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1.
Hydrochemical, inverse geochemical modelling and isotopic approaches are used to assess the hydrogeochemical evolution of groundwater from the basement aquifers in the southeastern part of the Plateaux Region, Togo. Groundwater originates from present-day rainwater infiltration and is mostly fresh and slightly acidic to neutral. Hydrochemical facies are predominantly mixed cations-HCO3 associated with Ca/Mg-Cl, Na-HCO3 and Na-Cl water types in equilibrium with kaolinite and Ca/Mg-smectites. They are related to silicates hydrolysis, anthropogenic contamination, nitrification/denitrification, mixing along flowpaths and dissolution/precipitation of secondary minerals. The pattern of flow paths is in accordance with an increasing trend in total dissolved solids (TDS) toward the potentiometric depression located in the central and southern parts of the aquifer system. Inverse geochemical modelling using the NETPATH-WIN model showed the relative importance of biotite, plagioclase and amphibole weathering and dissolution of secondary carbonate minerals along the flowpath, suggesting that an abundance of minerals is not necessarily the main factor controlling the groundwater chemistry evolution.  相似文献   

2.
Groundwater is the major water resource in Jordan and most of the groundwater basins are already exploited beyond their estimated safe yield. Azraq basin is one of the most important groundwater basins in Jordan, which supplies Amman with drinking water. However, due to overpumping from the shallow groundwater aquifers, the water level dropped dramatically and signs of salinization and depletion are starting to occur. The severe drawdown in the Azraq well‐field caused a reverse in the hydraulic gradient and consequently, the saltwater in the center of the basin (Qa‐Azraq) started to move in the direction of the well‐field. The salinization in the shallow aquifer (basalt/B5/B4) is believed to result from one of the following scenarios: (i) a reverse flow from Sabkha to the AWSA well field, (ii) an upward leakage from the middle aquifer system (B2/A7) and the combined B3 Aquitard‐B2/A7 aquifer, (iii) a dissolution process between the water and rock matrix due to lowering of the dynamic water levels during pumping which reached the mineralized formations underlying the Basalt. The salinization trend of some AWSA wells represented by the gradual increase of major ions is associated with rather constant stable isotopic contents. This indicates that these constituents originate from the main minerals existing in the matrix of the aquifers and thus this scenario is the most likely to occur.  相似文献   

3.
The impacts of long-term pumping on groundwater chemistry remain unclear in the Manas River Basin, Northwest China. In this study, major ions within five surface water and 105 groundwater samples were analyzed to identify hydrogeochemical processes affecting groundwater composition and evolution along the regional-scale groundwater flow paths using the multivariate techniques of hierarchical cluster analysis (HCA) and principal components analysis (PCA) and traditional graphical methods for analyzing groundwater geochemistry. HCA classified the groundwater samples into four clusters (C1 to C4). PCA reduced the dimensionality of geochemical data into three PCs, which explained 86% of the total variance. The results of HCA and PCA were used to identify three zones: “recharge,” “transition,” and “discharge.” In the recharge zone the groundwater type is Ca-HCO3-SO4 and is primarily impacted by the dissolution of calcite and silicate weathering. In the transition zone the groundwater type is Ca-HCO3-SO4-Cl and is impacted by rock dissolution and reverse ion exchange. In the discharge zone the groundwater type is Na-Cl and is impacted by evaporation and reverse ion exchange. In addition, anthropogenic activities impact the groundwater chemistry in the study area. The groundwater type generally changes from Ca-HCO3-SO4 in the recharge area to Na-Cl in the discharge area along the regional-scale groundwater flow paths. This study provides a process-based knowledge for understanding the interaction of groundwater flow patterns and geochemical evolution within the Manas River Basin.  相似文献   

4.
The study area is located on the western part of the alluvium‐filled gap between the Rajmahal hills on the west and the Garo hills on the east. Groundwater occurs under unconfined condition in a thick zone of saturation within the Quaternary alluvial sediments. Three hydrochemical facies with distinct characteristics have been identified which are dominated in general by alkaline earths and weak acids. The major‐ion chemistry of the area is controlled by weathering of silicate minerals, rainfall recharge, ion‐exchange processes and anthropogenic activities such as irrigation return flow and the application of inorganic fertilizers and pesticides. A stoichiometric approach suggests that mineral dissolution and anthropogenic activities contribute 79% and 21% of the total cations dissolved in groundwater. Principal component analysis (PCA) of 42 groundwater samples using 13 chemical parameters indicates that the combined processes of recharge of groundwater from rainfall, sediment water interaction, groundwater flow, infiltration of irrigation return water (which is arsenic rich due to the use of arsenic‐bearing pesticides, wood preservatives, etc. and the pumping of arsenic‐rich groundwater for agriculture purpose), oxidation of natural or anthropogenic organic matter and the reductive dissolution of ferric iron and manganese oxides play a key role in the evolution of groundwater in the study area. Factor 2 scores, associated with the infiltration of irrigation return water and spatial distribution of arsenic concentration reveal that the groundwater of the municipal area will not be affected by arsenic in the future in spite of heavy groundwater abstraction. Another PCA with geologic, geomorphic, anthropogenic, geochemical and landuse factors indicates that arsenic concentration in groundwater increases with increasing area of mango orchards, sand lithofacies and nitrate and decreases with increasing distance of paleochannel from the monitored well and depth of bore wells. High loading on nitrate may be attributed to the use of fertilizer, pesticides, etc. in mango orchards and agricultural land. High loadings on log pCO2, mango orchards (with negative sign) and phosphate (with positive sign) indicate that mango orchards provide the organic waste material which is decomposed to form organic carbon. The organic carbon undergoes oxidative carbon degeneration by different oxidants and increases the concentration of CO2 in the aquifer. The reducing condition thus developed in the aquifer helps to dissolve the arsenic adsorbed on iron hydroxide or oxy‐hydroxide coated margins of sand, iron rich heavy mineral grain margins, clay minerals and Fe–Mn concretions present in the aquifer matrix. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

5.
With the increasing demand for water resources, the utilization of marginal water resources of poor-quality has become a focus of attention. The brackish water developed in the Loess Plateau is not only salty but also famous for its ‘bitterness’. In the present work, multi-isotope analysis (Sr, B) was combined with geochemical analysis to gain insight into the hydrogeochemical evolution and formation mechanisms of brackish water. These results demonstrate that groundwater in the headwater is influenced by carbonate weathering. After the confluence of several tributaries in the headwater, the total dissolved solids (TDS) of water is significantly increased. The dissolution of evaporates is shown to be the main source of salinity in brackish water, which also greatly affects the strontium isotopic composition of water. This includes the dissolution of Mg-rich minerals, which is the main cause of the bitterness. Furthermore, the release of calcium from the dissolution of gypsum may induce calcite precipitation and incongruent dissolution of dolomite, which also contributes to the enrichment of magnesium. The highly fractionated boron isotopic values observed in the upstream groundwater were explained by the absorption with clay minerals. The inflow of brackish groundwater is the source of river water. Then evaporation further aggravates the salinization of river water, with water quality evolving to saline conditions in the lower reach. When the river reaches the valley plain, the 87Sr/86Sr ratios decreases significantly, which is primarily related to erosion of the riverbanks during runoff. These results indicate that water resource sustainability could be enhanced by directing focus to mitigating salinization in the source area of the catchment.  相似文献   

6.
ABSTRACT

Hydrogeochemical investigations were carried out with an objective to identify the processes affecting the chemistry of groundwater in the Coimbatore district of Tamil Nadu, India. Thirty-three groundwater samples were collected from representative wells for chemical analysis. Groundwater types identified from piper plots were Ca-Mg-Cl and Na-Cl. The dominance of ions was in the order of Na>Ca>Mg>K and Cl>HCO3>SO4>CO3. Spatial variation diagrams of ions were generated using the geostatistical analyst tool ArcGIS 9.3. According to these diagrams, most of the ions were higher in the northeast and southeast regions. This is attributed to the flow direction of the groundwater and high residence times. Gibbs diagrams identified rock–water interaction as an important geochemical process in the district. Evaporation, ion exchange, silicate weathering and dissolution of carbonate minerals were identified as other important hydrogeochemical processes which influence the groundwater chemistry of the study area.
EDITOR D. Koutsoyiannis ASSOCIATE EDITOR M. Besbes  相似文献   

7.
ABSTRACT

Multivariate statistical analysis and inverse geochemical modelling techniques were employed to deduce the mechanism of groundwater evolution in the hard-rock terrain of Telangana, South India. Q-mode hierarchical cluster analysis (HCA) and principal component analysis (PCA) were used to extract the hydrogeochemical characteristics and classify the groundwater samples into three principal groups. Use of thermodynamic stability diagrams and inverse geochemical modelling in PHREEQC identified the chemical reactions controlling hydrogeochemistry of each of the groups obtained from statistical analysis. The model output showed that a few phases are governing the water chemistry in this area and the geochemical reactions responsible for evolution of groundwater chemistry along the flow path are (i) dissolution of evaporite minerals (dolomite, halite); (ii) dissolution of primary silicate minerals (albite, anorthite, K-feldspar, biotite); (iii) precipitation of secondary silicate minerals (kaolinite, quartz, gibbsite, Ca-montmorillonite) along with anhydrite and calcite; and (iv) reverse ion exchange processes.  相似文献   

8.
ABSTRACT

Water quality in the arid regions has long been an issue of great concern in the world. In this study, quantitative research was carried out to create new knowledge to understand the processes that determine the variation in the groundwater chemical composition of the Yinchuan Plain, China. In this context, the distribution and zonation characteristics of groundwater in this area were assessed using geochemical modelling of groundwater quality evolution. The results show the existence of an obvious zonation from the recharge area to the discharge area in the study area. Dominant anions transform from HCO3 in the inclined pluvial area to HCO3·SO4·Cl in the discharge region, while the main cations vary from Ca and Mg to Na and Mg. The simulation results indicate that the evaporation process triggers 2–35% of groundwater loss, leading to an increase in the total dissolved solids. The irrigation leakage mixes with the groundwater at about 8:2, suggesting that the irrigation leakage dilutes the groundwater.  相似文献   

9.
Groundwater is a very significant water source used for irrigation and drinking purposes in the karst region, and therefore understanding the hydrogeochemistry of karst water is extremely important. Surface water and groundwater were collected, and major chemical compositions and environmental isotopes in the water were measured in order to reveal the geochemical processes affecting water quality in the Gaoping karst basin, southwest China. Dominated by Ca2+, Mg2+, HCO3? and SO42?, the groundwater is typically characterized by Ca? Mg? HCO3 type in a shallow aquifer, and Ca? Mg? SO4 type in a deeper aquifer. Dissolution of dolomite aquifer with gypsiferous rocks and dedolomitization in karst aquifers are important processes for chemical compositions of water in the study basin, and produce water with increased Mg2+, Ca2+ and SO42? concentrations, and also increased TDS in surface water and groundwater. Mg2+/Ca2+ molar ratios in groundwater decrease slightly due to dedolomitization, while the mixing of discharge of groundwater with high Mg2+/Ca2+ ratios may be responsible for Mg2+/Ca2+ ratios obviously increasing in surface water, and Mg2+/Ca2+ ratios in both surface water and groundwater finally tending to a constant. In combination with environmental isotopic analyses, the major mechanism responsible for the water chemistry and its geochemical evolution in the study basin can be revealed as being mainly from the water–rock interaction in karst aquifers, the agricultural irrigation and its infiltration, the mixing of surface water and groundwater and the water movement along faults and joints in the karst basin. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

10.
The study of groundwater hydrogeochemistry of the Paleozoic Basses-Laurentides sedimentary rock aquifer system in Québec produced a large geochemical dataset. Groundwater samples were collected at 153 sites over a 1500 km2 study area and analyzed for major and minor ions. The large number of data can lead to difficulties in the integration, interpretation and representation of the results. Two multivariate statistical methods, hierarchical cluster analysis (HCA) and principal components analysis (PCA), were applied to a subgroup of the dataset to evaluate their usefulness to classify the groundwater samples, and to identify geochemical processes controlling groundwater geochemistry. This subgroup consisted of 144 samples and 14 parameters (Ca2+, Mg2+, Na+, K+, , Cl−, , Fe2+, Mn2+, Br−, Sr2+, F−, Ba2+, HS−). Seven geochemically distinct clusters, C1–C7, resulted from the HCA. Samples from clusters C3, C4, C6 and C7 are mostly located in preferential recharge areas. The majority of these samples have Ca–Mg–HCO3 recharge groundwater (C3, C6, C7) and Na–HCO3 evolved groundwater (C4). Samples from the other three clusters (C1, C2, C5) are characteristic of an aquifer system under confined conditions. The majority of these samples have Na–HCO3 evolved groundwater (C1, C5) and Na–Cl ancient groundwater that exhibits elevated concentrations in Br− (C2). In addition to recognizing the importance of hydrogeological conditions on groundwater geochemistry, the distribution of clusters also showed the importance of the geological formations on minor and trace elements, such as Fe2+, Mn2+, Sr2+, F− and Ba2+. The first five components of the PCA account for 78.3% of the total variance in the dataset. Component 1 is defined by highly positive loadings in Na+, Cl− and Br− and is related to groundwater mixing with Champlain Sea water and solute diffusion from the marine clay aquitard. The high positive loadings in Ca2+ and Mg2+ of component 2 suggest the importance of dissolution of carbonate rocks in this aquifer system. From their characteristic loadings, the first two components are defined as the “salinity” and “hardness” components, respectively. Components 3–5 are related to more local and geological effects. The integration of the HCA and the PCA, with conventional classification of groundwater types, as well as with the hydrogeological and geological contexts, allowed the division of the region into four main geochemical areas, providing an improved regional picture of the aquifer system dynamics and hydrogeochemical evolution of groundwater. The following factors were recognized as influencing the evolution of groundwater identified in every geochemical area: (1) geological characteristics including sedimentary rock type and till mineralogy; (2) hydrogeological characteristics represented by the level of confinement and the hydraulic gradient; and (3) the geological history including the latest glaciation and the Champlain Sea invasion. With its integrated approach, this hydrogeochemical study contributes to the characterization and understanding of complex groundwater flow systems, and provides an example of the long-term geochemical evolution of hydrogeological systems after a major perturbation, in this case seawater invasion.  相似文献   

11.
The aim of this study is to evaluate the impact of the application of industrial fertilizers and liquid swine manure in groundwater in two pilot agricultural areas, San Pedro and Pichidegua, which have been under long‐term historic use of fertilizers. A comprehensive hydrogeological investigation was carried out to define the geology and the groundwater flow system. Chemical and isotopic tools were used to evaluate the distribution and behavior of the nitrate in the groundwater. The isotopic tools included δ18O, δ2H, and 3H, which provide information about the origin and residence time of the groundwater; δ15N‐NO3? and δ18O‐NO3?, which provide information about nitrate sources and processes that can affect nitrate along the groundwater flow system. The application rate of liquid manure and other fertilizers all together with land uses was also evaluated. The hydrogeological investigation identified the presence of a confined aquifer underneath a thick low‐permeability aquitard, whose extension covers most of the two study areas. The nitrate concentration data, excepting a few points in zones located near recharge areas in the upper part of the basins and lower areas at the valley outlets (San Pedro), showed nitrate concentration below 10 mgN/L at the regional scale. The isotope data for nitrate showed no influence of the liquid swine manure in the groundwater at the regional scale, except for the high part of the basins and the outlet of the San Pedro valley, which are areas fertilized by manure. This data showed that the regional aquifer on both pilot study areas is protected by the thick low‐permeability aquitard, which is playing an important role on nitrate attenuation. Evidence of denitrification was also found on both shallow and deep groundwater in the Pichidegua site. This study showed that a comprehensive hydrogeological characterization complemented by chemical and isotope data is key for understanding nitrate distribution and concentration in aquifers from areas with intensive agriculture activities.  相似文献   

12.
Stable isotopic (δDVSMOW and δ18OVSMOW) and geochemical signatures were employed to constrain the geochemical evolution and sources of groundwater recharge in the arid Shule River Basin, Northwestern China, where extensive groundwater extraction occurs for agricultural and domestic supply. Springs in the mountain front of the Qilian Mountains, the Yumen‐Tashi groundwater (YTG), and the Guazhou groundwater (GZG) were Ca‐HCO3, Ca‐Mg‐HCO3‐SO4 and Na‐Mg‐SO4‐Cl type waters, respectively. Total dissolved solids (TDS) and major ion (Mg2+, Na+, Ca2+, K+, SO42?, Cl? and NO3?) concentrations of groundwater gradually increase from the mountain front to the lower reaches of the Guazhou Basin. Geochemical evolution in groundwater was possibly due to a combination of mineral dissolution, mixing processes and evapotranspiration along groundwater flow paths. The isotopic and geochemical variations in melt water, springs, river water, YTG and GZG, together with the end‐member mixing analysis (EMMA) indicate that the springs in the mountain front mainly originate from precipitation, the infiltration of melt water and river in the upper reaches; the lateral groundwater from the mountain front and river water in the middle reaches are probably effective recharge sources for the YTG, while contribution of precipitation to YTG is extremely limited; the GZG is mainly recharged by lateral groundwater flow from the Yumen‐Tashi Basin and irrigation return flow. The general characteristics of groundwater in the Shule River Basin have been initially identified, and the results should facilitate integrated management of groundwater and surface water resources in the study area. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

13.
Reclaimed water is efficiently used to recover the dry river, but river water and groundwater may be impacted considering the water quality. Thus, it is critical to study the factors controlling water chemistry. Samples of reclaimed water, river and groundwater were collected monthly from January to September in 2010, in Huai River (North China). And samples were analyzed for major 15 physio-chemical parameters. Using hierarchical cluster analysis, 9 months are divided into two distinct groups, which show the clear temporal variation. In reclaimed water and river water, one group includes February, while the other includes other months. In shallow and deep groundwater, one group includes months from January to April, while the other encompasses others. Monitoring stations are classified into three groups. Group A with high value of ions and nitrogen (order: NH4-N > NO3-N > NO2-N) includes reclaimed water and river water. Group B with moderate concentration and nitrogen (order: NO3-N > NH4-N > NO2-N) includes all shallow groundwater and one deep groundwater. Group C with the low value and nitrogen (order: NO3-N > NO2-N > NH4-N), includes two deep groundwater. Using multivariate analysis and ionic relationships, river water chemistry is found to be controlled by reclaimed water and evaporation process; chemistry in shallow groundwater and one deep groundwater, with type of Na–Ca(Mg)–HCO3–Cl, is controlled by dissolution of calcite, carbonate weathering. Additionally, reactions of nitrification, denitrification and cation exchange occur in the infiltration of reclaimed water; chemistry in the other deep groundwater, with type of Ca–Mg–HCO3–Cl, is controlled by dissolution of calcite, carbonate weathering and denitrification.  相似文献   

14.
Major‐ion compositions of groundwater are employed in this study of the water–rock interactions and hydrogeochemical evolution within a carbonate aquifer system. The groundwater samples were collected from boreholes or underground tunnels in the Ordovician limestone of Yanzhou Coalfield where catastrophic groundwater inflows can be hazardous to mining and impact use of the groundwater as a water supply. The concentration of total dissolved solid (TDS) ranged from 961 to 3555 mg/l and indicates moderately to highly mineralized water. The main water‐type of the middle Ordovician limestone groundwater is Ca‐Mg‐SO4, with SO42‐ ranging from 537 to 2297 mg/l, and average values of Ca2+ and Mg2+ of 455.7 and 116.6 mg/l, respectively. The water samples were supersaturated with respect to calcite and dolomite and undersaturated or saturated with respect to gypsum. Along the general flow direction, deduced from increases of TDS and Cl‐, the main water–rock interactions that caused hydrogeochemical evolution of the groundwater within the aquifer were the dissolution of gypsum, the precipitation of calcite, the dissolution or precipitation of dolomite, and ion exchange. Ion exchange is the major cause for the lower mole concentration of Ca2+ than that of SO42‐. The groundwater level of Ordovician aquifer is much higher than that of C‐P coal‐bearing aquifers, so the potential flow direction is upward, and the pyrite in coal is not a possible source of sulfate; additional data on the stable sulfur and oxygen isotopic composition of the sulfate may be helpful to identify its origin. Although ion exchange probably accounts for the higher mole concentration of Na+ than that of Cl‐, the dissolution of aluminosilicate cannot be ruled out. The data evaluation methods and results of this study could be useful in other areas to understand flow paths in aquifers and to provide information needed to identify the origin of groundwater. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

15.
Rainwater, groundwater and soil-water samples were analysed to assess groundwater geochemistry and the origin of salinity in the Ochi-Narkwa basin of the Central Region of Ghana. The samples were measured for major ions and stable isotopes (δ18O, δ2H and δ13C). The Cl? content in rainwater decreased with distance from the coast. The major hydrochemical facies were Na-Cl for the shallow groundwaters and Ca-Mg-HCO3, Na-Cl and Ca-Mg-Cl-SO4 for the deep groundwaters. Groundwater salinization is caused largely by halite dissolution and to a minor extent by silicate weathering and seawater intrusion. Stable isotope composition of the groundwaters followed a slope of 3.44, suggesting a mixing line. Chloride profiles in the soil zone revealed the existence of salt crusts, which support halite dissolution in the study area. A conceptual flow model developed to explain the mechanism of salinization showed principal groundwater flow in the NW–SE direction.
EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR K. Heal  相似文献   

16.
We estimated the effects of hydrogeological and surface temperature warming on subsurface thermal regime from the temperature-depth profiles and hydrological data of groundwater quality both in the quaternary and tertiary systems in the Sendai Plain as a preliminary step toward reconstruction of climate changes.Annual mean air temperature in the plain has increased about 1.5 °C in the last 70 years and this surface warming resulted in low or negative thermal gradient. However, anomaly of thermal gradient was recognized in not all temperature-depth profiles. Groundwater chemical compositions and stable isotope data (δD and δ18O) show that the groundwater flow system has marked difference between those of tertiary and quaternary systems. Calculated results of three dimensional groundwater flow and heat transport model ensure the above hypothesis and shows that thermal gradient changes at close to basement of the quaternary system. The differences in groundwater flow systems are expressed as subsurface thermal gradient anomalies in the temperature-depth profiles in the Sendai Plain. Furthermore, one-dimensional numerical analyze including the effect of surface warming indicates that calculated profile has departure from steady state line at depths in 60-80 m agree well with observed one.  相似文献   

17.
Abstract

In order to evaluate groundwater quality and geochemical reactions arising from mixing between seawater and dilute groundwater, we performed a hydrochemical investigation of alluvial groundwater in a limestone-rich coastal area of eastern South Korea. Two sites were chosen for comparison: an upstream site and a downstream site. Data of major ion chemistry and ratios of oxygen–hydrogen isotopes (δ18O, δD) revealed different major sources of groundwater salinity: recharge by sea-spray-affected precipitation in the upstream site, and seawater intrusion and diffusion zone fluctuation in the downstream site. The results of geochemical modelling showed that Ca2+ enrichment in the downstream area is caused by calcite dissolution enhanced by the ionic strength increase, as a result of seawater–groundwater mixing under open system conditions with a constant PCO2 value (about 10?1.5 atm). The results show that, for coastal alluvial groundwater residing on limestone, significant hydrochemical change (especially increased hardness) due to calcite dissolution enhanced by seawater mixing should be taken into account for better groundwater management. This process can be effectively evaluated using geochemical modelling.

Editor D. Koutsoyiannis; Associate editor Y. Guttman

Citation Chae, G.-T., Yun, S.-T., Yun, S.-M., Kim, K.-H., and So, C.-S., 2012. Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea. Hydrological Sciences Journal, 57 (8),1–12.  相似文献   

18.
Significant uncertainty remains in understanding the groundwater flow pathways in the northeastern Qinghai–Tibet Plateau. Hydrogeochemical and isotopic data as well as hydrogeological data were combined to explore the groundwater flow path in a representative cold alpine catchment in the headwater region of the Heihe River. The results indicate that the suprapermafrost groundwater chemical components were mainly affected by calcite dissolution and evaporation, whereas the geochemistry of subpermafrost groundwater was controlled by dolomite and gypsum dissolution, calcite precipitation, and albite and halite dissolution. Distinct hydrogeochemical characteristics and controlling processes suggest a poor hydraulic connectivity between the suprapermafrost and subpermafrost groundwater. The hydraulic connectivity between permafrost groundwater and groundwater in the seasonally frozen area was confirmed by their similar hydrogeochemical features. In the seasonally frozen area, a silty clay layer with low permeability separates the aquifer into the deep (depth >20 m) and shallow (depth <20 m) flow paths. The deep groundwater was characterized by the enhanced dedolomitization and enhanced cation exchange processes compared with the shallow groundwater. Groundwater in the seasonally frozen area finally discharges as base flow into the stream. These results provide useful information about the groundwater flow systems in the unique alpine gorge catchments in Qinghai–Tibet Plateau. The above findings suggest that the permafrost distribution and the aquifer structures within the seasonally frozen area have significant impact on groundwater flow paths. Cross‐validation by drilling work and hydrograph data confirms that the hydrogeochemical and isotopic tracers combined with field investigations can be relatively low‐cost tools in interpreting the groundwater flow paths in similar alpine catchments.  相似文献   

19.
Located at southern coast of China, the Pearl River Delta (PRD) is facing serious water problems in both quantity and quality after its rapid urbanization in the last decade. Most remarkably, the local groundwater, that was used to be the source of drinking water before the urbanization was polluted due to poor management of the septic tanks. In order to study the effects of suburban development on local groundwater flow and water quality in the PRD region, Fengcun of Guangzhou has been chosen as the study area. In Fengcun, drinking water was groundwater before the 1990s, but now piped reservoir water is used by each family because the groundwater has been polluted. This study clarifies the source and process of the groundwater pollution from septic tanks using isotopic and geochemical characteristics, especially nitrate (NO3?) concentrations. Water samples were collected from the wells and ponds in Fengcun in March and July 2005 and in July 2006. Based on the pe–pH diagram, NO3? and ammonium of groundwater are from the effect of human activities, rather than from nitrification and ammonification of N2. NO3? pollution of groundwater is from point sources, and NO3? concentrations decrease from northeast to southwest. Groundwater is polluted rapidly by the leakage of septic tanks. NO3? concentrations of pollution sources were lower than 20 mg l?1 in March 2005, but had increased to about 120 mg l?1 in July 2006. This implies that groundwater protection should be strengthened in rural areas of the PRD. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

20.
The Chihuahua City region, located in the semiarid-arid northern highlands of Mexico, has experienced intensive groundwater abstraction during the last 40 years to meet water demands in the region. A geochemical survey was carried out to investigate the evolution from baseline to modern conditions of a 130-km flow path including the El Sauz–Chihuahua–Aldama–San Diego de Alcalá regions. The research approach included the use of major chemical elements, chlorofluorocarbons and environmental isotope (18O, 2H, 13C and 14C) tracers. Stable isotopes indicate that groundwater evolves from the evaporation of local rainfall and surface water. Groundwater located at the lower end of the flow section is up to 6000 years old and older groundwater in the order of 9000 years BP was found in a deep well located in the upper part of the flow system, implying contribution from a neighbour basin. The background groundwater chemistry upstream of Chihuahua City results from feldspar weathering. Beyond Chihuahua City the chemical conditions are strongly modified owing to disposal of sewage from public and industrial water supplies into the Rio Chuviscar, subsequent allocation of this water to agricultural irrigation areas and direct infiltration under the river bed. As a consequence, anions like chloride and sulphate are mainly related to surface sources. Nitrate is controlled in part by sewage from public supply and industry and in part by agricultural practices. Arsenic and fluoride are related to weathering of rock formations of local mineralized ranges and subsequent enrichment of the basin-fill by magmatic processes. The results of this study have implications for groundwater management in an arid region that depends entirely on groundwater for domestic, industrial and agricultural water consumption. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

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