以此为例,研宄了美国俄勒冈州中部集水区尺度的景观格局和过程在人类活动干扰下的时空动态.通过卫星遥感影像的应用,我们对1977年到2000年间赛勒支盆地土地覆盖的变化进行了检测.我们用陆地资源卫星1977年的多光谱影像(MSS), 1988年的专题影像(TM)' 2000年的增强专题影像(ETM+)高精度地定量分析了森林演替系列(如,演替后期的老针叶林和成熟针叶林,演替前期的年轻针叶林,以及更新的幼林）和其它土地覆盖类型的变化.景观的空间格局通过多种格局指数,例如,缀块指数、缀块形状复杂性指数、以及连接指数等进行了分析.同时,基于美国太平洋西北部主要森林类型和其它土地覆盖类型碳通量和碳贮量的空间数据库和文献资料,我们对 1977-2000年赛勒支盆地中的碳库及其在人类活动干扰下的变化作了测定.研宄结果揭示出,因为森林皆伐,老针叶林和成熟针叶林在1977-2000年间显著地减少,分别由占整个盆地土地覆盖面积的23%和12%, 减少为12%和7%;与此相反,年轻针叶林和无林地则分别从24%和5%增加为43%和14%.同时,因为采伐等干扰,留存的老针叶林和成熟针叶林空间分布格局的破碎度也迅速增加.集水区的碳收支在 1977-2000期间发生了巨大的变化.在收获干扰的压力下,在1977-2000年间,整个集水区的生态系统碳贮量从 17640797t 减少到 13405720t;净生态系统生产力(Net Ecosystem Production, NEP)由每年 100462tC 减少为每年76800tC.  相似文献   

17.
Maintaining the quality of surface water resources as one of the most vital water supplies has always been at the center of global concerns. A set of manifest and latent factors have yet been identified by researchers worldwide that are subject to affect the quality of surface water. Among which, the effect of land use change, due to a spatial and temporal complexity, is often not easily verifiable. The present study attempts to offer an index-based model to quantify vulnerability of surface water resources in a semi arid basin in central Iran against land use changes. For this, water quality data including Na, K, Mg, Ca, Sodium Adsorption Ratio (SAR), total anions (Sum. A), SO4, Cl, HCO3, EC, TDS, and pH were collected from hydrometric stations over a period of 26 years (1987?2013). In order to detect land use changes, the land use maps of the years 1987, 1998, 2002, 2009, and 2013 were prepared from TM satellite images using supervised classification method. At next step, changing patterns of different land uses were traced by Shanon’s Diversity Index (SHDI) as a metric of patch diversity indicating diversity and heterogeneity of a landscape over time. Relationship between the SHDI values and water quality indicators revealed the impact of land use changes on quality of surface water resources. Statistical analysis confirmed a significant relationship between nine water quality factors and water discharge in the basin during the study period. From 1998 to 2009, the greatest changes were visible in the total anions, Ca, SO4, and HCO3. These parameters along with salinity were increasing in almost all sub-basins. According to the results, conversion of poor rangelands to rain fed agriculture fields is the most apparent land use change occurred in the study area over the study period. In 1987, SHDI as an indicator of the diversity and changes in the basin, showed a significant relationship with good rangelands (R2 =–0.835). This indicates that fragmentation of the entire watershed area was initiated in 1987, which reached its peak in 2013. Generally speaking, urbanization, poor rangeland, and irrigated agriculture were recognized as three influential land uses adversely affect the water quality in the study area.  相似文献   

18.
ABSTRACT

Recently, the land surface in the Haihe River basin has changed, influencing the flood processes in the basin. To quantify this impact, seven typical sub-catchments were selected from different hydrological regions of the Haihe River basin for study. The non-parametric Mann-Kendall test was used to analyse for trends, and the non-parametric Pettitt test was adopted to detect any change point in the flood time series. Then, a hydrological model was established to simulate the effects of each potential driving factor on flood peak and volume. It was shown that flood peak and volume time series had decreased significantly, and the change point was around the year 1980. Groundwater depletion was not the main contribution to flood peak (FP) and volume (FV) decrease. In the Shifokou, Mubi and Lengkou sub-catchments, small hydraulic structures are the main driving factors for FP and FV decreasing. In the Xitaiyu, Daomaguan and Fuping sub-catchments, both land-use change and hydraulic structures are the main driving factors. The decreasing percentage decreases with the increase of the flood magnitude. The results provide valuable information for flood simulation and control in the Haihe River basin.  相似文献   

19.
Gu A  Gray F  Eastoe CJ  Norman LM  Duarte O  Long A 《Ground water》2008,46(3):502-509
Sulfate (S and O) isotopes used in conjunction with sulfate concentration provide a tracer for ground water contributions to base flow. They are particularly useful in areas where rock sources of contrasting S isotope character are juxtaposed, where water chemistry or H and O isotopes fail to distinguish water sources, and in arid areas where rain water contributions to base flow are minimal. Sonoita Creek basin in southern Arizona, where evaporite and igneous sources of sulfur are commonly juxtaposed, serves as an example. Base flow in Sonoita Creek is a mixture of three ground water sources: A, basin ground water with sulfate resembling that from Permian evaporite; B, ground water from the Patagonia Mountains; and C, ground water associated with Temporal Gulch. B and C contain sulfate like that of acid rock drainage in the region but differ in sulfate content. Source A contributes 50% to 70%, with the remainder equally divided between B and C during the base flow seasons. The proportion of B generally increases downstream. The proportion of A is greatest under drought conditions.  相似文献   

20.
Storage is a fundamental but elusive component of drainage basin function, influencing synchronization between precipitation input and streamflow output and mediating basin sensitivity to climate and land use/land cover (LULC) change. We compare hydrometric and isotopic approaches to estimate indices of dynamic and total basin storage, respectively, and assess inter-basin differences in these indices across the Oak Ridges Moraine (ORM) region of southern Ontario, Canada. Dynamic storage indices for the 20 study basins included the ratio of baseflow to total streamflow (baseflow index BFI), Q 99 flow and flow duration curve (FDC) slope. Ratios of the standard deviation of the streamflow stable isotope signal relative to that of precipitation were determined for each basin from a 1 year bi-weekly sampling program and used as indicators of total storage. Smaller ratios imply longer water travel times, smaller young water fractions (F yw, < ~2–3 months in age) in streamflow and greater basin storage. Ratios were inversely related to BFI and Q 99, and positively related to FDC slope, suggesting longer travel times and smaller F yw for basins with stable baseflow-dominated streamflow regimes. Inter-basin differences in all indices reflected topographic, hydrogeologic and LULC controls on storage, which was greatest in steep, forest-covered headwaters underlain by permeable deposits with thick and relatively uniform unsaturated zones. Nevertheless, differential sensitivity of indices to controls on storage indicates the value of using several indices to capture more completely how basin characteristics influence storage. Regression relationships between storage indices and basin characteristics provided reasonable predictions of aspects of the streamflow regime of test basins in the ORM region. Such relationships and the underlying knowledge of controls on basin storage in this landscape provide the foundation for initial predictions of relative differences in streamflow response to regional changes in climate and LULC.  相似文献   

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