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1.
This paper studies the effect of drought and pumping discharge on groundwater supplies and marine intrusion. The investigation concerns the Mamora coastal aquifer, northwest of Morocco. A large‐scale groundwater model was established to model (a) the amount of freshwater discharge towards the ocean and the sea water volumes flowing inland as a consequence of the inverse hydraulic gradient, (b) the impact of drought and pumping discharge on the water table level and, as a consequence, on marine water intrusion. In fact, the simulated submarine groundwater discharge (SGWD) would decrease from 864 m3/d/km in 1987 to 425 m3/d/km in 2000. The simulated volumes of sea water intruding the aquifer as a result of inverse hydraulic gradient would increase from 0·25 Mm3/y in 1987 to 0·3 Mm3/y in 2000. As a consequence of a negative rainfall gradient of −5 mm/y, the simulated SGWD would decline to 9 m3/d/km and the sea water intrusion (SWI) would increase to 0·35 Mm3/y since the year 2010. Due to insufficient data on the trend of pumping discharge, a hypothetical increase of this latter from 38·3 Mm3/y to 53·2 Mm3/y is simulated to induce an increase of marine water intrusion from 0·25 Mm3/y to 0·9 Mm3/y. Consequently, to optimally exploit this seemingly fragile coastal aquifer, a plan of future actions to implement is proposed. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

2.
This study explores the potential for predicting the spatial variation in subsurface water level change with crop growth stage from satellite data in Thabua Irrigation Project, situated in the northern central region of Thailand. The relationship between subsurface water level change from pumping water to irrigate rice in the dry season and the age of the rice was analysed. The spatial model of subsurface water level change was developed from the classification using greenness or (normalized difference vegetation index NDVI) derived from Landsat 5 Thematic Mapper data. The NDVI of 52 rice fields was employed to assess its relationship to the age of the rice. It was found that NDVI and rice age have a good correlation (R2 = 0·73). The low NDVI values (−0·059 to 0·082) in these fields were related to the young rice stage (0–30 days). NDVI and subsurface water level change were also correlated in this study and found to have a high correlation (Water level change (m day−1) = 0·3442 × NDVI − 0·0372; R2 = 0·96). From this model, the water level change caused by rice at different growth stages was derived. This was used to show the spatial variation of water level change in the project during the 1998–99 dry‐season cropping. This simple method of using NDVI relationships with water level change and crop growth stages proves to be useful in determining the areas prone to excessive lowering of the subsurface water level during the dry season. This could assist in the appropriate planning of the use of subsurface water resources in dry‐season cropping. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

3.
Spatial and temporal variations of the isotopic composition of precipitation over Thailand were investigated. The local meteoric water line for Thailand deviates slightly from the global meteoric water line, with lower slopes (7.62 ± 0.07, 7.59 ± 0.08) and intercepts (6.42 ± 0.39, 6.22 ± 0.42) using ordinary and precipitation weighted methods. Differences in spatial and temporal δ18O distributions between the tropical monsoon and tropical savanna climate zones were found due to differing moisture source contributions and seasonal precipitation patterns. The temporal data reveals that the northeast monsoon rains originate from isotopically-enriched local moisture with isotope values of −9.36 to −0.09‰ (mean − 3.73 ± 0.42‰), whereas the southwest monsoon clouds had a more significant rainout effect from Rayleigh distillation, with isotope values of −9.56 to −1.78‰ (mean − 5.40 ± 0.38‰). The precipitation amount at each site was negatively correlated with δ18O (−0.24 to −3.20‰ per 100 mm, R2 = 0.1–0.9). Furthermore, δ18O was negatively correlated with geography (latitude, altitude) for the southwest monsoon periods, as expected based on other observed correlations. However, an inverse correlation was seen in the northeast monsoon due to differing moisture transportation as part of the continental effect. The correlation coefficient (R) was higher in the southwest monsoon (−0.84 for latitude effect, −0.64 for altitude effect) than the northeast monsoon (0.67 for latitude effect, 0.35 for altitude effect). The spatial pattern of isotopic composition reflects the southwest monsoon more clearly than the northeast monsoon, but the two monsoons also have a cancelling impact on orographic patterns. An agreement of the δ18O and deuterium excess (d-excess) was a negative correlation and found to reflect precipitation sources and re-evaporation processes. The d-excess was slightly higher for the northeast monsoon, bringing moisture from the Pacific Ocean and travelling across the continent before reaching the observed stations. By contrast, the d-excess was relatively lower for the Indian Ocean's moisture in the southwest monsoon.  相似文献   

4.
Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg2+ in catchment runoff. We report the first annual time-series of δ26Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ26Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ26Mg values of throughfall (−0.73‰), but significantly different from the δ26Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ26Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ26Mg values of Mg2+ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ26Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ26Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.  相似文献   

5.
Fish mortality in the middle reaches of the Pilcomayo River (Bolivia), locally called ‘borrachera’, can be observed almost every year at the onset of the rainy season. In order to study the potential causes of the ‘borrachera’, suspended sediment (SS) and selected water quality parameters have been monitored from mid‐September until mid‐December 2010. Gill samples were taken and analysed, before and during the ‘borrachera’ event on December 7th 2010. Data on river discharge were obtained from a database. During the sampling period, the river hydrology changed dramatically. At the day of the ‘borrachera’, heavy rains in upstream reaches of the river catchment changed the river from a quiet stream into a turbulent river with extremely high concentrations of SS (> 100 g l?1). This may be caused by the inundation of the entire riverbed, which causes easily erodible material, left on the riverbanks at the end of the former rainy season, to be transported by the river during the first peak discharges. As concentrations of heavy metals in filtered water samples did not show higher values during the ‘borrachera’, it is concluded that the ‘borrachera’ is unlikely to be caused by heavy metal toxicity. Results showed a strong association between the SS concentration and the ‘borrachera’. Gills of fish collected during the ‘borrachera’ were clogged with sediment to such an extent that oxygen uptake became virtually impossible. High SS concentrations are therefore considered to be the cause of this typical fish mortality phenomenon. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

6.
Quantifying and understanding catchment sediment fluxes is crucial both from a scientific and environmental management perspective. To deepen the understanding of landuse impacts and climate change on sediment load, we explore factors controlling the suspended sediment load formation in the Northern Caucasus during the Anthropocene. We examine how sediment flux of various river basins with different land-use/landcover and glacier cover changes during the 1925–2018 period. Our analysis is based on observed mean annual suspended sediment discharges (SSD, kg s−1) and annual fluxes (SSL, t year−1) from 33 gauging stations of The Federal Service for Hydrometeorology and Environmental Monitoring (Russia). SSL series have been analysed to detect statistically significant changes during the 1925–2018 period. The occurrence of abrupt change points in SSD was investigated using cumulative sum (CUSUM) charts. We found that SSL has decreased by −1.17% per year on average at most gauges. However, the decline was not linear. Several transition years are expected in the region increasing trends from the 1950s and decreasing trends from 1988 to 1994. Correlation analyses showed that variation in SSL trend values is mainly explained by gauging station altitude, differences in landuse (i.e. the fraction of cropland), and catchment area. Nonetheless, more accurate quantifications of SSL trend values and more refined characterizations of the catchments regarding (historical) landuse, soil types/lithology, weather conditions, and topography may reveal other tendencies.  相似文献   

7.
The head velocity of the density current in the convergent and divergent channel is a key parameter for evaluating the extent to which suspended material travels, and for determining the type and distribution of sediment in the water body. This study experimentally evaluated the effects of the reach degree of convergence and divergence on the head velocity of the density current. Experiments were conducted in the flume with 6.0 m long, 0.72 m width and 0.6 m height. The head velocity was measured at three convergent degrees （-8°; -12°; -26°）, at three divergent degrees （8°; 12°; 26°） and two slopes （0.009, 0.016） for various discharges. The measured head velocity of the density current is compared with the head velocity of the density current in the constant cross section channel. Based on non-dimensional and statistical analysis, relations as linear multiple regression are offered for predicting head velocity of the density current in the convergent, divergent and constant cross section channel. Also the results of this research show that for the same slope and discharge, the head velocity of the density current in the convergent and divergent channel are greater and less than the head velocity of the constant cross section, respectively.  相似文献   

8.
Sediment yields were calculated on the ?anks of Merapi and Semeru volcanoes in Java, Indonesia, using two different methods. During the ?rst year following the 22 November 1994 eruption of Merapi, a sediment yield in excess of 1·5 × 105 m3 km?2 yr?1 was calculated in the Boyong River drainage basin, based on the volumes of sediment that were trapped by ?ve check dams. At Semeru, sediment discharges were assessed in the Curah Lengkong River from direct measurements on the lahars in motion and on the most signi?cant stream?ows. The calculated rate of sediment yield during one year of data in 2000 was 2·7 × 105 m3 km?2 yr?1. Sediment yields are dominated by rain‐triggered lahars, which occur every rainy season in several drainage basins of Merapi and Semeru volcanoes, mostly during the rainy season extending from October to April. The return period of lahars carrying sediment in excess of 5 × 105 m3 is about one year in the Curah Lengkong River at Semeru. At Merapi, the volume of sediments transported by a lahar did not exceed 2·8 × 105 m3 in the Boyong River during the rainy season 1994–95. On both volcanoes, the sediments are derived from similar sources: pyroclastic‐?ow/surges deposits, rockfalls from the lava domes, and old material from the riverbed and banks. However, daily explosions of vulcanian type at Semeru provide a more continuous sediment supply than at Merapi. Therefore, sediment yields are larger at Semeru. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

9.
In the Vietnamese Mekong Delta (VMD), water levels at some stations have increased. However, the factors that cause this rise in the VMD have not been identified. We considered four factors that may have contributed to the water level rise: (1) increased runoff from upstream, (2) sea‐level rise, (3) land subsidence, and (4) decrease in flood mitigation function because of construction of high dykes. We analysed daily maximum and minimum water levels, and mean daily water levels from 24 monitoring stations from 1987 to 2006. Using daily and annual water level differences, we classified the delta into two groups: one is dominated by flows from upstream, while the other is tide dominated. We then tested the trends of annual maximum and minimum water levels using the Mann–Kendall test, and identified the slope of the trend using the method of Sen. The areas of dyke construction were estimated using the Enhanced Vegetation Index (EVI) and Land Surface Water Index (LSWI) from the Moderate Resolution Imaging Spectroradiometer (MODIS) data. Results show (1) river inflow has little impact on rising water levels in the VMD, (2) the influence of high dykes on water level rise could not be quantified in this study, and (3) both maximum and minimum water levels significantly increased in the tide‐dominated area. Trend of annual minimum water level can be considered as the sum sea‐level rise and land subsidence. Therefore, we attribute 6.05 mm year?1 (80%) to land subsidence and 1.42 mm year?1 (20%) to sea level rise, indicating that inundations have been severe in the VMD, caused primarily by land subsidence. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

10.
The Kouris catchment is located in the south of the Troodos massif in Cyprus. The hydrology is driven by a Mediterranean climate, a mountainous topography, and a complex distribution of hydrogeological properties resulting from complex geology. To quantify the regional water balance further, a simple method using continuous streamflow records in the River Limnatis (Kouris catchment) was applied to calculate the actual evapotranspiration rate in the dry seasons. It was found that daily cycles of streamflow, recorded by automatic pressure logger, were caused by direct evaporation from the groundwater table and by transpiration of riparian forest. The daily amounts of ‘missing’ streamflow were calculated for the period 30 October–4 November 2001 and were extrapolated to the entire dry season and to the whole Kouris catchment. The actual evapotranspiration rate from the alluvial aquifer of the region is 2·4 ± 0·5 Mm3 for April–September 2001. The validity of the assumptions and the uncertainties in the estimates used in the method are discussed. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

11.
Precisely dated high-resolution speleothems may record past typhoon events, however, the state of the art cave monitoring is a prerequisite to identify suitable stalagmites for the reconstruction of such events. With this motivation, we examined the isotopic composition (δ18O and d-excess values) of rainfall, outside river, cave drip water, and an underground river in the Xianyun cave system, located in southeastern China. Monthly to bi-monthly monitoring of environmental and isotopic conditions was conducted for 1 year, from December 2018 to December 2019, including a typhoon event (August 24, 2019 to August 26, 2019), called Bailu. The δ18O of rainfall samples over the cave and outside river water ranged from −9.7‰ to −1.9‰ and −8.2‰ to −6.3‰, respectively, while the δ18O of Typhoon Bailu rainfall and instantaneous outside river water ranged from −19.6‰ to −6.3‰ and −10.4‰ to −7.7‰, respectively. Typhoon Bailu-induced rainfall showed distinctly negative δ18O values as compared to those of the monthly and bi-monthly rainfall, exhibiting a three-stage inverted U-shaped variation characteristic. Four drip water monitoring sites inside the cave revealed low variations during the studied period with average values of −7.8‰, −8.0‰, −8.0‰, and −8.1‰. However, during the typhoon, the drip water δ18O values exhibited similar characteristic as outside rainfall but with just 0.2‰ negative deviation owing to precipitation amount and drip water source reservoir. The integration of rainfall amount with drip water source reservoir determines the degree to which a typhoon isotopic signature gets diluted during epikarst infiltration. This study provides the first instrumental evidence of typhoon signal in karst system in southeastern China. Our results imply that the δ18O of drip water in Xianyun cave can instantaneously respond to typhoon rainfall. However, the 0.2‰ shift in drip water δ18O is difficult to be recorded by speleothems. We suggest multi-year monitoring to ascertain fully if the stalagmites could be used as paleotyphoon proxy.  相似文献   

12.
朱博渊  徐琪  朱玲玲  李义天 《湖泊科学》2023,35(5):1832-1843
近70年来荆江三口分流持续减少,为分析各历史阶段三口分流变化的驱动因素,根据1955—2021年干支流水文、地形实测资料开展研究,并基于控制变量法识别各驱动因素贡献比例。结果表明:三口分流阶段性减少,且集中在5—11月。长江上游降雨减少导致的干流来流偏枯以及下荆江裁弯、葛洲坝拦沙造成的干流河道冲刷和三口口门淤积对三口分流减少促进作用明显,调弦口堵口对三口分流影响不大,三峡水库蓄水后干流河道与三口口门同步冲刷,三口分流变化不大。长江上游汛期降雨减少明显,对5—11月三口分流减少影响较大,且三口分流主要发生于汛期干流中洪水位时,导致在下荆江裁弯期干流河床大幅下切条件下5—11月分流显著减少;葛洲坝调度、三峡水库初期调度和试验性蓄水调度也集中于5—11月,使得5—11月三口分流量分别减小0.4×108、12.5×108和38.6×108m3。调弦口堵口对三口分流的增大作用远小于降雨的减小作用,贡献比例为负值;下荆江裁弯对三口分流减少的贡献比例达85%;水库运用期降雨对三口分流减少的贡献最大,贡献比例大于50%,葛洲坝调度几乎不...  相似文献   

13.
Soil moisture plays a significant role in land-atmosphere interactions. Changing fractions of latent and sensible heat fluxes caused by soil moisture variations can affect near-surface air temperature, thus influencing the oasis's cooling effect in arid regions. In this study, the framework for the evaporative fraction (EF) dependence on soil moisture is used to analyse the impacts of soil moisture variation on near-surface air temperature and the oasis effect. The result showed that soil moisture's contribution rate to EF was significantly higher than that of EF to temperature. Under the interaction of temperature sensitivity to EF and EF to soil moisture, the ∂T/∂ϴ presented a similar tempo-spatial variation with both of the above. It was most significant in oasis areas during summer (−1.676), while it was weaker in plain desert areas during the autumn (−0.071). In the study region, the effect of soil moisture variation on air temperature can reach 0.018–0.242 K for different land-cover types in summer. The maximum variation of soil moisture in summer can alter air temperature by up to 0.386 K. The difference in temperature variability between the oasis and desert areas promoted the formation of the oasis effect. For different oasis, the multi-year average oasis cold effect index (OCI) ranged from −1.36 to −0.26 K. In comparison, the average summer OCI ranged from −1.38 to −0.29 K. The lower bound of the cooling effect of oasis ranged from −4.97 to −1.69 K. The analysis framework and results of this study will provide a new perspective for further research on the evolution process of the oasis effect and water–heat balance in arid areas.  相似文献   

14.
To detect the causal relationship between cave drip waters and stalagmite laminae, which have been used as a climate change proxy, three drip sites in Beijing Shihua Cave were monitored for discharge and dissolved organic carbon (DOC). Drip discharges and DOC were determined at 0 to 14‐day intervals over the period 2004–2006. Drip discharges show two types of response to surface precipitation variations: (1) a rapid response; and (2) a time‐lagged response. Intra‐annual variability in drip discharge is significantly higher than inter‐annual variability. The content of DOC in all drip waters varies inter‐ and intra‐annually and has good correlation with drip water discharge at the rapid response sites. High DOC was observed in July and August in the three years observed. The flushing of soil organic matter is dependent upon the intensity of rain events. The DOC content of drip water increases sharply above a threshold rainfall intensity (>50 mm d?1) and shows several pulses corresponding with intense rain events (>25 mm d?1). The DOC content was lower and less variable during the dry period than during the rainy period. The shape of DOC peak also varies from year to year as it is influenced by the intensity and frequency of rainfall. The different drip sites show marked differences in DOC response, which are dominated by hydrological behaviour linked to the recharge of the soil and karst micro‐fissure/porosity network. The results explain why not all stalagmite laminae are consistent with climate changes and suggest that the structure of the rainy season events could be preserved in speleothems. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

15.
The simultaneous transfer of pore fluid and vapour was studied in the unsaturated shallow subsurface of a Plio-Pleistocene marine mudstone badland slope in southwestern Taiwan during the dry season using field monitoring data and numerical simulations. Data from field monitoring show mass-basis water contents of ~0.05 to ~0.10 that decrease towards the unsaturated ground surface and were invariant during the middle part of the dry season, except for daily fluctuations. In addition, the observed daily fluctuations in water content correlate with fluctuations in bedrock temperature, especially at depths of 2.5–5.0 cm. Periodic increases in water content occurred most notably during the day, when the bedrock temperature showed the greatest increase. Water contents then decreased to the previous state as bedrock temperature decreased during the night. Calculated vapour fluxes within the mudstone during the day increased up to 6 × 10−6–1 × 10−5 kg m−2 s−1, deriving a 0.01–0.02 increase in mass-basis water content at 2.5 cm depth for a 12-h period. This agrees with field monitoring data, suggesting that increases in water content occurred due to vapour intrusions into the bedrock. Pore water electrical conductivity (EC) showed periodic variations due to vapour intrusion, and gradually increased between the ground surface and depths of 2.5–5.0 cm. In contrast, pore water EC gradually decreased between 15 and 40 cm depth. Calculated water fluxes at depths of 2.5–40.0 cm varied from −4 × 10−6 to −2 × 10−9 kg m−2 s−1. These fluxes generated an increase in solute concentrations at the ground surface, with negative values of water flux indicating an upwards movement of water towards the surface. We show that the increase in solute content due to solute transfer from depth is highly dependent on variations in water flux with depth. © 2020 John Wiley & Sons, Ltd.  相似文献   

16.
Based on field data of river discharge, tide, tidal bore, and riverbed topography, the characteristics of river discharge, the effect of river discharge on riverbed erosion and sedimentation, and the feedback effect of riverbed erosion and sedimentation on the tide and tidal bore in the Qiantang River are analyzed. The results show that the inter-annual and seasonal variation of river discharge in the Qiantang River is noticeable, while the seasonal distribution of river discharge tends to be un...  相似文献   

17.
While 1992 marked the first major dam – Manwan – on the main stem of the Mekong River, the post-2010 era has seen the construction and operationalisation of mega dams such as Xiaowan (started operations in 2010) and Nuozhadu (started operations in 2014) that were much larger than any dams built before. The scale of these projects implies that their operations will likely have significant ecological and hydrological impacts from the Upper Mekong Basin to the Vietnamese Delta and beyond. Historical water level and water discharge data from 1960 to 2020 were analysed to examine the changes to streamflow conditions across three time periods: 1960–1991 (pre-dam), 1992–2009 (growth) and 2010–2020 (mega-dam). At Chiang Saen, the nearest station to the China border, monthly water discharge in the mega-dam period has increased by up to 98% during the dry season and decreased up as much as −35% during the wet season when compared to pre-dam records. Similarly, monthly water levels also rose by up to +1.16 m during the dry season and dropped by up to −1.55 m during the wet season. This pattern of hydrological alterations is observed further downstream to at least Stung Treng (Cambodia) in our study, showing that Mekong streamflow characteristics have shifted substantially in the post-2010 era. In light of such changes, the 2019–2020 drought – the most severe one in the recent history in the Lower Mekong Basin – was a consequent of constructed dams reducing the amount of water during the wet season. This reduction of water was exacerbated by the decreased monsoon precipitation in 2019. Concurrently, the untimely operationalisation of the newly opened Xayaburi dam in Laos coincided with the peak of the 2019–2020 drought and could have aggravated the dry conditions downstream. Thus, the mega-dam era (post-2010) may signal the start of a new normal of wet-season droughts.  相似文献   

18.
Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis (18O, 2H, 3H, 14C, 13C, 34S, 18O-SO4, 87Sr, 37Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with δ18O values (−9.6 to −12.4) similar to local, modern precipitation (−7.4 to −10), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted δ18O values (−16 to −18) relative to local, modern precipitation, and 14C ages 32,000 to more than 47,000 years before present. Sulfate, δ18O, δ2H, δ34S, and δ18O-SO4 concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between 14C and Darcy age estimates indicate that 14C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.  相似文献   

19.
Fluoride (F−) concentration in groundwater can be used as an independent measure of the degradation of per- and polyfluoroalkyl substances (PFAS) at contaminated sites. This study assessed the impact of the groundwater matrix, oxidizing reagents, quenching agent, and sample handling procedures (filtration) on determinations of F−. F− was quantified using a fluoride-selective electrode (FSE) using matrix spike recovery (acceptable range 75 to 125%) and electrode slope performance (ideal range −54 to −60 mV). For the unaltered aqueous matrices considered (ultrapure water, ultrapure water with sodium chloride, and simulated groundwater), matrix spike recoveries were greater than 93% and acceptable electrode slopes (−59.5 ± 0.2 mV) were obtained. Matrix spike recoveries and electrode slopes when persulfate or permanganate was added were 87 and 93%, and −58.4 ± 1.3 and −47.3 ± 2.2 mV, respectively. Therefore, quantifying F− in matrices containing permanganate should involve use of either a matrix-matched calibration curve or the method of standard additions due to the low electrode slope. The addition of ascorbic acid as a quenching agent resulted in a decrease in matrix spike recoveries to <74% and suggests alternate quenching procedures should be used if an FSE is employed to measure F−. Removal of sediments by filtration prior to the addition of the fluoride spike led to improved matrix spike recoveries (>96%), which were otherwise underestimated using the FSE in the presence of sediments. While the FSE may be a quick and portable tool, its significant limitations need to be fully understood before it can be used to quantify the production of F− resulting from the potential degradation of PFAS at field sites.  相似文献   

20.
Elucidation of the fluvial processes influenced by dams provides better understanding of river protection and basin management. However, less attention has been given to the erosion intensity distribution of riverbeds and its association with channel morphology and hydrological conditions. Based on hydrological and topographic data, the spatial and temporal distributions of erosion intensity (2002–2014) influenced by the Three Gorges Dam (TGD) were analyzed for the Jingjiang reach of the Yangtze River. The mechanisms underlying the distribution of erosion intensity in response to hydrological conditions were investigated. The results are as follows: (1) The erosion intensities of different discharges were not uniform, and moderate flow (10 000–27 000 m3/s) produced the largest erosion magnitude among all flow ranges. Owing to the hydrological changes caused by flood reduction and prolongation of moderate flow duration after the TGD began operating, up to 70% of the erosion amount was caused by moderate flows. (2) The lateral distribution of erosion intensity was extremely uneven, as the proportion of cumulative erosion of the low‐flow channel within the bankfull channel reached 88% in 2013. This caused the channel to become narrower and deeper. (3) The longitudinal distribution of erosion intensity was inhomogeneous. The erosion intensity in the wide reaches was greater than that in the narrow reaches, leading to smaller differences in channel morphology along the river. (4) Changes in hydrological conditions influenced by the TGD, significant reduction of sediment concentration along with flood abatement, and increased duration of moderate flow discharges were the main factors affecting erosion distribution in the post‐dam period. Our conclusions can be applied to the Yangtze River as a basis for riverbed change estimations, and river management strategies. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

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