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1.
《Marine pollution bulletin》2009,58(6-12):767-774
The occurrence and phase distribution of polycyclic aromatic hydrocarbons (PAHs) in waters at the eight riverine outlets of the Pearl River Delta (China) were examined based on a monthly sampling program from March 2005 to February 2006. The total concentrations of PAHs in the aqueous phase and suspended particulate matter (SPM) combined ranged from 55.5 to 522 ng/L, at the mid level of the global values in rivers and estuaries. No clear temporal and spatial trends of PAH concentrations were found. However, the concentrations of PAHs associated with SPM coincided with the monthly precipitation of Guangzhou, indicating the importance of atmospheric deposition. The PAHs found in the region were likely derived from a combined pyrolytic and petrogenic origin, as suggested by the molecular indices of PAHs. Normalized partition coefficient (Koc) between water and SPM was correlated with octanol–water partition coefficient (Kow) to understand the environmental behavior of PAHs.  相似文献   

2.
Polycyclic aromatic hydrocarbons (PAHs) were detected in water and sediment samples collected from three mariculture zones in China’s northern Yellow Sea. In these samples, total PAH concentrations ranged from 110.8 ng/L to 997.2 ng/L and 142.2 ng/g dry weight (dw) to 750.2 ng/g dw, respectively. The log KOC values of the various PAH compounds examined in this study increased with the log KOW values, which is consistent with the prediction regarding PAH behavior in the environment. However, these KOC values were lower than the predicted values as a result of the effects of organic matters, which were abundant in the mariculture water. The isomeric ratios of the PAHs in sediment indicated that the source of the PAHs in the mariculture zones were mainly pyrolytic. The TEQcarc values of PAHs ranged from 7 ng TEQ/g dw to 92 ng TEQ/g dw, and only a few samples met the safe criterion with respect to individual PAH concentrations.  相似文献   

3.
The distribution of polycyclic aromatic hydrocarbons (PAHs) between various phases is fundamental in the control of their movement and impact in the marine environment. In this study samples of water and sediments were regularly collected from Brighton marina, UK, to quantify the intensity, spatial and temporal variations of PAH contamination. The results show clearly that PAH behaviour in marine systems is highly complex, and controlled by the interplay of PAH sources, compound physicochemical properties, water and sediment movement, and field conditions. Levels of total PAHs (16 compounds) in the dissolved phase were found to vary between <2 and 11,400 ng/l, with higher values observed in the winter months. Total PAH concentration in sediment samples varied between 24 and 4710 ng/g dry weight. PAHs in water were dominated by low molecular mass compounds (2-ring), while PAHs in sediments were mainly derived from 2-4 ring compounds. In addition, dissolved concentrations were increased during sediment dredging and after a period of severe rainfall. PAHs in Brighton marina are likely to be from both pyrolytic and petrogenic sources; as a result, field-derived distribution coefficients for individual PAHs between sediment and water tend to follow the equilibrium partition models, although slight exceedance is apparent. The extended partition model incorporating soot carbon has achieved limited success in better predicting PAH behaviour.  相似文献   

4.
A modified Jarvis–Stewart model of canopy transpiration (Ec) was tested over five ecosystems differing in climate, soil type and species composition. The aims of this study were to investigate the model's applicability over multiple ecosystems; to determine whether the number of model parameters could be reduced by assuming that site‐specific responses of Ec to solar radiation, vapour pressure deficit and soil moisture content vary little between sites; and to examine convergence of behaviour of canopy water‐use across multiple sites. This was accomplished by the following: (i) calibrating the model for each site to determine a set of site‐specific (SS) parameters, and (ii) calibrating the model for all sites simultaneously to determine a set of combined sites (CS) parameters. The performance of both models was compared with measured Ec data and a statistical benchmark using an artificial neural network (ANN). Both the CS and SS models performed well, explaining hourly and daily variation in Ec. The SS model produced slightly better model statistics [R2 = 0.75–0.91; model efficiency (ME) = 0.53–0.81; root mean square error (RMSE) = 0.0015–0.0280 mm h‐1] than the CS model (R2 = 0.68–0.87; ME = 0.45–0.72; RMSE = 0.0023–0.0164 mm h‐1). Both were highly comparable with the ANN (R2 = 0.77–0.90; ME = 0.58–0.80; RMSE = 0.0007–0.0122 mm h‐1). These results indicate that the response of canopy water‐use to abiotic drivers displayed significant convergence across sites, but the absolute magnitude of Ec was site specific. Period totals estimated with the modified Jarvis–Stewart model provided close approximations of observed totals, demonstrating the effectiveness of this model as a tool aiding water resource management. Analysis of the measured diel patterns of water use revealed significant nocturnal transpiration (9–18% of total water use by the canopy), but no Jarvis–Stewart formulations are able to capture this because of the dependence of water‐use on solar radiation, which is zero at night. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

5.
The fate and transport of highly hydrophobic chemicals are affected by the partitioning between water and dissolved organic carbon. Large variation in the partition coefficient (KDOCw) is often found, due to the selection of model organic matter or potential experimental artifacts. To investigate the roles of the type of organic matter on the partitioning of highly hydrophobic compounds, the partition coefficients of eight selected polycyclic aromatic hydrocarbons (PAHs), with 3–6 aromatic rings, were determined using a passive dosing/extraction method between water and model dissolved organic matter (humic acid, fulvic acid, sodium dodecyl sulfate micelle (SDS), and 2‐hydroxypropyl‐β‐cyclodextrin). Although the KDOCw values for 3–4 ring PAHs in this study were close to those reported in the literature, experimental KDOCw values between Aldrich humic acid (AHA) and water were higher than values reported in the literature for 5–6 ring PAHs. The KDOCw values were highest for AHA, followed by SDS and Suwannee river fulvic acid (SFA). The slopes of the linear regression between log KDOCw and log Kow were 1.23 (± 0.13), 0.82 (± 0.09), and 0.59 (± 0.13) for AHA, SDS, and SFA, respectively. The differences in the KDOCw values between AHA and the other organic matter (SDS, SFA, and CD) increased with increasing hydrophobicity of the PAHs, showing that the sorption of highly hydrophobic chemicals to the humic acid fraction may be important in the presence of mixed organic matter.  相似文献   

6.
《Marine pollution bulletin》2012,64(5-12):459-463
Seawater samples (including surface water and bottom water) were collected from the Western Taiwan Strait (WTS) during June 24–25, 2009; polycyclic aromatic hydrocarbons (PAHs) in dissolved phase and particulate phase were analyzed, respectively. The results showed that the total concentrations of PAHs in the dissolved phase and particulate phase were ranged from 12.3 to 58.0 ng L−1, and 10.3–45.5 ng L−1, which showed a low-middle contamination level in the China Seas. The spatial variability of PAHs may be related to the complicated currents of WTS, especially the Min-Zhe coastal current. PAHs diagnostic ratios suggested that PAHs mainly originated from the inputs of pyrolytic (combustion) sources, which might be contributed to land-based atmospheric deposition. The particle-water partition coefficients of individual PAH showed that partitions were not correlated with suspended particulate matter content, dissolved organic carbon or salinity, similar to the Yangtze coastal area.  相似文献   

7.
In this study, we tested a practical strategy useful for accurate chlorinated volatile organic compound (cVOC) sorption prediction. Corresponding to the feature of the superposition of adsorption due to thermally altered carbonaceous matter (TACM) with organic carbon‐water partitioning, a nonlinear Freundlich sorption isotherm covering a wide range of aqueous concentrations was defined by equilibrium sorption measurement at one or a few low concentration points with extrapolation to the empirical organic carbon‐water partition coefficient (Koc,e) near compound solubility. We applied this approach to obtain perchloroethene equilibrium sorption isotherm parameters for TACM‐containing glacial sand and gravel subsoil samples from a field site in New York. Sorption and associated Koc,c applicable to low (5–500 µg/L) and high (>100,000 µg/L) aqueous concentrations were determined in batch experiments. (The Koc,c is the organic carbon‐normalized sorption partition coefficient corresponding to aqueous concentration Cw.) The Koc,c measurements at low concentration (~5 µg/L) were 6 to 34 times greater than the Koc,e. The importance of this type of data is illustrated through presentation of its substantial impact on the site remedy. In so doing, we provide an approach that is broadly applicable to cVOC field sites with similar circumstances (low carbon content glacial sand and gravel with TACM).  相似文献   

8.
广州麓湖大气多环芳烃的干湿沉降   总被引：8，自引：2，他引：6  
以广州麓湖为小型城市湖泊的代表,对大气中多环芳烃的颗粒态沉降进行了连续一年的采样与分析. 结果表明,年均颗粒态多环芳烃的沉降通量为0.47mg/( m2·a). 全年直接由大气输入到麓湖的颗粒态多环芳烃总量约为0.1kg. 不同季节相比,夏季多环芳烃的沉降通量略高于秋季,而冬春季最高. 对比大气总悬浮颗粒物中多环芳烃的组成发现,当降雨量增大时,沉降颗粒物中多环芳烃的组成逐渐趋近于大气总悬浮物中多环芳烃的组成. 广州地区雨热同期、干冷咸至的季风气候特点,以及由此导致的大气颗粒物粒径变化和PAHs的气-粒分配变化,与大气PAHs污染程度一起,共同控制着沉降颗粒物中PAHs相对组成的季节变化.  相似文献   

9.
Conflicting sorption coefficients for ortho‐phenylphenol (OPP) have been reported in the literatures, which resulted in the conflicting assessments on OPP mobility in soil. To ascertain the sorption coefficient of OPP, batch experiments were performed based on OECD guideline 106, using three types of soils. Headspace solid‐phase microextraction (HS‐SPME) and GC‐MS were applied to the determination of OPP concentration in the liquid phase. The sorption isotherms obtained for all three soils under equilibrium conditions were described well, assuming linear sorption. The organic carbon normalized distribution coefficients (Koc) ranged from 894 to 1703 L kg?1, which suggested that OPP is moderately mobile in soil. The results also showed that the Koc value of OPP can be predicted precisely from Kow, whereas it was underestimated by one order of magnitude when water solubility is used.  相似文献   

10.
A peatland complex disturbed by berm construction in the 1950s was used to examine the long‐term impact of water table (WT) manipulation on peatland hydraulic properties and moisture retention at three adjacent sites with increasing depth to WT (WET, INTermediate reference and DRY). Saturated hydraulic conductivity (Ks) was found to decrease with depth by several orders of magnitude over a depth of 1–1.5 m at all sites. The depth dependence of WT response to rainfall was similar across sites: WT response increased from 1 : 1 at the surface, to 5 : 1 at 50 cm depth. While surface specific yield (Sy) values were similar across all sites, it decreased with depth at a rate of 0.014 cm?1 in hollows and 0.007 cm?1 in hummocks. Bulk density (ρb) exhibited similar depth‐dependent trends as Sy and explains a high amount of variance (r2 > 0.69) in moisture retention across a range of pore water pressures (?15 to ?500 cm H2O). Because of higher ρb, hollow peat had greater moisture retention, where site effects were minimal. However, the estimated residual water content for surface Sphagnum samples, while on average lower in hummocks (0.082 m3 m?3) versus hollows (0.087 m3 m?3), increased from WET (0.058 m3 m?3) to INT (0.088 m3 m?3) to DRY (0.108 m3 m?3) which has important implications for moisture stress under conditions of persistent WT drawdown. Given the potential importance of microtopographic succession for altering peatland hydraulic structure, our findings point to the need for a better understanding of what controls the relative height and proportional coverage of hummocks in relation to long‐term disturbance‐response dynamics. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

11.
Evapotranspiration (ET) is an essential component of the hydrological cycle and plays a critical role in water resource management. However, ET is often overlooked in order to transform rainfall to runoff for better streamflow simulation. Hydrological models are commonly used to estimate areal actual evapotranspiration (AET) after calibration against observed discharge. However, classical approaches are often inadequate to appropriately simulate other hydrologic components. Hence, it is important to introduce natural heterogeneity to enhance hydrological processes and reduce water balance errors. In this study, the effectiveness of introducing a constant crop coefficient (Kc), flux tower‐based Kc, and leaf area index (LAI) to three hydrological models (Three‐Parametric Hydrologic Model [TPHM], Génie Rural à 4 paramètres Journalier [GR4J], and Catchment hydrologic cycle Assessment Tool [CAT]) is assessed for the simulation of daily streamflow and AET in a mountainous mixed forest watershed (8.54 km2) in South Korea. The results show that the streamflow simulations after introduction of Kc and LAI to the original models are quite similar. However, the effectiveness of the AET estimation was significantly enhanced after introduction of the flux tower‐based Kc and LAI. The information criterion computed to compare the models reveals that the flux tower‐based Kc‐simulated AET demonstrated better agreement with the observed AET. The Pearson's correlation coefficients (R2) of the TPHM (8%), GR4J (55%), and CAT (55%) models also showed improvements that were greater than the constant based Kc simulation. Similarly, the limitations of the three models with respect to capturing seasonal variation as well as high and low flows were enhanced after the introduction of the flux tower‐based Kc, which adequately reproduced hydrological processes with minimum water balance errors and bias. A regression analysis revealed the potential of estimating Kc as a linear function of LAI (R2 = 0.84). The results of this study indicate that introduction of Kc and LAI to the conceptual rainfall–runoff models can be considered an effective approach to reduce water balance errors and uncertainties in hydrological models and improve the reliability of climate change studies and water resource management.  相似文献   

12.
Ambient concentrations of sulfur dioxide (SO2), nitrogen dioxide (NO2), and ozone (O3) were measured at 51 sampling points by passive sampling technique in Kocaeli, an important industrial city in Turkey. Samples were analyzed by UV‐spectrophotometry for NO2 and O3 and by ion chromatography for SO2, respectively. Concentrations of SO2, NO2, and O3 were determined to investigate their spatial distribution and source characterization. The sampling campaigns revealed an average concentration of 8 µg/m3 (max. 82 µg/m3) for SO2, and 14 µg/m3 (max. 40 µg/m3) for NO2, in summer; while average winter concentrations were 25 µg/m3 (max. 61 µg/m3) for SO2, and 50 µg/m3 (max. 100 µg/m3) for NO2. The maximum ozone concentrations were determined to be 86 µg/m3 in summer and 61 µg/m3 in winter downwind of the source areas of the precursor pollutant emissions. The results showed that NO2 and SO2 concentrations in industrial and urban areas were two to four times higher compared with rural areas in the summer and winter. In the light of the information obtained from the spatial interpolation of the pollutant concentrations, a selection of appropriate locations for continuous monitoring was suggested according to the European Community (EU) directives.  相似文献   

13.
The heterogeneous hydraulic conductivity (K) in water‐bearing formations controls subsurface flow and solute transport processes. Geostatistical techniques are often employed to characterize the K distribution in space based on the correlation between K measurements. However, at the basin scale, there are often insufficient measurements for inferring the spatial correlation. This is a widespread problem that we address in this study using the example of the Betts Creek Beds (BCB) in the Galilee Basin, Australia. To address the lack of data, we use a 1D stochastic fluvial process‐based model (SFPM) to quantify the total sediment thickness, Z( x ), and the sandstone proportion over the total thickness, Ps( x ), in the BCB. The semivariograms of Z( x ) and Ps( x ) are then extracted and used in sequential Gaussian simulation to construct the 2D spatial distribution of Z( x ) and Ps( x ). Ps( x ) can be converted to a K distribution based on classical averaging methods. The results demonstrate that the combination of SFPM and geostatistical simulation allows for the evaluation of upscaled K distribution with a limited number of K measurements. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

14.
Fifty-seven surface sediment samples were collected from the coast of southwest Taiwan and analyzed for polycyclic aromatic hydrocarbons (PAHs). Concentrations of total PAHs (28 PAH compounds) ranged from 15 to 907 ng g−1 dry weight. Diagnostic ratios showed that PAHs in the sediments of the Gaoping estuary were predominantly of petroleum origin, whereas sediments from the Kaohsiung coast contained principally combustion-derived PAHs. Principal component analysis indicated that emissions from automobiles and coal burning were the main sources of combustion-derived PAHs. The relatively high ratios of perylene/penta-aromatic PAH isomers in sediments from the Tainan coast and some off-shore stations on the Kaohsiung coast suggest a significant diagenetic PAH contribution. The study shows that certain diagnostic ratios are useful and sensitive in delineating the distribution of PAHs from specific sources in southwest Taiwan. The phenanthrene/anthracene ratio is a better indicator than the methylphenanthrenes/phenanthrene ratio for tracing petrogenic PAHs, and the benzo(a)anthracene/chrysene and indeno(1,2,3-c,d)pyrene/benzo(g,h,i)perylene ratios are more specific than the benzo(a)pyrene/benzo(e)pyrene and benzo(b)fluoranthcene/benzo(k)fluoranthcene ratios in distinguishing PAHs from various pyrogenic sources.  相似文献   

15.
Laccase from the white‐rot fungus Pleurotus florida, produced under solid‐state fermentation conditions, was used for the decolorization of reactive dye Remazol Brilliant Blue R (RBBR). RBBR was decolorized up to 46% by P. florida laccase alone in 10 min. In the presence of N‐hydroxybenzotriazole (HBT), the rate of decolorization was enhanced 1.56‐fold. Central composite design of response surface methodology with four variables namely, dye, enzyme, redox mediator concentrations, and time at five levels was applied to optimize the RBBR decolorization. The predicted optimum level of variables for maximum RBBR decolorization (87%) was found to be 52.90 mg L?1 (RBBR), 1.87 U mL?1 (laccase), 0.85 mM (HBT), and 7.17 min (time), respectively. The validation results showed that the experimental value of RBBR decolorization (82%) was close to the predicted one. The disappearance of C–N and C–X groups, and a small shift in N–H groups in Fourier‐transform infra red (FTIR) spectroscopy confirms the degradation of RBBR chromophore by laccase enzyme. The phytotoxicity of RBBR was considerably reduced after the treatment with laccase. RBBR decolorization kinetics; Km and Vmax were calculated to be 145.82 mg L?1 and 24.86 mg L?1 min, respectively.  相似文献   

16.
滆湖水体光学性质初步研究   总被引：3，自引：1，他引：2  
基于2009年7月至2010年6月滆湖全湖15个采样点的水体光学参数及相关水质理化因子数据,分析滆湖水体周年光合有效辐射(PAR)衰减特性,以期为滆湖沉水植物生态修复提供相关水体光学资料.结果表明,滆湖水体PAR衰减系数(Kd)周年变化范围为1.32～17.42 m-1.秋季Kd相对最小,平均值为2.35 m-1,变化范围为1.32 ～3.70 m-1;夏季Kd相对最大,平均值为6.23 m-1,变化范围为3.68～17.42 m-1.春、秋、冬季,滆湖水体真光层平均深度均满足沉水植物的生长需求,而在夏季滆湖水体真光层平均深度仅为0.84m,小于全湖平均水深(1.20 m),因此夏季PAR是限制沉水植物恢复的因子之一.滆湖水体Kd与透明度(SD)在秋、冬季的关系为:Kd =2.089 +0.705/SD.叶绿素a浓度和悬浮物浓度是影响滆湖水体Kd的重要因子之一.  相似文献   

17.
Spatial distribution, source apportionment, and potential ecological risks of sixteen polycyclic aromatic hydrocarbons (PAHs) and seven endocrine disrupting compounds (EDCs) in the intertidal sediment at the Shuangtaizi Estuary, Bohai Sea of China were analyzed. Results showed that the total PAH concentrations ranged from 28.79 ng g? 1 dw to 281.97 ng g? 1 dw (mean: 115.92 ng g? 1 dw) and the total EDC concentrations from 0.52 ng g? 1 dw to 126.73 ng g? 1 dw (mean: 37.49 ng g? 1 dw). The distribution pattern for the PAHs was generally different from that of the EDCs possibly due to their distinct sources and n-octanol-/water partition coefficients (KOW). Qualitative and quantitative analytical results showed that PAH sources were mainly from a mixture of pyrogenic and petrogenic contributions. The higher levels at the southeast of Geligang indicated that the EDC pollutants may have mainly originated from the plastic industry and other chemical plants located along the Liao River. Ecological risk assessment revealed that PAHs exhibited low ecotoxicological effects, whereas EDCs, especially 4-tert-octylphenol and bisphenol A, had high ecological hazard to the estuarine biota.  相似文献   

18.
青藏高原地区分布的湖泊数量众多、面积较大、分布范围广泛.受制于恶劣的自然条件,对该地区湖泊的光学吸收特性以及光合有效辐射衰减系数(Kd(PAR))的研究鲜有成果.本文依据2014和2015年间采集的13个典型高海拔、湖泊面积较大的湖库的现场实测数据和实验室测定数据,分析了采样湖库各个采样点的Kd(PAR)特征以及有色可溶性有机物(CDOM)、藻类颗粒物吸收及非色素颗粒物吸收特性,计算并分析了Kd(PAR)与透明度以及光学活性物质的关系.研究结果表明:青藏高原地区各湖库平均各项颗粒物吸收系数均较低,总颗粒物吸收系数在400~700 nm波段内不超过0.14 m~(-1)、CDOM吸收系数在355 nm波长处最高,为1.23 m~(-1)、最低接近于0、藻类颗粒物吸收特性不明显;实验数据完整的巴木错、格仁错和班公错的主导吸收组分各异,其中巴木错为CDOM吸收主导,格仁错与班公错为非色素颗粒物吸收主导;青藏高原采样湖泊总体Kd(PAR)平均值较小,仅为0.26 m~(-1),样点最大值出现在可鲁克湖(1.17 m~(-1)),最小值出现在普莫雍错(0.10 m~(-1));在采样湖泊中Kd(PAR)与透明度呈显著相关;Kd(PAR)与CDOM的相关性最强,叶绿素a浓度次之,与总悬浮颗粒物浓度的相关性最不显著.  相似文献   

19.
Surface sediment from 15 Italian marine protected areas (MPA) were analysed for polycyclic aromatic hydrocarbons (PAHs). The organic carbon percentage was also determined. Total PAH concentrations (ng g−1 d.w.) ranged from 0.71 (Penisola del Sinis) to 1550 (Miramare). Individual PAH analysis showed that three and four rings PAHs were the most frequently detected isomers and accounted for 60-70% of the PAH total concentrations. PAH ratio analysis showed a prevalence of pyrolytic PAH origin at most of the MPAs with exception of Porto Cesareo and Ustica where a petrogenic origin was detected. Results for organic carbon percentages ranged from 0.3% (Capo Rizzuto) to 2% (Punta Campanella). These results are comparable to other Mediterranean marine environments. However, our results shows that some MPAs, such as Miramare, Porto Cesareo, Isola Capo Rizzuto and Punta Campanella, are subject to strong pressure from urban and industrial activities where high PAH levels were detected.  相似文献   

20.
The point measurement of soil properties allows to explain and simulate plot scale hydrological processes. An intensive sampling was carried out at the surface of an unsaturated clay soil to measure, on two adjacent plots of 4 × 11 m2 and two different dates (May 2007 and February–March 2008), dry soil bulk density, ρb, and antecedent soil water content, θi, at 88 points. Field‐saturated soil hydraulic conductivity, Kfs, was also measured at 176 points by the transient Simplified Falling Head technique to determine the soil water permeability characteristics at the beginning of a possible rainfall event yielding measurable runoff. The ρb values did not differ significantly between the two dates, but wetter soil conditions (by 31%) and lower conductivities (1.95 times) were detected on the second date as compared with the first one. Significantly higher (by a factor of 1.8) Kfs values were obtained with the 0.30‐m‐diameter ring compared with the 0.15‐m‐diameter ring. A high Kfs (> 100 mm h?1) was generally obtained for low θi values (< 0.3 m3m?3), whereas a high θi yielded an increased percentage of low Kfs data (1–100 mm h?1). The median of Kfs for each plot/sampling date combination was not lower than 600 mm h?1, and rainfall intensities rarely exceeded 100 mm h?1 at the site. The occurrence of runoff at the base of the plot needs a substantial reduction of the surface soil permeability characteristics during the event, probably promoted by a higher water content than the one of this investigation (saturation degree = 0.44–0.62) and some soil compaction due to rainfall impact. An intensive soil sampling reduces the risk of an erroneous interpretation of hydrological processes. In an unstable clay soil, changes in Kfs during the event seem to have a noticeable effect on runoff generation, and they should be considered for modeling hydrological processes. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

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