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1.
Cosmogenic exposure dating of moraines during the last two decades has vastly improved knowledge on the timing of glaciation worldwide. Due to a variety of geologic complications, such as moraine degradation, snow cover, bedrock erosion and isotopic inheritance, samples from multiple large boulders (>1–2 m) often lead to the most accurate moraine age assignments. However, in many cases, large boulders are not available on moraines of interest. Here, I test the suitability of pebble collections from moraine crest surfaces as a sample type for exposure dating. Twenty-two 10Be ages from two Pleistocene lateral moraine crests in Pine Creek valley in the upper Arkansas River basin, Colorado, were calculated from both pebble and boulder samples. Ten 10Be ages from a single-crested Bull Lake lateral moraine range between 3 and 72 ka, with no statistical difference between pebble (n = 5) and boulder (n = 5) ages. The lack of a cluster of 10Be ages suggests that moraine degradation has led to anomalously young exposure ages. Twelve 10Be ages from a single-crested Pinedale lateral moraine have a bimodal age distribution; one mode is 22.0 ± 1.4 ka (three boulders, two pebble collections), the other is 15.2 ± 0.9 ka (two boulders, five pebble collections). The interpretation of the two age modes is that two glacier maxima of similar extent were attained during the late Pleistocene. Regardless of moraine age interpretations, that 10Be ages from pebble collections and boulders are indistinguishable on moraines of two different ages, and in two different age modes of the Pinedale moraine, suggests that pebble collections from moraine crests may serve as a suitable sample type in some settings.  相似文献   

2.
This paper highlights potential complications that may arise while using in situ produced 10Be to date exposure or burial events using diagenetic silica (chert). The initiation and evolution of large gravitational collapses in sedimentary rocks were constrained using cosmic ray exposure dating. Because these collapses occurred in a stratigraphic level composed of chert (diagenetic silica) concretions interbedded in limestone layers, their development was studied by performing in situ-produced 36Cl and 10Be concentration measurements in both the limestone and coexisting diagenetic silica (chert), respectively. Following the routinely used decontamination and preparation protocols for 10Be produced in diagenetic silica, large discrepancies were observed with exposure ages determined by 36Cl within carbonate for samples originating from the same scarp. While 36Cl exposure ages were clustered as expected for a unique single gravitational event, 10Be exposure ages were scattered along the same studied scarps. To determine the origin of such a bias, petrological investigations were carried out for chert (diagenetic silica). Thin sections highlighted a complex mineralogical texture characterized by remnant silicified ooids showing calcitic cores, calcite inclusions and a dominant amorphous hydrated silica (grain > 20 μm). To decipher and characterize the potential origins of the excess measured 10Be within diagenetic silica, all samples were first reprocessed following the routine decontamination protocol (HCL–H2SiF6 leachings and three partial HF dissolutions) but starting from three different grain size fractions (GS1: 1000–500, GS2: 500–250 and GS3: 250–50 μm). The resulting concentrations clearly showed a decreasing 10Be content as a function of the grain size, but still yielded 10Be exposure ages significantly higher than 36Cl counterparts. Because potential adsorption of 10Be at the surface of amorphous silica grains was suspected, partial dissolution steps following by a leaching step in hydroxylamine were investigated. Finally, it seems that an additional leaching in KOH allowed removal of the amorphous silica phase and the measured 10Be concentrations yielded 10Be exposure ages agreeing within uncertainties with the 36Cl ones. This work suggests that measuring in situ produced 10Be within chert (amongst other types of diagenetic silica, e.g. flint, hornstone, jasper, etc.) containing amorphous silica requires caution.  相似文献   

3.
A sequential chemical extraction procedure was developed and tested to investigate the utility of meteoric 10Be as a tracer for authigenic mineral formation beneath the East Antarctic Ice Sheet. Subglacial meltwater is widely available under the Antarctic Ice Sheet and dissolved gases within it have the potential to drive chemical weathering processes in the subglacial environment. Meteoric 10Be is a cosmogenic nuclide with a half-life of 1.39·106 years that is incorporated into glacier ice, therefore its abundance in the subglacial environment in Antarctica is meltwater dependent. It is known to adsorb to fine-grained particles in aqueous solution, precipitate with amorphous oxides/hydroxides, and/or be incorporated into authigenic clay minerals during chemical weathering. The presence of 10Be in chemical weathering products derived from beneath the ice therefore indicates chemical weathering processes in the subglacial environment. Freshly emerging subglacial sediments from the Mt. Achernar blue ice moraine were subject to chemical extractions where these weathering phases were isolated and 10Be concentrations therein quantified. Optimization of the phase isolation was developed by examining the effects of each extraction on the sample mineralogy and chemical composition. Experiments on 10Be desorption revealed that pH 3.2–3.5 was optimal for the extraction of adsorbed 10Be. Vigorous disaggregation of the samples before grain size separations and acid extractions is crucial due to the incorporation of the nuclide in clay minerals and its preferential absorption to clay-sized particles. 10Be concentrations of 2–22·107 atoms·g−1 measured in oxides and clay minerals in freshly emerging sediments strongly indicate subglacial chemical weathering in the catchment of the Mt. Achernar moraine. Based on total 10Be sample concentrations, local basal melt rates, and 10Be ice concentrations, sediment-meltwater contact in the subglacial environment is on the order of thousands of years per gram of underlying fine sediment. Strong correlation (R = 0.97) between 10Be and smectite abundance in the sediments supports authigenic clay formation in the subglacial environment. This suggests meteoric 10Be is a useful tool to characterize subglacial geochemical weathering processes under the Antarctic Ice Sheet.  相似文献   

4.
Cosmogenic nuclides in river sediment have been used to quantify catchment-mean erosion rates. Nevertheless, variable differences in 10Be concentrations according to grain size have been reported. We analyzed these differences in eleven catchments on the western side of the Andes, covering contrasting climates and slopes. The data include eight sand (0.5–1 mm) and gravel (1–3 cm) pairs and twelve sand (0.5–1 mm) and pebble (5–10 cm) pairs. The difference observed in three pairs can be explained by a difference in the provenance of the sand and coarser sediment. The other sand–pebble pairs show a lower 10Be concentration in the pebbles, except for one pair that shows similar concentrations. Two sand–gravel pairs show a lower 10Be concentration in the gravel and the other five pairs show a higher 10Be concentration in the gravel. Differences in climate do not reveal a particular influence on the 10Be concentration between pairs. The analysis supports a model where pebbles and gravel are mainly derived from catchment areas that are eroding at a faster rate. The five gravel samples with high 10Be concentrations probably contain gravel that were derived from the abrasion of cobbles exhumed at high elevations. In order to validate this model, further work should test if pebbles are preferentially exhumed from high erosion rate areas, and if the difference between pebbles with high 10Be concentrations and sand decreases when the erosion rate tends to be homogeneous within a catchment.  相似文献   

5.
Extreme erosion events can produce large short-term sediment fluxes. Such events complicate erosion rates estimated from cosmogenic nuclide concentrations in river sediment by providing sediment with a concentration different from the long-term basin average. We present a detrital 10Be study in southern Taiwan, with multiple samples obtained in a time sequence bracketing the 2009 Typhoon Morakot, to assess the impact of landslide sediment on 10Be concentrations (N10Be) in river sediment. Sediment samples were collected from 13 major basins, two or three times over the last decade, to observe the temporal variation of N10Be. Landslide inventories with time intervals of 5–6 years were used to quantify sediment flux changes. A negative correlation between N10Be and landslide areal density indicates dilution of N10Be by landslide sediment. Denudation rates estimated from the diluted N10Be can be up to three times higher than the lowest rate derived from the same basins. Observed increases imply that, 3 years after the passage of Typhoon Morakot, fluvial channels still contain a considerable amount of sediment provided by hillslope landslides during the event. However, higher N10Be in 2016 samples indicate that the contribution from landslide sediment at the sampled grain size has decreased with time. The correlation between changes in N10Be and landslide area and volume is not strong, likely resulting from the stochastic and complex nature of sediment transport. To simultaneously evaluate the volume of landslide-derived sediment and estimate the background denudation rate, associated with less impulsive sediment supply, we constructed a sediment-mixing model with the time series of N10Be and landslide inventories. The spatial pattern of background erosion rate in southern Taiwan is consistent with the regional tectonic framework, indicating that the landscape is evolving mainly in response to the tectonic forcing, and this signal is modified, but not obscured by impulsive sediment supply. © 2019 John Wiley & Sons, Ltd.  相似文献   

6.
In situ cosmogenic nuclides are an important tool for quantifying landscape evolution and dating fossil-bearing deposits in the Cradle of Humankind (CoH), South Africa. This technique mainly employs cosmogenic 10-Beryllium (10Be) in river sediments to estimate denudation rates and the ratio of 26-Aluminium (26Al) to 10Be (26Al/10Be), to constrain ages of sediment burial. Here, we use 10Be and 26Al concentrations in bedrock and soil above the Rising Star Cave (the discovery site of Homo naledi) to constrain the denudation rate and the exposure history of soil on the surface. Apparent 10Be-derived denudation rates obtained from pebble- to cobble-sized clasts and coarse-sand in soil (on average 3.59 ± 0.27 m/Ma and 3.05 ± 0.25 m/Ma, respectively) are 2-3 times lower than the bedrock denudation rates (on average 9.46 ± 0.68 m/Ma). In addition, soil samples yield an average 26Al/10Be ratio (5.12 ± 0.27) that is significantly lower than the surface production ratio of 6.75, which suggests complex exposure histories. These results are consistent with prolonged surface residence of up to 1.5 Ma in vertically mixed soils that are up to 3 m thick. We conclude that the 10Be concentrations accumulated in soils during the long near-surface residence times can potentially cause underestimation of single-nuclide (10Be) catchment-wide denudation rates in the CoH. Further, burial ages of cave sediment samples that consist of an amalgamation of sand-size quartz grains could be overestimated if a pre-burial 26Al/10Be ratio calculated from the surface production is assumed. © 2019 John Wiley & Sons, Ltd.  相似文献   

7.
A simple model for reconstructing the paleomagnetic field intensity with 10Be production rate was used for the first time in Loess 10Be studies of Luochuan profile. Using the LGM (Last Glacial Maxmium) method, the climatic effects and geomagnetic modulation effects on loess 10Be was separated and in turn the 80 ka geomagnetic excursion sequence reconstructed, of which the globally remarkable geomagnetic excursion events such as the Laschamp (42 ka), Mono Lake (32 ka) during the Last Glacial period were revealed and the paleo-geomagnetic intensity curve from Loess 10Be over the past 80 ka was quantitatively reconstructed. The reconstructed paleo-intensity fits well with the paleo-intensity curves (SINT200 and NAPIS75), which indicates the significance of global criterion of the 10Be paleo-intensity curve and the future direction of loess 10Be tracing studies. Results show the irregular variability of the East Asian monsoon precipitation in Loess Plateau is the main cause that has resulted in the ambiguity of the geomagnetic modulation of the 10Be record in the loess, and the intrinsic source component of the loess 10Be and inherited fraction of magnetic susceptibility (SUS) are characterized by the “quasi-homogeneous distribution” manner. Supported by the Key Innovation Project of the Chinese Academy of Sciences (Grant No. KZCX2-YW-118), the National Natural Science Foundation of China (Grant Nos: 40531003, 40121303, 40523002) and State Key Laboratory of Loess and Quaternary Geology in the Institute of Earth Environment of Chinese Academy of Sciences (Grant No. SKLLQG0712)  相似文献   

8.
We have measured the concentration of the cosmogenic isotope10Be in soil samples from various horizons at six sites, including three independently dated Rappahannock River terraces and a previously undated Piedmont soil to which we have assigned an age. All of the incident10Be can be accounted for in one of these soils and a second is within a factor of two. In three soils, whose concentrations vary widely with depth, a significant fraction of the incident10Be cannot be accounted for. Incomplete sampling, and enhanced Be mobility caused by organic components, are the probable reasons for the low inventory of Be from these three soils. Overall, the data from these six sites indicate that10Be accumulation could be used to assign ages to soils if Be is not mobilized and lost from the soil profile.  相似文献   

9.
Meteoric 10Be, due to its high affinity with soil and sediment particles, is widely used in geomorphologic and environmental studies attempting to evaluate the soil production/denudation rates or soil ages up to 107 years. However, the evolution of the 10Be distribution as a function of depth is poorly known in soils as revealed by recent reviews (Graly et al., 2010; Willenbring and von Blanckenburg, 2010). In this study, 10Be concentrations in the bulk and the 0–2 μm (lutum) granulometric fraction of samples along Luvisols profiles developed from loess in Northern France have been measured. The bulk 10Be concentrations are significantly higher in one of the three sites, likely reflecting differences in the inherited 10Be concentrations of the loess parent material as well as in the accumulation rates of the later. However, the bulk 10Be concentrations along all profiles are significantly correlated with the lutum (0–2 μm fraction) content, the maximum 10Be concentrations being evidenced in the Bt-horizon. Dominant adsorption of 10Be to the lutum has been furthermore corroborated by the mass-balance calculations with as much as 79.8 ± 9.0% of 10Be being associated with the lutum. Contrary to the bulk 10Be concentrations, the lutum 10Be concentrations showed several maxima coinciding with shifts in the coarse to fine silt ratio. This was interpreted as a change in the loess deposit dynamic. Finally, using numerical modeling approach based on the advection-diffusion equation, an average downward migration of 10Be by clay translocation was estimated. It ranges from 0.01 to 0.08 cm yr−1. Inherited 10Be in the loess parent material represented from 64 to 71% of the total 10Be content in the simulated soils. Vertical 10Be distributions and their maximum concentrations in the Bt-horizon thus mainly result from redistribution of the inherited 10Be by clay translocation and bioturbation.  相似文献   

10.
Cosmogenic 7Be is a natural tracer of short‐term hydrological processes, but its distribution in upland fluvial environments over different temporal and spatial scales has not been well described. We measured 7Be in 450 sediment samples collected from perennial channels draining the middle of the Connecticut River Basin, an environment that is predominantly well‐sorted sand. By sampling tributaries that have natural and managed fluctuations in discharge, we find that the 7Be activity in thalweg sediments is not necessarily limited by the supply of new or fine‐grained sediment, but is controlled seasonally by atmospheric flux variations and the magnitude and frequency of bed mobilizing events. In late winter, 7Be concentrations in transitional bedload are lowest, typically 1 to 3 Bq kg?1 as 7Be is lost from watersheds via radioactive decay in the snowpack. In mid‐summer, however, 7Be concentrations are at least twice as high because of increased convective storm activity which delivers high 7Be fluxes directly to the fluvial system. A mixed layer of sediment at least 8 cm thick is maintained for months in channels during persistent low rainfall and flow conditions, indicating that stationary sediments can be recharged with 7Be. However, bed mobilizing rain on snowmelt events in late Spring can ‘reset’ 7Be amounts and concentrations in the channel as previously buried ‘old’ sediment with low 7Be is mixed into the thalweg. We conclude that given proper temporal and spatial sampling, 7Be is a valuable tracer of seasonal‐timescale mass transport and exchange in coarse‐grained fluvial systems. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

11.
Episodic flood delivery provides the bulk of the solid discharge for many small to moderate river systems, including the Rhône River in the northwestern Mediterranean. Several recent studies have demonstrated that the fate of this sediment depends on the coherence between river discharge and energetic ocean conditions. The deposition of flood sediment in the ocean can be confirmed by common signatures of episodic discharge events: presence of 7Be, physical stratification, and elevated clay content associated with low 210Pb activities.  相似文献   

12.
Cosmogenic nuclide dating of glacial landforms may lead to ambiguous results for ice retreat histories. The persistence of significant cosmogenic concentrations inherited from previous exposure may increase the apparent exposure ages for polished bedrocks affected by limited erosion under ice and for erratic boulders transported by glaciers and previously exposed in high-altitude rock walls. In contrast, transient burying by moraines, sediments and snow decreases the apparent exposure age. We propose a new sampling strategy, applied to four sites distributed in the Arc and Arve valleys in the Western Alps, to better constrain the factors that can bias exposure ages associated with glacial processes. We used the terrestrial cosmogenic nuclide 10Be (TCN) to estimate the exposure time from paired sampling of depth profiles in polished bedrock and on overlying erratic boulders. For a given sampling site, the exposure ages for both the polished bedrock and boulder are expected to be the same. However, in six cases out of seven, boulders had significantly higher 10Be surface concentrations than those of the associated polished surfaces. In present and past glacial processes, the 10Be distribution with depth for boulders and bedrocks implies the presence of an inheritance concentration of 10Be. Our study suggests that 10Be concentrations in erratic boulders and in polished bedrocks provide maximum and minimum exposure ages of the glacial retreat, respectively. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

13.
In 2001, a small H4 chondrite, Frontier Mountain (FRO) 01149, was found on a glacially eroded surface near the top of Frontier Mountain, Antarctica, about 600 m above the present ice level. The metal and sulphides are almost completely oxidized due to terrestrial weathering. We used a chemical leaching procedure to remove weathering products, which contained atmospheric 10Be and 36Cl in a ratio similar to that found in Antarctic ice. The FRO 01149 meteorite has a terrestrial age of 3.0 ± 0.3 Myr based on the concentrations of the cosmogenic radionuclides 10Be, 26Al and 36Cl. This age implies that FRO 01149 is the oldest stony meteorite (fossil meteorites excluded) discovered on Earth. The noble gas cosmic ray exposure age of FRO 01149 is ~ 30 Myr. The meteorite thus belongs to the 33 Myr exposure age peak of H-chondrites.The bedrock surface on which FRO 01149 was found has wet-based glacial erosional features recording a former high-stand of the East Antarctic ice sheet. This ice sheet evidently overrode the highest peaks (> 2800 m a.s.l.) of the inland sector of the Transantarctic Mountains in northern Victoria Land. We argue that FRO 01149 was a local fall and that its survival on a glacially eroded bedrock surface constrains the age of the last overriding event to be older than ~ 3 Myr. The concentrations of in-situ produced cosmogenic 10Be, 26Al and 21Ne in a glacially eroded bedrock sample taken from near the summit of Frontier Mountain yield a surface exposure age of 4.4 Myr and indicate that the bedrock was covered by several meters of snow. The exposure age is also consistent with bedrock exposure ages of other summit plateaus in northern Victoria Land.  相似文献   

14.
The major uncertainty in relating cosmogenic-nuclide exposure ages to ages measured by other dating methods comes from extrapolating nuclide production rates measured at globally scattered calibration sites to the sites of unknown age that are to be dated. This uncertainty can be reduced by locating production rate calibration sites that are similar in location and age to the sites to be dated. We use this strategy to reconcile exposure age and radiocarbon deglaciation chronologies for northeastern North America by compiling 10Be production rate calibration measurements from independently dated late-glacial and early Holocene ice-marginal landforms in this region. 10Be production rates measured at these sites are 6–12% lower than predicted by the commonly accepted global 10Be calibration data set used with any published production rate scaling scheme. In addition, the regional calibration data set shows significantly less internal scatter than the global calibration data set. Thus, this calibration data set can be used to improve both the precision and accuracy of exposure dating of regional late-glacial events. For example, if the global calibration data set is used to calculate exposure ages, the exposure-age deglaciation chronology for central New England is inconsistent with the deglaciation chronology inferred from radiocarbon dating and varve stratigraphy. We show that using the regional data set instead makes the exposure age and radiocarbon chronologies consistent. This increases confidence in correlating exposure ages of ice-marginal landforms in northeastern North America with glacial and climate events dated by other means.  相似文献   

15.
A combination of numerical analysis and 10Be concentrations measured in sediment samples from the high‐relief Torrente catchment, southern Spain, allows us to investigate the sampling requirements for determining erosion rates using cosmogenic nuclides in high‐relief, landslide‐dominated terrain. We use simple modelling to quantify the effect of particle spalling and/or landsliding on erosion rates determined using a cosmogenic in‐situ produced isotope. Analytical results show that the cosmogenic nuclide concentration of a surface experiencing regular detachment of a grain or block may be considered to be in steady state, and ‘in‐situ’ erosion rates estimated, when an appropriate number of spatially independent samples are amalgamated. We present equations that enable calculation of the number of bedrock samples that must be amalgamated for the estimation of mean erosion rates on an outcrop experiencing regular detachment of a grain or chip of thickness L every T years. Our findings confirm that mean catchment erosion rates may be reliably estimated from 10Be concentrations in fluvial sediment in high‐relief rapidly eroding terrain. These catchment‐wide integrated erosion rates can be calculated where erosion is primarily accomplished through shallow (<3 m) spalling processes; where deep‐seated (>3 m) landslides are the dominant mode of erosion only minimum erosion rates can be determined. Lastly, we present erosion rate measurements from the Torrente catchment that reveal variation of two orders of magnitude (0·03–1·6 m ka?1) quantifying the high degree of spatial variation in erosion rates expected within rapidly uplifting catchments. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

16.
We use cosmogenic 10Be and 26Al in both bedrock and fluvial sediments to investigate controls on erosion rates and sediment supply to river basins at the regional scale in the Kimberley, NW Australia. The area is characterised by lithologically controlled morphologies such as cuestas, isolated mesas and extensive plateaus made of slightly dipping, extensively jointed sandstones. All sampled bedrock surfaces at plateau tops, ridgelines, and in the broader floodplain of major rivers over the region show similar slow lowering rates between 0.17 and 4.88 m.Myr-1, with a mean value of 1.0 ± 0.6 m.Myr-1 (n=15), whilst two bedrock samples collected directly within river-beds record rates that are one to two orders of magnitude higher (14.4 ± 1.5 and 20.9 ± 2.5 m.Myr-1, respectively). Bedrock 26Al/10Be ratios are all compatible with simple, continuous sub-aerial exposure histories. Modern river sediment yield lower 10Be and 26Al concentrations, apparent 10Be basin-wide denudation rates ranging between 1.8 and 7.7 m.Myr-1, with a median value of 2.6 m.Myr-1, more than double the magnitude of bedrock erosion rates. 26Al/10Be ratios of the sediment samples are lower than those obtained for bedrock samples. We propose that these depleted 26Al/10Be ratios can largely be explained by the supply of sediment to river basins from the slab fragmentation and chemical weathering of channel gorge walls and plateau escarpments that result in diluting the cosmogenic nuclide concentration in river sediments measured at the basin outlets. The results of a mass-balance model suggest that ~60–90% of river sediment in the Kimberley results from the breakdown and chemical weathering of retreating vertical sandstone rock-walls in contrast to sediment generated by bedrock weathering and erosion on the plateau tops. This study emphasises the value of analysing two or more isotopes in basin-scale studies using cosmogenic nuclides, especially in slowly eroding post-orogenic settings. © 2019 John Wiley & Sons, Ltd.  相似文献   

17.
We present a sensitivity analysis of the isochron approach of Goehring et al. (2013) for paired measurements of in situ 14C/10Be from glacially sculpted bedrock surfaces. This analysis tests how sensitive the resulting exposure durations from this technique are to both the number of samples analyzed and their locations along a glacial trough transect, using a dataset from Goehring et al. (2011) as a test case. A simple equally weighted combinatorial approach was employed to (1) generate non-repetitive combinations of n subsets of samples arranged from the ten possible samples (where n < 10), and (2) estimate the exposure duration and uncertainty for each set of simulations. Results from the Goehring et al. (2011) data indicate that five samples evenly distributed along a transect parallel to the ice margin are the minimum number of samples required for this method, while eight or more samples provide an optimal combination of accuracy and precision at the 1σ level. These findings should be applicable to paired in situ 14C/10Be measurements from other polished bedrock troughs at glacial margins, but need further experimental confirmation.  相似文献   

18.
The influx of10Be into a globigerinid ooze core (CH72-02) from the eastern North Atlantic has been studied. This core contains a depositional record of the first 11 δ18O stages covering the last 423 ka. It is shown that the marine deposition of10Be is strongly influenced by the sedimentation of clays. Clay particles appear 10 times more efficient than the carbonate component as a carrier in bringing10Be to the bottom sediments. In core CH72-02, the deposition rates of10Be averaged over each oxygen-isotope stage for the past 11 stages show a scatter of ±40% about the mean value of 6.6 × 108 atoms cm−2 ka−1. However, after correction for changes in lithology, the data show that the production rate of10Be over the same period has varied no more than ±25%, and the variations are not systematic in that high or low10Be production appear to be associated with either cold or warm climates. On the time scale of this investigation (intervals of ca. 50 ka over the last 420 ka, with resolutions as fine as 10 ka for portions of the record), it is unlikely that the shielding effect of the solar wind has deviated by more than ±25% or the geomagnetic field intensity has deviated by more than a factor of 1.6 from their long-term averages.  相似文献   

19.
We report concentrations of cosmogenic 10Be and 36Cl used to determine erosion depths in the recently deglaciated bedrock at Goldbergkees in the Eastern Alps. The glacier covered the sampling sites during the Little Ice Age (LIA) until c. 1940. The youngest ages calculated from these concentrations match the known exposure time after the post‐LIA exposure of <100 years. The apparent age (no cover, no erosion) of most samples, however, is significantly older. We show that the measured nuclide concentrations represent subglacial erosion depths, rather than exposure times. In particular, erosion depths calculated using 10Be and 36Cl concentrations of individual samples match well, whereas apparent 36Cl ages are consistently older than 10Be ages. The bedrock at the ‘youngest’ surfaces was deeply eroded (≥ 297 cm) by the Goldbergkees during the late Holocene. In contrast, bedrock at the margin of the LIA ice extent was eroded ≤35 cm. These values convert to subglacial erosion rates on the order of 0.1 mm/a to >5 mm/a. While modeled erosion rates depend on the duration of glacial cover and erosion intrinsic to the different exposure scenarios used for calculation (700–3300 years), modeled total erosion depths are insensitive (5–20% change). Analysis of erosion depths on the transverse valley profile shows a general trend of greatest erosion part way up the valley side and less erosion under thin ice at the lateral margin. A second profile along the valley axis indicates depth of erosion is greatest where the ice abuts the foot of the investigated bedrock riegel and at its lee side just beyond the crest. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

20.
Uptake of atmospheric CO2 during sample collection and analysis, and consequent lowering of estimated ages, has rarely been considered in radiocarbon dating of groundwater. Using field and laboratory experiments, we show that atmospheric CO2 can be easily and rapidly absorbed in hyperalkaline solutions used for the extraction of dissolved inorganic carbon, resulting in elevated 14C measurements. Kinetic isotope fractionation during atmospheric CO2 uptake may also result in decrease of δ13C, leading to insufficient corrections for addition of dead carbon by geochemical processes. Consequently, measured 14C values of groundwater should not be used for age estimation without corresponding δ13C values, and historical 14C data in the range of 1 to 10% modern Carbon should be re‐evaluated to ensure that samples with atmospheric contamination are recognized appropriately. We recommend that samples for 14C analysis should be collected and processed in the field and the laboratory without exposure to the atmosphere. These precautions are considered necessary even if 14C measurements are made with an accelerator mass spectrometer.  相似文献   

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