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1.
The study area is situated along the Zolotica river in NW Russia, located within the Kola–Dvyna Rift System in the Baltic Shield that developed during Meso and Neoproterozoic times. A 9-m thick section made up of shallow marine sediments of Upper Ediacaran age was sampled in this locality. Two volcaniclastic levels from the middle part of the section yielded an age of 556 Ma. (U/Pb SHRIMP-II on zircons). Two magnetic components were successfully isolated, component A (Decl = 157.1, Incl = 68.0, 95 = 1.9°, N = 575 in situ) carried by magnetite and component B (Decl = 120.3, Incl = − 31.7, 95 = 3.9°, N = 57, bedding corrected), carried by haematite. While component A is thought to represent a younger overprint direction, the in situ direction for component B on the other hand, is dissimilar to any expected younger direction and is considered to be primary magnetisation in origin, acquired during or soon after deposition of the sediments in the Late Ediacaran. The corresponding palaeomagnetic pole for component A in situ is located at Lon = 55.4°E, Lat = 31°N, A95 = 2.7° and for component B at Lon = 110°E, Lat = 28.3°S, A95 = 3.8°, N = 57. Combined with other palaeomagnetic poles of the same tectonostratigraphic unit an alternative apparent polar wander path for the Late Proterozoic–Early Palaeozoic of Baltica is proposed. Such an alternative path shows that after the mid Cryogenian (750 Ma), the poles that were situated over South Africa (p.d.c.) moved to the east until they reached Australia during the Late Ediacaran (555 Ma) where they remained approximately stationary until the beginning of the Cambrian (545 Ma). Finally, they moved to the northwest until they reached the Arabian Peninsula in the Early Ordovician. Palaeolatitudes indicate that Baltica situated near the equator from the Cryogenian through to the Ediacaran moving gradually to the south at c. 1 cm/yr. During the Late Early Ediacaran, the plate suddenly began to drift northward at c. 8 cm/yr and in the boundary with the Cambrian it was positioned in low to intermediate latitudes. Finally, Baltica began to move back to the south at c. 13 cm/yr until in the Early Ordovician, reaching intermediate to high southern latitudes.  相似文献   

2.
This study investigates the seismic demands due to the catastrophic 1999 Mw=7.4 Kocaeli and the Mw=7.1 Duzce earthquakes. The inelastic response spectra for the Kocaeli and Duzce earthquakes are investigated for systems with known strength and ductility. An analytical fiber element model is developed for a typical reinforced concrete building in Turkey. The interstory drifts are calculated from nonlinear dynamic analysis using 26 recorded strong-motion data from the 1999 Kocaeli and the Duzce earthquakes. In the dynamic analysis, the structural members are modeled by employing distributed plasticity fiber elements and both geometrical as well as material nonlinearities are taken into account. This study shows that the ductility and interstory drift demands due to the Kocaeli and the Duzce earthquakes were very severe (well above the code prescribed values) even for moderately inelastic structures. It is apparent from the results that the forward directivity effect is the most influential factor on the interstory drift demand. Both the distance to the fault rupture and the site conditions affect seismic demands, but the site conditions and the local topography are more influential than the distance from the fault rupture. This study shows that substantial damage should be expected in a future earthquake at all districts of Istanbul, but especially at Avcilar, Cekmece, Fatih, Bakirkoy and the Zeytinburnu districts. It is also shown that base isolation may substantially improve the performance of a structure in the inelastic domain and base isolated structures may be designed for lower minimum lateral strengths and higher strength reduction factors.  相似文献   

3.
A phase transition in pure CaSiO3 perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO3 perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al2O3 content dissolved in CaSiO3 perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO3(+ 3 wt.% Al2O3) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range.  相似文献   

4.
The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe2SiO4 olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K0 = 1.19 ± 0.10 Mbar and K0′ = 7 ± 4, and if we assume K0′ = 5: K0 = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made.  相似文献   

5.
Pressure–volume measurements have been performed for CaSiO3 perovskite to 108 GPa at 300 K using NaCl and argon pressure-transmitting media, and energy dispersive X-ray diffraction (EDXD) in a diamond-anvil cell (DAC). By determining a parameter that is the product of the elastic anisotropy, S, and the uniaxial stress component, t, for each data point, we define the stress condition of the sample. For different points at the same pressure in a temperature-quenched sample, the St value can differ by as much as a factor of 5, indicating heterogeneity in the stress condition. This may be responsible for the large scatter of earlier PV measurements in the DAC which in general used a large diameter X-ray beam. Also, the St value provides insight into the elastic anisotropy, S, of CaSiO3 perovskite and platinum. The sign of S (positive) for CaSiO3 perovskite agrees with first principles calculations but the magnitude may be inconsistent. A new compression curve at 300 K was obtained for CaSiO3 perovskite by using those data points which represent the most nearly hydrostatic conditions. It is observed that the data points with high St values yield larger volumes than the points with small St values at a given pressure. By selecting the data points having low St values (St≤0.005), combining with lower pressure large volume press (LVP) measurements and fitting to third order Birch–Murnaghan equation of state (EOS), we find that CaSiO3 perovskite is more compressible (V0=45.58±0.05 Å3, KT0=236±4 GPa, and KT0′=3.9±0.2 GPa) than suggested by previous studies. The density and bulk modulus of CaSiO3 perovskite at lower mantle pressures and 300 K are 1–3% greater and 5–15% smaller, respectively, than found in previous studies. This study demonstrates that defining the stress state of the sample is crucial to obtain an accurate 300 K compression curve for unquenchable high-pressure phases.  相似文献   

6.
Chemical heterogeneities in the Martian mantle are believed to result from the crystallization of a magma ocean in the first 100 million years of its history. Shergottite meteorites from Mars are thought to retain a compositional record of such early differentiation and the resulting mineralogy at different depths. The coupled 176Lu–176Hf and 147Sm–143Nd isotope systematics in 9 shergottites are used here to investigate these issues. Three compositional groups in the shergottites display distinct isotope systematics. One group, commonly termed as depleted, is characterized by positive 176Hfi from + 46.2 to + 50.4 and 143Ndi from + 36.2 to + 39.1. Another, termed as enriched, has negative 176Hfi = − 16.5 to − 13.2 and 143Ndi = − 7.0 to − 6.5. The third group is intermediate between the depleted and enriched groups with positive 176Hfi = + 30.0 to + 33.4 and 143Ndi = + 16.9. Together, they describe mixing curves between 176Hf/177Hf, 143Nd/144Nd, Lu/Hf, and Sm/Nd, implying that they sample two distinct sources in the Martian mantle. All shergottites are characterized by (Sm/Nd)source < (Sm/Nd)sample, but (Lu/Hf)source > (Lu/Hf)sample. This decoupling can be explained by two successive partial melting episodes in the depleted shergottite source and localized in the Martian upper mantle. The genesis of shergottites can be modeled using non-modal equilibrium partial melting in a source initially composed of 60% olivine, 21% clinopyroxene, 9% orthopyroxene, and 10% garnet, with degrees of partial melting of 8.8% and 3.9%, respectively, for the two successive events. The enriched end-member of the shergottite mixing curve is best modeled by late-stage quenched residual melt resulting from the crystallization of a magma ocean. The depleted shergottite source may be modeled as a mixture of cumulates and residual melt, as convection in the Martian magma ocean is expected to reduce the incompatible trace element heterogeneity in the final solidified layers. Consequently, equilibrium crystallization is preferred to model the crystallization of the Martian magma ocean. The models that best explain the shergottite data are those where the magma ocean is at a depth of at least 1350 km in Mars.  相似文献   

7.
Osamu  Ujike  Alan M.  Goodwin  Tomoyuki  Shibata 《Island Arc》2007,16(1):191-208
Abstract   Volcanic rocks from the Upper Keewatin assemblage ( ca 2720 Ma) were geochemically classified into five groups; komatiites, tholeiitic rocks having near-flat primitive mantle-normalized abundance patterns, Nb-enriched basalts and andesites (NEBA) plus normal calc-alkaline (NCA) rocks, adakites and shoshonites. The adakites having [La/Yb]N >30 and <30 were probably derived from felsic magmas formed by partial melting of a subducted slab at relatively greater and smaller depths, respectively. Ascending adakite magmas, by interaction with the overlying mantle wedge, decreased in Al2O3 / Y ratio and selectively lost high-field strength elements, thereby forming mantle sources for both NEBA + NCA and shoshonite magmas. Under the influence of a mantle plume, the source of komatiites, the NEBA + NCA magmas were generated from that part of the mantle wedge metasomatized by adakite magmas having [La / Yb]N <30, and tholeiitic magmas from unmetasomatized part of the same mantle wedge. Magmas of both adakites having [La / Yb]N >30 and shoshonites were generated in a normal Archean Arc system setting.  相似文献   

8.
Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a PT liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献   

9.
Primitive basaltic single eruptions in the Big Pine Volcanic Field (BPVF) of Owens Valley, California show systematic temporal–compositional variation that cannot be described by simple models of fractional crystallization, partial melting of a single source, or crustal contamination. We targeted five monogenetic eruption sequences in the BPVF for detailed chemical and isotopic measurements and 40Ar/39Ar dating, focusing primarily on the Papoose Canyon sequence. The vent of the primitive (Mg# = 69) Papoose Canyon sequence (760.8 ± 22.8 ka) produced magmas with systematically decreasing (up to a factor of two) incompatible element concentrations, at roughly constant MgO (9.8 ± 0.3 (1σ) wt.%) and Na2O. SiO2 and compatible elements (Cr and Ni) show systematic increases, while 87Sr/86Sr systematically decreases (0.7063–0.7055) and εNd increases (− 3.4 to − 1.1). 187Os/188Os is highly radiogenic (0.20–0.31), but variations among four samples do not correlate with other chemical or isotopic indices, are not systematic with respect to eruption order, and thus the Os system appears to be decoupled from the dominant trends. The single eruption trends likely result from coupled melting and mixing of two isotopically distinct sources, either through melt-rock interaction or melting of a lithologically heterogeneous source. The other four sequences, Jalopy Cone (469.4 ± 9.2 ka), Quarry Cone (90.5 ±17.6 ka), Volcanic Bomb Cone (61.6 ± 23.4 ka), and Goodale Bee Cone (31.8 ± 12.1 ka) show similar systematic temporal decreases in incompatible elements. Monogenetic volcanic fields are often used to decipher tectonic changes on the order of 105–106 yr through long-term changes in lava chemistry. However, the systematic variation found in Papoose Canyon (100–102 yr) nearly spans that of the entire volcanic field, and straddles cutoffs for models of changing tectonic regime over much longer time-scales. Moreover, ten new 40Ar/39Ar ages combined with chemistry from all BPVF single eruption sequences show the long-term trend of BPVF evolution comprises the overlapping, temporal–compositional trends of the monogenetic vents. This suggests that the single eruption sequences contain the bulk of the systematic chemical variation, whereas their aggregate compositions define the long-term trend of volcanic field evolution.  相似文献   

10.
Values of bulk modulus (K), shear modulus (G) and mechanical quality factor (Q) have been determined for polycrystalline samples across the CaTiO3 (CST0)–SrTiO3 (CST100) solid solution by resonant ultrasound spectroscopy. Because of similarities with low frequency elastic and anelastic anomalies due to twin wall motion reported in previous studies, a working hypothesis is developed in which dissipation processes are interpreted in terms of twin wall displacements. At high temperatures in CST50 the stability field of the I4/mcm structure is marked by the disappearance of all resonance peaks (superattenuation). This is attributed to anelastic domain wall sliding. At room temperature the I4/mcm phase of CST70 and CST80 has values of G which are lower than those of cubic or orthorhombic phases, and a concomitant drop in Q is interpreted as implying that the domain wall pinning process reported elsewhere to occur below 400–450 K is only partial. A similar drop in G and Q was found in CST95 below the transition at 238 K. The I4/mcm ↔ Pbcm transition in CST70 at 230 K is marked by an abrupt increase in Q, suggesting that mobile twins in crystals with the I4/mcm structure become effectively immobile in antiferroelectric crystals with the Pbcm structure. The I4/mcm ↔ Pnma transition in CST50 is marked by a similarly abrupt increase in Q, consistent with twin walls becoming effectively immobile also in crystals with the Pnma structure. A fall in Q below 800 K in CST0, however, could imply that a degree of twin wall mobility might develop in Pnma crystals if the tetragonal spontaneous strain departs significantly from zero. The remarkable attenuation behaviour of crystals with the I4/mcm structure at the relatively low stress conditions which apply during resonances of a parallelepiped with edge dimensions of 2–4 mm, is consistent with the view that a characteristic signature for tetragonal CaSiO3 in the Earth's lower mantle should be a marked attenuation of seismic waves.  相似文献   

11.
Statistical relations between different earthquake parameters, such as M0 (seismic moment), ES (seismic energy), τa (apparent stress), A (rupture area), g (average slip acceleration), are investigated. For this purpose, a kinematic earthquake model representing averaged earthquake rupture process is formulated. The model implies a scaling relationship for τa as a function of three other parameters, related to kinematic (M0), geometric (A) and material (g) source characteristics, which, according to the model, can change independently. This scaling relation is used to explain statistical trends that characterize different earthquake data sets (including micro-, small, moderate and large events) plotted in the log τa − log M0 space, and to determine the area in this space, where typical earthquakes occur. The scaling relationship is interpreted in terms of the apparent stress minimum (i.e., the most uniform among the possible earthquake rupture patterns). It is concluded that, although the apparent stress increases on an average with increasing seismic moment, small and large earthquakes are essentially similar.  相似文献   

12.
The accumulation of MF radar wind and hydroxyl temperature measurements at Davis from 1997 to 2005 has enabled the compilation of a climatology of long-period (period >1 day) wave activity. A time domain filtering technique that makes allowance for the differing sampling characteristics of the measurements is described and wave amplitudes are presented for 1.7–4, 4–8 and 8–16 day period bands. Product averages of the time series yield horizontal heat and momentum fluxes for the height of the hydroxyl layer (approximately 86 km). The climatology is then discussed in terms of current knowledge of planetary wave characteristics and forcing. Heat and momentum fluxes during the year of the southern hemisphere stratospheric warming (2002) are also presented.  相似文献   

13.
14.
15.
Hydrogeochemical investigations along an E–W transect in the middle Meghna basin show groundwater chemistry and redox condition vary considerably with the change in geology. Groundwater in the Holocene shallow (<150 m bgl) alluvial aquifer in western part of the transect is affected by high arsenic concentration (As > 10 μg/l) and salinity. On the other hand, groundwater from the Pliocene Dupi Tila sandy aquifer in the eastern part is fresh and low in As (<10 μg/l). The Holocene shallow aquifers are high in dissolved As, , Fe and dissolved organic carbon (DOC), but generally low in and . High concentrations (250–716 mg/l) together with high DOC concentrations (1.4–21.7 mg/l) in these aquifers reflect active sources of degradable natural organic matter that drives the biogeochemical process. There is generally de-coupling of As from other redox-sensitive elements. In contrast, the Pliocene aquifers are low in As, and DOC. Molar ratio of /H4SiO4 suggests that silicate weathering is dominant in the deeper Holocene aquifers and in the Pliocene aquifers. Molar ratios of Cl/ and Na+/Cl suggest mixing of relict seawater with the fresh water as the origin of groundwater salinity. Speciation calculations show that saturation indices for siderite and rhodochrosite vary significantly between the Holocene and Pliocene aquifers. Stable isotopes (δ2H and δ18O) in groundwater indicate rapid infiltration without significant effects of evaporation. The isotopic data also indicates groundwater recharge from monsoonal precipitation with some impact of altitude effect at the base of the Tripura Hills in the east. The results of the study clearly indicate geological control (i.e. change in lithofacies) on groundwater chemistry and distribution of redox-sensitive elements such as As along the transect.  相似文献   

16.
Monitoring the water balance of Lake Victoria, East Africa, from space   总被引:3,自引:0,他引:3  
Sean Swenson  John Wahr   《Journal of Hydrology》2009,370(1-4):163-176
Using satellite gravimetric and altimetric data, we examine trends in water storage and lake levels of multiple lakes in the Great Rift Valley region of East Africa for the years 2003–2008. GRACE total water storage estimates reveal that water storage declined in much of East Africa, by as much as , while altimetric data show that lake levels in some large lakes dropped by as much as 1–2 m. The largest declines occurred in Lake Victoria, the Earth’s second largest freshwater body. Because the discharge from the outlet of Lake Victoria is used to generate hydroelectric power, the role of human management in the lake’s decline has been questioned. By comparing catchment water storage trends to lake level trends, we confirm that climatic forcing explains only about 50decline. This analysis provides an independent means of assessing the relative impacts of climate and human management on the water balance of Lake Victoria that does not depend on observations of dam discharge, which may not be publically available. In the second part of the study, the individual components of the lake water balance are estimated. Satellite estimates of changes in lake level, precipitation, and evaporation are used with observed lake discharge to develop a parameterization for estimating subsurface inflows due to changes in groundwater storage estimated from satellite gravimetry. At seasonal timescales, this approach provides closure to Lake Victoria’s water balance to within . The third part of this study uses the water balance of a downstream water body, Lake Kyoga, to estimate the outflow from Lake Victoria remotely. Because Lake Kyoga is roughly 20 times smaller in area than Lake Victoria, its water balance is strongly influenced by inflow from Lake Victoria. Lake Kyoga has been shown to act as a linear reservoir, where its outflow is proportional to the height of the lake. This model can be used with satellite altimetric lake levels to estimate a time series of Lake Victoria discharge with an rms error of about .  相似文献   

17.
Grain-growth kinetics in wadsleyite was investigated using a multianvil high-pressure apparatus. Fine-grained wadsleyite aggregates were synthesized by isostatic hot-pressing and were subsequently annealed under high pressure and temperature in a controlled chemical environment. Wadsleyite samples show normal grain-growth characterized by a log-normal grain-size distribution following the relation, where n is a constant, L the grain-size at time t, L0 the grain-size at time t = 0 and k is a rate constant that depends on temperature T and chemical environments (fO2: oxygen fugacity in Pa, COH: water content in H/106Si) as:
  相似文献   

18.
The Bakjisan Syncline is located in the northwestern part of the Taebaeksan Basin, Korea. New paleomagnetic data for the Upper Carboniferous–Lower Triassic Pyeongan Supergroup from the Pyeongchang area on the west limb of the Bakjisan Syncline have been obtained, and synthesized and compared with previous data from the Jeongseon area on the east limb of the syncline. A total of 350 specimens were collected from 21 sites to clarify the relationship between the spatial distribution of remagnetized areas and the thrust system in the Taebaeksan Basin. The characteristic remanent magnetization (ChRM) isolated from all samples was a remagnetized component acquired after tilting of the strata and carried by various magnetic minerals (magnetite, hematite and pyrrhotite). From rock magnetic studies, electron microscope observations and XRD analyses, the pervasive remagnetization is interpreted to be associated mainly with a fluid-mediated chemical remanent magnetization (CRM). This is consistent with the results of previous work in adjacent areas. The paleomagnetic pole position (88.3°E, 83.9°N, A95 = 4.9°) from the Pyeongan Supergroup in the Bakjisan Syncline indicates that the timing of the remagnetization event is Early Tertiary times (i.e. Paleocene to Eocene) by comparison with reliable paleopoles from the Korean Peninsula. Early Tertiary CRMs are also reported from previous studies of an adjacent region within the northwestern part of the Taebaeksan Basin. In contrast, a primary remanent magnetization was reported in the southeastern part of the Taebaeksan Basin. This implies that the major thrust system (the Gakdong thrust) which separates the two regions has caused them to experience substantially different geologic histories since deposition of the strata. Since many thrusts with NS trend are observed in the northwestern part of the Taebaeksan Basin compared with the southeastern region, it appears that the remagnetizing fluids pervasively penetrated the northwestern part of the basin by utilizing the already well-developed thrust system.  相似文献   

19.
New U–Pb age-data from zircons separated from a Northland ophiolite gabbro yield a mean 206Pb/238U age of 31.6 ± 0.2 Ma, providing support for a recently determined 28.3 ± 0.2 Ma SHRIMP age of an associated plagiogranite and  29–26 Ma 40Ar/39Ar ages (n = 9) of basalts of the ophiolite. Elsewhere, Miocene arc-related calc-alkaline andesite dikes which intrude the ophiolitic rocks contain zircons which yield mean 206Pb/238U ages of 20.1 ± 0.2 and 19.8 ± 0.2 Ma. The ophiolite gabbro and the andesites both contain rare inherited zircons ranging from 122–104 Ma. The Early Cretaceous zircons in the arc andesites are interpreted as xenocrysts from the Mt. Camel basement terrane through which magmas of the Northland Miocene arc lavas erupted. The inherited zircons in the ophiolite gabbros suggest that a small fraction of this basement was introduced into the suboceanic mantle by subduction and mixed with mantle melts during ophiolite formation.

We postulate that the tholeiitic suite of the ophiolite represents the crustal segment of SSZ lithosphere (SSZL) generated in the southern South Fiji Basin (SFB) at a northeast-dipping subduction zone that was initiated at about 35 Ma. The subduction zone nucleated along a pre-existing transform boundary separating circa 45–20 Ma oceanic lithosphere to the north and west of the Northland Peninsula from nascent back arc basin lithosphere of the SFB. Construction of the SSZL propagated southward along the transform boundary as the SFB continued to unzip to the southeast. After subduction of a large portion of oceanic lithosphere by about 26 Ma and collision of the SSZL with New Zealand, compression between the Australian Plate and the Pacific Plate was taken up along a new southwest-dipping subduction zone behind the SSZL. Renewed volcanism began in the oceanic forearc at 25 Ma producing boninitic-like, SSZ and within-plate alkalic and calc-alkaline rocks. Rocks of these types temporally overlap ophiolite emplacement and subsequent Miocene continental arc construction.  相似文献   


20.
In this paper the chemistry of major and trace elements and, for the first time, strontium isotopic ratios measured in running waters from the Arno River Basin (Tuscany, central-northern Italy) and thermal springs discharging in the same hydrographic system are presented and discussed. Classical graphical methods (e.g. mixing diagrams) have here been improved to identify, in a correct statistical sample space, extreme chemical compositions attributable to the action of geochemical processes and/or inherited from specific lithologies (namely contributions or components 1, 2 and 3) to be used in inverse modeling procedures, due to the absence of clear end-members. A linear least squares problem, with non-negativity constraints and distances, as required for compositional data (convex linear mixing) was solved by considering the contribution of the most discriminant variables given by the 87Sr/86Sr isotopic ratios and the concentration of Ca2+, Mg2+, Sr and Rb. Following such approach, it can be assumed (p < 0.05) that component 1, characterized by a Ca2+(Mg2+)– radiogenic-rich (87Sr/86Sr = 0.71274; Rb/Sr = 0.039), represents a dominant feature at basin scale, with a weight ranging from 69% to 100%. Much lower percentages are related to component 2, represented by a Ca2+(Mg2+)– facies with intermediate 87Sr/86Sr (0.70874) and low Rb/Sr (2.8 × 10−4) ratios and component 3, identified by Ca2+ facies with less radiogenic 87Sr/86Sr (0.70827) and low Mg2+/Ca2+ (0.011) ratios. These components are mainly dominated by the dissolution of evaporitic rocks and/or mixing with thermal waters in the southern part of the Arno River Basin and by dissolution of the carbonatic fraction, kinetically favored with respect to that of the silicatic minerals, in the upper reaches of the main course and its tributaries, respectively.  相似文献   

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