共查询到20条相似文献，搜索用时 46 毫秒
1.
L. Brusca A. Aiuppa W. D'Alessandro F. Parello P. Allard A. Michel 《Journal of Volcanology and Geothermal Research》2001,108(1-4)
Systematic analysis of major and minor elements in groundwaters from springs and wells on the slopes of Mt. Etna in 1995–1998 provides a detailed geochemical mapping of the aquifer of the volcano and of the interactions between magmatic gas, water bodies and their host rocks. Strong spatial correlations between the largest anomalies in pCO2 (pH and alkalinity) K, Rb, Mg, Ca and Sr suggest a dominating control by magmatic gas (CO2) and consequent basalt leaching by acidified waters of the shallow (meteoric) Etnean aquifer. Most groundwaters displaying this magmatic-type interaction discharge within active faulted zones on the S–SW and E lower flanks of the volcanic pile, but also in a newly recognised area on the northern flank, possibly tracking a main N–S volcano-tectonic structure. In the same time, the spatial distribution of T°C, TDS, Na, Li, Cl and B allows us to identify the existence of a deeper thermal brine with high salinity, high content of B, Cl and gases (CO2, H2S, CH4) and low K/Na ratio, which is likely hosted in the sedimentary basement. This hot brine reaches the surface only at the periphery of the volcano near the Village of Paternò, where it gives rise to mud volcanoes called “Salinelle di Paternò”. However, the contribution of similar brines to shallower groundwaters is also detected in other sectors to the W (Bronte, Maletto), SW (Adrano) and SE (Acireale), suggesting its possible widespread occurrence beneath Etna. This thermal brine is also closely associated with hydrocarbon fields all around the volcano and its rise, generally masked by the high outflow of the shallow aquifer, may be driven by the ascent of mixed sedimentary–magmatic gases through the main faults cutting the sedimentary basement. 相似文献
2.
Geochemical studies on cold meteoric waters, post-1980 hot spring waters, fumarole emissions from the dacite dome, and volcanic rocks at Mount St. Helens (MSH) from 1985 to 1989 show that magmatic volatiles are involved in the formation of a new hydrothermal system. Hot spring waters are enriched in 18O by as much as 2 and display enrichments in D relative to cold waters. A well-defined isotopic trend is displayed by the isotopic composition of a>400°C fumarole condensate collected from the central crater in 1980 (-33 D, +6 18O), of condensate samples collected on the dome, and of cold meteoric and hot spring waters. The trend indicates that mixing occurs between local meteoric water and magmatic water degassing from the dacite dome. Between 30 and 70% magmatic water is present in the dome fumarole discharges and 10% magnatic water has been added to the waters of the hydrothermal system. Relations between Cl, SO4 and HCO3 indicate that the hot spring waters are immature volcanic waters formed by reaction of rocks with waters generated by absorption of acidic volcanic fluids. In addition, the B/Cl ratios of the spring waters are similar to the B/Cl ratios of the fumarole condensates (0.02), values of 13C in the HCO3 of the hot springs (-9.5 to-13.5) are similar to the magmatic value at MSH (-10.5), and the 3He/4He ratio, relative to air, in a hot spring water is 5.7, suggesting a magmatic origin for this component.managed by Martin Marietta Energy Systems, Inc., under contract DE-AC05-84OR21400 with the US Department of Energy 相似文献
3.
Crystallization paths of basaltic (1763 eruption) and hawaiitic (1865 and 1329 eruptions) scoria from Etna were deduced from mineralogy and melt inclusion chemistry. The volatile behaviour was investigated through the study of melt inclusions trapped in the phenocrysts and those of the whole rocks and the matrix glasses. The results from the 1763 eruption point to the early crystallization of olivine Fo 81.7 from a water-rich alkaline basalt, with high Cl (1750–2000 ppm) and S (2100–2400 ppm) concentrations. The hawaiitic melt inclusions trapped in olivine Fo 74, salite and plagioclase are characterized by a decrease in Cl/K2O and S/K2O ratios. In each investigated system there is good correlation between K2O and P2O5. In the whole rocks, Cl ranges from 980 to 1680 ppm, from basaltic to hawaiitic lavas, whereas S (110–136 ppm) remains low. Cl and S behaviour in the 1763 magma suggests an early degassing stage of Cl and S, with CO2 and a water-rich gaseous phase for a pressure close to 100 MPa, consistent with a permanent outgassing at the summit craters of Etna. During the eruption, the sulphur remaining in the hawaiitic liquid is lost, and the degassing of chlorine is limited. Such a degassing model can be extended to the 1865 and 1329a.d. eruptions. 相似文献
4.
Neil C. Sturchio Stanley N. Williams Nestor P. Garcia Adela C. Londono 《Bulletin of Volcanology》1988,50(6):399-412
Hot springs and steam vents on the slopes of Nevado del Ruiz volcano provide evidence regarding the nature of hydrothermal activity within the summit and flanks of the volcano. At elevations below 3000 m, alkali-chloride water is discharged from two groups of boiling springs and several isolated warm springs on the western slope of Nevado del Ruiz. Chemical and isotopic geothermometers suggest that the boiling springs are fed by an aquifer having a subsurface equilibration temperature of at least 175°C, and the sampled warm spring is fed by an aquifer having a subsurface equilibration temperature near 150°C. Similarities in conservative solute ratios (e.g., B/Cl) indicate that the alkali-chloride waters may be related to a single reservoir at depth. Isotopic ratios of hydrogen and oxygen indicate that recharge for the alkali-chloride aquifers comes mostly from higher elevations on the volcano. Steam vents and steam-heated bicarbonate-sulfate springs at higher elevations, along a linear structural trend with the alkali-chloride springs, may be derived partly from the alkali-chloride water at depth by boiling. Steam from the vents (84°C) yields a gas geothermometer temperature of 209°C. Acid-sulfate-chloride and acid-sulfate waters are discharged widely from warm springs above 3000 m on the northern and eastern slopes of Nevado del Ruiz. Similarities in B/Cl and SO4/Cl ratios suggest that the acid waters are mixtures of water from an acid-sulfate-chloride reservoir with various proportions of shallow, dilute groundwater. The major source of sulfate, halogens, and acidity for the acid waters may be high-temperature magmatic gases. Available data on hot spring temperatures and compositions indicate that they have remained fairly stable since 1968. However, the eruption of November 13, 1985 apparently caused an increase in sulfate concentration in some of the acid springs that peaked about a year after the eruption. Long-term monitoring of hot spring compositions over many years will be required to better define the effects of volcanic activity on the Nevado del Ruiz hydrothermal system. 相似文献
5.
Magmatic gases extracted and analysed from basaltic rocks collected in the FAMOUS area near 36°50′ N in the Atlantic ocean show that the total amount of gas included in the samples varies between about 500 ppm to 1600 ppm. The main gaseous phases included in the various types of basalts consist of CO2 (270–700 ppm), CO (150–800 ppm), HCl (100–1000 ppm), H2 (0–50 ppm), SO2 (up to 175 ppm), N2 (up to about 213 ppm) and traces of hydrocarbons (up to about 24 ppm). The relative amount of CO, CO2 and SO2 varies with both the degree of crystallinity of the rock and with fractional crystallization and/or fractional melting. The glassy margin of pillow lavas have a higher CO/CO2 ratio than the more crystalline interior. The most fractionated rocks of the series rich in clinopyroxene are depleted in the CO/CO2 ratio and have a higher SO2 content than do the most mafic end members rich in olivine. Early-formed olivine was crystallized in a reducing environment rich in CO and H2 with respect to later formed mineral associations. It is likely that the carbon and sulfur oxidation is taking place at a relatively shallow depth during magmatic ascent or during volcanism. The ocean floor volcanics when compared to subaerial basalts are depleted in SO2 and have on the average ten times more H2. 相似文献
6.
7.
Water, F, and Cl contents of melt inclusions in phenocrysts from the 2-ka-old Taupo and Hatepe plinian tephras, and the 22-ka-old Okaia tephra from the Taupo volcanic center, New Zealand, were measured by electron and ion microprobe. Major and trace element chemistry of the inclusions is similar to that of bulk rock, supporting our assumption that volatile contents of inclusions are representative of the magma in which the crystals grew. Inclusions in the 2-ka Taupo plinian tephra contain a mean of 4.3 wt% H2O, 450 ppm F, and 1700 ppm Cl; from the Hatepe plinian tephra 4.3 wt% H2O, 430 ppm F, and 1700 ppm Cl; and from the Okaia tephra 5.9 wt% H2O, 470 ppm F, and 2100 ppm Cl. Sulfur was below the detection limit of 200 ppm. The constant H2O, F and Cl from a number of stratigraphic horizons in the tephra deposits suggest that the Taupo and Hatepe plinian tephras (>8.2 km3 magma volume) were derived from a magma body that did not contain a strong volatile gradient. By inference, there is no pre-eruptive volatile difference between these plinian eruptions and a phrea-toplinian eruption which occurred between the two. Virtually no major element zonation is seen in this eruptive sequence. Although the Okaia tephra was also erupted from the Taupo volcanic center, probably from a similar vent area, its higher volatile contents and distinct composition as compared to the Taupo tephras show that it was derived from a different, and possibly deeper, magma body. 相似文献
8.
D. E. White 《Bulletin of Volcanology》1966,29(1):481-483
The potential of a geothermal area is primarily dependent on volume and temperature of the reservoir and adequacy of fluid supply. Inadequate fluid supply may be a more common limiting factor than inadequate heat supply, for heat stored in the upper 10,000 ft of many hot spring systems is 1,000 to 10,000 times their annual natural heat flow. Except in very porous reservoirs, most of this heat is stored in rocks rather than in pore fluids. Geothermal fields can be classified as hot spring systems or as deep insulated reservoirs with little surface expression; gradations also exist. Hot spring systems have high near-surface permeability, at least locally on faults and fractures, permitting fluids to escape at high rates. Owing to vigorous circulation and escaping fluids and heat, near-surface temperatures are high, but temperatures deep in the system are lower than would prevail with inhibited escape. Deep reservoirs with little surface expression require permeable reservoir rocks capped by insulating rocks of low permeability. Larderello, Italy, and Salton Sea, California, have slight leakage, but others may have no leakage. Liquid water, which can be at temperatures far above 100° C because of existing pressures, is generally the dominant fluid. Steam can form by boiling as hot water rises to levels of lower pressure. However, in several explored systems the heat supply is so high and rate of discharge of water so low that steam exists even deep in the system. Dry steam areas are probably rare. About 30 areas in the United States have been explored for geothermal energy, but dry steam has been proved only at « The Geysers ». Extensive utilisation of geothermal energy must therefore depend largely upon steam « flashed » from hot water with decrease in pressure. Problems that confront broad utilisation of geothermal energy include: 1) discovery of reservoirs with adequate supply of energy and natural fluids; 2) deposition of CaCO; or SiO2; 3) chemical corrosion; 4) objectionable chemicals in some effluents; and 5) inapplicability of existing public laws. The optimum environment for a geothermal reservoir includes:
- 1.Potent source of heat, such as a magma chamber. A depth of at least two miles provides enough pressure to insure water of high temperature; 5 miles may be too deep for effective transfer of heat to circulating water. Such heat sources are most likely to occur in regions of late Cenozoic volcanism. 相似文献
9.
The fate of B, Cl and Li in the subducted oceanic mantle and in the antigorite breakdown fluids 总被引：2，自引：0，他引：2
Marco Scambelluri Othmar Müntener Thomas T Pettke 《Earth and Planetary Science Letters》2004,222(1):217-234
We present an inventory of B, Cl and Li concentrations in (a) key minerals from a set of ultramafic samples featuring the main evolutionary stages encountered by the subducted oceanic mantle, and in (b) fluid inclusions produced during high-pressure breakdown of antigorite serpentinite. Samples correspond to (i) nonsubducted serpentinites (Northern Apennine and Alpine ophiolites), (ii) high-pressure olivine-bearing antigorite serpentinites (Western Alps and Betic Cordillera), (iii) high-pressure olivine-orthopyroxene rocks recording the subduction breakdown of antigorite serpentinites (Betic Cordillera). Two main dehydration episodes are recorded by the sample suite: partial serpentinite dewatering during formation of metamorphic olivine, followed by full breakdown of antigorite serpentine to olivine+orthopyroxene+fluid. Ion probe and laser ablation ICP-MS (LA ICP-MS) analyses of Cl, B and Li in the rock-forming minerals indicate that the hydrous mantle is an important carrier of light elements. The estimated bulk-rock B and Cl concentrations progressively decrease from oceanic serpentinites (46.7 ppm B and 729 ppm Cl) to antigorite serpentinites (20 ppm B and 221 ppm Cl) to olivine-orthopyroxene rocks (9.4 ppm B and 45 ppm Cl). This suggests release of oceanic Cl and B in subduction fluids, apparently without inputs from external sources. Lithium is less abundant in oceanic serpentinites (1.3 ppm) and the initial concentrations are still preserved in high-pressure antigorite serpentinites. Higher Li contents in olivine, Ti-clinohumite of the olivine-orthopyroxene rocks (4.9 ppm bulk rock Li), as well as in the coexisting fluid inclusions, suggest that their budget may not be uniquely related to recycling of oceanic Li, but may require input from external sources.Laser ablation ICP-MS analyses of fluid inclusions in the olivine-orthopyroxene rocks enabled an estimate of the Li and B concentrations in the antigorite breakdown fluid. The inclusion compositions were quantified using a range of salinity values (0.4-2 wt.% NaClequiv) as internal standards, yielding maximum average fluid/rockDB∼5 and fluid/rockDLi∼3.5. We also performed model calculations to estimate the B and Cl loss during the two dehydration episodes of serpentinite subduction. The first event is characterized by high fluid/rock partition coefficients for Cl (∼100) and B (∼60) and by formation of a fluid with salinity of 4-8 wt.% NaClequiv. The antigorite breakdown produces less saline fluids (0.4-2 wt.% NaClequiv) and is characterized by lower partition coefficients for Cl (25-60) and B (12-30). Our calculations indicate that the salinity of the subduction fluids decreases with increasing depths. fluid/rockDB/fluid/rockDCl<1 (∼0.5) indicates that Cl preferentially partitions into the evolved fluids relative to B and that the B/Cl of fluids progressively increases with increasing depths and temperatures.Despite light element release in fluids, appreciable B, Cl and Li are still retained in chlorite, olivine and Ti-clinohumite beyond the antigorite stability field. This permits a bulk storage of about 10 ppm B, 45 ppm Cl and 5 ppm Li, i.e., concentrations much higher than in mantle reservoirs. Chlorite is the Cl repository and its stability controls the Cl and H2O budget beyond the antigorite stability; B and Li are bound in olivine and clinohumite. The subducted oceanic mantle thus retains light elements beyond the depths of arc magma sources, potentially introducing anomalies in the upper mantle. 相似文献
10.
Jacob B. Lowenstern Heather Bleick Jorge A. Vazquez Jonathan M. Castro Peter B. Larson 《Bulletin of Volcanology》2012,74(10):2303-2319
We investigated the distribution of Cl, F, Li, and Be in pumices, obsidians, and crystallized dome rocks at Chaitén volcano in 2008?C2009 in order to explore the behavior of these elements during explosive and effusive volcanic activity. Electron and ion microprobe analyses of matrix and inclusion glasses from pumice, obsidian, and microlite-rich dome rock indicate that Cl and other elements were lost primarily during crystallization of the rhyolitic dome after it had approached the surface. Glass in pumice and microlite-free obsidian has 888?±?121?ppm Cl, whereas residual glass in evolved microlite-rich dome rock generally retains less Cl (as low as <100?ppm). Estimated Cl losses were likely >0.7?Mt Cl, with a potential maximum of 1.8?Mt for the entire 0.8-km3 dome. Elemental variations reflect an integrated bulk distribution ratio for Cl?>?1.7 (1.7 times more Cl was degassed or incorporated into crystals than remained in the melt). Because Cl is lost dominantly as the very last H2O is degassed, and Cl is minimally (if at all) partitioned into microlites, the integrated vapor/melt distribution ratio for Cl exceeds 200 (200 times more Cl in the evolved vapor than in the melt). Cl is likely lost as HCl, which is readily partitioned into magmatic vapor at low pressure. Cl loss is accelerated by the change in the composition of the residual melt due to microlite growth. Cl loss also may be affected by open-system gas fluxing. Integrated vapor-melt distribution ratios for Li, F, and Be all exceed 1,000. On degassing, an unknown fraction of these volatiles could be immediately dissolved in rainwater. 相似文献
11.
HuaGuo Wen RongCai Zheng Hairuo Qing MingTao Fan YanAn Li BoShi Gong 《中国科学:地球科学(英文版)》2013,56(12):2080-2093
Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1–1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values (δ18OPDB) range from 5.89‰ to 14.15‰ with an average of 9.69‰. The ratio of 87Sr/86Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca2+, Mg2+ and Fe2+. Under the driving flow power of magmatic heat, gravity and compaction, the hydrothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered “hydroexplosion breccias”. In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hydrotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China. 相似文献
12.
Pantelleria Island, located in the Sicily Channel Rift Zone (Italy), is the type locality for the peralkaline rhyolitic rocks called pantellerites. In the last 50 ka, after the large Green Tuff caldera-forming eruption, volcanic activity at Pantelleria has consisted of effusive and explosive eruptions mostly vented inside and along the rim of the caldera and producing silicic lava flows, lava domes and poorly dispersed pantelleritic pumice fall deposits. Basaltic cinder cones and lava flows are only present outside the caldera in the NW sector of the island. The most recent basaltic (Cuddie Rosse, ～ 20 ka) and pantelleritic (Cuddia Randazzo and Cuddia del Gallo, ～ 6 ka) pyroclastic products were sampled to investigate magmatic volatile contents through the study of melt inclusions.The melt inclusions in pyroxene and olivine phenocrysts of Cuddie Rosse scoriae have an alkali basalt composition. The dissolved volatiles comprise 0.9–1.6 wt.% H2O, several hundred ppm of CO2, 1600–2000 ppm of sulphur and 500–900 ppm of chlorine. The water–carbon dioxide couple gives a confining pressure ～ 2 kbar prior to the eruption. This result indicates that episodes of magma ponding and crystallization occurred in the upper crust prior to eruption. The melt inclusions in feldspar, fayalite and aenigmatite phenocrysts of Cuddia del Gallo and Cuddia Randazzo pumice have a pantelleritic composition (Agpaitic Indices 1.3–2.1), up to 4.4 wt.% H2O, 8700 ppm Cl, 6000 ppm F, and CO2 below the detection limit. Sulphur averaging 420 ppm has been measured in Cuddia Randazzo melt inclusions. These data indicate relatively high volatile contents for these low-energy Strombolian-type eruptions. Melt inclusions in Cuddia del Gallo pumice show the most evolved composition (Agpaitic Indices 2–2.1) and the highest volatile content, in agreement with fluid saturation conditions in the magma chamber prior to the eruption. This implies a confining pressure of ～ 1 kbar for the top of the pantelleritic reservoir. The composition of melt inclusions and mineralogical assemblage of Cuddia Randazzo pumice indicate that it has a lower evolutionary degree (Agpaitic Indices 1.3–1.8) and lower pre-eruptive Cl and H2O contents than Cuddia del Gallo pumice. An increase in pressure due to the exsolution of volatiles in the upper part of the pantelleritic reservoir may have triggered the Cuddia del Gallo explosive eruption. Evidence of widespread pre-eruptive mingling between trachytes and pantellerites suggests that the intrusion of trachytic magma into the pantelleritic reservoir likely played a major role in destabilizing the magma system just prior to the Cuddia Randazzo event. 相似文献
13.
Fumarolic activity of Avachinsky and Koryaksky volcanoes, Kamchatka, from 1993 to 1994 总被引：1，自引：0，他引：1
Yuri A. Taran Charles B. Connor Vyacheslav N. Shapar Alexandre A. Ovsyannikov Arthur A. Bilichenko 《Bulletin of Volcanology》1997,58(6):441-448
Volcanic gas and condensate samples were collected in 1993–1994 from fumaroles of Koryaksky and Avachinsky, basaltic andesite
volcanoes on the Kamchatka Peninsula near Petropavlovsk–Kamchatsky. The highest-temperature fumarolic discharges, 220 °C
at Koryaksky and 473 °C at Avachinsky, are water-rich (940–985 mmol/mol of H2O) and have chemical and isotopic characteristics typical of Kamchatka–Kurile, high- and medium-temperature volcanic gases.
The temperature and chemical and water isotopic compositions of the Koryaksky gases have not changed during the past 11 years.
They represent an approximate 2 : 1 mixture of magmatic and meteoric end members. Low-temperature, near-boiling-point discharges
of Avachinsky Volcano are water poor (≈880 mmol/mol); Their compositions have not changed since the 1991 eruption, and are
suggested to be derived from partially condensed magmatic gases at shallow depth. Based on a simple model involving mixing
and single-step steam separation, low water and high CO2 contents, as well as the observed Cl concentration and water isotopic composition in low-temperature discharges, are the
result of near-surface boiling of a brine composed of the almost pure condensed magmatic gas. High methane content in low-temperature
Avachinsky gases and the 220 °C Koryaksky fumarole, low C isotopic ratio in CO2 at Koryaksky (–11.8‰), and water isotope data suggest that the "meteoric" end member contains considerable amounts of the
regional methane-rich thermal water discovered in the vicinity of both volcanoes.
Received: 2 May 1996 / Accepted: 5 November 1996 相似文献
14.
I. Iwasaki T. Ozawa M. Yoshida T. Katsura B. Iwasaki M. Kamada 《Bulletin of Volcanology》1964,27(1):79-80
Chemical properties of magmatic emanation can be estimated roughly by i) volatiles from rocks by heating at various temperatures, ii) volcanic emanations, iii) residual magmatic emanations, iv) calculation from chemical equilibrium between volatile matters and magmas. Magmatic emanation is assumed to consist all of the volatile matters in magmas such asH 2 O, HCl, HF, SO 2 H 2 S, H 2,CO 2,N 2 and others (halides, etc.) at about 1200°C, although various kinds of magmatic emanations can be formed at different conditions. Magmatic emanation separated from magmas will change their chemical properties by many factors such as changes of temperature and pressure (displacement of chemical equilibrium), and reactions with other substances and it will differentiate into volcanic gases, volcanic waters, volcanic sublimates, and hydrothermal deposits (hot spring deposits). At temperatures above the critical point of water, separation of solid phase (sublimates), liquid phase, and displacement of chemical equilibrium may take place, and gaseous phase will gradually change their chemical properties as will be seen at many fumaroles. Chloride, hydrogen, andSO 2 contents will gradually decrease along with lowering temperature. Once aqueous liquid phase appears below the critical point of water, all the soluble materials may dissolve into this hydrothermal solution. Consequently, the gaseous phase at this stage must have usually a little hydrogen chloride as is observed at many fumaroles. Aqueous solutions must be of acidic nature by dissolution of acid forming components, and by hydrolysis (Chloride type). When a self-reduction-oxidation reaction of sulfurous acid takes place, an aqueous solution of sulfate type will be formed. At this stage, solid phases consist of the remained sublimates which are difficultly soluble in aqueous solution, and deposits formed by reaction in the hydrothermal solutions. The gaseous phases below the boiling point of water, have usually a little water, and consist mainly ofCO 2 type,H 2 S type,N 2 type, and mixed type owing to elimination or addition of components by reactions with waters or wall rocks according to their geological conditions. Aqueous solutions which was of acidic nature must be changed into alkaline solutions by reaction with wall rocks for a long time. When the oxidation of sulfur compounds takes place, an aqueous solution of sulfate type will be formed. Hydrogen sulfide type of water will be formed by reaction of sulfides with acid waters or absorption of hydrogen sulfide. Carbonate type of water will be formed whenCO 2 is absorbed. Solid phases at this stage consist usually of hydrothermal deposits except for that at solfatara or mofette. The course of differentiation of magmatic emanation could take place in more complicated ways than that of magmatic differentiation. 相似文献
15.
Petrology and sulfur and chlorine emissions of the 1963 eruption of Gunung Agung,Bali, Indonesia 总被引：3，自引：0，他引：3
The 1963 eruption of Gunung Agung produced 0.95 km3 dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for
magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex
compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite
rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield
basaltic andesite with a temperature of 1040–1100 °C at an assumed pressure of 2 kb, f O2>NNO, and an average melt volatile content (H2O±CO2) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in
phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix
glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic
method to products of the 1963 eruption for estimating volatile release yields of 2.5×1012 g (Mt) of SO2 and 3.4 Mt of Cl released from the 0.65 km3 of juvenile tephra which contributed to stratospheric injection of H2SO4 aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of
SO2 release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO2 was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning
of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent
high-S-release eruptions of more evolved and oxidized magmas (El Chichón, Pinatubo), the petrologic method gives values two
orders of magnitude less than independent estimates of SO2 emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions
of more mafic magmas, suggest that SO2 emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those
from more-evolved magma eruptions.
Received: 29 June 1994 / Accepted: 25 April 1996 相似文献
16.
Forty-two elements have been measured via INAA and RNAA in six samples of five rocks from a 2-m tan-gray boulder-2 breccia (South Massif), in four soils from the South Massif and a valley soil. The chemical composition of the four metaclastic rocks corresponds to “high alumina” (52% Pl) and medium-K KREEP-type rocks. Rock 72335,2 is a medium K anorthositic gabbro (74% Pl). Both the North and South Massifs appear to be medium-K KREEP in composition and thus may represent a single stratigraphic unit of the Serenitatis basin event. Four soils of the South Massif are identical in composition to medium-K KREEP; they are more feldspathic and lower in LIL trace elements relative to the boulder-2 rocks. The valley soil 75081 is like the 10084 soil; both soils are high in TiO2 and both are deficient in KREEP. Th and U give a sharp distinction between the valley and highland soils. The South Massif rocks and soils contain siderophiles at the 2–4% Cl level and show an ancient meteoritic pattern. Five samples of the four rocks have Ir/Au ratios of ± 0.02 which we assign to the Serenitatis basis planetesimal. The valley soil at Camelot Crater has low siderophiles (1% Cl). Our systematic study of four shadowed and exposed soils does not support the labile hypothesis for Cd, In, Tl and Zn. We observe no volatile (atmophile) movement from the South Massif highland soils to the valley soil 75081. The volatiles Cs and Tl appear to have been fractionated in the boulder-2 rocks during cratering, brecciation and metamorphic processes. The uniform ratio of FeO/MnO = 80–85, observed for all previous mare and highland sites, also holds for the Taurus-Littrow site. 相似文献
17.
Newly discovered Late Cretaceous adakites in South Fujian Province: Implications for the late Mesozoic tectonic evolution of Southeast China 
下载免费PDF全文
下载免费PDF全文 The Yongchun pluton is a Late Cretaceous adakitic intrusion in South Fujian Province, Southeast China, with associated metal mineralization. An understanding of the Yongchun pluton is helpful in tectono‐magmatic evolutionary processes, and is important in explaining the origin of related porphyry‐type deposits. Zircons from three samples of the pluton were analyzed by laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS), yielding U–Pb ages of 99.50 ±0.87 Ma, 97.74 ±0.59 Ma, and 99.65 ±0.92 Ma. These ages are similar to those of the Sifang, Luoboling, and Sukeng plutons, all of which are related to Cu–Pb–Zn–Mo mineralization within the study area. The Yongchun pluton comprises high‐potassium, calc‐alkaline, metaluminous rocks, with average A/CNK values of 0.91, 87Sr/86Sr ratios of 0.705 51 to 0.706 83, εNd(t) values of ?4.63 to ?5.90, and two‐stage Nd model (T2DM) ages of 1.49–1.39 Ga, indicating the magmas were generated by partial melting of Mesoproterozoic continental crust mixed with mantle‐derived magmas. The pluton has geochemical characteristics typical of adakites, such as a high Sr content (average 553 ppm), and low Y (average 15.2 ppm) and Yb (average 1.61 ppm) contents, indicating that the parental magma was formed under high‐pressure conditions. The magmatism was associated with thickening of the lower crust during a change in subduction angle and convergence rate of the paleo‐Pacific Plate at 100 Ma. The compression was limited to South Fujian Province. 相似文献
18.
Mantle-derived magmatic gas releasing features at the Rehai area, Tengchong county, Yunnan Province, China 总被引：3，自引：0，他引：3
This paper deals with the chemical and isotopic compositions of escaped gases from the Rehai geothermal area in Tengchong
county of Yunnan Province. Results indicate that there is the mantle-derived magmatic intrusion in shallow crust at this area.
Modern mantle-derived magmatic volatiles are being released currently in a steady stream by way of active faults. The escaped
gases are mostly composed of CO2, together with subordinate amounts of H2S, N2, H2, CH4, SO2, CO and He. At the studied area, the north-south directed fault is the deepest, and it may be interlinked with the deep-seated
thermal reservoir that would be directly recharged by the mantle-derived magmatic volatile. The He, C isotopic evidence reveals
that the modern active magma beneath Rehai area may originate from the historical mantle-derived magma which caused the latest
eruptive activity of volcanoes in that region. 相似文献
19.
Natural hot spring waters ascending rapidly to the surface become supersaturated with respect to quartz because of rapid cooling, separation of steam and sluggish deposition of quartz and other crystallineSiO 2 phases. Large amounts of silica are likely to be deposited in hot spring systems only after the solubility of amorphous silica has been exceeded. Cristobalite and chaleedony probably form in hot spring systems only by the crystallization of previously deposited silica gel rather than by direct deposition from solution. Experimental data indicate that the solubilit of quartz in water rises with increasing temperature along the vapor pressure curve to a maximum value of 725 ppm at 330°C. However, the maximum amount of silica likely, to occur in hot spring systems where quartz precipitates at depth is appreciably greater. Steam formation during adiabatic cooling of a water quickly brought to the surface from 330°C at depth might leave the silica in the remaining liquid concentrated to about 1150 to 1400 ppm. Under such conditions, amorphous silica might precipitate (probably as a colloidal suspension) after the water cooled below about 200°C to 250°C. Waters initially in equilibrium with quartz at a temperature less than 210°C probably will precipitate amorphous silica in channelways underground only when and where large quantities of steam separate from the waters as a result of sudden decreases in pressure or hydrostatic head. Above 150° to 200°C amorphous silica and volcanic glass can contribute very large quantities of silica to the solution. However, at these temperatures in natural systems they are eventually converted to crystalline phases. Thus, control of dissolved silica at depth is likely to be relatively short lived in respect to the ages of most hot spring systems. The dissolved-silica content of 90 hot spring waters from Yellowstone National Park was measured colorimetrically in the field immediately after collection. Comparison with laboratory studies on the solubility of amorphous silica indicates that many waters in «alkaline» springs are markedly undersaturated with silica with respect to amorphous silica at the temperatures of the pools. Thus, the dissolved silica content of these waters cannot be accounted for by equilibria with amorphous silica. Rather, silica appears to be controlled by the dissolution, deposition, or alteration of other silica-bearing phases at depth. Furthermore, many springs now have compositions essentially identical (with respect to all components) to those determined in 1888, indicating that either equilibrium or steady state conditions have prevailed at depth for a long time. Veins of fine-grained quartz were found in drill core from the Upper Basin, and it is reasonable to assume that quartz controlled the quantity of silica in solution in those places of deposition. Possibly the silica content of the surface waters might allow an estimate of the temperatures at which these waters were last in equilibrium with quartz at depth. Assuming adiabatic cooling along the vapor pressure curve and correcting for steam formation, quartz solubility data compared with natural water analyses suggests that underground temperatures approach 205°C in the Upper Geyser Basin of Yellowstone. In the Norris Geyser Basin, underground temperatures of 245°C are suggested. 相似文献
20.
利用水文地球化学数据建立温泉水文循环模型, 探讨温泉水文地球化学变化与地震的关系, 对中强地震短临流体异常判断具有重要的意义。 通过对石棉公益海温泉水常量元素、 微量元素和氢氧同位素以及锶同位素的测量, 探讨了该区域水文地球化学时空变化特征。 因此, 于2008年10月至2019年9月, 共对公益海温泉采集水样206个, 并对温泉水中离子组分和浓度, 温泉逸出气组分、 温泉气体同位素、 碳同位素和氢氧同位素含量进行测量。 分析结果表明: ① 公益海温泉主要为Na-HCO3·Cl型水, δD、 δ18O同位素测值分别为-14.19‰~-14.83‰和-108.67‰~-110.47‰, 分布于大气降水线附近, 说明温泉水主要源于大气降水; ② 据SiO2地温计计算热储温度约94.12℃, 循环深度约4.3 km, 表明大气降水入渗地下, 在热源加热后, 沿着断层和裂隙循环到地表, 形成温泉补给; 并且, 锶同位素和微量元素研究发现, 87Sr和86Sr主要来自硅酸盐类矿物, 微量元素含量较低, 水岩反应程度较弱; ③ 通过对研究区进行长时间连续观测发现, 在公益海周围300 km范围内的3个五级以上的地震使温泉水中常量元素的浓度, 分别出现了震前异常、 同震响应和震后效应。 推测这可能是因为公益海温泉位于公益海断裂和安宁河断裂的交会区, 推测周围的地震会触发公益海温泉水中的离子地球化学特征产生变化。 结合已有地质资料与公益海温泉水文地球化学数据, 建立公益海断裂带温泉水文循环模型, 这些对公益海断裂带周围未来中强地震短临流体异常判断具有重要的意义。 相似文献