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1.
Although acidifying deposition in western North America is lower than in many parts of the world, many high‐elevation ecosystems there are extremely sensitive to acidification. Previous studies determined that the Mount Zirkel Wilderness Area (MZWA) has the most acidic snowpack and aquatic ecosystems that are among the most sensitive in the region. In this study, spatial and temporal variability of ponds and lakes in and near the MZWA were examined to determine their sensitivity to acidification and the effects of acidic deposition during and after snowmelt. Within the areas identified as sensitive to acidification based on bedrock types, there was substantial variability in acid‐neutralizing capacity (ANC), which was related to differences in hydrological flowpaths that control delivery of weathering products to surface waters. Geological and topographic maps were of limited use in predicting acid sensitivity because their spatial resolution was not fine enough to capture the variability of these attributes for lakes and ponds with small catchment areas. Many of the lakes are sensitive to acidification (summer and autumn ANC < 100 µeq L?1), but none of them appeared to be threatened immediately by episodic or chronic acidification. In contrast, 22 ponds had minimum ANC < 30 µeq L?1, indicating that they are extremely sensitive to acidic deposition and could be damaged by episodic acidification, although net acidity (ANC < 0) was not measured in any of the ponds during the study. The lowest measured pH value was 5·4, and pH generally remained less than 6·0 throughout early summer in the most sensitive ponds, indicating that biological effects of acidification are possible at levels of atmospheric deposition that occurred during the study. The aquatic chemistry of lakes was dominated by atmospheric deposition and biogeochemical processes in soils and shallow ground water, whereas the aquatic chemistry of ponds was also affected by organic acids and biogeochemical processes in the water column and at the sediment–water interface. These results indicate that conceptual and mechanistic acidification models that have been developed for lakes and streams may be inadequate for predicting acidification in less‐understood systems such as ponds. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

2.
In the decades since dramatic reductions in acid emissions and subsequent deposition in North America and Europe, the vast majority of research on aquatic chemical recovery has focused on trends in acid–base concentrations during baseflow conditions. Missing from such assessments is consideration of higher flow periods, when flow paths and chemical concentrations change and episodic acidification may occur. Stream samples collected weekly and bi‐hourly during high‐flow storm events from 1992 to 2015 at three watersheds representing a gradient in response to acid deposition in the south‐eastern United States were used to evaluate temporal trends in acid anions, base cations, acid neutralizing capacity (ANC), and pH for each of five distinct flow exceedance regimes, as well as trends in concentration–discharge (C–Q) relationships. For the most well‐buffered watershed (mean ANC = 220 μeq L?1), ANC and pH increased at a similar rate for baseflow and storm flow conditions. Decreases in sulfate controlled ANC trends at higher flows, whereas smaller sulfate decreases in combination with base cation increases resulted in similar ANC improvements for low‐flow periods. For the most acid sensitive watershed (mean ANC = 10 μeq L?1), no trends in ANC or pH were observed for the lowest flows (>90% flow exceedance), whereas reductions in sulfate resulted in significant increases in ANC during higher flow conditions. At all sites, greater rates of sulfate decline during high‐flow, as compared with low‐flow, conditions are likely a result of a reduced capacity of near surface soils to adsorb and retain sulfur in these non‐glaciated watersheds. Overall, consistent increases in pH (~0.01–0.02 pH units year?1) during higher flow conditions (<10% flow exceedance) in contrast to the variable trends observed during lower flows (>50% flow exceedance) illustrate that episodic acidification is recovering at an equal or greater rate than chronic acidification in these watersheds.  相似文献   

3.
Monte-Carlo simulations were used to assess the extent of shortterm alkalinity depressions occuring in Sierra Nevada lakes due to acidic deposition events. The Episodic Event Model (EEM) was used to simulate spring snowmelt events. Snow course data, precipitation data and lake acidification surveys were used to derive values for the EEM parameters. Spring snowmelt events were shown to have great impacts on the water quality of Sierran lakes. Lakes are likely to be most affected by the early-spring snowmelt event because the epilimnion depth is at a minimum, which indicates minimum dilution. Under annual average loading conditions, no Sierran lake has been reported as acidic although 29% of the lakes have alkalinities less than 40 µeq/L indicating a sensitivity to acidification. In simulations of early-spring snowmelt events, using present-day acidic loading conditions, it was estimated 79% ± 9% of the lakes would experience shortterm lake alkalinity depressions to levels less than 40 µeq/L. The results provided by the model simulations are valuable in establishing upper and lower limits on the extent of possible episodic acidification to lake-resources-at-risk. The most critical parameters controlling the magnitude of lake alkalinity depressions during snowmelt episodic events are a) the lake area to watershed area ratio — a measure of input loading, and b) the epilimnion volume — a measure of dilution and mixing.  相似文献   

4.
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5.
Observations from the US Environmental Protection Agency's Episodic Response Project (ERP) in the North‐eastern United States are used to develop an empirical/mechanistic scheme for prediction of the minimum values of acid neutralizing capacity (ANC) during episodes. An acidification episode is defined as a hydrological event during which ANC decreases. The pre‐episode ANC is used to index the antecedent condition, and the stream flow increase reflects how much the relative contributions of sources of waters change during the episode. As much as 92% of the total variation in the minimum ANC in individual catchments can be explained (with levels of explanation >70% for nine of the 13 streams) by a multiple linear regression model that includes pre‐episode ANC and change in discharge as independent variables. The predictive scheme is demonstrated to be regionally robust, with the regional variance explained ranging from 77 to 83%. The scheme is not successful for each ERP stream, and reasons are suggested for the individual failures. The potential for applying the predictive scheme to other watersheds is demonstrated by testing the model with data from the Panola Mountain Research Watershed in the South‐eastern United States, where the variance explained by the model was 74%. The model can also be utilized to assess ‘chemically new’ and ‘chemically old’ water sources during acidification episodes. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

6.
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7.
Relationships between stream chemistry and elevation, area, Anakeesta geology, soil properties, and dominant vegetation were evaluated to identify the influence of basin characteristics on baseflow and stormflow chemistry in eight streams of the Great Smoky Mountains National Park. Statistical analyses were employed to determine differences between baseflow and stormflow chemistry, and relate basin‐scale factors governing local chemical processes to stream chemistry. Following precipitation events, stream pH was reduced and aluminium concentrations increased, while the response of acid neutralizing capacity (ANC), nitrate, sulfate, and base cations varied. Several basin characteristics were highly correlated with each other, demonstrating the interrelatedness of topographical, geological, soil, and vegetative parameters. These interrelated basin factors uniquely influenced acidification response in these streams. Streams in higher‐elevation basins (>975 m) had significantly lower pH, ANC, sodium, and silicon and higher nitrate concentrations (p < 0.05). Streams in smaller basins (<10 km2) had significantly lower nitrate, sodium, magnesium, silicon, and base cation concentrations. In stormflow, streams in basins with Anakeesta geology (>10%) had significantly lower pH and sodium concentrations, and higher aluminium concentrations. Chemical and physical soil characteristics and dominant overstory vegetation in basins were more strongly correlated with baseflow and stormflow chemical constituents than topographical and geological basin factors. Saturated hydraulic conductivity, of all the soil parameters, was most related to concentrations of stormflow constituents. Basins with higher average hydraulic conductivities were associated with lower stream pH, ANC, and base cation concentrations, and higher nitrate and sulfate concentrations. These results emphasize the importance of soil and geological properties influencing stream chemistry and promote the prioritization of management strategies for aquatic resources. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

8.
M. Newson  A. Baker  S. Mounsey 《水文研究》2001,15(6):989-1002
The forested Coalburn catchment (1·5 km2) in northern England experiences episodic stream acidification. To plan for sustainable management of the plantation forest cycle, an understanding is required of the flow pathways and hydrochemical routing signatures of the organic and mineral soils that make up the source areas for runoff. A tentative mixing model, based on simple water chemistry exists for the major (terrestrial) sources and buffers of acidification; it is being expanded and consolidated by a detailed approach to the organic components of runoff, via sampling and analysis of the luminescence of surface waters at the catchment outlet and in two distinctive feeder streams. Luminescence measurements are presented that permit a simple apportionment of source areas. However, the technique also appears to have potential for identifying differential flow sourcing between the acrotelm and catotelm of intact peat deposits and for clarifying the influence of forest root systems in altering the organic chemistry of infiltrating waters. Applications may include the monitoring and prediction of coloured water events for the water supply industry. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

9.
Acid‐neutralizing capacity (ANC) is an important index for streamwater acidification caused by external factors (i.e. chronic acid deposition) and internal factors such as soil acidification due to nitrification. In this study, the influence of forest clear‐cutting and subsequent regrowth on internal acidification was investigated in central Japan, where stream pH (near 7·0) and ANC (above 0·1 meq L?1) are high. pH, the concentrations of major cations (Na+, K+, Mg2+ and Ca2+), major anions (NO3?, Cl? and SO42?) and dissolved silica (Si), and ANC were measured in 33 watersheds of various stand ages, during 2002 to 2004. Only NO3? concentration decreased with stand age, whereas pH, ANC, and concentrations of the sum of base cations (BC) and Si were negatively correlated with the minimum elevation of the watershed. The correlation between the BC/Si ratio and minimum elevation suggested that factors contributing to acid neutralization changed at 1100 m above sea level. In watersheds at lower elevations (?1100 m), the relatively high contribution of soil water with longer soil contact times should result in higher ANC, and cation exchange reactions should be the dominant process for acid neutralization due to deposition of colluvial soils on the lower slope. In contrast, in higher‐elevation watersheds (≥1100 m), weathered residual soils are thin and the small contribution of deeper groundwater results in lower ANC. These results suggest that the local acid sensitivity is determined by the hydrological and geomorphologic factors generated by steep topography. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

10.
Factors affecting water chemistry of alpine lakes   总被引：2，自引：0，他引：2  
During a four-year study (1988–1991), 413 lakes in the Central Alps (Italy, Switzerland and Austria) were investigated to quantify their acidification. The ionic content of the lakes was generally low: 68% of them had alkalinity values of less than 200 µeq 1–1 and were regarded as sensitive to acidification. Moreover, 36% of the lakes showed alkalinity values of less than 50 µeq 1–1. Redundancy Analysis was used to relate the hydrochemistry of 187 lakes to their catchment characteristics. Calcite weathering was the main factor influencing lake chemistry. The same analysis, applied to a subset of 101 lakes lying in watersheds exclusively composed of silicic rocks, showed that lake chemistry was influenced by silicate weathering and nitrogen uptake. These processes were found to be mainly related to lake altitude and the fraction of the watershed not covered by vegetation, i.e. controlled by temperature. The importance of these relations to explain the pH shift produced by climatic variation is also discussed.  相似文献   

11.
Regional estimates of acid neutralizing capacity (ANC) in stream waters are found using a regression model. The model has landscape classifications based on catchment characteristics as its main independent variables. It also includes continuously varying covariates. Landscape classifications and covariates are selected from a priori scientific understanding of acidification processes. Parameter estimates for the model are found using measurements of ANC in 50 streams in Galloway, south‐west Scotland with a history of acidification. The parameterized model is then used to provide ANC simulations for streams throughout a subregion, assuming conservative mixing of ANC through the flow network. The stream water sampling survey is designed to reduce the variance of parameter estimates. A variance model is suggested for the concentrations, and this is used to simulate the variance of ANC concentrations throughout the subregion. Monte Carlo simulation is used to estimate the distribution of the length of river reach with ANC less than zero. © Crown Copyright 2004. Reproduced with the permission of Her Majesty's Stationery Office. Published by John Wiley & Sons, Ltd.  相似文献   

12.
Episodic flood delivery provides the bulk of the solid discharge for many small to moderate river systems, including the Rhône River in the northwestern Mediterranean. Several recent studies have demonstrated that the fate of this sediment depends on the coherence between river discharge and energetic ocean conditions. The deposition of flood sediment in the ocean can be confirmed by common signatures of episodic discharge events: presence of 7Be, physical stratification, and elevated clay content associated with low 210Pb activities.  相似文献   

13.
管锡东  蒋宏忱  姜颖  陈旭 《湖泊科学》2021,33(6):1940-1950
大气酸沉降会导致地表水体酸化和富营养化,同时气候变暖也会影响湖泊水体环境,湖泊生态系统如何响应二者相互作用是全球变化研究的热点之一.我国西南地区是全球酸沉降负荷最高的地区之一,然而目前对酸沉降影响下地表水环境变化规律知之甚少.本文以重庆四面山龙潭湖为研究对象,通过沉积岩芯的210Pb测年和硅藻分析,并结合流域历史资料数据,揭示龙潭湖过去近百年来水环境变化及其主要驱动因子.结果表明,1926-1968年,龙潭湖以Achnanthidium minutissimum和Encyonema silesiacum占优势;随后,Lindavia bodanica快速增加至峰值后逐渐减少,伴随Aulacoseira alpigena和Aulacoseira ambigua含量上升.硅藻组合中以适应中性和弱碱性水体的属种为主,嗜酸性属种含量很少,表明目前水体总体维持弱碱性,这得益于当地紫色砂页岩和森林土壤对于酸沉降的缓冲作用.尽管目前龙潭湖仍维持弱碱性,1980s以来硅藻推导水体酸碱度下降、中富营养种增加,表明酸沉降降低水体碱度并提高营养水平.气候变暖加剧水体热力分层和营养富集,导致适应扰动、贫营养环境的L.bodanica减少.2010年以来,中富营养属种略有减少反映湖泊富营养化有所减缓.  相似文献   

14.
The sources of episodic pH decline in four streams from northern Sweden during the autumn of 1996 were quantified. The events, in which pH dropped by between 1·0 and 2·4 units, were preceded by an extensive summer drought. Total organic carbon, which increased 100% to 160% during peak flow, was the most important driving mechanism of the episodic pH decline. Sulphate, however, was relatively more important during these autumn events than during spring flood. In the sites where past and present anthropogenic deposition were believed to be the main source of sulphate in stream water, sulphate contributed less than 0·3 pH units to the pH decline. In catchments where natural sources of sulphate are known to be important, sulphate contributed up to 0·6 units of pH decline. The export of sulphate during the episodes was two to nine times higher than what was expected from deposition only. The drought preceding the study episodes resulted in some of the lowest ground water levels during the 1990s in that region. The large export of sulphate was probably due to oxidation of natural sulphate bearing minerals in the soil and/or previously deposited sulphate driven by the low ground water level preceding the episodes. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

15.
In 1994, a network of small catchments (GEOMON) was established in the Czech Republic to determine input–output element fluxes in semi-natural forest ecosystems recovering from anthropogenic acidification. The network consists from 16 catchments and the primary observations of elements fluxes were complemented by monitoring of biomass stock, element pools in soil and vegetation, and the main water balance components. Over last three decades, reductions of SO2, NOx and NH3 emissions were followed by sulphur (S) and nitrogen (N) deposition reductions of 75% and 30%, respectively. Steeper declines of strong acid anion concentrations compared to cations (Ca, Mg, Na, K, NH4) in precipitation resulted in precipitation pH increase from 4.5 to 5.2 in bulk precipitation and from 4.0 to 5.1 in spruce throughfall. Stream chemistry responded to changes in deposition: S leaching declined. However at majority of catchments soils acted as a net source of S to runoff, delaying recovery. Stream pH increased at acidic streams (pH < 6) and aluminium concentration decreased. Stream nitrate (NO3) concentration declined by 60%, considerably more than N deposition. Stream NO3 concentration was tightly positively related to stream total dissolved nitrogen to total phosphorus (P) ratio, suggesting the role of P availability on N retention. Trends in dissolved organic carbon fluxes responded to both acidification recovery and to runoff temporal variation. An exceptional drought occurred between 2014 and 2019. Over this recent period, streamflow decreased by ≈ 40% on average compared to 1990s, due to the increases of soil evaporation and vegetation transpiration by ≈ 30% and declines in precipitation by ≈ 15% on average across the elevational gradient. Sharp decreases of stream runoff at catchments <650 m a.s.l. corresponded to areas of recent forest decline caused by bark beetle infestation on drought stressed spruce forests. Understanding of the interactions among legacies of acidification and eutrophication, drought effects on the water cycle and forest disturbance dynamics is requisite for effective management of forested ecosystems under anthropogenic influence.  相似文献   

16.
Long-term ecosystem studies are valuable for understanding integrated ecosystem response to global changes in atmospheric deposition and climate. We examined trends for a 35-year period (1982/83–2017/18) in concentrations of a range of solutes in precipitation and stream water from nine headwater catchments spanning elevation and surficial geology gradients at the Turkey Lakes watershed (TLW) in northeastern Ontario, Canada. Average annual water year (WY, October to September) concentrations in precipitation significantly declined over the period for sulphate (SO42−), nitrate (NO3−) and chloride (Cl−), while calcium (Ca2+) and potassium (K+) concentrations increased, resulting in a significant pH increase from 4.2 to 5.7. Trends in stream chemistry through time are generally consistent with expectations associated with acidification recovery. Concentration of many stream water solutes (SO42−, Cl−, calcium [Ca2+], magnesium [Mg2+] and NH4+ generally decreased, while others (silica [SiO2] and dissolved organic carbon [DOC]) generally increased. Increases were also observed for alkalinity (six of nine catchments), acid neutralizing capacity ([ANC]; six of nine catchments) and pH (eight of nine catchments), while conductivity declined (six of nine catchments). Variability in trends among catchments are associated with differences in surficial geology and wetland cover. While absolute solute concentrations were generally lower at bedrock dominated high-elevation catchments compared to till dominated lower elevation catchments, the rate of change of concentration was often greater for high elevation catchments. This study confirms continued, but non-linear stream chemistry recovery from acidification, particularly at the less buffered high and moderate elevation sites. The heterogeneity of responses among catchments highlights our incomplete understanding of the relative importance of different mechanisms influencing stream chemistry and the consequences for downstream ecosystems.  相似文献   

17.
Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two‐component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea‐salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre‐event and event water travelling along the shallow subsurface flow path. Pre‐event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre‐event–event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration–discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

18.
In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984–2001 and 1992–2001) and surface water chemistry (1992–2001) were determined in two of the most acid‐sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO42?), nitrate (NO3?), and base cation (CB) concentrations and increasing pH during 1984–2001, but few significant trends during 1992–2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO42? concentrations at all sites, and decreasing trends in NO3?, CB, and H+ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid‐neutralizing capacity (ANC) increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO42? trends, but it caused several significant non‐flow‐corrected trends in NO3? and ANC to become non‐significant, suggesting that trend results for flow‐sensitive constituents are affected by flow‐related climate variation. SO42? concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation–surface water comparisons, reflecting a strong link between S emissions, precipitation SO42? concentrations, and the processes that affect S cycling within these regions. NO3? and H+ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation–surface water comparisons, indicating that variation in local‐scale processes driven by factors such as climate are affecting trends in acid–base chemistry in these two regions. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

19.
Scientists and water users are concerned about the potential impact on water resources, particularly during low-flow periods, of freshwater withdrawals for hydraulic fracturing (fracking). Therefore, the objective of this paper is to assess the potential impact of hydraulic fracturing on water resources in the Muskingum watershed of Eastern Ohio, USA, especially due to the trend of increased withdrawals for hydraulic fracking during drought years. The Statistical Downscaling Model (SDSM) was used to generate 30 years of plausible future daily weather series in order to capture the possible dry periods. The data generated were incorporated in the Soil and Water Assessment Tool (SWAT) to examine the level of impact due to fracking at various scales. Analyses showed that water withdrawal due to hydraulic fracking had a noticeable impact, especially during low-flow periods. Clear changes in the 7-day minimum flows were detected among baseline, current and future scenarios when the worst-case scenario was implemented. The headwater streams in the sub-watersheds were highly affected, with significant decrease in 7-day low flows. The flow alteration in hydrologically-based (7Q10, i.e. 7-day 10-year low flow) or biologically-based (4B3 and 1B3) design flows due to hydraulic fracking increased with decrease in the drainage area, indicating that the relative impact may not be as great for higher order streams. Nevertheless, change in the annual mean flow was limited to 10%.  相似文献   

20.
Non-perennial streams comprise over half of the global stream network and impact downstream water quality. Although aridity is a primary driver of stream drying globally, surface flow permanence varies spatially and temporally within many headwater streams, suggesting that these complex drying patterns may be driven by topographic and subsurface factors. Indeed, these factors affect shallow groundwater flows in perennial systems, but there has been only limited characterisation of shallow groundwater residence times and groundwater contributions to intermittent streams. Here, we asked how groundwater residence times, shallow groundwater contributions to streamflow, and topography interact to control stream drying in headwater streams. We evaluated this overarching question in eight semi-arid headwater catchments based on surface flow observations during the low-flow period, coupled with tracer-based groundwater residence times. For one headwater catchment, we analysed stream drying during the seasonal flow recession and rewetting period using a sensor network that was interspersed between groundwater monitoring locations, and linked drying patterns to groundwater inputs and topography. We found a poor relationship between groundwater residence times and flowing network extent (R2 < 0.24). Although groundwater residence times indicated that old groundwater was present in all headwater streams, surface drying also occurred in each of them, suggesting old, deep flowpaths are insufficient to sustain surface flows. Indeed, the timing of stream drying at any given point typically coincided with a decrease in the contribution from near-surface sources and an increased relative contribution of groundwater to streamflow at that location, whereas the spatial pattern of drying within the stream network typically correlated with locations where groundwater inputs were most seasonally variable. Topographic metrics only explained ~30% of the variability in seasonal flow permanence, and surprisingly, we found no correlation with seasonal drying and down-valley subsurface storage area. Because we found complex spatial patterns, future studies should pair dense spatial observations of subsurface properties, such as hydraulic conductivity and transmissivity, to observations of seasonal flow permanence.  相似文献   

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