共查询到10条相似文献，搜索用时 359 毫秒
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Brittany R. Kruger Brent J. Dalzell Elizabeth C. Minor 《Aquatic Sciences - Research Across Boundaries》2011,73(3):405-417
In this study, samples were taken from three contrasting freshwater sources and amended with salt in order to determine the
influence of salinity and dissolved organic matter (DOM) composition on DOM recovery via ultrafiltration and solid phase extraction
(SPE) with C18 disks. Salt addition caused variable recovery of DOM when using C18 SPE, and ultraviolet–visible spectroscopic characterization of the extracted material showed spectral responses that varied
among sample sources. In contrast, increasing sample salinity from 0 to 30 ppt consistently caused a 15–25% reduction in the
amount of high molecular weight DOM isolated by ultrafiltration for both dissolved organic carbon (DOC) and chromophoric DOM
(CDOM), regardless of DOM composition. We hypothesize that a change in conformation (such as coiling or disaggregation) of
DOM molecules occurs in the presence of salt, allowing them to pass through the ultrafiltration membrane and thereby decreasing
the DOM retained by ultrafiltration. These results are important because they demonstrate that changes in salinity can influence
DOM recovery in estuaries. Interpretation of DOM characteristics along estuarine gradients needs to account for potential
artifacts introduced by sample isolation techniques. 相似文献
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Megan J. Macdonald Elizabeth C. Minor 《Aquatic Sciences - Research Across Boundaries》2013,75(4):509-522
The input and fate of dissolved organic matter (DOM) can have important consequences for coastal zone productivity in large lakes and oceans. Chromophoric DOM (CDOM) is often delivered to coastal zones from rivers and streams and affects light penetration in a water column. CDOM can protect biota from damaging ultraviolet (UV) light by acting as sunscreen, resulting in increased ecosystem productivity. Alternatively, CDOM can decrease ecosystem productivity by absorbing light needed for photosynthesis and forming photoreaction products that are harmful to coastal zone biota. Increased urbanization of watersheds and seasonal differences in weather patterns change the delivery pathways, reactivity, input, and energy flow of DOM (and its CDOM component) into aquatic systems. This study investigated the effects of watershed and season on the concentrations and potential photodegradation of stream-derived DOM in Lake Superior tributaries, chosen to be geographically and geologically similar but differing in land use. Organic carbon analysis, UV–Visible spectrophotometry, and terrestrial (land use) analysis were used to investigate differences among samples and sample treatments. The major differences in DOM concentration and photochemical response appeared seasonal rather than site specific, with snow-melt samples showing stronger and more consistent changes in UV–Visible parameters while base-flow samples showed stronger and more consistent losses in DOC. 相似文献
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The spatial and diurnal tidal variability of dissolved organic carbon (DOC) concentrations and the composition of dissolved
organic matter (DOM), as evaluated by high-temperature catalytic oxidation and excitation–emission matrix combined with parallel
factor analysis (EEM–PARAFAC), respectively, were determined in Liverpool Bay. EEM–PARAFAC modeling resulted in six fluorescent
components characterized as terrestrial humic-like (two), microbial humic-like (two), and protein-like (two). The spatial
distributions of DOC and the four humic-like components were negatively correlated with salinity in the high-salinity waters
observed in this study (30.41–33.75), suggesting that terrestrial DOM was conservatively distributed. The spatial patterns
of protein-like components were largely different from those of DOC, humic-like components, and chlorophyll a, suggesting that these distributions were the combined result of production and degradation in the bay in addition to river
inputs. These findings suggest that the DOM dynamics in Liverpool Bay are strongly controlled by river-dominated allochthonous
DOM inputs with some less significant contributions of autochthonous DOM within the bay. In addition, the temporal variations
of DOM associated with the diurnal tidal cycles were determined at one inshore (31.34–32.24 salinity) and one offshore (33.64–33.75
salinity) station in the bay. Negative linear relationships between salinity and DOM characteristics, i.e., DOC, humic-like,
and protein-like components, were observed at the inshore station. In contrast, no relationship was observed at the offshore
station, suggesting that the export of DOM through rivers and possibly tidal flats have a noticeable influence on DOM concentration
and composition up to a relatively elevated salinity of around 33 in Liverpool Bay. 相似文献
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We used a comparative data set for 25 lakes in Denmark sampled during summer to explore the influence of lake morphometry,
catchment conditions, light availability and nutrient input on lake metabolism. We found that (1) gross primary production
(GPP) and community respiration (R) decline with lake area, water depth and drainage ratio, and increase with algal biomass
(Chl), dissolved organic carbon (DOC) and total phosphorus (TP); (2) all lakes, especially small with less incident light,
and forest lakes with high DOC, have negative net ecosystem production (NEP < 0); (3) daily variability of GPP decreases with
lake area and water depth as a consequence of lower input of nutrients and organic matter per unit water volume; (4) the influence
of benthic processes on free water metabolic measures declines with increasing lake size; and (5) with increasing lake size,
lake metabolism decreases significantly per unit water volume, while depth integrated areal rates remain more constant due
to a combination of increased light and nutrient limitation. Overall, these meta-parameters have as many significant but usually
weaker relationships to whole-lake and benthic metabolism as have TP, Chl and DOC that are directly linked to photosynthesis
and respiration. Combining water depth and Chl to predict GPP, and water depth and DOC to predict R, lead to stronger multiple
regression models accounting for 57–63% of the variability of metabolism among the 25 lakes. It is therefore important to
consider differences in lake morphometry and catchment conditions when comparing metabolic responses of lakes to human impacts. 相似文献
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E. Durisch-Kaiser A. Doberer J. Reutimann A. Pavel S. Balan S. Radan B. Wehrli 《Aquatic Sciences - Research Across Boundaries》2011,73(1):21-33
The transformation of dissolved inorganic nitrogen (DIN) and soluble reactive phosphorous (SRP), and the release of dissolved
organic and particulate N and P, were analyzed in two lake complexes (Uzlina–Isac and Puiu–Rosu–Rosulet) of the Danube Delta
wetland during flood conditions in May and at low water level in September 2006. The Uzlina–Isac complex was hydrologically
tightly-connected with the Danube River and was flushed with river-borne nutrients and organic matter. These lakes acted as
effective transformers for nutrients and produced large amounts of fresh biomass, that promoted the excretion of dissolved
organic N and P during active growth. Biomass breakdown created particulate matter (<0.45 μm), which was widely liberated
during low flow in the fall. The Puiu–Rosu–Rosulet complex was characterized by a more distant position to the Danube and
proximity to the Black Sea, and received dominantly transformed organic compounds from the flow-through water and vast vegetation
cover. Due to reduced nutrient input, the internal production of organic biomass also was reduced in these more remote lakes.
Total N and P export from the lake nearest to the shelf was governed by dominantly dissolved organic and particulate compounds
(mean 58 and 82%, respectively). Overall, this survey found that these highly productive wetlands efficiently transform nutrients
into a large pool of dissolved organic and particulate N and P. Hence, wetland lakes may behave widely as net sources of organic
N and P to downstream waters and coastal marine systems. 相似文献
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Andrea Lübben Olaf Dellwig Sandra Koch Melanie Beck Thomas H. Badewien Sibylle Fischer Rainer Reuter 《Ocean Dynamics》2009,59(2):263-275
The spatial and temporal distributions of chromophoric dissolved organic matter (CDOM) and dissolved organic carbon (DOC)
was studied in the East-Frisian Wadden Sea (Southern North Sea) during several cruises between 2002 and 2005. The spatial
distribution of CDOM in the German Bight shows a strong gradient towards the coast. Tidal and seasonal variations of dissolved
organic matter (DOM) identify freshwater discharge via flood-gates at the coastline and pore water efflux from tidal flat
sediments as the most important CDOM sources within the backbarrier area of the Island of Spiekeroog. However, the amount
and pattern of CDOM and DOC is strongly affected by various parameters, e.g. changes in the amount of terrestrial run-off,
precipitation, evaporation, biological activity and photooxidation. A decoupling of CDOM and DOC, especially during periods
of pronounced biological activity (algae blooms and microbial activity), is observed in spring and especially in summer. Mixing
of the endmembers freshwater, pore water, and open sea water results in the formation of a coastal transition zone. Whilst
an almost conservative behaviour during mixing is observed in winter, summer data point towards non-conservative mixing. 相似文献
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《Limnologica》2021
The influence of dissolved organic matter (DOM) on mineral extraction from salt lake brines depend on DOM quality. This study contributes to our knowledge of DOM’s metal binding behavior in hypersaline environments by characterization of DOM from lakes in the Qaidam Basin, i.e., Qarhan Lake (LQDOM), Da Qaidam (DQDOM) and West Ginair Salt Lake (WGDOM). The DOM was fractionated based on solid phase extraction (SPE) and ultrafiltration (UF), and the spectral and metal binding behavior of these fractions were studied by absorption spectroscopy, Pb(II) titration techniques and fluorescence parallel factor (PARAFAC) analysis. The results showed that bulk DOM generally contained more dissolved organic carbon (DOC), lower specific UV absorbance (SUVA254), higher fluorescence and biological indices, comparable humification index, and lower condition stability constants compared to the other nature waters. Compared with UF, SPE-derived DOM exhibited higher DOC recovery and aromaticity and lower carbohydrate yield. It appeared that the SPE procedure used affects the spectral composition of bulk DOM to a larger extent than UF. Source and molecular weight (MW)-dependent differences in abundance and quality of brine DOM was indicated by higher SUVA254 in high MW DOM, for LQDOM and DQDOM, and humic-like fluorophores were mainly in high MW-DOM in each lake. Moreover, the high MW humic-like component exhibited higher metal binding potential than the bulk and low MW counterparts for LQDOM and DQDOM, while the inverse was observed for WGDOM. This study revealed the effects of isolation techniques on interpretation of DOM characteristics, and meanwhile highlighted the importance of origin- and MW-dependent DOM in manipulating the behavior, fate, and bioavailability of heavy metals in salt lake brine. 相似文献