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1.
《Acta Geochimica》2017,(2)
Petrography and geochemistry of the altered and unaltered host rocks surrounding the Koktokay No.3 pegmatite revealed that the unaltered amphibolite is mainly composed of hornblende, plagioclase, and ilmenite.Beyond these primary components, the altered host rocks contain a few newly formed minerals, including biotite,tourmaline, chlorine, and muscovite. The alteration zone surrounding the Koktokay No.3 pegmatite is limited to 2.0 m, characterized by biotitization, tourmalization, and chloritization. In the altered host rocks, the contents of SiO_2, MgO, MnO, Na_2O, and TiO_2 did not vary greatly.However, Al_2O_3 showed a weak decreasing trend with the increasing distance from the pegmatite contact zone, while Fe_2O_3 and CaO showed an increasing trend. The contents of Li, Rb, and Cs in the altered host rocks were much higher than those in the unaltered host rocks, decreasing with distance from the contact. The chondrite-normalized rare earth element(REE) pattern of the altered and unaltered host rock was right-inclined from La to Lu, but enriched in light REEs over heavy REEs after hydrothermal alteration. An isocon plot shows that some oxides migrated in with an order of P_2O_5K_2O TiO_2Al_2O_3SiO_2MnO≥MgO, while others migrated out with an order of Na_2O CaO Fe_2O_3. For REEs, the migration ratios are positive values withCs Rb Li Nb Ta Be, signifying that all REEs migrated from the exsolved magmatic fluid into the altered host rocks. It was concluded that diffusion was the only mechanism for migration of ore-forming elements in the alteration zone. The effective diffusion coefficients(Deff)of LiF, RbF, and CsF were estimated under a fluid temperature of 500–550 °C. Using a function of concentration(C(x,t)) and distance(x), the order of migration distance was determined to be LiF CsF RbF, with diffusion times of (3.39 ± 0.35)× 10~6,(3.19 ± 0.28) × 10~5 and(6.33 ± 0.05) × 10~5 years, respectively. 相似文献
2.
《中国科学:地球科学》2017,(11)
皖南地区燕山期岩浆作用强烈,可划分为早阶段(152~137Ma)和晚阶段(136~122Ma).野外调查发现,屯溪地区沿青山-长陔发育一条燕山期花岗岩带,与钼多金属矿床具有密切的成因关系.黄山岩体是皖南地区代表性的正长花岗岩体,目前尚未发现与成矿有关.锆石LA-ICP-MS定年结果表明,青山-长陔带4个花岗岩体的形成时代一致,介于(140±4)~(141±2)Ma,属于燕山期早阶段岩浆作用.黄山花岗岩体的形成时代为(129±2)Ma,属于晚阶段岩浆作用,青山-长陔带花岗岩具有较高的SiO_2含量,相对富K_2O、低P_2O_5以及中等程度的Al_2O_3含量,属于高钾钙碱性系列准铝质Ⅰ型花岗岩.这些岩石均表现出富集大离子亲石元素和轻稀土元素,亏损高场强元素,中等程度的Eu负异常,为岛弧或大陆壳源岩浆地球化学特征.样品的~(87)Sr/~(86)Sr(t)介于0.7120~0.7125,ε_(Nd)(t)值为-7.24~-4.38,锆石ε_(Hf)(t)值为-4.4~6.7,类似于同时期皖南成矿花岗闪长岩.综合地球化学研究表明,皖南燕山期成矿花岗闪长岩为中-新元古代增生加厚下地壳部分熔融的产物,而青山-长陔带花岗岩为这种岩浆经过斜长石+角闪石+上溪群的结晶分异同化混染(AFC)过程形成.黄山花岗岩富SiO_2和K_2O,Al_2O_3含量中等,具有海鸥式稀土元素配分型式和显著的Eu负异常.相比青山-长陔带花岗岩,黄山岩体具有更加显著的Ba、Sr、P和Ti的负异常,没有Nb和Ta的亏损,为高钾钙碱性准铝质A型花岗岩,其ε_(Hf)(t)值介于-6.6~-1.2,类似于早阶段成矿花岗闪长岩.黄山花岗岩同样起源于中-新元古代增生地壳的深熔作用,但岩浆源区为经过了燕山期早阶段Ⅰ型中酸性岩浆抽取后的残留麻粒岩质地壳.两期花岗岩的比较研究表明,早阶段花岗岩形成于相对厚的下地壳环境,温度较低,源区为中-新元古代增生地壳,富含成矿物质,岩浆AFC演化过程进一步加强了成矿物质的富集;而晚阶段A型花岗岩起源深度较浅,形成温度更高,源区由于早期的岩浆抽取作用而亏损成矿物质,从而成矿能力较弱,指示从早至晚,岩浆作用阶段从后造山转变为非造山.后者对应着古太平洋板块俯冲角度加大背景下的弧后拉张环境. 相似文献
3.
风尘堆积中SiO_2/Al_2O_3值与粒度的关系及其对东亚冬季风的指示意义 总被引：2，自引：0，他引：2
在渭南及洛川剖面将基本未经历风化的黄土样品分离成8个粒级后进行化学分析,结果表明,<50 μm的各粒级样品中SiO_2/Al_2O_3分子比与粒度φ值呈明显线性负相关,即在<50 μm粒级范围内颗粒越粗,黄土的SiO_2/Al_2O_3值越大;而<50 μm各粒级的含量之和占全岩的98％以上.在黄土层中,SiO_2/Al_2O_3与全岩粒度变化有较好的可对比性,而在古土壤中SiO_2/Al_2O_3值反映出一系列全岩粒度无法揭示的信息. 相似文献
4.
《中国科学:地球科学》2016,(3)
包头东正长岩位于内蒙古包头市东,阴山南麓,是华北克拉通北缘三叠纪碱性岩带最西端的岩体.本文对此岩体进行了锆石U-Pb年代学、矿物化学、岩石地球化学和Sr-Nd同位素的研究,讨论了其成因及源区地幔性质.岩体由霞石辉石正长岩和碱性长石正长岩组成,锆石LA-ICPMS U-Pb年龄为(214.7±1.1)Ma,为晚三叠世岩浆活动的产物.单斜辉石(从核部到边部,成分由透辉石向霓石-普通辉石演化),黑云母,正长石和霞石是岩体主要组成矿物.岩体稀土总量较高,稀土配分模式为右倾,无明显铕异常;相对富集轻稀土元素和大离子亲石元素(如Rb、Ba、Sr和Pb),亏损重稀土元素和高场强元素(如Nb、Ta和Ti);具有富集的Sr-Nd同位素组成,初始~(87)Sr/~(86)Sr为0.7061~0.7067,εNd(t)值为–9.0~–11.2.矿物学和地球化学数据揭示包头东正长岩属于硅不饱和钾质-超钾质碱性岩岩浆系列,高CaO、Fe_2O_3、K_2O、Na_2O含量,低SiO_2含量,富水,高温,高氧逸度;岩体起源于位于石榴石稳定区富含金云母的古老,富集岩石圈地幔.包括包头东正长岩在内的华北克拉通北缘三叠纪钾质碱性岩带的发育,揭示华北克拉通北缘下覆岩石圈地幔受到了来自古亚洲洋俯冲板片(及上覆沉积物)流体/熔体的交代改造;晚三叠世,华北克拉通北缘已经进入了被破坏大陆边缘的强烈伸展演化阶段. 相似文献
5.
《Acta Geochimica》2020,(3)
Zircon stability in silicate melts—which can be quantitatively constrained by laboratory measurements of zircon saturation—is important for understanding the evolution of magma.Although the original zircon saturation model proposed by Watson and Harrison(Earth Planet Sci Lett 64(2):295-304,1983) is widely cited and has been updated recently,the three main models currently in use may generate large uncertainties due to extrapolation beyond their respective calibrated ranges.This paper reviews and updates zircon saturation models developed with temperature and compositional parameters.All available data on zircon saturation ranging in composition from mafic to silicic(and/or peralkaline to peraluminous)at temperatures from 750 to 1400℃ were collected to develop two refined models(1 and 2) that may be applied to the wider range of compositions.Model 1 is given by lnC_(Zr)(melt)=(14.297±0.308)+(0.964 ± 0.066).M-(11113±374)/r,and model 2 given by lnC_(Zr)(melt)=(18.99±0.423)-(1.069±0.102)·lnG-(12288±593)/T,where C_(Zr)(melt) is the Zr concentration of the melt in ppm and parameters M [=(Na+K+2 Ca)/(Al·Si)](cation ratios) and G [=(3·Al_2 O_3+SiO_2)/(Na_(2-)O+K_2 O+CaO+MgO+FeO)](molar proportions)represent the melt composition.The errors are at one sigma,and T is the temperature in Kelvin.Before applying these models to natural rocks,it is necessary to ensure that the zircon used to date is crystallized from the host magmatic rock.Assessment of the application of both new and old models to natural rocks suggests that model 1 may be the best for magmatic temperature estimates of metaluminous to peraluminous rocks and that model 2 may be the best for estimating magmatic temperatures of alkaline to peralkaline rocks. 相似文献
6.
《Acta Geochimica》2021,(1)
There are several Pan-African granitoid plutons widely distributed in Shillong Plateau,NE India.Nongpoh(506.7 ± 7 Ma) and Mylliem(480-430 Ma) plutons were chosen for the petrological and geochemical study to constrain their petrogenesis.Nongpoh pluton consists of coarse-grained porphyritic quartz-monzogranite(NQM)and Mylliem pluton consists of medium to coarse-grained porphyritic granite(MG).The constituent minerals are K-feldspar,plagioclase,quartz,and biotite in both granitoids with accessory minerals of hornblende,zircon,sphene,and ilmenite.Both NQM and MG are metaluminous to weakly peraluminous(A/CNK=0.82-1.06),exhibit varied ranges of SiO_2(NQM:58.4-64.9 wt%;MG:66.9-69.9 wt%),and display a clear compositional gap in the Harker variation diagram.NQM contains higher abundances of CaO,MgO and Fe2O_3~t and similar K_2O and total alkali contents compared to MG.They have distinctive geochemical features typical of highly fractionated I-type granitoids such as higher abundances of K_2O,Al_2O_3,MgO,CaO,Al_2O_3+ CaO 15 wt% and A/CNK 1.1,low P_2O_5 content,enrichment in LILE,depletion in HFSE and HREE and highly fractionated REE patterns with moderate Eu anomalies,implying magma generation in a post-collisional extension setting and thinning induced asthenosphere upwelling,accompanied by the partial melting of the overlying enriched lithospheric mantle.The multi-element diagram of both NQM and MG shows pronounced negative anomalies at Ba,Nb,Sr,P,Zr,and Ti which implies a major role of crystal fractionation in their petrogenesis.High concentrations of Th,U,and Pb in the granitoid types point to additional involvement of crustal components in their generation.However,MGs with more pronounced positive spikes at U,Th,and Pb compared to NQM in multi-element diagram suggests the involvement of more felsic crustal material.The observed geochemical features of the granitoid types thus suggest that they are genetically unrelated to each other and their parental magmas were modified during magmatic differentiation processes.We suggest that the NQM and MG were formed as a result of fractional crystallization of compositionally diverse hybrid magmas produced due to mingling and mixing of an enriched lithospheric mantle-derived melts with lower crust-and middle crust-derived melts respectively during a period of extension late in the cycle of PanAfrican orogeny. 相似文献
7.
《中国科学:地球科学》2017,(7)
南岭地区中-晚侏罗世含铜铅锌与含钨花岗岩的矿物学和地球化学特征截然不同.含铜铅锌花岗岩主要为准铝质含角闪石的花岗闪长岩,具有较高的CaO/(Na_2O+K_2O)比值、LREE/HREE比值和δEu值,较低的Rb/Sr比值,Ba、Sr、P、Ti轻微亏损,分异演化程度较低.含钨花岗岩为高分异演化的过铝质花岗岩,其CaO/(Na_2O+K_2O)比值、LREE/HREE比值和δEu值较低,Rb/Sr比值较高,Ba、Sr、P、Ti强烈亏损.含铜铅锌花岗岩主要形成于155.2~167.0Ma,峰值为160.6Ma,含钨花岗岩主要形成于151.1~161.8Ma,峰值为155.5Ma,两者存在约5Ma的时差.在湘南铜山岭含铜铅锌和魏家含钨花岗岩系统研究基础上,结合南岭地区中-晚侏罗世含铜铅锌与含钨花岗岩的对比,提出了两类含矿花岗岩的成因模式.古太平洋板块俯冲导致软流圈上涌和玄武质岩浆底侵.底侵玄武质岩浆加热促使下地壳镁铁质角闪岩相基底首先发生部分熔融,形成与铜铅锌矿化有关的花岗闪长质岩浆.随着玄武质岩浆底侵,中-上地壳富白云母变质沉积基底发生部分熔融,形成与钨矿化有关的花岗质岩浆.花岗岩源区成分的差异导致花岗岩成矿专属性不同,源区部分熔融的时间先后导致了含铜铅锌与含钨花岗岩之间存在5Ma左右的时差. 相似文献
8.
9.
《Acta Geochimica》2020,(4)
We report U–Pb dating of zircon,as well as geochemical and Hf isotope data,in order to constrain the formation time,magma source,and tectonic setting of granite porphyry dykes in the Xicha gold–(silver) district in southern Jilin Province,Northeast China.The zircon grains are euhedral–subhedral,display oscillatory growth zoning and have Th/U ratios varying between 0.11 and 0.78,which together imply a magmatic origin.The dating results indicate the porphyry formed in the Early Cretaceous (122±1 Ma)and it contains SiO_2=70.64–72.31 wt%,Al_2O_(3-)=13.99–14.64 wt%,K_2O+Na_2O=6.96–7.81 wt%K_2O/Na_2O=1.24–2.10,and A/CNK=1.11–1.41.Chemically,the porphyry belongs to a high-K calc-alkaline S-type granite.Chondrite-normalized rare earth elements (REE)patterns show LREE enrichment,light rare earth elements(LREE)/heavy rare earth elements (HREE)=9.93–11.97(La/Yb)_N=11.08–15.16,and d Eu=0.69–0.95.On the trace element spider diagram,large ion lithophile elements such as Rb,Ba,K,Th,and U are enriched,whereas the high field strength elements Ti and P are depleted.The e Hf(t) values of zircon from the granite porphyry vary between-17.1 and-13.2,and their Hf two-stage model ages vary from 2.01 to 2.26 Ga,implying that the magma was derived from partial melting of old lower crust.The granite porphyry dykes and many A-type granites in the region formed at the same time,suggesting an extensiona environment.The combination of the occurrence of strong magmatism,large-scale mineralization,and extensiona tectonics throughout much of Eastern China indicate that the Early Cretaceous was a period of significant lithospheric thinning.The southern Jilin Province,therefore,experienced lithospheric thinning during the Early Cretaceous. 相似文献
10.
《Acta Geochimica》2016,(4)
Experiments on the partitioning of Cu between different granitic silicate melts and the respective coexisting aqueous fluids have been performed under conditions of 850 °C, 100 MPa and oxygen fugacity(f O_2) buffered at approaching Ni–Ni O(NNO). Partition coefficients of Cu(DCu= cfluid/cmelt) were varied with different alumina/alkali mole ratios [Al_2O_3/(Na_2O·K_2O), abbreviated as Al/Alk], Na/K mole ratios, and Si O_2 mole contents. The DCu increased from 1.28 ± 0.01 to 22.18 ± 0.22 with the increase of Al/Alk mole ratios(ranging from 0.64 to 1.20)and Na/K mole ratios(ranging from 0.58 to 2.56). The experimental results also showed that DCuwas positively correlated with the HCl concentration of the starting fluid.The DCuwas independent of the Si O_2 mole content in the range of Si O_2 content considered. No DCuvalue was less than 1 in our experiments at 850 °C and 100 MPa, indicating that Cu preferred to enter the fluid phase rather than the coexisting melt phase under most conditions in the melt-fluid system, and thus a significant amount of Cu could be transported in the fluid phase in the magmatichydrothermal environment. The results indicated that Cu favored partitioning into the aqueous fluid rather than themelt phase if there was a high Na/K ratio, Na-rich, peraluminous granitic melt coexisting with the high Cl-fluid. 相似文献